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At least 109 records · Page 6

Characterization of MoS 2 films via simultaneous grazing incidence X-ray diffraction and grazing incidence X-ray fluorescence (GIXRD/GIXRF)

Physical vapor deposited (PVD) molybdenum disulfide (nominal composition MoS 2 ) is employed as a thin film solid lubricant for extreme environments where liquid lubricants are not viable. The tribological properties of MoS 2 are highly dependent on morphological attributes such as film thickness, orientation, crystallinity, film density, and stoichiometry. These structural characteristics are controlled by tuning the PVD process parameters, yet undesirable alterations in the structure often occur due to process variations between deposition runs. Nondestructive film diagnostics can enable improved yield and serve as a means of tuning a deposition process, thus enabling quality control and materials exploration. Grazing incidence X-ray diffraction (GIXRD) for MoS 2 film characterization provides valuable information about film density and grain orientation (texture). However, the determination of film stoichiometry can only be indirectly inferred via GIXRD. The combination of density and microstructure via GIXRD with chemical composition via grazing incidence X-ray fluorescence (GIXRF) enables the isolation and decoupling of film density, composition, and microstructure and their ultimate impact on film layer thickness, thereby improving coating thickness predictions via X-ray fluorescence. We have augmented an existing GIXRD instrument with an additional X-ray detector for the simultaneous measurement of energy-dispersive X-ray fluorescence spectra during the GIXRD analysis. This combined GIXRD/GIXRF analysis has proven synergetic for correlating chemical composition to the structural aspects of MoS 2 films provided by GIXRD. We present the usefulness of the combined diagnostic technique via exemplar MoS 2 film samples and provide a discussion regarding data extraction techniques of grazing angle series measurements.

MoS2

Solar Array Flight Experiment (SAFE)

The solar arrays flight experiment consists of four experiments on two different flights. The first experiment, termed the baseline, has a basic purpose to demonstrate the flight readiness of lightweight solar array technology for solar electric propulsion and other payload power applications. The early availability of this experiment and its basic large space structure characteristics make it a logical candidate to demonstrate other disciplines critical to large space structures. These demonstrations form the basis for three other solar array experiments, two in remote sensing and one in control. All of these experiments are briefly reviewed in this paper.

Schock, R. W.

Control pole placement relationships

Using a simplified Large Space Structure (LSS) model, a technique was developed which gives algebraic relationships for the unconstrained poles. The relationships, which were obtained by this technique, are functions of the structural characteristics and the control gains. Extremely interesting relationships evolve for the case when the structural damping is zero. If the damping is zero, the constrained poles are uncoupled from the structural mode shapes. These relationships, which are derived for structural damping and without structural damping, provide new insight into the migration of the unconstrained poles for the CFPPS.

Ainsworth, O. R.

A preliminary look at control augmented dynamic response of structures

The augmentation of structural characteristics, mass, damping, and stiffness through the use of control theory in lieu of structural redesign or augmentation was reported. The standard single-degree-of-freedom system was followed by a treatment of the same system using control augmentation. The system was extended to elastic structures using single and multisensor approaches and concludes with a brief discussion of potential application to large orbiting space structures.

Ryan, R. S.

A preliminary look at control augmented dynamic response of structures

This report deals with the augmentation of structural characteristics, mass, damping, and stiffness through the use of control theory in lieu of structural redesign or augmentation. Treated first is the standard single-degree-of-freedom system followed by a treatment of the same system using control augmentation. The system is extended to elastic structure using single and multisensor approaches and concludes with a brief discussion of potential application to large orbiting space structures.

Jewell, R. E.

Vibration of a large space beam under gravity effect

The structural characteristics of a large simply supported beam subjected to gravity are described. The nonlinear governing equations for both the static and the dynamic response are derived and solved analytically. The results show the feasibility of verifying the on-orbit dynamic characteristics of a large space beam by utilizing ground test data of such a structure. It is noted that the gravity effect interacts mostly with the first vibration mode. It was also found that the system of a large space beam subjected to its own weight is a hardening system. The differential equation for the asymmetric mode is a Duffing type equation. However, the governing equation for the symmetric mode has an additional quadratic term. It is this term that causes the maximum vibration amplitudes at different phases to be non-identical.

Shih, C.-F.

Structural investigation of protein kinase C inhibitors

The phospholipid and Ca2+ dependent protein kinase (PKC) plays an essential role in a variety of cellular events. Inhibition of PKC was shown to arrest growth in tumor cell cultures making it a target for possible antitumor therapy. Calphostins are potent inhibitors of PKC with high affinity for the enzyme regulatory site. Structural characteristics of calphostins, which confer the inhibitory activity, are investigated by comparing their optimized structures with the existing models for PKC activation. The resulting model of inhibitory activity assumes interaction with two out of the three electrostatic interaction sites postulated for activators. The model shows two sites of hydrophobic interaction and enables the inhibitory activity of gossypol to be accounted for.

NASA Discipline Exobiology

Conservation of Pax gene expression in ectodermal placodes of the lamprey

Ectodermal placodes contribute to the cranial ganglia and sense organs of the head and, together with neural crest cells, represent defining features of the vertebrate embryo. The identity of different placodes appears to be specified in part by the expression of different Pax genes, with Pax-3/7 class genes being expressed in the trigeminal placode of mice, chick, frogs and fish, and Pax-2/5/8 class genes expressed in the otic placode. Here, we present the cloning and expression pattern of lamprey Pax-7 and Pax-2, which mark the trigeminal and otic placodes, respectively, as well as other structures characteristic of vertebrate Pax genes. These results suggest conservation of Pax genes and placodal structures in basal and derived vertebrates.

NASA Discipline Evolutionary Biology

Release of the NASA Parallel Electric-Gas Architecture with Synergistic Utilization Scheme (PEGASUS) OpenVSP Model

The Open VSP model represents the geometry of PEGASUS as is currently modeled. PEGASUS is a concept vehicle that will not be physically produced. As such, the baseline model is subject to change without notice or requirement that updates are provided external to NASA. The current baseline is derived from the outer mold line (OML) of the ATR 42-500. As such, planform areas for the wing, fuselage, vertical tail, and horizontal tail mimic those published in public ATR 42 literature. NASA Aeronautics Systems Analysis Branch (ASAB) does not contain any proprietary data on the ATR 42, thus the PEGASUS model does not contain any proprietary or sensitive information. Further, model details that are required for an actual aircraft such as airfoils, twist distributions and propeller geometries are unknown at this time, and generic stand-ins are used within the OpenVSP model. The intent is to provide this model to Georgia Tech ASDL to allow the ASDL team to model the impact of the propulsion system at the wingtip’s impact on structural characteristics. The ASDL will be using the model to generate estimated aerodynamic load and structural members for analysis.

PEGASUS

Raman spectroscopic studies of carbon in extra-terrestrial materials

The measurements obtained here indicate ways in which micro-Raman spectroscopy can be used to elucidate structural characteristics and distribution of carbon in meteorites and interplanetary dust particles (IDPs). Existing information about structurally significant aspects of Raman measurements of graphite is combined with structurally relevant findings from the present micro-Raman studies of carbons prepared by carbonization of polyvinylidine chloride (PVDC) at various temperatures and natural material, as well as several acid residues from the Allende and Murchison meteorites in order to establish new spectra-structure relationships. Structural features of many of the materials in this study have been measured by x ray analysis and electron microscopy: thus, their structural differences can be directly correlated with differences in the Raman spectra. The spectral parameters consequently affirmed as indicators of structure are used as a measure of structure in materials that have unknown carbon structure, especially IDPs. The unique applicability of micro-Raman spectroscopy is realized not only in the ability to conveniently measure spectra of micron-size IDPs, but also micro-sized parts of an inhomogeneous material. Microcrystalline graphite is known to give Raman spectra that differ dependent on crystallite size (see e.g., Lespade, et. al., 1984, or Nemanich and Solin, 1979). The spectral changes that accompany decreasing particle size include increase in the ratio (R) of the intensity of the band near 1350 cm(-1) (D band) to that of the band near 1600 cm(-1) (G band) increase in the half width of the D band (wD) increase in the frequency maximum of the G band and increase in the half-width (wG) of the 2nd order band near 2700 cm(-1) (G) band.

Macklin, John

Experimental estimation of the statistical parameters of vibrations of a shell (using a digital computer), 1

The distribution pattern of the amplitudes of vibrations, measured at various points on the surface of a shell, stimulated by a point source of harmonic force in the sound frequency range was studied experimentally. This pattern permits a valid spacing estimate to be carried out of the average structural characteristics of the vibrations, which are used for both estimation of the vibration excitability of the structure and for estimation of the effectiveness of use of a vibration-absorbing covering.

Kanayev, B. A.

Aircraft ground vibration testing at the NASA Dryden Flight Research Facility, 1993

The NASA Dryden Flight Research Facility performs ground vibration testing to assess the structural characteristics of new and modified research vehicles. This paper updates the research activities, techniques used, and experiences in applying this technology to aircraft since 1987. Test equipment, data analysis methods, and test procedures used for typical test programs are discussed. The data presented illustrate the use of modal test and analysis in flight research programs for a variety of aircraft. This includes a technique to acquire control surface free-play measurements on the X-31 airplane more efficiently, and to assess the effects of structural modifications on the modal characteristics of an F-18 aircraft. In addition, the status and results from current research activities are presented. These data show the effectiveness of the discrete modal filter as a preprocessor to uncouple response measurements into simple single-degree-of-freedom responses, a database for the comparison of different excitation methods on a JetStar airplane, and the effect of heating on modal frequency and damping.

Kehoe, Michael W.

Structural design aspects of reusable surface insulation thermal protection systems.

Low density fiber ceramic materials coated with refractory ceramics meet the requirements of reusable low weight thermal protection systems. The structural characteristics of this class of material impose unique design and analysis requirements on the application to spacecraft structural elements. Finite element type stress analysis techniques are required to adequately predict the structural response of the system. Parametric analyses have been performed to determine the response of the system to variations in geometry, and to thermal and structural load conditions. Sensitivity of coating, insulation and attachment stresses are presented and critical failure modes are identified.

Michalak, R. J.

Canopy Spectral Invariants: Application to Classification of Forest Types from Hyperspectral Data - Part 2

Many studies have been conducted to demonstrate the ability of hyperspectral data to discriminate plant dominant species. Most of them have employed the use of empirically based techniques, which are site specific, requires some initial training based on characteristics of known leaf and/or canopy spectra and therefore may not be extendable to operational use or adapted to changing or unknown land cover. In this paper we propose a physically based approach for separation of dominant forest type using hyperspectral data. The radiative transfer theory of canopy spectral invariants underlies the approach, which facilitates parameterization of the canopy reflectance in terms of the leaf spectral scattering and two spectrally invariant and structurally varying variables - recollision and directional escape probabilities. The methodology is based on the idea of retrieving spectrally invariant parameters from hyperspectral data first, and then relating their values to structural characteristics of three-dimensional canopy structure. Theoretical and empirical analyses of ground and airborne data acquired by Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) over two sites in New England, USA, suggest that the canopy spectral invariants convey information about canopy structure at both the macro- and micro-scales. The total escape probability (one minus recollision probability) varies as a power function with the exponent related to the number of nested hierarchical levels present in the pixel. Its base is a geometrical mean of the local total escape probabilities and accounts for the cumulative effect of canopy structure over a wide range of scales. The ratio of the directional to the total escape probability becomes independent of the number of hierarchical levels and is a function of the canopy structure at the macro-scale such as tree spatial distribution, crown shape and size, within-crown foliage density and ground cover. These properties allow for the natural separation of dominant forest classes based on the location of points on the total escape probability vs the ratio log-log plane.

Schull, M. A.

Optimum structural design of robotic manipulators with fiber reinforced composite materials

High-speed robotic arms with advanced structural characteristics can be fabricated from optimally tailored fiber reinforced composites. An integrated design methodology is presented for the optimal structural synthesis of composite robotic manipulators. Optimum configurations of ply angles and ply thicknesses are predicted for maximum structural end-effector stiffness and maximum end-effector load carrying capacity, without altering the geometric dimensions of the links. Multiple posture finite element-based static performance criteria are implemented. A new finite element has been developed for the modeling of tubular composite links. Unique features are the inclusion of shear effects and coupling between stretching and flexure. Numerical solutions are obtained via an efficient optimization algorithm. Applications to an existing SCARA-class manipulator illustrate the effectiveness of the method and demonstrate the dramatic influence of the multi-postural design criteria on the optimal design. For a filament wound structure using a high strength carbon fiber in a thermoplastic matrix, the resultant optimum ply configurations have increased the specific stiffness and specific load capacity by factors of 1.5 and 16, respectively, in comparison to identically sized aluminum links.

Saravanos, D. A.

Coherent structures: Comments on mechanisms

There is now overwhelming evidence that in most turbulent flows there exist regions moving with the flow where the velocity and vorticity have a characteristic structure. These regions are called coherent structures because within them the large-scale distributions of velocity and/or vorticity remain coherent even as these structures move through the flow and interact with other structures. Since the flow enters and leaves the bounding surfaces of these structures, a useful definition for coherent structures is that they are open volumes with distinctive large-scale vorticity distributions. Possible fruitful directions for the study of the dynamics of coherent structures are suggested. Most coherent structures research to data was concentrated on measurement and kinematical analysis; there is now a welcome move to examine the dynamics of coherent structures, by a variety of different methods. A few of them will be described.

Hunt, J. C. R.