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At least 109 records · Page 6

Dawn Maps the Surface Composition of Vesta

By 7-October-2011, the Dawn mission will have completed Survey orbit and commenced high altitude mapping of 4-Vesta. We present a preliminary analysis of data acquired by Dawn's Framing Camera (FC) and the Visual and InfraRed Spectrometer (VIR) to map mineralogy and surface temperature, and to detect and quantify surficial OH. The radiometric calibration of VIR and FC is described. Background counting data acquired by GRaND are used to determine elemental detection limits from measurements at low altitude, which will commence in November. Geochemical models used in the interpretation of the data are described. Thermal properties, mineral-, and geochemical-data are combined to provide constraints on Vesta s formation and thermal evolution, the delivery of exogenic materials, space weathering processes, and the origin of the howardite, eucrite, and diogenite (HED) meteorites.

Prettyman, T.↗

Mercury - Surface composition from the reflection spectrum.

The reflection spectrum for the integral disk of the planet Mercury was measured and was found to have a constant positive slope from 0.32 to 1.05 micrometers, except for absorption features in the infrared. The reflectivity curve matches closely the curve for the lunar upland and mare regions. Thus, the surface of Mercury is probably covered with a lunar-like soil rich in dark glasses of high iron and titanium content. Pyroxene is probably the dominant mafic mineral.

Mccord, T. B.↗

The surface composition of Charon - Tentative identification of water ice

The Mar. 3, 1987, Charon occultation by Pluto was observed in the infrared at 1.5, 1.7, 2.0, and 2.35 micrometers. Subtraction of fluxes measured between second and third contacts from measurements made before and after the event has yielded individual spectral signatures for each body at these wavelengths. Charon's surface appears depleted in methane relative to Pluto. Constancy of flux at 2.0 micrometers throughout the event shows that Charon is effectively black at this wavelength, which is centered on a very strong water absorption band. Thus, the measurements suggest the existence of water ice on Pluto's moon.

Marcialis, Robert L.↗

Titania and Oberon: Surface Composition from New Near-Infrared Observations and Reflectance Models

Here we report the combination of new near-ir spectra (1.45-2.48 micrometers), of Titania and Oberon obtained in September 1995 at a resolving power of approx. 800, with older near-ir observations (0.5- 1.44 micrometers), and recent UV (0.22-0.48 micrometers) observations obtained with HST. Previous interpretations suggest these surfaces are chiefly composed of water ice and varying amounts of spectrally neutral material. The new near-ir data provide the opportunity to search for absorption bands that could be attributable to surface materials other than water ice and because the combined spectra include such a broad wavelength region, to undertake improved models of water and neutral components on the surface. The calculated near-ir geometric albedos clearly exhibit three broad spectral features. Two (1.52- & 2.05 micrometer) have previously been used to demonstrate the presence of water ice on these satellites. The third (approx. 1.65 micrometer), suggests the presence of hexagonal water ice at low temperatures, and may provide a mechanism of estimating the surface temperature. There is no spectral evidence for ices of CO2, CO, NH3 or CH4. At UV wavelengths there is a broad absorption near 0.27-0.28 micrometer previously attributed to OH formed by magnetospheric-surface interactions and retained at the low surface temperatures of these satellites. Surface components used in a Hapke scattering models include values for a combination of irradiated water ice in the UV and hexagonal water ice at 100k in the near-ir (IR), amorphous carbon (AC), and tholins (T) (produced from gas and solid). Results of these models suggest the surfaces of Titania/Oberon are composed of IW (-77/52%) with AC the next most abundant component (approx. 19/52%) and finally T (approx. 4/7%).

Roush, Ted L.↗

The Surface Compositions of Triton, Pluto, and Charon

Neptune's satellite Triton, and the planet-satellite binary Pluto and Charon, are the most distant planetary bodies on which ices have been directly detected. Triton and Pluto have very similar dimensions and mean densities, suggesting a similar or common origin. Through earth-based spectroscopic observations in the near-infrared, solid N2, CH4, and CO have been found on both bodies, with the additional molecule C02 on Triton. N2 dominates both surfaces, although the coverage is not spatially uniform. On Triton, the CH4 and CO are mostly or entirely frozen in the N2 matrix, while CO2 may be spatially segregated. On Pluto, some CH4 and the CO are frozen in the N2 matrix, but there is evidence for additional CH4 in a pure state, perhaps lying as a lag deposit on a subsurface layer of N2. Despite their compositional and dimensional similarities, Pluto and Triton are quite different from one another in detail. Additional hydrocarbons and other volatile ices have been sought spectroscopically but not yet have been detected. The only molecule identified on Pluto's satellite Charon is solid H2O, but the spectroscopic data are of low precision and admit the presence of other ices such as CH4.

Cruikshank, Dale P.↗

Atmospheric and surface compositional studies of Mercury and the moon

The atmosphere of the Moon and Mercury will be studied by means of high resolution spectroscopy of sodium and potassium resonance line emissions. The variation of metal vapor abundances with time, and with location will be measured with a view to understanding the origin and evolution of these elements in the atmospheres of the Moon and Mercury. Infrared spectroscopic measurements will be made of Mercury to determine the surface mineralogy, predicated on the availability of the Kuiper Airborne Observatory and infrared charge coupled device (CCD). During the past year, an excellent series of measurements were completed of the spatial distribution of sodium on Mercury. Sodium was found to be concentrated at the polar regions, and to be displaced towards the terminator by solar radiation pressure. Sodium and potassium were discovered in the atmosphere of the Moon. The ratio of sodium to potassium approximates that of the lunar regolith. Thermal infrared measurements of Mercury showed that the Christiansen peak was located shortwards of 8 micrometer, which indicates an acidic mineralogy.

Potter, A. E.↗

Surface composition of Kuiper belt object 1993SC

The 1.42- to 2.40-micrometer spectrum of Kuiper belt object 1993SC was measured at the Keck Observatory in October 1996. It shows a strongly red continuum reflectance and several prominent infrared absorption features. The strongest absorptions in 1993SC's spectrum occur near 1.62, 1.79, 1.95, 2.20, and 2.32 micrometers in wavelength. Features near the same wavelengths in the spectra of Pluto and Neptune's satellite Triton are due to CH4 on their surfaces, suggesting the presence of a simple hydrocarbon ice such as CH4, C2H6, C2H4, or C2H2 on 1993SC. In addition, the red continuum reflectance of 1993SC suggests the presence of more complex hydrocarbons.

NASA Discipline Exobiology↗

Surface composition of solid-rocket exhausted aluminum oxide particles

Particulate samples of aluminum oxide were collected on Teflon filters from the exhaust plume of the Space Shuttle (STS-61A, October 30, 1985) over the altitude interval 4.6-7.6 km immediately after launch. These particles were analyzed using SEM, energy-dispersive X-ray analysis, electron spectroscopy for chemical analysis, X-ray fluorescent spectroscopy, and conventional wet-chemical techniques. The samples were 0.6-1.0 percent surface-chlorided (chlorided meaning predominantly aluminum chlorides and oxychlorides, possibly including other adsorbed forms of chloride) by weight. This level of chloriding is about one-third of the amount determined previously from laboratory-prepared alumina and surface site samples of solid-rocket-produced alumina (SRPA) after both had been exposed to moist HCl vapor at temperatures down to ambient. This level is equivalent to previous laboratory results with samples exposed to moist HCl at temperatures above the boiling point of water. It is suggested that the present lower chloriding levels, determined for samples from a 'dry' Shuttle exhaust cloud, underscore the importance of a liquid water/hydrochloric acid phase in governing the extent of surface chloriding of SRPA. The reduced chloriding is not trivial with respect to potential physical/chemical modification of the SRPA particle surfaces and their corresponding interaction with the atmosphere.

Cofer, Wesley R., III↗

Development of laminar flow control wing surface composite structures

The dramatic increases in fuel costs and the potential for periods of limited fuel availability provided the impetus to explore technologies to reduce transport aircraft fuel consumption. NASA sponsored the Aircraft Energy Efficiency (ACEE) program beginning in 1976 to develop technologies to improve fuel efficiency. This report documents the Lockheed-Georgia Company accomplishments under NAS1-16235 LFC Laminar-Flow-Control Wing Panel Structural Design And Development (WSSD); Design, manufacturing, and testing activities. An in-depth preliminary design of the baseline 1993 LFC wing was accomplished. A surface panel using the Lockheed graphite/epoxy integrated LFC wing box structural concept was designed. The concept was shown by analysis to be structurally efficient and cost effective. Critical details of the surface and surface joints were demonstrated by fabricating and testing complex, concept selection specimens. Cost of the baseline LFC aircraft was estimated and compared to the turbulent aircraft. The mission fuel weight was 21.7 percent lower for the LFC aircraft. The calculation shows that the lower fuel costs for LFC offset the higher incremental costs of LFC in less than six months.

Lineberger, L. B.↗

Enabling electrochemical N 2 reduction to NH 3 in the low overpotential region using non-noble metal Bi electrodes via surface composition modification

The electrochemical N 2 reduction reaction (ENRR) that can produce NH 3 using water as the hydrogen source at ambient temperature and pressure can be an exciting alternative to the Haber–Bosch process. The major challenge for electrochemical NH 3 production is the competing hydrogen evolution reaction (HER), which seriously limits the faradaic efficiency (FE) for NH 3 production. To date, noble metal electrocatalysts that are inactive for the HER have mainly been investigated for the ENRR. Studies reporting a FE greater than 10% for NH 3 production using non-noble metal catalysts in the low overpotential region (E ≤ 0.2 V vs. RHE) are very rare. This study reports effective electrochemical surface modification strategies that drastically increase the ENRR activity of a non-noble Bi electrode in the low overpotential region and achieve a FE for NH 3 production as high as 13.2% at -0.2 V vs. RHE in pH 7.5 phosphate buffer. Finally, the effect of each of the surface modifications on the activity for the ENRR and the electrode stability during the ENRR were systematically elucidated, which may be used to develop general strategies to enhance the ENRR activities of other non-noble metal electrodes in the low overpotential region.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Surface compositional mapping by spectral ratioing of ERTS-1 MSS data in the Wind River Basin and Range, Wyoming

The author has identified the following significant results. ERTS data collected in August and October 1972 were processed on digital and special purpose analog recognition computers using ratio enhancement and pattern recognition. Ratios of band-averaged laboratory reflectances of some minerals and rock types known to be in the scene compared favorably with ratios derived from the data by ratio normalization procedures. A single ratio display and density slice of the visible channels of ERTS MSS data, Channel 5/Channel 4 (R5,4), separated the Triassic Chugwater formation (redbeds) from other formations present and may have enhanced iron oxide minerals present at the surface in abundance. Comparison of data sets collected over the same area at two different times of the year by digital processing indicated that spectral variation due to environmental factors was reduced by ratio processing.

Vincent, R. K.↗

Pluto's Global Surface Composition Through Pixel-by-Pixel Hapke Modeling of New Horizons Ralph LEISA Data

On July 14th 2015, NASA's New Horizons mission gave us an unprecedented detailed view of the Pluto system. The complex compositional diversity of Pluto's encounter hemisphere was revealed by the Ralph/LEISA infrared spectrometer on board of New Horizons. We present compositional maps of Pluto defining the spatial distribution of the abundance and textural properties of the volatiles methane and nitrogen ices and non-volatiles water ice and tholin. These results are obtained by applying a pixel-by-pixel Hapke radiative transfer model to the LEISA scans. Our analysis focuses mainly on the large scale latitudinal variations of methane and nitrogen ices and aims at setting observational constraints to volatile transport models. Specifically, we find three latitudinal bands: the first, enriched in methane, extends from the pole to 55degN, the second dominated by nitrogen, continues south to 35 degN, and the third, com- posed again mainly of methane, reaches 20 degN. We demonstrate that the distribution of volatiles across these surface units can be explained by differences in insolation over the past few decades. The latitudinal pattern is broken by Sputnik Planitia, a large reservoir of volatiles, with nitrogen playing the most important role. The physical properties of methane and nitrogen in this region are suggestive of the presence of a cold trap or possible volatile stratification. Furthermore our modeling results point to a possible sublimation transport of nitrogen from the northwest edge of Sputnik Planitia toward the south.

Protopapa, S.↗

Masses, radii, temperatures, luminosities and surface compositions of white dwarfs

The masses, radii, temperature, luminosities and compositions of white dwarf stars are discussed, with particular emphasis on those areas in which considerable work remains to be done. It is pointed out that radii for stars of known parallax are available, together with masses and their variance. Consideration is then given to the difficulties involved in the determination of the temperatures of the hottest stars and helium stars by means of Stromgren or multichannel photometry, and it is noted that the frequency of binaries among the hottest degenerates seems too high to be due to chance. Results of IUE observations of the UV spectra of three DA and one DO star are discussed, with attention given to the similarities between UV-derived and ground-based determinations of temperatures and surface gravities. The metal abundances of hydrogen and helium degenerate stars are finally considered, and spectral classes and abundances of the helium atmosphere degenerates are tabulated.

Greenstein, J. L.↗

Mineralogy of the Martian Surface: Crustal Composition to Surface Processes

Over the course of this award we have: 1) Completed and published the results of a study of the effects of hyperfine particles on reflectance spectra of olivine and quartz, which included the development of scattering codes. Research has also progressed in the analysis of the effects of fine particle sizes on clay spectra. 2) Completed the analysis of the mineralogy of dark regions, showed the insitu compositions are highly correlated to the SNC meteorites, and determined that the martian mantle was depleted in aluminum prior to 2-3 GA ago; Studies of the mineralogic heterogeneity of surficial materials on Mars have also been conducted. and 3) Performed initial work on the study of the physical and chemical processes likely to form and modify duricrust. This includes assessments of erosion rates, solubility and transport of iron in soil environments, and models of pedogenic crust formation.

Mustard, John F.↗