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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6

Shrub Expansion Can Counteract Carbon Losses From Warming Tundra

Arctic warming is causing substantial compositional, structural, and functional changes in tundra vegetation including shrub and tree-line expansion and densification. However, predicting the carbon trajectories of the changing Arctic is challenging due to interacting feedbacks between vegetation composition and structure, and surface characteristics. We conduct a sensitivity analysis of the current-date to 2100 projected surface energy fluxes, soil carbon pools, and CO 2 fluxes to different shrub expansion rates under future emission scenarios (intermediate—RCP4.5, and high—RCP8.5) using the Arctic-focused configuration of E3SM Land Model (ELM). We focus on Trail Valley Creek (TVC), an upland tundra site in the western Canadian Arctic, which is experiencing shrub densification and expansion. We find that shrub expansion did not significantly alter the modeled surface energy and water budgets. However, the carbon balance was sensitive to shrub expansion, which drove higher rates of carbon sequestration as a consequence of higher shrubification rates. Thus, at low shrub expansion rates, the site would become a carbon source, especially under RCP8.5, due to higher temperatures, which deepen the active layer and enhance soil respiration. At higher shrub expansion rates, TVC would become a net CO 2 sink under both Representative Concentration Pathway scenarios due to higher shrub productivity outweighing temperature-driven respiration increase. Our simulations highlight the effect of shrub expansion on Arctic ecosystem carbon fluxes and stocks. We predict that at TVC, shrubification rate would interact with climate change intensity to determine whether the site would become a carbon sink or source under projected future climate.

Yazbeck, Theresia [The Ohio State Univ., Columbus,↗

Heat Loss Characteristics and Energy Use of Piperazine with the Advanced Stripper (PZAS) at the UT-SRP Pilot Plant

Heat duty and heat loss were measured at the pilot plant at UT Austin. Heat loss was measured with energy balances using water. Heat loss was studied using surface temperature measurements over 68 different locations at the pilot plant. Surface temperature measurements indicated that bare metal surfaces were the primary source of heat loss from the pilot plant. Heat loss from bare metal surfaces was at least 50% controlled by natural convection and in many cases was as high as 75% natural convection controlled. Measured heat loss at the pilot plant was 20100 BTU/hr and overall heat loss did not show any dependence on the heat rate of the plant. Compared to PZAS™ at the National Carbon Capture Center, heat loss relative to heat rate was higher at 38%. The relative heat loss at the pilot plants was found to decrease by 20% per MW of added capacity. Measured net heat duty was found to be dependent on measured lean loading and cold rich bypass flow rate. Measured net heat duty was between 2.2 and 2.4 GJ/tonne at an optimum lean loading of 0.2–0.21 mol/mol. Data reconciliation by Aspen Plus® Data Fit™ underpredicted CO2 flow rate by 20% due to an overprediction of lean loading by 19%, indicating a necessary change in thermodynamic parameters in the model. This resulted in an over prediction of heat duty by 33% on average.

Amine scrubbing, stripper, energy requirement, hea↗

Thermomechanical Stress and Creep-Fatigue Analysis of a High-Temperature Prototype Receiver for Heating Particles

This work presents a three-dimensional (3D) thermomechanical model of a prototype-scale enclosed light trapping solar receiver for heating particles. Results of the thermoelastic model are used to estimate receiver lifetime under maximum flux conditions. A computational fluid dynamics (CFD) model is first developed to predict the temperature fields in a multi-panel assembly under steady operating conditions. Solar flux distributions on the receiver are obtained from the software package SolTrace and applied to the 3D thermal model. The subsequent particle heating is captured through a simplified 1D energy balance. Panel reradiation is considered through a surface-to-surface radiation model and natural convection loss to the surrounding air is captured in a representative fluid domain surrounding the receiver. The resulting temperature fields from the CFD analysis are used as inputs for a thermoelastic mechanical model with representative boundary conditions. With the resultant temperature and stress fields, a creep-fatigue damage and lifetime analysis is performed using the linear damage accumulation (LDA) theory. The Manson-Coffin formula and Larson Miller correlation are used to calculate the fatigue and creep, respectively. A maximum damage (corresponding to a 30-year service life) is defined for design assessment. The model was first developed and verified in detail by comparing with published results in the literature (temperature and stress profiles and distributions, and creep/fatigue damage fractions) for tubular solar receivers with supercritical carbon dioxide as the working fluid. It was then implemented to model a planar-cavity receiver with various design parameters. Specifically, three different design geometries are considered, and the results show that a maximum temperature of approximately 1200 K could be reached for each design with the given incident solar flux, with the main difference being the distribution of these temperatures. Preliminary resulting stresses for the small-scale prototype without design optimization vary from 20 MPa to 250 MPa for each design, with the maximum stresses occurring on the front face and concave geometry on the side of the panel. In future work, the developed methodology shown here will be applied to analyze a full-scale (50-150 MWth) receiver.

concentrated solar power↗

Phase-field modeling and experiments of dynamic fracture in single crystal quartz

Predicting the onset and characteristics of brittle fracture is important for a wide range of engineering and geological material applications. In this paper, we study important aspects of brittle fracture in α-quartz by phase-field modeling and experiments using a top-down approach. In the modeling framework, the work term in the Griffith energy balance is replaced with internal energy contributions that represent surface energy, thermal energy, and elastic strain energy stored in defects. This allows parametrization of individual energy contributions in terms of internal state variables and keeps track of energy partitioning after the onset of fracture. The path and history dependence of fracture is included in evolution laws for internal state variables, e.g., entropy evolution, while the energy remains a true potential. In the experimental part, dynamic compression experiments coupled with X-ray phase contrast imaging are performed on cube-like samples with a hole. In the top-down analysis, dynamic compression and three point bending experiments from the literature are simulated with the developed phase-field damage model. In conclusion, the fitted model highlights the strain rate, size, and stress state dependence of damage nucleation and evolution in single crystal α-quartz.

36 MATERIALS SCIENCE↗

Observation and Reanalysis Derived Relationships Between Cloud and Land Surface Fluxes Across Cumulus and Stratiform Coupling Over the Southern Great Plains

Abstract Understanding interactions between low clouds and land surface fluxes is critical to comprehending Earth's energy balance, yet their relationships remain elusive, with discrepancies between observations and modeling. Leveraging long‐term field observations over the Southern Great Plains, this investigation revealed that cloud‐land interactions are closely connected to cloud‐land coupling regimes. Observational evidence supports a dual‐mode interaction: coupled stratiform clouds predominate in low sensible heat scenarios, while coupled cumulus clouds dominate in high sensible heat scenarios. Reanalysis data sets, MERRA‐2 and ERA‐5, obscure this dichotomy owing to a shortfall in representing boundary layer clouds, especially in capturing the initiation of coupled cumulus in high sensible heat scenarios. ERA‐5 demonstrates a relatively closer alignment with observational data, particularly in capturing relationships between cloud frequency and latent heat, markedly outperforming MERRA‐2. Our study underscores the necessity of distinguishing different cloud coupling regimes, essential to the understanding of their interactions for advancing land‐atmosphere interactions.

54 ENVIRONMENTAL SCIENCES↗

The two radiative states of the Arctic atmosphere and their impacts on the surface energy budget of sea ice

The surface energy budget (SEB) is a central regulator of Arctic climate and sea ice evolution, yet its processes remain poorly constrained due to sparse observations and complex, coupled surface-atmosphere interactions. This study leverages year-long measurements from the Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) to provide the most comprehensive assessment to date of the central Arctic SEB and its modulation by atmospheric variability. Ship- and ice-based observations from October 2019 to September 2020 were used to directly measure or tightly constrain each term of the SEB, leading to exceptional energetic closure with the seasonal snow and ice mass balance. The analysis reveals strong seasonal transitions in atmosphere-surface energy transfer that are modulated by the atmospheric state and constrained by the ability of the surface temperature to respond. Classification of the atmosphere into its two dominant radiative states—the semi-transparent (ST) and opaque (OP)—highlights the central role of synoptic-scale variability in clouds. The ST atmospheric state dominated the long winter ice growth season, with limited cloudiness supporting persistent surface radiative cooling and ice growth. The OP state, associated with liquid-containing or thick ice clouds, became dominant in spring, with the combination of increased solar heating and cloud surface longwave warming driving ice and snow melt. Eddy covariance versus bulk approaches for deriving surface turbulent heat fluxes provide vastly different perspectives on the role of turbulence in modulating the SEB. These results establish a high-quality benchmark dataset for Arctic SEB studies and demonstrate how the balance of atmospheric radiative states exerts a first-order control on the annual evolution of the sea ice. The findings have broad implications for advancing observing technologies, understanding Arctic amplification, improving climate models, and predicting future sea ice change.

54 ENVIRONMENTAL SCIENCES↗

Radiative feedbacks on land surface change and associated tropical precipitation shifts

Changes in land surface albedo and land surface evaporation modulate the atmospheric energy budget by changing temperatures, water vapor, clouds, snow and ice cover, and the partitioning of surface energy fluxes. Here idealized perturbations to land surface properties are imposed in a global model to understand how such forcings drive shifts in zonal mean atmospheric energy transport and zonal mean tropical precipitation. For a uniform decrease in global land albedo, the albedo forcing and a positive water vapor feedback contribute roughly equally to increased energy absorption at the top of the atmosphere (TOA), while radiative changes due to the temperature and cloud cover response provide a negative feedback and energy loss at TOA. Decreasing land albedo causes a northwards shift in the zonal mean intertropical convergence zone (ITCZ). The combined effects on ITCZ location of all atmospheric feedbacks roughly cancel for the albedo forcing; the total ITCZ shift is comparable to that predicted for the albedo forcing alone. For an imposed increase in evaporative resistance that reduces land evaporation, low cloud cover decreases in the northern mid-latitudes and more energy is absorbed at TOA there; longwave loss due to warming provides a negative feedback on the TOA energy balance and ITCZ shift. Imposed changes in land albedo and evaporative resistance modulate fundamentally different aspects of the surface energy budget. However, the pattern of TOA radiation changes due to the water vapor and air temperature responses are highly correlated for these two forcings because both forcings lead to near-surface warming.

54 ENVIRONMENTAL SCIENCES↗

Subgrid-scale horizontal and vertical variation of cloud water in stratocumulus clouds: a case study based on LES and comparisons with in situ observations

Abstract. Stratocumulus clouds in the marine boundary layer cover a large fraction of ocean surface and play an important role in the radiative energy balance of the Earth system. Simulating these clouds in Earth system models (ESMs) has proven to be extremely challenging, in part because cloud microphysical processes such as the autoconversion of cloud water into precipitation occur at scales much smaller than typical ESM grid sizes. An accurate autoconversion parameterization needs to account for not only the local microphysical process (e.g., the dependence on cloud water content qc and cloud droplet number concentration Nc) but also the subgrid-scale variability of the cloud properties that determine the process rate. Accounting for subgrid-scale variability is often achieved by the introduction of a so-called enhancement factor E. Previous studies of E for autoconversion have focused more on its dependence on cloud regime and ESM grid size, but they have largely overlooked the vertical dependence of E within the cloud. In this study, we use a large-eddy simulation (LES) model, initialized and constrained with in situ and surface-based measurements from a recent airborne field campaign, to characterize the vertical dependence of the horizontal variation of qc in stratocumulus clouds and the implications for E. Similar to our recent observational study (Zhang et al., 2021), we found that the inverse relative variance of qc, an index of horizontal homogeneity, generally increases from cloud base upward through the lower two-thirds of the cloud and then decreases in the uppermost one-third of the cloud. As a result, E decreases from cloud base upward and then increases towards the cloud top. We apply a decomposition analysis to the LES cloud water field to understand the relative roles of the mean and variances of qc in determining the vertical dependence of E. Our analysis reveals that the vertical dependence of the horizontal qc variability and enhancement factor E is a combined result of condensational growth throughout the lower portion of the cloud and entrainment mixing at cloud top. The findings of this study indicate that a vertically dependent E should be used in ESM autoconversion parameterizations.

54 ENVIRONMENTAL SCIENCES↗

Monthly Mean In Situ Surface Flux Observations Paired with Satellite-Derived and Reanalysis-Based Flux Data for the Great Lakes Region, 2001–2020

Surface radiative and turbulent heat fluxes over the Great Lakes strongly influence regional hydrological and meteorological processes, and their accurate representation is critical for numerical weather prediction and coupled atmosphere–lake modeling. However, direct flux observations are spatially sparse across the region, so gridded reanalysis and satellite-derived products are often used for climatological analyses and model evaluation despite differences in their flux representations. This dataset provides processed, quality-controlled, monthly mean surface flux observations from the Great Lakes Evaporation Network (GLEN), AmeriFlux, and the National Data Buoy Center, paired with spatiotemporally matched flux estimates from two reanalysis products, the fifth generation European Centre for Medium-Range Weather Forecasts (ECMWF) reanalysis dataset (ERA5) and the Modern Era Reanalysis for Research and Applications, version 2 (MERRA-2), and two satellite-derived products, the Clouds and Earth's Radiant Energy Systems Energy Balanced and Filled (CERES-EBAF) and the Cloud, Albedo and Surface Radiation dataset from AVHRR data - Edition 3 (CLARA-A3). The dataset includes sixteen observational stations with variable temporal coverage within 2001–2020. For each station, a CSV file contains monthly time series of available flux variables, including surface downwelling shortwave radiation (SW), surface downwelling longwave radiation (LW), sensible heat (SH) flux, and latent heat flux (LH), alongside matched gridded product values where available. Columns in the CSV file correspond to different variables sourced from each dataset, with column titles structured as "{dataset}_{variable}". Columns with relevant metadata are also provided in each CSV file, including station latitude and longitude, monthly timestamps, and the name of the sourced observational data. These files are structured for direct use in common analysis tools, including Microsoft Excel, Python pandas, and Python matplotlib. This dataset supports climatological analysis of the Great Lakes regional surface energy budget, evaluation of satellite-derived and reanalysis-based flux products, and development or validation of flux representations in numerical weather prediction and coupled atmosphere–lake models.

Great Lakes↗

Toward Stable, High‐Energy, Partially Disordered Mn‐Rich Spinel Cathodes by Revealing and Mitigating Surface Degradation

Mn-rich cathodes balance performance and sustainability but suffer from limited cyclability due to Mn dissolution and cathode-to-anode crosstalk. The Jahn-Teller (J-T) effect of Mn 3+ is often linked to the above phenomena, such as in spinel LiMn 2 O 4 . However, in typical voltage ranges, significant Mn 3+ only appears near the end of discharge, highlighting the need to reassess its role in driving Mn dissolution, structural degradation, and battery performance. Here, the spinel cathode's degree of disorder is tailored to expand the Mn redox range, enabling segmentation into J-T active and less active voltage ranges. Cycling at segmented voltage windows reveals surface degradation mechanisms with and without the major J-T effect. Despite a stronger J-T effect below 3.6 V vs. Li/Li + , Mn dissolution is less significant than above 3.6 V. Expanding the cycling window to 2.0–4.3 V causes severe degradation as the J-T active range induces a tetragonal phase and Mn 2+ -rich surface, driving Mn dissolution and consuming Li-ion inventory in full cells. Reducing electrolyte acidity minimizes Mn 3+ disproportionation, enabling a stable dopant-free Mn-only cathode with a 250 mAh g −1 specific capacity. These findings demonstrate that full cells using Mn-rich cathodes have the potential to avoid the notorious crosstalk problem through electrolyte engineering.

25 ENERGY STORAGE↗

Mid-latitude clouds contribute to Arctic amplification via interactions with other climate feedbacks

Abstract Traditional feedback analyses, which assume that individual climate feedback mechanisms act independently and add linearly, suggest that clouds do not contribute to Arctic amplification. However, feedback locking experiments, in which the cloud feedback is disabled, suggest that clouds, particularly outside of the Arctic, do contribute to Arctic amplification. Here, we reconcile these two perspectives by introducing a framework that quantifies the interactions between radiative feedbacks, radiative forcing, ocean heat uptake, and atmospheric heat transport. We show that including the cloud feedback in a comprehensive climate model can result in Arctic amplification because of interactions with other radiative feedbacks. The surface temperature change associated with including the cloud feedback is amplified in the Arctic by the surface-albedo, Planck, and lapse-rate feedbacks. A moist energy balance model with a locked cloud feedback exhibits similar behavior as the comprehensive climate model with a disabled cloud feedback and further indicates that the mid-latitude cloud feedback contributes to Arctic amplification via feedback interactions. Feedback locking in the moist energy balance model also suggests that the mid-latitude cloud feedback contributes substantially to the intermodel spread in Arctic amplification across comprehensive climate models. These results imply that constraining the mid-latitude cloud feedback will greatly reduce the intermodel spread in Arctic amplification. Furthermore, these results highlight a previously unrecognized non-local pathway for Arctic amplification.

58 GEOSCIENCES↗

Energy balance in the DSSAT-CSM-CROPGRO model

One potential way to improve crop growth models is for the models to predict energy balance and evapotranspiration (ET) from first principles, thus serving as a check on “engineered” ET methodology. In this paper, we present new implementations and the results of an energy balance model (EBL) developed by Jagtap and Jones (1989) and then implemented in DSSAT’s CROPGRO (CG-EBL) model by Pickering et al. (1995) as a linked energy balance-photosynthesis model that has not been field-tested until now. The energy balance code computes evapotranspiration and other energy balance components, as well as a canopy air temperature, based on three sources (sunlit leaves, shaded leaves, soil surface). Model performance was evaluated with measured biomass and energy fluxes from two sites in Nebraska, namely, the US-Ne2 irrigated maize-soybean rotation field and the US-Ne3 rainfed maize-soybean rotation field, which are part of the Ameriflux eddy covariance network (htt ps://ameriflux.lbl.gov/sites). After implementing new aerodynamic resistances and the stomatal conductance model of the Ball–Berry–Leuning, crop growth, evapotranspiration and soil temperature were simulated well by the EBL model. The EBL improved ET predictions slightly over the often-used FAO56 method [Penman–Monteith (Allen et al., 1998)] for 4 of the 5 years evaluated for both irrigated and rainfed conditions. Further, a significant improvement was achieved using EBL for the simulation of soil temperature at the various depths compared to STEMP, the original subroutine in DSSAT for simulating soil temperature. Compared to the other available DSSAT methods, the EBL explicitly simulates the impacts of crop morphology, physiology and management on the crop’s environment and energy and mass exchange, which in turn directly affect the water use and irrigation requirements, phenology, photosynthesis, growth, sterility, and yield of the crop.

54 ENVIRONMENTAL SCIENCES↗

Cloud-atmosphere impacts on the central Arctic surface energy budget (Final Report)

This project investigated how clouds and atmosphere-sea ice interactions shape the central Arctic surface energy budget using observations from the MOSAiC expedition and coordinated model experiments. Analyses focused on three themes. First, a new method applied to thermistor string data revealed that snow thermal conductivity is systematically higher than assumed in most models, strongly influencing conductive heat flux and sea ice growth, especially under clear skies. Second, a full annual cycle of surface energy budget observations, combined with detailed cloud microphysical retrievals, demonstrated how cloud regimes regulate radiative, turbulent, and conductive fluxes, driving seasonal contrasts in sea ice energy balance: in winter, radiative forcing elicits strong turbulent and conductive responses, while in summer excess energy is primarily partitioned into surface melt. Third, these observations were used to evaluate and improve regional and global forecast models. While some models captured key Arctic cloud-radiation states, most exhibited persistent deficiencies in representing liquid-containing clouds, snow-on-sea-ice processes, and flux responses to radiative forcing. Together, these results provide unprecedented benchmarks for understanding coupled Arctic processes, improve parameterizations of snow, sea ice, and cloud interactions, and highlight critical pathways by which atmospheric variability drives sea ice change in a rapidly evolving Arctic system. Lastly, the project was a resounding success, resulting in 38 peer-reviewed publications and dozens of presentations, while also supporting an early career scientist.

54 ENVIRONMENTAL SCIENCES↗

A mass conservative, well balanced, tangency preserving and energy decaying method for the shallow water equations on a sphere

Here a fully discrete surface finite element method is proposed for solving the viscous shallow water equations in a bounded Lipschitz domain on the sphere based on a general triangular mesh. The method consists of a modified Crank–Nicolson method in time and a Galerkin surface finite element method in space for the fluid thickness H and the fluid velocity u. A finite element space tangential to the sphere at all finite element nodes is proposed to approximate the fluid velocity u. The proposed method has second-order accuracy in time and first-order accuracy in space, and preserves mass conservation, well balancedness, tangency of velocity to the sphere, and energy decay. Numerical experiments are presented to illustrate the accuracy of the proposed method and the preservation of the physical properties, including mass conservation, well balancedness, and energy decay. A numerical simulation of ocean mesoscale activity on a circular basin with a continental shelf is provided.

97 MATHEMATICS AND COMPUTING↗