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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

How Water Attacks MXene

Two-dimensional (2D) transition metal carbides and nitrides (MXenes) have shown outstanding performances in electrochemical energy storage and many other applications. However, the stability of MXene remains a concern, especially its quick degradation in aqueous solutions under ambient conditions. Here, we report on the water/Ti 3 C 2 O 2 -MXene interfacial chemistry from first-principles molecular dynamics simulations at room temperature. Surprisingly, we find that the water molecules can attack the basal plane of Ti 3 C 2 O 2 and pull the surface Ti atoms out, thereby reconstructing the surface. Further, by tracking close encounters of water molecules and surface Ti atoms on the basal plane of Ti 3 C 2 O 2 , we show that the attack is initiated by the chemisorption of a water molecule on a surface Ti atom, followed by the breaking of Ti–C bonds and deprotonation of the water molecule, leading to the formation of Ti–OH on the Ti 3 C 2 O 2 surface and a hydronium ion in the aqueous phase. Our finding highlights the susceptibility of Ti 3 C 2 O 2 MXene to water attack, supporting recent experimental observations. Furthermore, we demonstrate that preventing close encounters of water molecules and the surface Ti atoms is key to the stability of the basal plane and can be realized by negatively charging the surface (thereby reorienting the O atoms of water away from the surface) or converting the surface O to -OH groups (thereby shifting the water layer further away from the surface). Our insights and approach highlight the importance of the reactivity of water when interfacing with 2D materials such as MXenes.

36 MATERIALS SCIENCE↗
NASA NTRS1992

Stability of a nonorthogonal stagnation flow to three-dimensional disturbances

A similarity solution for a low Mach number nonorthogonal flow impinging on a hot or cold plate is presented. For the constant density case, it is known that the stagnation point shifts in the direction of the incoming flow and that this shift increases as the angle of attack decreases. When the effects of density variations are included, a critical plate temperature exists; above this temperature the stagnation point shifts away from the incoming stream as the angle is decreased. This flowfield is believed to have application to the reattachment zone of certain separated flows or to a lifting body at a high angle of attack. Finally, the stability of this nonorthogonal flow to self similar, 3D disturbance is examined. Stability properties of the flow are given as a function of the parameters of this study; ratio of the plate temperature to that of the outer potential flow and angle of attack. In particular, it is shown that the angle of attack can be scaled out by a suitable definition of an equivalent wavenumber and temporal growth rate, and the stability problem for the nonorthogonal case is identical to the stability problem for the orthogonal case.

Lasseigne, D. G.↗
NASA NTRS1991

Stability of a non-orthogonal stagnation flow to three dimensional disturbances

A similarity solution for a low Mach number nonorthogonal flow impinging on a hot or cold plate is presented. For the constant density case, it is known that the stagnation point shifts in the direction of the incoming flow and that this shift increases as the angle of attack decreases. When the effects of density variations are included, a critical plate temperature exists; above this temperature the stagnation point shifts away from the incoming stream as the angle is decreased. This flow field is believed to have application to the reattachment zone of certain separated flows or to a lifting body at a high angle of attack. Finally, the stability of this nonorthogonal flow to self similar, 3-D disturbances is examined. Stability properties of the flow are given as a function of the parameters of this study; ratio of the plate temperature to that of the outer potential flow and angle of attack. In particular, it is shown that the angle of attack can be scaled out by a suitable definition of an equivalent wavenumber and temporal growth rate, and the stability problem for the nonorthogonal case is identical to the stability problem for the orthogonal case.

Lasseigne, D. G.↗
NASA NTRS1974

Raman scattering applied to hypersonic air flow

The Raman scattering technique was applied to measure the local static temperature and gas number density over a sharp-edge flat-plate model in a Mach 5 nozzle of the Langley nozzle test chamber with air as the test gas. The angle of attack varied from -5 to 15 deg, and the stagnation temperature varied from 317 to 442 K, with stagnation pressures ranging from 170 kN to 2.8 MN/sq m. The measured values of static temperature and density ranged from 60 to 100 K and from 0.03 to 0.8 kg/cu m, respectively. A comparison with calculated values based on static pressure measurements along the model shows that the Raman scattering technique is a viable measurement method in applications to high-speed three-dimensional flows.

Hillard, M. E., Jr.↗
NASA NTRS1976

Static force tests of a sharp leading edge delta-wing model at ambient and cryogenic temperatures with a description of the apparatus employed

A sharp leading edge delta-wing model was tested through an angle-of-attack range at Mach numbers of 0.75, 0.80, and 0.85 at both ambient and cryogenic temperatures in the Langley 1/3-meter transonic cryogenic tunnel. Total pressure was varied with total temperature in order to hold test Reynolds number constant at a given Mach number. Agreement between the aerodynamic data obtained at ambient and cryogenic temperatures indicates that flows with leading-edge vortex effects are duplicated properly at cryogenic temperatures. The test results demonstrate that accurate aerodynamic data can be obtained by using conventional force-testing techniques if suitable measures are taken to minimize temperature gradients across the balance and to keep the balance at ambient (warm) temperatures during cryogenic operation of the tunnel.

Kilgore, R. A.↗
NASA NTRS1981

Preflight reentry heat transfer analysis of Space Shuttle

Preflight predictions of the structural temperature distributions during entry are compared with data from the initial Shuttle flight. Finite element thermal analysis programming was used to model the heat flow on Shuttle structures and actual gas properties of air were employed in the analyses of aerodynamic heating. Laminar, separated, and turbulent heat fluxes were calculated for varying locations on the craft using velocity-attitude and angle-of-attack projections taken from the nominal STS-1 trajectory. Temperature time histories of the first flight are compared with laminar and turbulent flow assumptions and an unpredicted rapid cooling 1800 sec into entry is credited to inaccurate assumptions of structural heat dissipative properties or flow conditions in that time phase of the flight; additional discrepancies in descriptions of heating of the upper fuselage are attributed to a lack of knowledge of the complex flow patterns existing over that area of the Shuttle body.

Ko, W. L.↗
NASA NTRS1978

Experimental Studies of the Formation/Deposition of Sodium Sulfate in/from Combustion Gases

Processes related to the hot corrosion of gas turbine components were examined in two separate investigations. Monochromatic laser light was used to probe condensation onset and condensate film growth (via interference of reflected light) on electrically heated ribbons immersed in seeded, flat flame combustion product gases. Boron trichloride is used as the seed gas in these preliminary experiments conducted to obtain precise measurements of the dew point/deposition rates. Because of the importance of gaseous Na(g) as a precursor to NaSO4 formation, the kinetics and mechanisms of the heterogeneous reaction H(g) + NaCl(s) yields Na(g) + HCl(g) was studied using atomic absorption spectroscopy combined with microwave discharge-vacuum flow reactor techniques at moderate temperatures. Preliminary results indicate the H-atom attack of solid NaCl vaporization is negligible; hence the corresponding gas phase (homogeneous) reaction no role in the observed Na(g) production.

Rosner, D. E.↗
NASA NTRS1983

Aromatic Polyimides With Group VI Linkages

New polymer system combines thermal and solvent resistant properties of aromatic polyimides with processability of PPX polymers. PPX polymers include polyphenylene oxide, polyphenylene sulfide, and polyphenylene sulfone classes. Generally more processable by hot melt or thermoplastic techniques than aromatic polyimides. PPX systems more susceptible to attack by solvents and have lower glass transition temperatures than PI group.

St. Clair, T. L.↗
NASA NTRS1983

Cyclic oxidation of superalloys

The development of mathematical/computer models of cyclic oxidation in high-temperature alloys is described. The acceleration of oxidation attack caused by the spalling of protective oxide scales is discussed. The COREST paralinear model based on empirical data, designed by Barrett and Pressler, is found to be of limited value. Basic research on the spalling process in different alloy systems is reviewed, and the phenomenon is characterized: occurring mainly within the oxide, it is caused by the different thermal expansion coefficients of oxide and metal and is a linear function of the total retained oxide. This information has been used in the development of the discrete oxide-spall model COSP and in its modification by addition of a diffusion-zone-profile model to predict the failure of components (Heckel and Nesbitt, unpublished). The COSP model is shown to produce good predictions of cyclic oxidation under a variety of conditions, using data from simple isothermic tests.

Lowell, C. E.↗
NASA NTRS1984

Experimental and analytical investigation of a freezing point depressant fluid ice protection system

A glycol-exuding porous leading edge ice protection system was tested in the NASA Icing Research Tunnel. Stainless steel mesh, laser drilled titanium, and composite panels were tested on two general aviation wing sections. Two different glycol-water solutions were evaluated. Minimum glycol flow rates required for anti-icing were obtained as a function of angle of attack, liquid water content, volume median drop diameter, temperature, and velocity. Ice accretions formed after five minutes of icing were shed in three minutes or less using a glycol fluid flow equal to the anti-ice flow rate. Two methods of predicting anti-ice flow rates are presented and compared with a large experimental data base of anti-ice flow rates over a wide range of icing conditions. The first method presented in the ADS-4 document typically predicts flow rates lower than the experimental flow rates. The second method, originally published in 1983, typically predicts flow rates up to 25 percent higher than the experimental flow rates. This method proved to be more consistent between wing-panel configurations. Significant correlation coefficients between the predicted flow rates and the experimental flow rates ranged from .867 to .947.

Albright, A. E.↗
NASA NTRS1953

Free-jet Altitude Investigation of a 20-inch Ram-jet Combustor with a Rich Inner Zone of Combustion for Improved Low-temperature-ratio Operation

An investigation of the altitude performance of a 20-inch-diameter high-temperature-ratio ram-jet combustor which had been redesigned to provide good combustor efficiency over a wide range of temperature ratios was conducted at zero angle of attack in a free-jet facility at a Mach number of 3.0. Configurations investigated incorporated a cylindrical control sleeve which confined the injected fuel at low over-all fuel-air ratios to about 40 percent of the engine air flow. This provided an optimum fuel-air mixture over a portion of the flame holder when the over-all fuel-air ratio was about 0.02. The configurations with the control sleeve operated with good combustor efficiency at fuel-air ratios as lean as 0.015, whereas the original engine had a lean blow-out limit at a fuel-air ratio of about 0.03. The control sleeve had little effect upon the high-fuel-air-ratio performance of the engine.

COMBUSTION, RAM-JET ENGINES↗
NASA NTRS1956

Boundary-layer Transition at Supersonic Speeds

Recent results of the effects of Mach number, stream turbulence, leading-edge geometry, leading-edge sweep, surface temperature, surface finish, pressure gradient, and angle of attack on boundary-layer transition are summarized. Factors that delay transition are nose blunting, surface cooling, and favorable pressure gradient. Leading-edge sweep and excessive surface roughness tend to promote early transition. The effects of leading-edge blunting on two-dimensional surfaces and surface cooling can be predicted adequately by existing theories, at least in the moderate Mach number range.

Low, George M↗
NASA NTRS2003

NiAl Coatings Investigated for Use in Reusable Launch Vehicles

As part of its major investment in the area of advanced space transportation, NASA is developing new technologies for use in the second- and third-generation designs of reusable launch vehicles. Among the prototype rocket engines being considered for these launch vehicles are those designed to use liquid hydrogen as the fuel and liquid oxygen as the oxidizer. Advanced copper alloys, such as copper-chromium-niobium (Cu-8(at.%)Cr- 4(at.%)Nb, also referred to as GRCop-84), which was invented at the NASA Glenn Research Center, are being considered for use as liner materials in the combustion chambers and nozzle ramps of these engines. However, previous experience has shown that, in rocket engines using liquid hydrogen and liquid oxygen, copper alloys are subject to a process called blanching, where the material undergoes environmental attack under the action of the combustion gases. In addition, the copper alloy liners undergo thermomechanical fatigue, which often results in an initially square cooling channel deforming into a dog-house shape. Clearly, there is an urgent need to develop new coatings to protect copper liners from environmental attack inside rocket chambers and to lower the temperature of the liners to reduce the probability of deformation and failure by thermomechanical fatigue.

Raj, Sai V.↗
NASA NTRS2007

The X-43A Flight Research Program: Lessons Learned on the Road to Mach 10

During an aerospace engineer's undergraduate studies, he or she will attend classes in aerodynamics, thermodynamics, structures, stability and control, dynamics, design, propulsion, and computer science, along with the related courses in mathematics, physics, statistics, and chemistry required to understand the material. Upon graduation, the new engineer will have acquired a basic knowledge of how to build an aerospace vehicle. What only comes through experience, however, is the understanding of the inevitable imperfect process through which an aerospace vehicle is built. This is the adventure of turning a basic concept into functional hardware. Engineers working on a project must often deal with ambiguous situations. They are routinely asked by management to provide risk assessments of a project, yet even after careful analysis uncertainties remain. The project must be accomplished within finite limits of time and money. The question an engineer answers is whether the solution to potential problem is worth the cost and schedule delay, or if the solution might actually be worse than the problem it is meant to solve. Review protocols are established to ensure that an unknown has not been overlooked. But these cannot protect against an unknown unknown. Examples of these situations can be found in the history of the X-43A Hyper-X (Hypersonic Experiment) program. In this NASA project, a supersonic combustion ramjet (scramjet) engine was flight tested on a subscale vehicle. The X-43A Hyper-X Research Vehicle (HXRV) was launched from a B-52B mothership, then boosted to the test speed by a modified Pegasus rocket first stage, called the Hyper-X Launch Vehicle (HXLV). Once at the proper speed and altitude, the X-43A separated from the booster, stabilized itself, and then the engine test began. Although wind-tunnel scramjet engine tests had begun in the late 1950s, before the Hyper-X program there had never been an actual in-flight test of such an engine integrated with an appropriate airframe. Thus, while the scramjet had successfully operated in the artificial airflow of wind tunnels, the concept had yet to be proven in real air. These conditions meant changes in density and temperature, as well as changes in angle of attack and sideslip of a free-flying vehicle. A wind tunnel is limited in its ability to simulate these subtle factures, which have a major impact on almost any vehicle, but especially that of a scramjet's performance. The Hyper-X project was to provide a real-world benchmark of the ground test data. The full scale X-43A engine would be operated in the wind tunnel, and then flown, and the data from its operation would then be compared with projections. If these matched, the wind tunnel data would be considered a reliable design tool for future scramjet. If there were significant differences, the reasons for these would have to be identified. Until such information was available, scramjets would lack the technological maturity to be considered for future space launch or high-speed atmospheric flight vehicles.

Peebles, Curtis↗
NASA NTRS2017

Residual Stresses in a NiCrY-Coated Powder Metallurgy Disk Superalloy

Protective ductile coatings will be necessary to mitigate oxidation and corrosion attack on superalloy disks exposed to increasing operating temperatures in some turbine engine environments. However, such coatings must be resistant to harmful surface cracking during service. The objective of this study was to investigate how residual stresses evolve in such coatings. Cylindrical gage fatigue specimens of powder metallurgy-processed disk superalloy LSHR were coated with a NiCrY coating, shot peened, and then subjected to fatigue in air at room and high temperatures. The effects of shot peening and fatigue cycling on average residual stresses and other aspects of the coating were assessed. Shot peening did induce beneficial compressive residual stresses in the coating and substrate. However, these stresses became more tensile in the coating with subsequent heating and contributed to cracking of the coating in long intervals of cycling at 760 C. Substantial compressive residual stresses remained in the substrate adjacent to the coating, sufficient to suppress fatigue cracking. The coating continued to protect the substrate from hot corrosion pitting, even after fatigue cracks initiated in the coating.

superalloy↗
NASA NTRS1991

Airfoil transition and separation studies using an infrared imaging system

An infrared imaging system was used to detect the thermal signature of boundary-layer flow regimes on a NACA 0012 airfoil from zero angle of attack up to separation. The boundary-layer transition from laminar to turbulent flow and the onset of separation could be seen on the airfoil thermograms. The findings were compared against the behavior of aluminum foil tufts observable both visually and with the infrared imaging system. This arrangement offers the option of using the infrared imaging system both for flow regime detection through surface thermography and flow visualization by the aluminum foil tufts. Ultimately the surface temperature changes due to variation in the angle of attack of a lifting surface provide a means for interpretation of the boundary-layer flow regimes.

Gartenberg, Ehud↗
DOE OSTI2020

ALLOY SELECTION AND C-276 CODE DESIGN VALUE EXTENSION FOR ADVANCED MOLTEN SALT TECHNOLOGY TEST FACILITIES EXPERIMENTATION

Molten halide salts are being considered as working fluids for nuclear and concentrated solar power applications. High temperature molten fluoride and chloride salts are known to preferentially attack and deplete Cr in alloys, which leads to the use of high-Ni lower-Cr alloys in test facilities for advanced Molten Salt Technology. Alloys 600 and C-276 are two commercially available Ni alloys that have moderate Cr contents and are qualified to the maximum temperature of 649°C and 677°C (1,200°F and 1,251°F), respectively, in the Boiler and Pressure Vessel Code. Both alloys have good corrosion resistance to acids, are resistant to stress-corrosion cracking, and have long track records of use in the chemical industry. Comparatively, Alloy C-276 has a similar Cr content but much higher allowable stresses for temperatures greater than 600°C (1,112°F). Therefore, it has been considered as a structural material for test facilities that require operations at 700°C (1,292°F) or greater to develop high-temperature Molten Salt Technology. To meet the requirements, the current code design values were extended based on some experimental data. Analysis showed that above current Codified maximum temperature, strength of the alloy is mainly controlled by creep rupture life under the average stress, although the Sc creep rate criterion is close to the Favg.Savg rupture criterion. This paper presents the intended test facilities and the design requirements, alloy selection considerations, literature review, data analysis, and proposed allowable stress extension based on some creep test data for C-276 at temperatures greater than 677°C (1,251°F). Further research activities are also briefly mentioned.

Ren, Weiju↗
NASA NTRS1991

Heat transfer, velocity-temperature correlation, and turbulent shear stress from Navier-Stokes computations of shock wave/turbulent boundary layer interaction flows

The properties of 2-D shock wave/turbulent boundary layer interaction flows were calculated by using a compressible turbulent Navier-Stokes numerical computational code. Interaction flows caused by oblique shock wave impingement on the turbulent boundary layer flow were considered. The oblique shock waves were induced with shock generators at angles of attack less than 10 degs in supersonic flows. The surface temperatures were kept at near-adiabatic (ratio of wall static temperature to free stream total temperature) and cold wall (ratio of wall static temperature to free stream total temperature) conditions. The computational results were studied for the surface heat transfer, velocity temperature correlation, and turbulent shear stress in the interaction flow fields. Comparisons of the computational results with existing measurements indicated that (1) the surface heat transfer rates and surface pressures could be correlated with Holden's relationship, (2) the mean flow streamwise velocity components and static temperatures could be correlated with Crocco's relationship if flow separation did not occur, and (3) the Baldwin-Lomax turbulence model should be modified for turbulent shear stress computations in the interaction flows.

Wang, C. R.↗