Search NASA⌕ Search

SEARCH · Search NASA

Results for “transportation phase optimization”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6

Advanced CO 2 Capture Solvent Systems for Dynamic Power Generation: Quarterly Research Performance Progress Report, QR4 (Q4FY24)

We developed an integrated Computational Fluid Dynamics (CFD) model to simulate the multi-physics coupled cooling process of mixed gas by cold water within a Direct Contact Cooler (DCC) equipped with a rotating packing bed (RPB). The model captures the interactions between fluid dynamics, heat transfer, mass transport, and phase transitions, while accounting for key operational variables such as RPB rotational speed and the mass flow rates of both liquid and gas. The CFD model has been validated using experimental data, specifically by comparing predicted outflow gas and liquid temperatures to measured results. Our findings demonstrate the significant effects of RPB rotational speed and mass flow rates on cooling performance, providing valuable insights for optimizing DCC efficiency in industrial applications.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

The effect of nonuniform wind shear on the intensification and reflection of mountain waves

A study is made of the intensification and reflection of mountain waves when the shear of the basic wind profile is nonuniform. A two-layer atmospheric model is treated, and the wind profile in the troposphere is assumed to be parabolic. The Scorer parameter includes the wind profile curvature term, which may not be neglected if the Richardson number Ri is finite. When Ri is finite, the optimal phase difference across the troposphere for maximum surface velocity intensifications is found to be slightly greater than Pi. As Ri increases, the optimal phase difference decreases with Ri and approaches the limiting value Pi. This implies that waves approximately reverse phase between the surface and the tropopause for maximum wave intensifications in most physically realistic atmospheric situations. The concept of Eliassen and Palm concerning the additivity of the vertical wave energy fluxes is expanded (valid at least up to the parabolic wind profile), by which the upward and downward energy transporting modes are identified.

Hyun, J. M.↗

Simultaneous Retrieval of Aerosol and Surface Optical Properties from Combined Airborne- and Ground-Based Direct and Diffuse Radiometric Measurements

This paper presents a new method for simultaneously retrieving aerosol and surface reflectance properties from combined airborne and ground-based direct and diffuse radiometric measurements. The method is based on the standard Aerosol Robotic Network (AERONET) method for retrieving aerosol size distribution, complex index of refraction, and single scattering albedo, but modified to retrieve aerosol properties in two layers, below and above the aircraft, and parameters on surface optical properties from combined datasets (Cloud Absorption Radiometer (CAR) and AERONET data). A key advantage of this method is the inversion of all available spectral and angular data at the same time, while accounting for the influence of noise in the inversion procedure using statistical optimization. The wide spectral (0.34-2.30 m) and angular range (180 ) of the CAR instrument, combined with observations from an AERONET sunphotometer, provide sufficient measurement constraints for characterizing aerosol and surface properties with minimal assumptions. The robustness of the method was tested on observations made during four different field campaigns: (a) the Southern African Regional Science Initiative 2000 over Mongu, Zambia, (b) the Intercontinental Transport Experiment-Phase B over Mexico City, Mexico (c) Cloud and Land Surface Interaction Campaign over the Atmospheric Radiation Measurement (ARM) Central Facility, Oklahoma, USA, and (d) the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) over Elson Lagoon in Barrow, Alaska, USA. The four areas are dominated by different surface characteristics and aerosol types, and therefore provide good test cases for the new inversion method.

Gatebe, C. K.↗

Computational Fluid Dynamics Analysis of the Molten Salt Tritium Transport Experiment Test Section

Tritium, a radionuclide produced through neutron capture by lithium and other elements (beryllium and fluoride) in molten salts, presents unique challenges to radionuclide release. This is true for both fusion energy breeder blankets and molten salt fission reactors. The fundamental understanding of tritium transport is crucial to the safe design and operation of these reactors. The Molten Salt Tritium Transport Experiment (MSTTE), currently under construction at Idaho National Laboratory, aims to investigate tritium transport phenomena using a forced-convection fluoride salt loop. This loop is designed to study various transport mechanisms, such as permeation through metals and gas-liquid interactions, and is intended to support future research on tritium extraction units. A critical aspect of the MSTTE loop design is ensuring a fully developed velocity profile before the fluid reaches the permeation test section where measurements are made. This study employs computational fluid dynamics to model the salt flow behavior within the MSTTE permeation test section. A realizable k-ε turbulent model with enhanced wall treatment is used to simulate the single-phase, vertical upward flow of molten salt FLiNaK under isothermal conditions. The simulation results indicated flow distortion and underdeveloped profiles at all planned flow rates within the test section due to the 85-deg sharp bend. To address this issue, a reduced diameter with a reducer and expander and a flow conditioner are investigated to achieve fully developed flow. The analysis showed that the flow conditioner successfully corrected the flow profile, achieving fully developed behavior at a flow rate of 50 liters per minute (LPM). In conclusion, this research enhances our understanding of flow dynamics in molten salt systems and contributes to optimizing tritium transport control technologies.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Development of Low-Cost, High-Performance, Easy-To-Apply, Non-Flammable, Inorganic Phase Change Material (PCM) Technology (Project Final Report)

This report describes a 45-months long research program focused on the development of novel, easy-to-apply, non-flammable, and high-performance inorganic phase change materials (PCMs) for building and industrial applications. The University of Massachusetts Lowell (UML) formed a world-class team consisting of researchers form InsolCorp (only N. American manufacturer of inorganic PCM systems for building applications), and a group of industrial advisors, to develop a universal/multipurpose, simple-to-manufacture and cost-effective PCM technology. The project team expects that the results of this work will spur in the future the adoption of thermal storage materials – a key building energy saving technology as identified by DOE BTO – for a variety of building envelope applications. The main goal of this project was to demonstrate a suite of low-cost, multipurpose, and durable inorganic PCM formulations with phase transition temperatures encompassing typical building applications (between +5 o C and +55 o C). The first objective was to design, fabricate, and experimentally validate a performance of inexpensive, durable, highly efficient, non-flammable, and easy to manufacture PCMs. To allow a variety of building applications, the project team focused on formulations that exhibit repeatable phase transitions between +5 o C and +55 o C. To follow the DOE BTO cost efficiency target without compromising thermal performance, our work was based on inorganic compounds (mostly salt hydrates) and their blends, which represent a fraction of the cost of most of organic PCMs with about twice as high density as well as significantly higher thermal conductivity and phase change enthalpy. The second objective was to develop easy-to-manufacture and -install packaging/encapsulation designs that are 1) a superior barrier to current state-of-the-art macro-packaging, which significantly reduces the risk of loss of hydration water and PCM leak, and 2) optimal in enhancing the heat exchange rates with the surroundings and within the PCM core to ensure complete charging/discharging of the entire PCM within the product. Finally, the project’s intend was to scale-up the fabrication process to demonstrate installation on system-scale applications, and to validate the performance under field conditions. This work aimed at developing low-cost, high-energy storage, and reliable latent heat storage technology for building applications. This development was realized by formulating and integrating the following two technology components: 1) inorganic salt hydrate based PCMs that have high latent enthalpies and are low-cost and durable, and 2) PCM encapsulation (packaging) technology that maximizes PCM concentration and enhances heat transport characteristics in the product and with the external environment/materials. High thermal storage capacity, low cost and fire resistance are key to the building market entry for PCM technology. Therefore, the project’s focus was on salt-hydrate-based formulations which satisfy all these criteria. Packaging and/or encapsulation of PCM is a key processing step. The project team recognized that a low-cost and simple-to-manufacture salt hydrate-based PCM technology holds the best chance to be successful in the building construction market, a market which is traditionally extremely sensitive to cost and where commodity thermal insulations are the benchmark for envelope-related energy saving measures. That is why, in this project, the main intention was to minimize the production cost and maximize the product energy storage density without sacrificing the PCM performance. It was achieved through: 1. Minimizing the non-PCM components (plastics, additives, packaging/encapsulation materials, etc.) because they are significantly more expensive than salt hydrates, 2. Using highly thermally conductive and lightweight PCM carrier (packaging material) to facilitate more complete phase cycling, and 3. Optimizing the thickness and minimizing air spaces in product design (such as in pouched PCM). For this purpose, our approach was to enable an easy system design, including selection of the PCM operating temperatures, optimizing the necessary heat storage capacity (by stacking together several layers of PCM products), and if needed, a synchronized usage of PCM products of different temperatures. A specially designed, robust, highly thermally conducting and highly impermeable packaging (to retain salt hydrate water during phase transition cycles) was designed and tested to increase the overall system thermal performance and durability. All PCM products developed during this project were tested in both lab scale and in full scale field conditions. It is expected that, after further developments and commercialization, the developed PCM technologies may be also applied in space conditioning, energy storage technologies, and heat transfer applications.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Recent Advancements in Modeling and Simulation of Entry Systems at NASA

This paper describes recent development of modeling and simulation technologies for entry systems in support of NASA’s exploration missions. Mission-tailored research and development in modeling of entry systems occurs across the Agency (e.g., within the Orion and Mars 2020 Programs), however the aim of this paper is to discuss the broad, cross-mission research conducted by NASA’s Entry Systems Modeling (ESM) Project, which serves as the Agency’s only concerted effort toward advancing entry systems across a range of technical disciplines. Technology development in ESM is organized and prioritized from a system-level perspective, resulting in four broad technical areas of investment: (1) Predictive material modeling, (2) Shock layer kinetics and radiation, (3) Computational and experimental aerosciences, and (4) Guidance, navigation, and control. Investments in thermal protection material modeling are geared toward high-fidelity, predictive models capable of handling complex structures, with an eye toward optimizing design performance and quantifying thermal protection system reliability. New computational tools have been developed to characterize material properties and behavior at the microstructural level, and experimental techniques (molecular beam scattering, micro-computed tomography, among others) have been developed to measure material kinetics, morphology, and other parameters needed to inform and validate detailed simulations. Advancements have also been made in macrostructural simulation capability to enable 3-D system-scale calculations of material response with complex topological features, including differential recession of tile gaps. Research and development in the area of shock layer kinetics has focused on air and CO2-based atmospheres. Capacity and capability of the NASA Ames Electric Arc Shock Tube (EAST) have been expanded in recent years and analysis of resulting data has led to several improvements in kinetic models, while simultaneously reducing uncertainties associated with radiative heat transfer predictions. First-principles calculations of fundamental kinetic, thermodynamic, and transport data, along with state-specificmodels for non-equilibrium flow regimes, have also yielded new insights and have the potential to vastly improve model fidelity. Aerosciences is a very broad area of interest in entry systems, yet a number of important challenges are being addressed: Coupled fluid-structure simulations of parachute inflation and dynamics; Experimental and computational studies of vehicle dynamics; Multi-phase flow with dust particles to simulate entry environments at Mars during dust storms; Studies of roughness-induced heating augmentation relevant to tiled and woven thermal protection systems; and Advanced numerical methods to optimize computational analyses for desired accuracy versus cost. Guidance and control in the context of entry systems has focused on development of methods for multi-axis control (i.e. pitch and yaw, rather than bank angle alone) of spacecraft during entry and descent. With precision landing requirements driven by Mars human exploration goals, recent efforts have yielded 6-DOF models of multi-axis control with propulsive descent of both inflatable and rigid ellipsled-like architectures. Results for both configurations have demonstrated the ability to land within the 50-meter precision requirement demanded by Mars human exploration missions, while also reducing propellant requirements by enabling more efficient control through entry and descent. Ongoing research in GN&C is developing mechanical specifications for the systems and establishing engineering feasibility.

aerothermodynamics↗

Recent Advancements in Modeling and Simulation of Entry Systems at NASA

This paper describes recent development of modeling and simulation technologies for entry systems in support of NASA's exploration missions. Mission-tailored research and development in modeling of entry systems occurs across the Agency (e.g., within the Orion and Mars 2020 Programs), however the aim of this paper is to discuss the broad, cross-mission research conducted by NASA's Entry Systems Modeling (ESM) Project, which serves as the Agency's only concerted effort toward advancing entry systems across a range of technical disciplines. Technology development in ESM is organized and prioritized from a system-level perspective, resulting in four broad technical areas of investment: (1) Predictive material modeling, (2) Shock layer kinetics and radiation, (3) Computational and experimental aerosciences, and (4) Guidance, navigation, and control. Investments in thermal protection material modeling are geared toward high-fidelity, predictive models capable of handling complex structures, with an eye toward optimizing design performance and quantifying thermal protection system reliability. New computational tools have been developed to characterize material properties and behavior at the microstructural level, and experimental techniques (molecular beam scattering, micro-computed tomography, among others) have been developed to measure material kinetics, morphology, and other parameters needed to inform and validate detailed simulations. Advancements have also been made in macrostructural simulation capability to enable 3-D system-scale calculations of material response with complex topological features, including differential recession of tile gaps. Research and development in the area of shock layer kinetics has focused on air and CO2-based atmospheres. Capacity and capability of the NASA Ames Electric Arc Shock Tube (EAST) have been expanded in recent years and analysis of resulting data has led to several improvements in kinetic models, while simultaneously reducing uncertainties associated with radiative heat transfer predictions. First-principles calculations of fundamental kinetic, thermodynamic, and transport data, along with state-specific models for non-equilibrium flow regimes, have also yielded new insights and have the potential to vastly improve model fidelity. Aerosciences is a very broad area of interest in entry systems, yet a number of important challenges are being addressed: Coupled fluid-structure simulations of parachute inflation and dynamics; Experimental and computational studies of vehicle dynamics; Multi-phase flow with dust particles to simulate entry environments at Mars during dust storms; Studies of roughness-induced heating augmentation relevant to tiled and woven thermal protection systems; and Advanced numerical methods to optimize computational analyses for desired accuracy versus cost. Guidance and control in the context of entry systems has focused on development of methods for multi-axis control (i.e. pitch and yaw, rather than bank angle alone) of spacecraft during entry and descent. With precision landing requirements driven by Mars human exploration goals, recent efforts have yielded 6-DOF models of multi-axis control with propulsive descent of both inflatable and rigid ellipsled-like architectures.

Barnhardt, Michael D.↗

Enhanced heat transport in environmental systems using microencapsulated phase change materials

A methodology for enhanced heat transport and storage that uses a new two-component fluid mixture consisting of a microencapsulated phase change material (microPCM) for enhanced latent heat transport is outlined. SBIR investigations for NASA, USAF, SDIO, and NSF since 1983 have demonstrated the ability of the two-component microPCM coolants to provide enhancements in heat transport up to 40 times over that of the carrier fluid alone, enhancements of 50 to 100 percent in the heat transfer coefficient, practically isothermal operation when the coolant flow is circulated in an optimal manner, and significant reductions in pump work.

Colvin, D. P.↗

Development of a SMA-Based, Slat-Gap Filler for Airframe Noise Reduction

Noise produced by unsteady flow around aircraft structures, termed airframe noise, is an important source of aircraft noise during the approach and landing phases of flight. Conventional leading-edge-slat devices for high lift on typical transport aircraft are a prominent source of airframe noise. Many concepts for slat noise reduction have been investigated. Slat-cove fillers have emerged as an attractive solution, but they maintain the gap flow, leaving some noise production mechanisms unabated, and thus represent a nonoptimal solution. Drooped-leading-edge (DLE) concepts have been proposed as "optimal" because the gap flow is eliminated. The deployed leading edge device is not distinct and separate from the main wing in DLE concepts and the high-lift performance suffers at high angles of attack (alpha) as a consequence. Elusive high-alpha performance and excessive weight penalty have stymied DLE development. The fact that high-lift performance of DLE systems is only affected at high alpha suggests another concept that simultaneously achieves the high-lift of the baseline airfoil and the noise reduction of DLE concepts. The concept involves utilizing a conventional leading-edge slat device and a deformable structure that is deployed from the leading edge of the main wing and closes the gap between the slat and main wing, termed a slat-gap filler (SGF). The deployable structure consists of a portion of the skin of the main wing and it is driven in conjunction with the slat during deployment and retraction. Benchtop models have been developed to assess the feasibility and to study important parameters. Computational models have assisted in the bench-top model design and provided valuable insight in the parameter space as well as the feasibility.

Turner, Travis L.↗

Flight tests of the Digital Integrated Automatic Landing System (DIALS)

The design, development, implementation and flight tests of the Digital Integrated Automatic Landing System (DIALS) are discussed. The system was implemented and flight tested on the Transport Systems Research Vehicle (TSRV), a Boeing 737-100. The design uses modern optimal control methods. The direct digital design obtained uses a 10 Hz rate for the sampling of sensors and the control commands. The basic structure of the control law consists of a steady state Kalman filter followed by a control gain matrix. The sensor information used includes Microwave Landing System (MLS) position, attitude, calibrated airspeed, and body accelerations. The phases of the final approach considered are localized and steep glideslope capture (which may be performed simultaneously or independently), localizer and glideslope track, crab/decrab, and flare to touchdown. The system can capture, track, and flare from conventional, as well as steep, glideslopes ranging from 2.5 deg to 5.5 deg. All of the modes of the control law including the Kalman filters were implemented on the TSRV flight computers which use fixed point arithmetic with 16 bit words. The implementation considerations are described as well as an analysis of the flight test results.

Halyo, N.↗

Embedding Climate Change in Urban Planning and Urban Design in New York City

Confronting the challenges of a rapidly urbanizing world threatened by climate change requires expanding the traditional influence and capabilities of urban planning and urban design, integrating climate science, natural systems and compact urban form to configure dynamic, desirable and healthy communities. Cost-effective planning and design measures that help mitigate emissions while bringing adaptive benefits should be prioritized. The chapter draws from the publication Climate Change and Cities (Cambridge University Press 2018) by the Urban Climate Change Research Network (UCCRN). The two-phase New York City case study by the Urban Design Climate Lab at the New York Institute of Technology and a team of international urban design climate experts illustrates how this emerging expertise can be replicated and implemented worldwide. Its focus on configuring people-centered public spaces that enhance energy efficiency and improve public health draws from four urban climate factors: improving efficiency of urban systems, both in energy and transportation; optimizing the form and layout of urban districts to enhance ventilation; promoting appropriate building materials with high reflectivity; and increasing green and blue urban infrastructure. The chapter highlights a set of tools and methods to measure success.

Resiliency↗

Modifying high-order aeroelastic math model of a jet transport using maximum likelihood estimation

The design of control laws to damp flexible structural modes requires accurate math models. Unlike the design of control laws for rigid body motion (e.g., where robust control is used to compensate for modeling inaccuracies), structural mode damping usually employs narrow band notch filters. In order to obtain the required accuracy in the math model, maximum likelihood estimation technique is employed to improve the accuracy of the math model using flight data. Presented here are all phases of this methodology: (1) pre-flight analysis (i.e., optimal input signal design for flight test, sensor location determination, model reduction technique, etc.), (2) data collection and preprocessing, and (3) post-flight analysis (i.e., estimation technique and model verification). In addition, a discussion is presented of the software tools used and the need for future study in this field.

Anissipour, Amir A.↗

Application of pneumatic lift and control surface technology to advanced transport aircraft

The application of pneumatic (blown) aerodynamic technology to both the lifting and the control surfaces of advanced transport aircraft can provide revolutionary changes in the performance and operation of these vehicles, ranging in speed regime from Advanced Subsonic Transports to the High Speed Civil Transport, and beyond. This technology, much of it based on the Circulation Control Wing blown concepts, can provide aerodynamic force augmentations of 80 to 100 (i.e., return of 80-100 pounds of force per pound of input momentum from the blowing jet). This can be achieved without use of external mechanical surfaces. Clever application of this technology can provide no-moving-part lifting surfaces (wings/tails) integrated into the control system to greatly simplify aircraft designs while improving their aerodynamic performance. Lift/drag ratio may be pneumatically tailored to fit the current phase of the flight, and takeoff/landing performance can be greatly improved by reducing ground roll distances and liftoff/touchdown speeds. Alternatively, great increases in liftoff weights and payloads are possible, as are great reductions in wing and tail planform size, resulting in optimized cruise wing designs. Furthermore, lift generation independent of angle of attack provides much promise for increased safety of flight in the severe updrafts/downdrafts of microbursts and windshears, which is further augmented by the ability to sustain flight at greatly reduced airspeeds. Load-tailored blown wings can also reduce tip vorticity during highlift operations and the resulting vortex wake hazards near terminal areas. Reduced noise may also be possible as these jets can be made to operate at low pressures. The planned presentation will support the above statements through discussions of recent experimental and numerical (CFD) research and development of these advanced blown aerodynamic surfaces, portions of which have been conducted for NASA. Also to be presented will be predicted performance of advanced transports resulting from these devices. Suggestions will be presented for additional innovative high-payoff research leading to further confirmation of these concepts and their application to advanced efficient commercial transport aircraft.

Englar, Robert J.↗

Semi-span model testing in the national transonic facility

The present work was motivated by an ongoing research program at NASA Langley Research Center to develop a semi-span testing capability for the National Transonic Facility (NTF). This test technique is being investigated as a means to design and optimize high-lift devices at flight Reynolds numbers in a ground test facility. Even though the freestream Mach numbers of interest are around .20, the flow around a transport wing with high lift devices deployed may contain regions of compressible flow. Thus to properly model the flow physics, a compressible flow solver may be required. However, the application of a compressible flow solver at low Mach numbers can be problematic. The objective of this phase of the project is to directly compare the performance of two widely used three-dimensional compressible Navier-Stokes solvers at low Mach numbers to both experimental data and to results obtained from an incompressible Navier-Stokes solver. The geometries of interest are two isolated wings with different leading edge sweep angles. The compressible Navier-Stokes solvers chosen, TLNS3D-MB and CFL3D, which were developed at NASA Langley Research Center (LaRC), represent the current state-of-the-art in compressible 3-D Navier-Stokes solvers. The incompressible Navier-Stokes solver, INS3D-UP, developed recently at NASA Ames Research Center (ARC), represents the current state-of-the-art in incompressible Navier-Stokes solvers.

Chokani, Ndaona↗

Development of an Energy-Efficient and High-Productivity Ammonia Recovery and Removal Process Using Resin-Wafer Electrodeionization

As efforts to develop various energy resources, ammonia energy is emerging as a promising carbon-free fuel alternative. Recovering high-concentration ammonia and ammonium from wastewater potentially offers significant environmental and economic benefits. However, research on recovery technologies for industries such as semiconductors remains limited. This study develops an efficient, energy-saving ammonia recovery technology using Resin Wafer Electrodeionization (RW-EDI), specifically for the semiconductor industry. RW-EDI shows promise for recovering ammonia from high-concentration wastewater. By optimizing parameters, such as voltage and initial concentration, a balance between productivity and energy consumption is achieved. Results indicate that ammonium and fluoride ion transport kinetics are similar, with minimal competition and selectivity values between 0.95 and 1.08. As the initial ammonia/ammonium concentration increases from 500 to 8000 ppm, reaction rate constants and the overall mass transfer coefficient decrease. Increasing the voltage can enhance mass transfer and eliminate barriers. Ion transport primarily occurs in the RW solid phase, accounting for 93.89% of the total current. Additionally, RW-EDI shows superior specific energy consumption within a concentration range of 500 ppm to 8000 ppm, outperforming technologies like electrodialysis by reducing specific energy consumption from 8−15 kWh/kg-NH 4 + to 1.2−2.5 kWh/kg-NH 4 + . This study highlights RW-EDI’s potential for ammonia recovery, providing valuable insights for future applications in wastewater treatment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Ramjet propulsion for single-stage-to-orbit vehicles

The concept of single stage earth-to-orbit transportation is studied with respect to existing and projected ramjet technology. Four types of ramjet are analyzed: fan ejector, fan ramjet, supersonic combustion ramjet, and fan ramjet with turbojet boosters. A fan ramjet with a removable fan, with separate rockets for the non-air-breathing flight phase, is considered superior to an ejector ramjet, for both ease of orbit insertion and payload boost capability. Vehicle design is also discussed in terms of trajectory integration and optimization, aerodynamic trim and stability, and complete mass estimation. Graphs are presented showing Mach number for air-breathing and non-air-breathing flight, specific impulse from various ramjet engines, and orbital-insertion parameters.

Martin, J. A.↗

Not all fugitives are bad: The case for using them to form low tortuosity - high porosity electrodes

This work focuses on the inclusion of an insoluble fugitive phase during slurry processing to form composite battery electrodes. The fugitive phases consist of natural derived products like alginic acid, sucrose, rice and potato starch, and carrageenans such as Irish Moss and synthetic pore-formers based on polymethyl methacrylate. The fugitive phases can be anaerobically thermally removed (350 °C) during binder crosslinking and electrode drying steps, resulting in electrodes with low tortuosities (approaching theoretical Bruggemann limits for spherical particles) and high porosities approaching 80%. The resulting ∼3 mg/cm 2 loaded electrodes suffer from poor electrical connectivity, lowering the effective material utilization, but represent an approach that could be utilized for the formation of solid-state batteries with infilling of materials into well-defined pores and optimized transport pathways.

25 ENERGY STORAGE↗

Modeling the Effect of Material Properties on Liquid-Alkaline Water Electrolysis

Liquid-alkaline water electrolyzers (LAWEs) use electricity to drive the conversion of water to H 2 and O 2 gas. These devices benefit from the use of low-cost nickel electrodes and metal-oxide separators, but suffer from lower current densities and higher cell voltages than proton-exchange-membrane water electrolyzers. Identifying the inefficiencies that result in this poor performance is key to mitigating losses and optimizing LAWEs. Here, we report an experimentally-validated 1-D continuum model of a LAWE that elucidates the gradients within the cell, simulates H 2 crossover, and projects the energy improvements made possible by modulating the properties of the electrodes and separator. The model captures the Nernstian polarization losses and the distribution of gas- and liquid-phases within the electrodes, enabling quantification of energy losses associated with kinetic, ohmic, and bubble-induced (mass-transport) resistances. Simulations demonstrate that LAWE can achieve energy intensities of 50 kWh kg −1 of H 2 at 1 A cm −2 using improved electrode and separator properties.

08 HYDROGEN↗