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Mesh Convergence Requirements for Composite Damage Models

The ability of the finite element method to accurately represent the response of objects with intricate geometry and loading renders the finite element method as an extremely versatile analysis technique for structural analysis. Finite element analysis is routinely used in industry to calculate deflections, stress concentrations, natural frequencies, buckling loads, and much more. The method works by discretizing complex problems into smaller, simpler approximations that are valid over small uniform domains. For common analyses, the maximum size of the elements that can be used is often be determined by experience. However, to verify the quality of a solution, analyses with several levels of mesh refinement should be performed to ensure that the solution has converged. In recent years, the finite element method has been used to calculate the resistance of structures, and in particular that of composite structures. A number of techniques such as cohesive zone modeling, the virtual crack closure technique, and continuum damage modeling have emerged that can be used to predict cracking, delaminations, fiber failure, and other composite damage modes that lead to structural collapse. However, damage models present mesh refinement requirements that are not well understood. In this presentation, we examine different mesh refinement issues related to the representation of damage in composite materials. Damage process zone sizes and their corresponding mesh requirements will be discussed. The difficulties of modeling discontinuities and the associated need for regularization techniques will be illustrated, and some unexpected element size constraints will be presented. Finally, some of the difficulties in constructing models of composite structures capable of predicting transverse matrix cracking will be discussed. It will be shown that to predict the initiation and propagation of transverse matrix cracks, their density, and their saturation may require models that are significantly more refined than those that have been contemplated in the past.

Davila, Carlos G.↗

Integration and Demonstration of Monitoring, Modeling, and Prediction of DV-1 Amendment Performance at the Bench Scale: DV-1 Amendment Demonstration

During fiscal years 2024 and 2025, the U.S. Department of Energy’s Hanford Field Office commissioned Pacific Northwest National Laboratory to conduct applied research aimed at reducing the cost, time, and uncertainty associated with in situ treatment of vadose zone contaminants at the Hanford Site. This report outlines the integration of three key research efforts into a meso-scale demonstration designed to advance field-scale solutions that aim to (1) optimize the delivery of chemical amendments to contaminated soils, (2) reduce uncertainty in amendment delivery performance assessment using advanced monitoring techniques, and (3) provide real-time insights into when and where amendment-induced precipitation reactions occur in the subsurface. To achieve these objectives, the tank-scale (~ 1 cubic meter) Geophysical Imaging of Flow and Transport (GIFT) system was developed. GIFT enables experimental testing of amendment delivery while incorporating automated multi-modal monitoring approaches, including pressure measurements, direct fluid sampling, and remote time-lapse geophysical imaging. The data generated from these monitoring techniques will serve as inputs for a generative artificial-intelligence-driven digital twin – a numerical simulation model designed to honor observed data while quantifying uncertainty in simulation accuracy. Using this simulator, researchers will refine an amendment injection strategy to maximize delivery efficiency within a low-permeability soil zone. Monitoring data will be interpreted through simulated outputs to enhance understanding of the injection process. The efficacy of this integrated approach will be evaluated through direct sampling at the conclusion of the experiment.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Geothermal Play-Fairway Analysis of Washington State Prospects: Final Report

The Washington State Geothermal Play-Fairway Analysis overcomes the exploration challenges posed by dense vegetation, glacial deposits, and extreme precipitation. The geothermal play-fairways we target are locations where heat, permeability, and saturated porosity are present in sufficient volume to provide adequate heat exchange at depths accessible by modern drilling technology. The three study areas lie along the Cascade Range magmatic arc and are near Mount Baker, Mount St. Helens, and the Wind River Valley. The seven-year project is divided into three phases. In Phase 1 we build on a previous statewide assessment of geothermal resources and develop an initial modeling approach. The results are a series of favorability, uncertainty, and risk maps for three targeted study areas. Based on these initial results, we collect new geologic and geophysical data to further refine our modeling and reduce exploration uncertainty in Phase 2. We improve the modeling method to handle the new data and update the favorability, uncertainty, and risk maps. We also update the conceptual geothermal resource models. In Phase 3 we validate our modeling approach by drilling two temperature-gradient holes and collecting and analyzing core, image logs, and new geochemistry. Our modeling approach improves on an earlier statewide method through a more-rigorous and detailed assessment of heat and permeability. Permeability potential is assessed through geomechanical modeling of the deformation that can generate and maintain reservoir porosity and permeability. Metrics to inform heat potential include temperature-gradient wells, which are sparse in Washington; proximity of Quaternary volcanic vents and young intrusive rock; spring temperature; and reservoir temperature inferred from geothermometry. We weight the individual components using an expert-guided approach known as the Analytical Hierarchy Process. During Phase 2 we also develop a fluid-filled fracture model, and an infrastructure model that helps to delineate areas which are more favorable for geothermal development based on proximity to transmission lines, elevation, land ownership and use restrictions, and availability of process water. New geologic and geophysical data is collected during Phase 2 in each of our three main study areas. At Mount Baker and north of Mount St. Helens we conduct 1:24,000-scale geologic mapping and lidar analysis to better constrain the location and character of surface faults; detailed mapping in the Wind River Valley was completed just prior to the start of this project. Ages of intrusive rocks are determined with 40 Ar/ 39 Ar geochronology, though all of our samples are Miocene or older. We collect ground based gravity observations (a total of 1,580 new stations) in all of our study areas and ground-based magnetic lines (a total of 93 km) at Mount Baker. These data are combined with existing gravity and aeromagnetic data and used to constrain fault locations and geometry. Two to three cross sections are constructed at each study area using the mapped surface geology and forward-modeling of the gravity and magnetic data; these cross sections form the basis for our updated conceptual models. We collect magnetotelluric surveys at Mount Baker and Mount St. Helens and these data are inverted to form a resistivity model from the surface to about 10 km depth; each model shows conductive zones that can be interpreted as upwelling geothermal fluids. At Mount St. Helens we deploy a passive seismic array and use the newly detected events to refine the location of the Saint Helens seismic zone. We also employ ambient-noise tomography to develop a detailed seismic-velocity model for the study area and use this model to help constrain our cross sections and conceptual model. Based on the new data collected during Phase 2—and our updated models—we develop a campaign of temperature-gradient holes and core analysis to validate our modeling in Phase 3. Drill hole MB76-31 is located near Little Park Creek, 11 km west-southwest of the summit of Mount Baker, and is 1,471 ft deep. About 410 ft of core from the lower portion of the hole—and image logs from ~175 ft below ground surface to the bottom—are collected and analyzed. Water samples are collected and processed for geothermometry. Drill hole MSH17-24 is located along upper Schultz Creek, 16 km north-northeast of Mount St. Helens and has core from 470 ft to the bottom at 1,053 ft. We did not collect image logs due to borehole stability concerns, but water samples are collected and analyzed for geothermometry. Repeat temperature-gradient measurements are made at both sites and thermal conductivity is measured from core samples. At MB76-31, the equilibrated temperature gradient of 64°C/km and calculated heat flow of 141–159 mW/m 2 is more than twice the regional average. Detailed mapping and analysis of the core, coupled with correlation to the image logs, indicates a history of permeability generation consistent with our predictions of high permeability. Because the site has high favorability in the Phase 2 model, we consider the results a positive validation of the modeling. At site MSH17-24, the equilibrated temperature gradient of ~15°C/km and calculated heat flow of 41–43 mW/m 2 are similar to regional. Geochemical analysis of the water samples indicates a meteoric source without any geothermal component. Detailed outcrop-based mapping of fault exposures near the drill site and analysis of image logs from nearby boreholes indicates a history of permeability generation consistent with our predictions. Because the site has low favorability in the Phase 2 model, we consider the results a positive validation of the modeling. Together, the two sites provide a reasonably positive validation of the Phase 2 modeling and should encourage future use of this modeling approach.

15 GEOTHERMAL ENERGY↗

Comparison of Zirconium Redistribution in BISON EBR-II Models Using FIPD and IMIS Databases with Experimental Post Irradiation Examination

Metallic fuels have seen increased interest for future sodium fast reactors due to their material properties: high thermal conductivities and advantageous neutronic properties allow for greater fission densities. One drawback to typical metallic fuels is zirconium redistribution, which impacts this advantageous material and its neutronic properties. Unfortunately, the processes behind zirconium migration behavior are understood using first principles, so before these fuels are implemented in future fast reactors, characterization and fuel qualification regimes must be completed. These activities can be supported through the use of robust modeling using the most accurate empirical models currently available to fuel researchers around the world. The tool that allows researchers to model this complex coupled thermo-mechanical behavior and nuclear properties is BISON. Additionally, BISON model parameters need to be compared against PIE measurements. The current work utilizes two fuel pins from EBR-II experiment X441 to optimize various model parameters, including porosity correction factor, thermal conductivity, phase transition temperature, and diffusion coefficient multipliers, before implementing the final model for seven fuel pins with differing characteristics. To properly evaluate the BISON simulations, the results are compared to PIE metallography data for each fuel pin, to ensure the zirconium redistribution is properly reflected in the simulation results. Six out of seven analyzed fuel pins demonstrate good agreement between the metallography images and BISON results, showing alignment of the Zr-rich, Zr-depleted, and moderately Zr-enriched zones at various axial heights along the fuel pins. Further work is needed to refine the model parameters for general pin use.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Metallographic Preparation of Space Shuttle Reaction Control System Thruster Electron Beam Welds for Electron Backscatter Diffraction

A Space Shuttle Reaction Control System (RCS) thruster failed during a firing test at the NASA White Sands Test Facility (WSTF), Las Cruces, New Mexico. The firing test was being conducted to investigate a previous electrical malfunction. A number of cracks were found associated with the fuel closure plate/injector assembly (Fig 1). The firing test failure generated a flight constraint to the launch of STS-133. A team comprised of several NASA centers and other research institutes was assembled to investigate and determine the root cause of the failure. The JSC Materials Evaluation Laboratory was asked to compare and characterize the outboard circumferential electron beam (EB) weld between the fuel closure plate (Titanium 6Al-4V) and the injector (Niobium C-103 alloy) of four different RCS thrusters, including the failed RCS thruster. Several metallographic challenges in grinding/polishing, and particularly in etching were encountered because of the differences in hardness, ductility, and chemical resistance between the two alloys and the bimetallic weld. Segments from each thruster were sectioned from the outboard weld. The segments were hot-compression mounted using a conductive, carbon-filled epoxy. A grinding/polishing procedure for titanium alloys was used [1]. This procedure worked well on the titanium; but a thin, disturbed layer was visible on the niobium surface by means of polarized light. Once polished, each sample was micrographed using bright field, differential interference contrast optical microscopy, and scanning electron microscopy (SEM) using a backscatter electron (BSE) detector. No typical weld anomalies were observed in any of the cross sections. However, areas of large atomic contrast were clearly visible in the weld nugget, particularly along fusion line interfaces between the titanium and the niobium. This prompted the need to better understand the chemistry and microstructure of the weld (Fig 2). Energy Dispersive X-Ray Spectroscopy (EDS) was used to confirm the chemical composition of the variations in contrast in these areas. Niobium alloys generally require exposure to more aggressive chemical reagents than titanium alloys for etching because of niobium s chemical resistance; therefore, the titanium portion of the sample was etched first. A five second immersion in Kroll s reagent revealed a general microstructure on the titanium portion of the sample; however, the titanium heat affected zone closest to the weld, was over-etched due to higher concentrations of refined grains and an increase in eta-phase. The Kroll s etchant also revealed some microstructure in the weld nugget itself; the niobium portion of the sample remained unetched.

Martinez, James↗

Application of the Refined Zigzag Theory to the Modeling of Delaminations in Laminated Composites

The Refined Zigzag Theory is applied to the modeling of delaminations in laminated composites. The commonly used cohesive zone approach is adapted for use within a continuum mechanics model, and then used to predict the onset and propagation of delamination in five cross-ply composite beams. The resin-rich area between individual composite plies is modeled explicitly using thin, discrete layers with isotropic material properties. A damage model is applied to these resin-rich layers to enable tracking of delamination propagation. The displacement jump across the damaged interfacial resin layer is captured using the zigzag function of the Refined Zigzag Theory. The overall model predicts the initiation of delamination to within 8% compared to experimental results and the load drop after propagation is represented accurately.

Groh, Rainer M. J.↗

Microstructure, Hardness, and Residual Stress of the Dissimilar Metal Weldments of SA508-309L/308L-304L

A dissimilar metal weldment consisting of SA508-309L-308L-304L is widely used in light-water nuclear reactors. These weldments demonstrate dissimilar susceptibility to stress corrosion cracking that are related to the microstructure, properties, and residual stress. In this work, microstructures, hardness, and the residual stress distribution of the dissimilar metal weldments were investigated, with the correlation of increased hardness in the heat-affected zone (HAZ) to the microstructure. 304L HAZ demonstrated similar grain morphology as the base material, and the increase in hardness was primarily attributed to the increased dislocation density. SA508 HAZ demonstrated a change of grain morphology resulting from the different peak temperatures and cooling rates. The increased hardness in the SA508 HAZ was attributed to the refined grain morphology, higher dislocation density, and higher number density of precipitates. A ~ 20–30-μm-wide martensitic zone formed at the fusion boundary of SA508-309L, where Cr-rich carbide precipitates were observed, with the average size and the number density of 44.1 ± 16.9 nm and 1.5 × 10 21 m ₋3 , respectively. In conclusion, residual stress results demonstrated the largest tensile stress at 309L butter, indicating its high cracking susceptibility.

36 MATERIALS SCIENCE↗

Application of ERTS-1 data to the protection and management of New Jersey's coastal environment

The author has identified the following significant results. A Coastal Zone Surveillance Program has been developed in which systematic comparisons of early ERTS-1 images and recently acquired images are regularly made to identify areas where changes have occurred. A methodology for assessing and documenting benefits has been established. Quantification of benefits has been directed toward four candidate areas: shore protection, ocean outfalls, coastal land resources, and offshore waste disposal. A refinement in the change detection analysis procedure has led to greater accuracy in spotting developmental changes in the Coastal Zone. Preliminary conclusions drawn from the Shore Erosion case study indicate that in the northern test area (developed beach) erosion has occurred more often, is generally more severe, and the beach is slower to recover than in the southern test area (natural beach). From these data it appears that it may be possible to define areas most likely to experience further erosion. The assumption of continued erosion in areas that have at one time experienced severe erosion is supported by the simple fact that as a beach narrows wave energy is concentrated on a narrower beach surface. The higher energy condition subsequently results in accelerated erosion.

Yunghans, R. S.↗

Characterization of macrosegregation in ESR IN-718

Aspects of macrosegregation theory, such as dendrite arm spacing, pool profile and mushy zone depth are beneficial to developing consumable melting process for Ion Nickel IN-718, Electro-Slag Refining, especially ESR. Aspects of microsegregation theory, such as correlation of dendrite arm spacing with heat transfer mechanisms and local solidification time, are used to minimize remnant dendritism in both ESR and Vacuum Arc Remelting VAR IN-718. Specifically, ESR IN-718 must be optimized by developing practices which maximize ingot cooling rate and minimize the steepness of the solidus and liquidus isotherms. The knowledge concerning macrosegregation in consumable melted IN-718 is in the form of correlations. Since the isotherm steepness is undoubtedly involved, investigations which include a microgravity environment might separate microsegregation effects from macrosegregation effects. Accounting for the effects of gravity and density differences between the metal pool and the interdendritic fluid, in combination with the pool and mushy zone profiles, can lead to improved melting solidification practices for IN-718, and allow prediction of macrosegregation tendency to be incorporated into high temperature alloy design.

Domingue, J. A.↗

Ambient field seismology in critical zone hydrological sciences

Passive ambient noise monitoring is an emerging tool in environmental seismology, leveraging the ambient seismic field to assess temporal variations in shallow subsurface properties. This review focuses on the potential and challenges of using scattered coda waves from noise correlation functions to monitor critical zone dynamics. The sensitivity of seismic velocities to various environmental factors, including precipitation, snowmelt, atmospheric pressure, and groundwater fluctuations, underscores the method’s versatility. While coda waves excel in detecting subtle changes due to their scattered nature, ballistic waves provide higher spatial resolution, albeit with challenges in source stability. Advances in seismic sensing, including distributed acoustic sensing and low-cost geophone networks, have enabled high-resolution monitoring of hydrological processes, subsurface deformation, and seismic hazards. Integrating seismic data with hydrological models provides insights into water storage, pore pressure changes, and soil moisture dynamics. However, limitations in spatial resolution, calibration with ground truth data, and coupled effects between environmental factors remain key challenges. This review emphasizes the importance of interdisciplinary approaches in refining methodologies, enhancing sensor deployments, and addressing data gaps. Passive seismic monitoring offers opportunities to understand critical zone processes and their broader impacts on seismic hazards and environmental sustainability.

58 GEOSCIENCES↗

Longitudinal Effects on Plant Species Involved in Agriculture and Pandemic Emergence Undergoing Changes in Abiotic Stress

In this work we identify changes in high-resolution zones across the globe linked by environmental similarity that have implications for agriculture, bioenergy, and zoonosis. We refine exhaustive vector comparison methods with improved similarity metrics as well as provide multiple methods of amalgamation across 744 months of climatic data. The results of the vector comparison are captured as networks which are analyzed using static and longitudinal comparison methods to reveal locations around the globe experiencing dramatic changes in abiotic stress. Specifically we (i) incorporate updated similarity scores and provide a comparison between similarity metrics, (ii) implement a new feature for resource optimization, (iii) compare an agglomerative view to a longitudinal view, (iv) compare across 2-way and 3-way vector comparisons, (v) implement a new form of analysis, and (vi) demonstrate biological applications and discuss implications across a diverse set of species distributions by detecting changes that affect their habitats. Species of interest are related to agriculture (e.g., coffee, wine, chocolate), bioenergy (e.g., poplar, switchgrass, pennycress), as well as those living in zones of concern for zoonotic spillover that may lead to pandemics (e.g., eucalyptus, flying foxes).

Cashman, Mikaela↗

Containerless processing of beryllium

Melting and solidification of a beryllium alloy containing 1.5% BeO by weight in the weightless environment of space has produced cast beryllium with a relatively uniform dispersion of BeO throughout. Examination of the cast material shows that it is coarse grained, although the BeO is not heavily agglomerated in the flight specimen. Ground based comparison experiments show extreme agglomeration and segregation of BeO, resulting in large zones which are practically free of the oxide. Several postulated hypotheses for the failure to grain refine the beryllium are formulated. These are: (1) spherodization of the BeO particles during specimen preparation and during the molten phase of the experiment; (2) loss of nucleation potency through aging in the molten phase; and (3) inability of BeO to act as a grain refiner for beryllium. Further investigation with non spherodized particles and shorter dwell times molten may delineate which of these hypotheses are valid. The results of this flight experiment indicate that the weightless environment of space is an important asset in conducting research to find grain refiners for beryllium and other metals for which cast dispersions of grain refining agents cannot be prepared terrestrially due to gravitationally driven settling and agglomeration.

Wouch, G.↗

Mechanical properties of glasses impacted by debris or micrometeorites

Mechanical strength measurements on five glasses and one glass ceramic exposed on the Long Duration Exposure Facility (LDEF) have revealed no damage exceeding experimental limits of error after exposure. The measurement technique subjected less than 5 percent of the sample surface area to stresses above 90 percent of the failure strength. Seven micrometeorite or space debris impacts occurred at locations which were not in that portion of the sample subjected to greater than 90 percent of the applied stress. In consequence of this, the impact events on the sample were not detected in mechanical strength measurements. The physical form and structure of the impact sites was carefully examined to determine the influence of those events upon stress concentration associated with the impact and the resulting mechanical strength influence. The size of the impact site insofar as it determines flaw size for fracture purposes was examined. Surface topography of the impacts reveals that six of the seven sites display impact melting. The classical melt crater structure is surrounded by a zone of fractured glass. Residual stresses arising from shock compression and from cooling of the impact fused zone cannot be included in fracture mechanics analyses based on simple flaw size analyses. Strategies for refining estimates of mechanical strength degradation by impact events are presented.

Kinser, Donald L.↗

Hydrocarbon Burn Facility, SWMU 007 Per- and Polyfluoroalkyl Substances (PFAS) Assessment Report Addendum

This document discusses the Per-and Polyfluoroalkyl Substances (PFAS) assessment activities performed from May through August 2023 at the Hydrocarbon Burn Facility (HBF) located at Kennedy Space Center (KSC), Florida. HBF was used for firefighting training between 1966 and 1994. Aqueous film-forming foams (AFFFs) that contained PFAS were used as suppressants for fighting petroleum fuel fires during training. PFAS sampling was first completed at HBF in 2015. This PFAS Assessment Report Addendum (ARA) is a continuation of sampling efforts, with an overall objective to further delineate PFAS concentrations in groundwater to the pGCTLs and the United States Environmental Protection Agency (EPA) Tapwater Regional Screening Levels (RSLs) dated November 2023 and better understand groundwater to surface water interaction at the Site. The field activities presented in this PFAS ARA were conducted between May and August 2023 and included the collection of 132 direct push groundwater samples and the collection of five colocated surface water, sediment, and pore water samples from locations south/southeast of HBF in August 2023. Exceedances of the pGCTLs and Tapwater RSLs were observed in the direct push groundwater results; however, groundwater has been delineated to the pGCTLs. Exceedances of the Florida provisional Surface Water Screening Levels (pSWSLs) were observed in surface water and porewater, and concentrations of PFAS in these media confirm PFAS migration within surface channels to the south of the HBF site area. Maximum sediment concentrations, which correlate with the maximum surface water and porewater concentrations, demonstrate that PFAS impacted surface water is the source of sediment impacts. Overall, elevated concentrations of PFAS are centered on the HBF site area that trend north and south along the surface water filled swales and along the edge of Banana River. Based on analytical results, not all surface water features in this area exhibit evidence of transport. PFAS migration/transport appears to be more dominant in surface water features during the wet season. Discharges to the Banana River primarily occur where surface water facilitates transport. In contrast, groundwater transport is more effective during the dry season. During precipitation events in either the dry season or the wet season, there appears to be migration from the intermediate groundwater zone to the shallow zone into the surface water features. Additional sampling and data collection is recommended to support further refinement of PFAS groundwater delineation, a remedial alternative evaluation, and the fate and transport model.

Jennifer Buel↗

Soil Gas Survey Results Supporting Groundwater Correction Action Plan (GCAP) Development for the Moab Site

A soil gas survey was performed at the Moab Uranium Mill Tailings Remedial Action (UMTRA) Project Site during the week of November 6, 2023. Soil gas surveys are used to characterize residual subsurface sources of volatile contaminants, such as volatile organic compounds, as well as contaminants that generate a surrogate indicator gas or otherwise influence soil gas composition. The primary objective of the Moab soil gas survey was to confirm, identify, quantify, and refine secondary contaminant source area locations for uranium and ammonium/ammonia (NH 4 + /NH 3 ) in the vadose zone and shallow groundwater. The overarching goal was to provide information to assist in developing the technical basis for the Groundwater Compliance Action Plan (GCAP). Specifically, the soil gas data will support the deployment of source control technologies; e.g., where supplementary capping, removal actions, or amendments might be beneficial.

54 ENVIRONMENTAL SCIENCES↗

Soil Gas Survey Results Supporting Groundwater Correction Action Plan (GCAP) Development for the Moab Site

A soil gas survey was performed at the Moab Uranium Mill Tailings Remedial Action (UMTRA) Project Site during the week of November 6, 2023. Soil gas surveys are used to characterize residual subsurface sources of volatile contaminants, such as volatile organic compounds, as well as contaminants that generate a surrogate indicator gas or otherwise influence soil gas composition. The primary objective of the Moab soil gas survey was to confirm, identify, quantify, and refine secondary contaminant source area locations for uranium and ammonium/ammonia (NH 4 + /NH 3 ) in the vadose zone and shallow groundwater. The overarching goal was to provide information to assist in developing the technical basis for the Groundwater Compliance Action Plan (GCAP). Specifically, the soil gas data will support the deployment of source control technologies; e.g., where supplementary capping, removal actions, or amendments might be beneficial.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Cratering in glasses impacted by debris or micrometeorites

Mechanical strength measurements on five glasses and one glass-ceramic exposed on LDEF revealed no damage exceeding experimental limits of error. The measurement technique subjected less than 5 percent of the sample surface area to stresses above 90 percent of the failure strength. Seven micrometeorite or space debris impacts occurred at locations which were not in that portion of the sample subjected to greater than 90 percent of the applied stress. As a result of this, the impact events on the sample were not detected in the mechanical strength measurements. The physical form and structure of the impact sites was carefully examined to determine the influence of those events upon stress concentration associated with the impact and the resulting mechanical strength. The size of the impact site, insofar as it determines flaw size for fracture purposes, was examined. Surface topography of the impacts reveals that six of the seven sites display impact melting. The classical melt crater structure is surrounded by a zone of fractured glass. Residual stresses arising from shock compression and from cooling of the fused zone cannot be included in the fracture mechanics analyses based on simple flaw size measurements. Strategies for refining estimates of mechanical strength degradation by impact events are presented.

Wiedlocher, David E.↗

Space-based crystal growth and thermocapillary flow

The demand for larger crystals is increasing especially in applications associated with the electronic industry, where large and pure electronic crystals (notably silicon) are the essential material to make high-performance computer chips. Crystal growth under weightless conditions has been considered an ideal way to produce bigger and hopefully better crystals. One technique which may benefit from a microgravity environment is the float-zone crystal-growth process, a containerless method for producing high-quality electronic material. In this method, a rod of material to be refined is moved slowly through a heating device which melts a portion of it. Ideally, as the melt resolidifies it does so as a single crystal which is then used as substrate for building microelectronic devices. The possibility of contamination by contact with other material is reduced because of the 'float' configuration. However, since the weight of the material contained in the zone is supported by the surface-tension force, the size of the resulting crystal is limited in Earth-based productions; in fact, some materials have properties which prevent this process from being used to manufacture crystals of reasonable size. Consequently, there has been a great deal of interest in exploiting the microgravity environment of space to grow larger size crystals of electronic material using the float-zone method. In addition to allowing larger crystals to be grown, a microgravity environment would also significantly reduce the magnitude of convection induced by buoyancy forces during the melting state. This type of convection was once thought to be at least partially responsible for the presence of undesirable nonuniformities--called striations--in material properties observed in float-zone material. However, past experiments on crystal growth under weightless conditions found that even with the absence of gravity, the float-zone method sometimes still results striations. It is believed that another mechanism is playing a dominant role in the microgravity environment.

Shen, Yong-Hong↗