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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,081 records · Page 60

Regulatory helix plays a key role in genetic ON-OFF switching for the 2’-deoxyguanosine sensing mRNA element

Transcriptional riboswitches, noncoding mRNA elements that operate in cis to regulate gene expression, have a promising potential in medicine, synthetic biology and directed evolution. They bind to cellular metabolites or metal ions with high specificity, leading to conformational rearrangements that facilitate the activation or premature termination of transcription for downstream genes. This elegant mechanism for feedback regulation of metabolic pathways has been identified in prokaryotes and a few in eukaryotes. Our chemical probing of the 2’-deoxyguanosine (2’-dG)-sensing riboswitch demonstrates that the overall conformational state of the full-length riboswitch (dGsw-fl) is unresponsive to the 2’-dG. Although binding proceeds as expected, dGsw-fl exclusively populates an OFF state of transcriptional inhibition. We chemically probed the structure of a known dGsw transcriptional intermediate (dGsw-int) to evaluate the possibility of a cotranscriptional regulatory role. Interestingly, apo dGsw-int adopts an alternative conformation in which a stable anti-terminator helix is formed, leading to an ON state where transcription can proceed. In the presence of 2’-dG, this anti-terminator helix is destabilized to produce a conformation reminiscent of the full-length, OFF-state dGsw. Using a fluorescence quenching assay, we demonstrate that binding 2’-dG to early transcriptional intermediates can inhibit the formation of the anti-terminator helix, locking dGsw in an OFF state. These data suggest that metabolite sensing occurs during a brief window of time between the synthesis of two transcriptional intermediates. Our studies indicate that dGsw does not function as a binary ON−OFF switch, but instead fine-tunes the transcription of downstream genes during RNA synthesis using key intermediates.

59 BASIC BIOLOGICAL SCIENCES↗

Cu-Doped Iron Oxide for the Efficient Electrocatalytic Nitrate Reduction Reaction

The electrochemical nitrate reduction reaction (NO 3 RR) is a promising alternative synthetic route for sustainable ammonia (NH 3 ) production, because it not only eliminates nitrate (NO 3 – ) from water but also produces NH 3 under mild operating conditions. However, owing to the complicated eight-electron reaction and the competition from the hydrogen evolution reaction, developing catalysts with high activities and Faradaic efficiencies (FEs) is highly imperative to improve the reaction performance. In this study, Cu-doped Fe 3 O 4 flakes are fabricated and demonstrated to be excellent catalysts for electrochemical conversion of NO 3 – to NH 3 , with a maximum FE of ~100% and an NH 3 yield of 179.55 ± 16.37 mg h –1 mg cat –1 at –0.6 V vs RHE. Here, theoretical calculations reveal that doping the catalyst surface with Cu results in a more thermodynamically facile reaction. These results highlight the feasibility of promoting the NO 3 RR activity using heteroatom doping strategies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Selective Growth of a Discontinuous Subnanometer Pd Film on Carbon Defects for Li–O 2 Batteries

A high charge overpotential and poor cycle stability are the limiting factors in lithium-oxygen (Li-O 2 ) batteries, causing poor round-trip efficiency and cell failure. Many types of electrocatalysts have been explored to facilitate the oxygen evolution reaction (OER). However, even with the application of catalysts, it is still difficult to achieve stable operation as the carbon electrode (especially the defects) easily undergoes side reactions. To achieve high stability and round-trip efficiency, the rational design of OER catalysts and stable carbon electrodes are required. Herein, we employ a wet impregnation chemistry method to form a thin layer of palladium nanoparticles on the surface of carbon, which largely suppresses the side reaction through a selective coating on the carbon defect sites. Simultaneously, the Pd films serve as an electrocatalyst enabling the OER reaction with a very low overpotential. Overall, this rational design improves overall cell efficiency and extends the cycle life of the lithium-oxygen battery.

25 ENERGY STORAGE↗

Integrated modeling of advanced tokamaks for tearing mode avoidance on DIII-D

Understanding the physics of the onset and evolution of tearing modes (TMs) in tokamak plasmas is crucial for high-performance steady-state operations. The onset condition of (m,n) = (2,1) tearing stability, $Δ′$ > $Δ_c^′$> 0, has been studied in DIII-D steady-state hybrid discharges with accurate equilibrium reconstruction and well-measured plasma profiles. Here, m is the poloidal mode number and n is the toroidal mode number. The onset of n = 1 TMs is carefully identified using the Mirnov array to determine in-phase signals for the onset time and using electron cyclotron emission measurements to trace back from the saturated island width in the experiments for both initial island width and its growth rate. The tearing stability index $Δ′$ at TM onset is calculated in multiple ways, using the modified Rutherford equation and using the PEST-III or resistive DCON magnetohydrodynamic codes, and the results are in reasonable agreement with each other. The calculated $Δ′$ is compared with an analytical formula of the tearing stability threshold $Δ_c^′$ to determine the condition for the mode onset, $Δ′$ > $Δ_c^′$. Finally, the local gradient effect of the plasma current and the pressure profiles on the tearing stability is investigated in terms of the difference between $Δ′$ and $Δ_c^′$ through a series of modeled equilibria with the parametric variations. A database of experimental mode instability onsets is compatible with the simulated regions of instability obtained from the parametric variations.

Linear stability analysis↗

Origin for electrochemically driven phase transformation in the oxygen electrode for a solid oxide cell

The next generation of fuel cells, electrolyzers, and batteries requires higher power, faster kinetics, and larger energy density, which necessitate the use of compositionally complex oxides to achieve multifunctionalities and activity. These compositionally complex oxides may change their phases and structures during an electrochemical process—a so-called “electrochemically driven phase transformation.” The origin for such a phase change has remained obscure. The aim of this paper is to present an experimental study and a theoretical analysis of phase evolution in praseodymium nickelates. Nickelate-based electrodes show up to 60 times greater phase transformation during operation when compared with thermally annealed ones. Theoretical analysis suggests that the presence of a reduced oxygen partial pressure at the interface between the oxygen electrode and the electrolyte is the origin for the phase change in an oxygen electrode. Guided by the theory, the addition of the electronic conduction in the interface layer leads to the significant suppression of phase change while improving cell performance and performance stability.

25 ENERGY STORAGE↗

Quantum process identification: a method for characterizing non-markovian quantum dynamics

Established methods for characterizing quantum information processes do not capture non-Markovian (history-dependent) behaviors that occur in real systems. These methods model a quantum process as a fixed map on the state space of a predefined system of interest. Such a map averages over the system's environment, which may retain some effect of its past interactions with the system and thus have a history-dependent influence on the system. Although the theory of non-Markovian quantum dynamics is currently an active area of research, a systematic characterization method based on a general representation of non-Markovian dynamics has been lacking. In this article we present a systematic method for experimentally characterizing the dynamics of open quantum systems. Our method, which we call quantum process identification (QPI), is based on a general theoretical framework which relates the (non-Markovian) evolution of a system over an extended period of time to a time-local (Markovian) process involving the system and an effective environment. In practical terms, QPI uses time-resolved tomographic measurements of a quantum system to construct a dynamical model with as many dynamical variables as are necessary to reproduce the evolution of the system. Through numerical simulations, we demonstrate that QPI can be used to characterize qubit operations with non-Markovian errors arising from realistic dynamics including control drift, coherent leakage, and coherent interaction with material impurities.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Modes and Mechanisms of Pacific Decadal-Scale Variability

The modes of Pacific decadal-scale variability (PDV), traditionally defined as statistical patterns of variance, reflect to first order the ocean's integration (i.e., reddening) of atmospheric forcing that arises from both a shift and a change in strength of the climatological (time-mean) atmospheric circulation. While these patterns concisely describe PDV, they do not distinguish among the key dynamical processes driving the evolution of PDV anomalies, including atmospheric and ocean teleconnections and coupled feedbacks with similar spatial structures that operate on different timescales. In this review, we synthesize past analysis using an empirical dynamical model constructed from monthly ocean surface anomalies drawn from several reanalysis products, showing that the PDV modes of variance result from two fundamental low-frequency dynamical eigenmodes: the North Pacific–central Pacific (NP-CP) and Kuroshio–Oyashio Extension (KOE) modes. Both eigenmodes highlight how two-way tropical–extratropical teleconnection dynamics are the primary mechanisms energizing and synchronizing the basin-scale footprint of PDV. While the NP-CP mode captures interannual- to decadal-scale variability, the KOE mode is linked to the basin-scale expression of PDV on decadal to multidecadal timescales, including contributions from the South Pacific.

54 ENVIRONMENTAL SCIENCES↗

MJO CP Tensor Decompositions

SAND2025-14273O MJO CP Tensor Decompositions is a Python tool for computing canonical polyadic (CP) decompositions of MERRA2 observational data to understand the onset and evolution of the Madden-Julian Oscillation (MJO). Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525.

Bull, Diana [Sandia National Lab. (SNL-CA), Liverm↗

Plasma Wall Interaction with 3-D Plasma Boundaries

The interaction of the edge plasma and the material surfaces is one of the most critical challenges on the path to harness fusion power as new, fundamental energy source. This challenge typically combines the thrust to reach high density, low temperature (detached) plasmas in front of the divertor target plates as well as understanding the plasma material interaction (PMI) in particular in this regime. The combination of both research thrusts represents an extraordinarily challenging subject encompassing spatial scales spanning nanometers to meters in all states of matter and across a broad energy range. Modeling capabilities, which help to interpret data from nowadays experiments and enable extrapolation to future devices are urgently required. This is in particular true for toroidal magnetic confinement devices with three-dimensional (3D) plasma boundaries. Such plasma boundary geometries occur in tokamaks, when small amplitude magnetic perturbations are used to stabilize the unruly edge plasma or in stellarators, that are inherently 3D plasma confinement devices. In this project, the impact of 3D plasma boundaries on the plasma material interaction (PMI) was assessed. This work focused on plasma boundary conditions, in which high-density conditions at the material surfaces yield mitigation of the otherwise immense heat and particle loads that these materials would see. These so-called high recycling and eventually detached plasma regimes are of great interest for future reactor operation. In the project, key features that are unique to 3D boundaries were explored in comparison to canonically assumed axisymmetric plasma edge situations in tokamaks. In particular, the relevance of the 3D boundary situation in the extrapolation to the plasma boundary solution at ITER, the next step fusion energy experiment under construction as a multi-national, world-wide large-science experiment in southern France, has been explored. The EMC3-EIRENE plasma edge fluid and kinetic neutral transport code has been advanced to cope with the challenging and unprecedented conditions in the ITER boundary plasma including 3D fields that are planned to be used to suppress harmful edge instabilities, the so-called edge localized modes. This is a vital integration challenge for ITER and the results from this grant have provide a leading capability for this assessment. It was shown that the detachment process in a 3D edge solution for ITER follows the recycling regimes that are known from axisymmetric solutions, but that multiple plasma exhaust channels connected to the material surfaces are established which feature individual recycling characteristics. Because these channels touch the material surfaces in the divertor in a 3D geometry, the compatibility with the plasma material interaction (PMI), including erosion and impurity generation has been found to be an important part of the integration challenge. To address this, the fully 3D plasma material interaction code ERO2 has been adapted to these ITER specific geometries and a homogeneous mixing model was implemented, that allows to consider the mixing of Be and Was used at ITER in the PMI modeling. This model enhancement has been used to study non-local migration of Be in the JET ITER like wall configuration and it has been shown that with this model such complex migration processes in ITER relevant plasma shapes and with ITER relevant plasma boundary conditions can be addressed. The combined modeling approach using EMC3-EIRENE as a plasma boundary transport code and the ERO2 specialized PMI model will be an asset for the continued preparations of ITER operation as well as for Fusion Pilot Plant efforts that have emerged in the U.S. during the evolution of this grant. The predictive capability of this numerical tool has been validated at the DIII-D US national fusion facility. Here, dedicated plasma edge diagnostics were implemented to measure the impurity household around a 3D edge plasma during ELM suppression by 3D fields. Dedicated experiments with local material probes using these diagnostics and the state-of-the-art suite of boundary measurements at DIII-D have shown that the 3D perturbation of the plasma edge that is excreted by such 3D control fields yield a perturbation of the plasma boundary flux structure and hence also of the resulting PMI. The 3D boundary plasma is composed out of helical magnetic flux channels that intersect the divertor targets at an angle relative to the main guiding field, i.e., the toroidal magnetic field component of the tokamak. A similar effect has been measured as well on limiter surfaces during the startup campaign at the new stellarator experiment Wendelstein 7-X. These experiments ad initial analysis with the ERO plasma material interaction model, suggested that the place of erosion for a given particle from the surface and its re-deposition can be different in such 3D field geometries yielding potentially a significant level of net-erosion. This is not the case for axisymmetric solutions, where it was shown in the past that the eroded particles are effectively re-deposited into gaps produced by erosion at the same position and hence the net-erosion levels are small. For ITER, the quest to suppress the ELMs and at the same time maintain the integrity of the divertor is an issue, which these fundamental findings will help to resolve. The coupling of this work to the extrapolation in the ITER program has been addressed by both the PI and the lead numerical scientist being ITER Science Fellows in the duration of the contract and forward. A second focus in the exploration of 3D boundary effects on tokamaks and stellarators has been set on the measurement of helium exhaust features with such 3D fields. This is important because He represents the ash of the fusion process and needs to be exhausted. It was shown that 3D field application compatible with suppression of ELMs yields an increase of the helium exhaust performance. The ratio of the effective helium confinement time over the energy confinement time was reduced by almost 50% which demonstrated that the impact of helium accumulation in the plasma core with respect to the confinement of energy to sustain the fusion reaction is significantly improved with such 3D control fields. It was shown that this is the case for tokamaks as well as stellarators. At the Large helical Device in Japan, a similar enhancement of the helium exhaust features when small amplitude additional 3D fields were applied was measured. This is an important additional function of 3D field application and its impact on ITER is presently being studied in combination with investigations of helium exhaust in 3D field geometries of stellarator devices.

3D plasma edge transport↗

Liquid Abrasive Cutter Power Generation Unit Requirements

This document details the requirements for the purchase of a power generating unit (PGU) for an updated Liquid Abrasive Cutter (LAC) for use in field conditions. The system will provide high pressure water and will be integrated with existing waterjet cutting attachments to cut various materials. The system will be standalone, requiring only water, and electrical energy. Cutting heads, attachments, and a garnet delivery system are not included in this specification. This system is an evolution of the existing LAC (developed at LLNL). The PGU specified herein will have the ability to operate on electrical power via an electric motor, and accept input power from a variety of sources, such as an engine-driven generator, battery pack, solar, shore power, or micro-grid.

42 ENGINEERING↗

What's new on the moon?

As a result of the Apollo program and other lunar probes, questions that remained unsolved during centuries of speculation and scientific study can now be answered concerning the composition, core, surface, age, and history of the moon. Data obtained from lunar samples and instruments on the lunar surface are being used to gain insight into the history of the earth and the other planets, planetary evolution, the development of planetary magnetic fields, the nature of the solar wind, and how the Sun operates. Projects suggested for using the moon to increase understanding of geophysics are described.

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Experiments to ensure Space Station fire safety - A challenge

Three experiments have been formulated in order to address prominent fire safety requirements aboard the NASA Space Shuttle; these experiments are to be conducted as part of a Space Station-based Technology Development Mission for the growth phase of Space Station construction and operation. The experiments are: (1) an investigation of the flame-spread rate and combustion-product evolution in the burning of typical spacecraft materials in low gravity; (2) an evaluation of the interaction of fires and candidate fire extinguishers in low gravity; and (3) an investigation of the persistence and propagation of smoldering and deep-seated combustion in low gravity.

Youngblood, W. W.↗

Long-lived space observatories for astronomy and astrophysics

NASA's plan to build and launch a fleet of long-lived space observatories that include the Hubble Space Telescope (HST), the Gamma Ray Observatory (GRO), the Advanced X Ray Astrophysics Observatory (AXAF), and the Space Infrared Telescope Facility (SIRTF) are discussed. These facilities are expected to have a profound impact on the sciences of astronomy and astrophysics. The long-lived observatories will provide new insights about astronomical and astrophysical problems that range from the presence of planets orbiting nearby stars to the large-scale distribution and evolution of matter in the universe. An important concern to NASA and the scientific community is the operation and maintenance cost of the four observatories described above. The HST cost about $1.3 billion (1984 dollars) to build and is estimated to require $160 million (1986 dollars) a year to operate and maintain. If HST is operated for 20 years, the accumulated costs will be considerably more than those required for its construction. Therefore, it is essential to plan carefully for observatory operations and maintenance before a long-lived facility is constructed. The primary goal of this report is to help NASA develop guidelines for the operations and management of these future observatories so as to achieve the best possible scientific results for the resources available. Eight recommendations are given.

Savage, Blair D.↗

Spike: AI scheduling for Hubble Space Telescope after 18 months of orbital operations

This paper is a progress report on the Spike scheduling system, developed by the Space Telescope Science Institute for long-term scheduling of Hubble Space Telescope (HST) observations. Spike is an activity-based scheduler which exploits artificial intelligence (AI) techniques for constraint representation and for scheduling search. The system has been in operational use since shortly after HST launch in April 1990. Spike was adopted for several other satellite scheduling problems; of particular interest was the demonstration that the Spike framework is sufficiently flexible to handle both long-term and short-term scheduling, on timescales of years down to minutes or less. We describe the recent progress made in scheduling search techniques, the lessons learned from early HST operations, and the application of Spike to other problem domains. We also describe plans for the future evolution of the system.

Johnston, Mark D.↗

Space transfer concepts and analysis for exploration missions. Implementation plan and element description document (draft final). Volume 3: Nuclear thermal rocket vehicle

This document presents the nuclear thermal rocket (NTR) concept design developed in support of the Space Transfer Concepts and Analysis for Exploration Missions (STCAEM) study. The evolution of the NTR concept is described along with the requirements, guidelines and assumptions for the design. Operating modes and options are defined and a systems description of the vehicle is presented. Artificial gravity configuration options and space and ground support systems are discussed. Finally, an implementation plan is presented which addresses technology needs, schedules, facilities and costs.

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Space transfer concepts and analysis for exploration missions. Implementation plan and element description document (draft final). Volume 5: Nuclear electric propulsion vehicle

The nuclear electric propulsion (NEP) concept design developed in support of the Space Transfer Concepts and Analysis for Exploration Missions (STCAEM) study is presented. The evolution of the NEP concept is described along with the requirements, guidelines, and assumptions for the design. Operating modes and options are defined and a systems description of the vehicle is presented. Artificial gravity configuration options and space and ground support systems are discussed. Finally, an implementation plan is presented which addresses technology needs, schedules, facilities and costs.

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Space transfer concepts and analysis for exploration missions. Implementation plan and element description document (draft final). Volume 4: Solar electric propulsion vehicle

This document presents the solar electric propulsion (SEP) concept design developed as part of the Space Transfer Concepts and Analysis for Exploration Missions (STCAEM) study. The evolution of the SEP concept is described along with the requirements, guidelines and assumptions for the design. Operating modes and options are defined and a systems description of the vehicle is presented. Artificial gravity configuration options and space and ground support systems are discussed. Finally, an implementation plan is presented which addresses technology needs, schedules, facilities, and costs.

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Space transfer concepts and analysis for exploration missions. Implementation plan and element description document (draft final). Volume 6: Lunar systems

NASA's two Office of Space Flight (Code M) Space Transfer Vehicle (STV) contractors supported development of Space Exploration Initiative (SEI) lunar transportation concepts. This work treated lunar SEI missions as the far end of a more near-term STV program, most of whose missions were satellite delivery and servicing requirements derived from Civil Needs Data Base (CNDB) projections. Space Transfer Concepts and Analysis for Exploration Missions (STCAEM) began to address the complete design of a lunar transportation system. The following challenges were addressed: (1) the geometry of aerobraking; (2) accommodation of mixed payloads; (3) cryogenic propellant transfer in Low Lunar Orbit (LLO); (4) fully re-usable design; and (5) growth capability. The leveled requirements, derived requirements, and assumptions applied to the lunar transportation system design are discussed. The mission operations section includes data on mission analysis studies and performance parametrics as well as the operating modes and performance evaluations which include the STCAEM recommendations. Element descriptions for the lunar transportation family included are a listing of the lunar transfer vehicle/lunar excursion vehicle (LTV/LEV) components; trade studies and mass analyses of the transfer and excursion modules; advanced crew recovery vehicle (ACRV) (modified crew recovery vehicle (MCRV)) modifications required to fulfill lunar operations; the aerobrake shape and L/D to be used; and some costing methods and results. Commonality and evolution issues are also discussed.

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