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At least 1,081 records · Page 60

National Emission Standards for Hazardous Air Pollutants – Radionuclide Emissions (CY 2019)

The U.S. Department of Energy (DOE), National Nuclear Security Administration Nevada Field Office (NNSA/NFO) operates the Nevada National Security Site (NNSS) and the North Las Vegas Facility (NLVF). From 1951 through 1992, the NNSS was the continental testing location for U.S. nuclear weapons. The release of radionuclides from NNSS activities has been monitored since the initiation of atmospheric testing. After 1962, testing was limited to underground detonations, which greatly reduced radiation exposure to the public. Since the end of nuclear testing in 1992, radiation monitoring has focused on detecting airborne radionuclides from historically contaminated soils because this source dominates the potential offsite dose. These radionuclides are derived from re-suspension of soil (primarily by wind) and emission of tritium-contaminated soil moisture through evapotranspiration. Low amounts of legacy-related tritium are also emitted to air at the NLVF, an NNSS support complex in North Las Vegas.

99 GENERAL AND MISCELLANEOUS↗

Effective Kitchen Ventilation for Healthy Zero Net Energy Homes with Natural Gas

Past studies indicate that kitchen ventilation that minimally complies with California’s Residential Building Code is inadequate at controlling combustion pollutants from natural gas burners and particulate matter produced during cooking. Effectiveness is further limited by misperceptions that kitchen ventilation is infrequently needed. This project developed the technical basis for updating kitchen ventilation requirements to protect health in new California homes, especially in smaller homes common among low-income renters. Tasks included (1) a field study of ventilation equipment performance and indoor air quality in 23 low-income apartments at four sites; (2) analysis of range hood use related to cooking time and household parameters using data from 54 houses and 17 low-income apartments; (3)a measurement-based study to quantify performance of over-the-range microwave ovens with integrated exhaust fans;and (4) pollutant exposure simulations to inform capture efficiency standards.The field study found operational deficiencies with mechanical ventilation systems in a substantial fraction of low-income apartments that affected performance, resulting in higher exposures to pollutants generated indoors. Using gas cooking burners produced high short-term and weekly time-averaged nitrogen dioxide in apartments.Range hoods were used more frequently with cooking in houses (36percent) than apartments (28percent); use increased with overall cooking frequency in a home and with duration of cooktop but not oven events; actual use was correlated to, but lower than,self-reported use;and use was more frequent in houses when cooking generated any fine particulate matter (PM2.5)or when high PM2.5resulted from cooking in apartments. Performance of over-the-range microwaves with integrated exhaust fans was similar to that of range hoods of comparable price. Simulation analysis found that performance standards need to be updated to ensure that kitchen exhaust ventilation adequately protects for substantial cooking in new California residences.

03 NATURAL GAS↗

Commissioning of new CVD/ALD Furnace at Fermilab

The new CVD/ALD furnace that we are commissioning at Fermilab will allow us to deposit thin films of superconducting materials on RF cavities on different shapes, 1 cell and 9 cells 1.3GHz and 1 cell and 5 cells 650MHz. This furnace is capable to perform two different types of deposition: chemical vapor deposition and atomic layer deposition. Different materials are under investigation to push accelerating superconducting RF cavities to support higher accelerating fields and to operate with lower power loss. The first tests are focusing on the alternative A15 superconductors as: Nb3Ge, Nd3Ga, Nb3Sn, V3Si. The furnace has two different sources of precursors: 1) chlorine furnace, where we can produce the precursors in-situ, so we can build our own precursors and test how the deposited material is affecting the cavity performance, 2) 6 different bubblers, 3 low temperature bubblers and 3 high temperature bubblers. The deposition chamber is a versatile chamber with two independ ent vacuum volumes, to ensure a higher cleanliness of the deposited material. The furnace is designed to have two different configurations: High temperature, up to 1400 C, and low temperature, up to 400 C.

Grassellino, Laura↗

The Utility of Waste Tank Historical Reviews in Bulk Waste Removal Operations at the Savannah River Site – 25271

SRMC is actively working to remove, treat, and dispose radioactive waste generated by the separation facilities at SRS since their initial operations in the 1950s. The separation facilities at SRS have produced nuclear materials for a variety of purposes, particularly national defense, and continue to support the disposition of spent fuel through the Accelerated Basin Deinventory program. In almost 70 years of operation, nearly 625,000 m3 (165 million gallons) of radioactive waste have been generated and transferred to the tank farm facilities at SRS [1]. As a result of volume reduction (e.g., evaporation) and waste solidification (e.g., vitrification), approximately 127,000 m3 (33.5 million gallons) of material remain as of June 30, 2024 [2]. This liquid waste has since been stored in 51 large underground waste tanks present on the site. These waste tanks may contain up to 4,921 m3 (1.3 million gallons) of radioactive waste each in the form of saltcake or sludge. SRMC’s contract is to treat and dispose of this waste, clean the tanks, and operationally close them. To date, 8 of the 51 waste tanks have been operationally closed. Waste retrieval and tank closure activities are ongoing in an additional 17 tanks through either operations in the field or in design [3].

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Analyses of Dose Rates for Second Inner Reflector Plug Replacement at Spallation Neutron Source

The Inner Reflector Plug (IRP) is a central component of the Spallation Neutron Source (SNS) target monolith, which houses the liquid mercury target and four liter-sized neutron moderator units. It is exposed to high-level radiation fields during routine operation and builds up significant activity. The IRP needs to be replaced due to moderator neutron poison and decoupler burn-out, which is used for shaping neutron pulses. The first IRP exchange took place in March 2018 and next one, which is IRP2, is planned to be replaced during the facility maintenance period in the end of December 2025, beginning of January 2026 calendar year. The replacement of IRP is a complex task due to its location in the area receiving high irradiation, being under significant amount of shielding, and size, which requires removal in segments. For planning the replacement workflow to help to reduce radiation exposure to workers dose rates for each stage of extraction/replacement operation are predicted.

42 ENGINEERING↗

Measurement of Local Impedance Characteristics of In-Plane PEM Electrolyzer Component Features via Segmented Cell

Segmented cells are a class of advanced diagnostic devices that enable the measurement of current distribution within the active area of an electrochemical cell, allowing for the evaluation of localized impacts from operating conditions, flow fields and component inhomogeneities. Segmented cell devices have been applied to support R&D efforts for the advancement of polymer electrolyte membrane fuel cell technologies and more recently proton exchange membrane water electrolysis (PEMWE). Beyond current density distributions, segmented cells have been successfully deployed to collect the distribution of other relevant parameters such as high frequency resistance and electrode potentials. Very recently, a promising impedance method has been reported for water electrolysis where a one-dimensional segmented cell is coupled to a multichannel potentiostat, to enable the measurement of local cell impedances, further expanding the diagnostic capabilities of the segmented cell. In this study, we will present recent efforts to accurately measure local impedance characteristics for a PEMWE cell using a two-dimensional segmented cell device coupled with a multichannel potentiostat. The distribution of local resistances, i.e. high frequency, charge transfer, mass transport and catalyst layer, and iR-free overpotentials were successfully measured after eliminating sources of random and systematic error. We will discuss the application of this diagnostic on a cell containing a 1 cm feature simulating an ionomer skin. The results from these tests give insights if such an irregularity needs to be classified as a defect, and highlight the usefulness of coupling impedance spectroscopy with segmented cells for holistic spatial diagnostics of electrochemical devices.

08 HYDROGEN↗

Comfort in High-Performance Homes in a Hot-Humid Climate

TO5 2.3.2: Large-Scale Temperature Study Although space-conditioning systems are required to meet standards such as those in the Air Conditioning Contractors of America (ACCA) Manual RS (Rutkowski 1997) and the ASHRAE Standard 55 (ASHRAE 2013) comfort criteria, little is known about how space-conditioning systems are actually operating in the field and if these systems are meeting those standards. Unconventional space-conditioning systems may be necessary for low-load homes in the future. It is important to know how current systems are functioning in existing homes and to what temperatures occupants typically set the thermostats in their homes. The U.S. Department of Energy's Building America research team IBACOS set out to find some answers. By using low-cost data loggers and occupant surveys to monitor 37 single-family homes that have standard heating, ventilating, and air-conditioning (HVAC) equipment, the team gained insight into how sensitive occupants are to comfort in their homes relative to the ACCA and ASHRAE standards. This study focused on one climate zone (hot-humid); however, future studies may find differences among occupants- ideas of thermal comfort in other climate zones. Data were collected from installed sensors during a 2-month period from late August 2014 through late October 2014. The final aspect of this project was to review the business metrics associated with builders involved in a comfort and performance guarantee program. The results of this study-taken as an aggregate-show that the homes provided room-to-room temperature differences less than 6 degrees F 95% of the time. Temperature differences were less than 4 degrees F 80% of the time. Some homes showed better or worse performance. On average, two-story homes had a 3.3 degrees F temperature difference between rooms; single-story homes had an average of a 2.2 degrees F temperature difference between rooms. Occupants who did not use programmable thermostats had an average set point of 75 degrees F. Homes in which the thermostats were programmed with a setback schedule showed a median baseline temperature value of 74 degrees F and had a median afternoon setback of 75 degrees F. System runtime was analyzed and showed that the room-to-room temperature uniformity in some homes worsened during an on cycle, whereas the uniformity improved in other homes. That is, when the system was running, some rooms were receiving too much or too little air relative to the rest of the house, and the temperatures in those rooms were moving away from the temperatures of the other rooms in the house. Finally, analysis of the thermostat data shows a wide degree of variability among homes in the study. Interpretation of the measured data suggests that 21 occupants made no regular adjustments to the thermostats in their homes, seven had regular setbacks, seven showed varying setbacks, and 10 appeared to follow no pattern (with random adjustments). Ultimately, the data show that current systems are maintaining expected levels of comfort. As expected, it is more challenging to maintain a uniform temperature in all rooms of two-story homes, and future systems should address this issue. Furthermore, the data show that the majority of homes maintained relative humidity levels below 60% without any supplemental dehumidification

ACCA Manual RS↗

Rapid evolution of aerosol particles and their optical properties downwind of wildfires in the western US

Abstract. During the first phase of the Biomass Burn Operational Project (BBOP) field campaign, conducted in the Pacific Northwest, the DOE G-1 aircraft was used to follow the time evolution of wildfire smoke from near the point of emission to locations 2–3.5 h downwind. In nine flights we made repeated transects of wildfire plumes at varying downwind distances and could thereby follow the plume's time evolution. On average there was little change in dilution-normalized aerosol mass concentration as a function of downwind distance. This consistency hides a dynamic system in which primary aerosol particles are evaporating and secondary ones condensing. Organic aerosol is oxidized as a result. On all transects more than 90 % of aerosol is organic. In freshly emitted smoke aerosol, NH4+ is approximately equivalent to NO3. After 2 h of daytime aging, NH4+ increased and is approximately equivalent to the sum of Cl, SO42, and NO3. Particle size increased with downwind distance, causing particles to be more efficient scatters. Averaged over nine flights, mass scattering efficiency (MSE) increased in ∼ 2 h by 56 % and doubled in one flight. Mechanisms for redistributing mass from small to large particles are discussed. Coagulation is effective at moving aerosol from the Aitken to accumulation modes but yields only a minor increase in MSE. As absorption remained nearly constant with age, the time evolution of single scatter albedo was controlled by age-dependent scattering. Near-fire aerosol had a single scatter albedo (SSA) of 0.8–0.9. After 1 to 2 h of aging SSAs were typically 0.9 and greater. Assuming global-average surface and atmospheric conditions, the observed age dependence in SSA would change the direct radiative effect of a wildfire plume from near zero near the fire to a cooling effect downwind.

54 ENVIRONMENTAL SCIENCES↗

Version 4 CALIPSO Imaging Infrared Radiometer ice and liquid water cloud microphysical properties – Part I: The retrieval algorithms

Following the release of the version 4 Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) data products from the Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) mission, a new version (version 4; V4) of the CALIPSO Imaging Infrared Radiometer (IIR) Level 2 data products has been developed. The IIR Level 2 data products include cloud effective emissivities and cloud microphysical properties such as effective diameter and ice or liquid water path estimates. Dedicated retrievals for water clouds were added in V4, taking advantage of the high sensitivity of the IIR retrieval technique to small particle sizes. This paper (Part I) describes the improvements in the V4 algorithms compared to those used in the version 3 (V3) release, while results will be presented in a companion (Part II) paper. The IIR Level 2 algorithm has been modified in the V4 data release to improve the accuracy of the retrievals in clouds of very small (close to 0) and very large (close to 1) effective emissivities. To reduce biases at very small emissivities that were made evident in V3, the radiative transfer model used to compute clear-sky brightness temperatures over oceans has been updated and tuned for the simulations using Modern-Era Retrospective analysis for Research and Applications version 2 (MERRA-2) data to match IIR observations in clear-sky conditions. Furthermore, the clear-sky mask has been refined compared to V3 by taking advantage of additional information now available in the V4 CALIOP 5 km layer products used as an input to the IIR algorithm. After sea surface emissivity adjustments, observed and computed brightness temperatures differ by less than ±0.2 K at night for the three IIR channels centered at 08.65, 10.6, and 12.05 µm, and inter-channel biases are reduced from several tens of Kelvin in V3 to less than 0.1 K in V4. We have also improved retrievals in ice clouds having large emissivity by refining the determination of the radiative temperature needed for emissivity computation. The initial V3 estimate, namely the cloud centroid temperature derived from CALIOP, is corrected using a parameterized function of temperature difference between cloud base and top altitudes, cloud absorption optical depth, and CALIOP multiple scattering correction factor. As shown in Part II, this improvement reduces the low biases at large optical depths that were seen in V3 and increases the number of retrievals. As in V3, the IIR microphysical retrievals use the concept of microphysical indices applied to the pairs of IIR channels at 12.05 and 10.6 µm and at 12.05 and 08.65 µm. The V4 algorithm uses ice look-up tables (LUTs) built using two ice habit models from the recent “TAMUice2016” database, namely the single-hexagonal-column model and the eight-element column aggregate model, from which bulk properties are synthesized using a gamma size distribution. Four sets of effective diameters derived from a second approach are also reported in V4. Here, the LUTs are analytical functions relating microphysical index applied to IIR channels 12.05 and 10.6 µm and effective diameter as derived from in situ measurements at tropical and midlatitudes during the Tropical Composition, Cloud, and Climate Coupling (TC4) and Small Particles in Cirrus Science and Operations Plan (SPARTICUS) field experiments.

54 ENVIRONMENTAL SCIENCES↗

A modified Stillinger-Weber potential for TlBr and its polymorphic extension

TlBr is promising for g- and x- radiation detection, but suffers from rapid performance degradation under the operating external electric fields. To enable molecular dynamics (MD) studies of this degradation, we have developed a Stillinger-Weber type of TlBr interatomic potential. During this process, we have also addressed two problems of wider interests. First, the conventional Stillinger-Weber potential format is only applicable for tetrahedral structures (e.g., diamond-cubic, zinc-blende, or wurtzite). Here we have modified the analytical functions of the Stillinger-Weber potential so that it can now be used for other crystal structures. Second, past modifications of interatomic potentials cannot always be applied by a broad community because any new analytical functions of the potential would require corresponding changes in the molecular dynamics codes. Here we have developed a polymorphic potential model that simultaneously incorporates Stillinger-Weber, Tersoff, embedded-atom method, and any variations (i.e., modified functions) of these potentials. As a result, we have implemented this polymorphic model in MD code LAMMPS, and demonstrated that our TlBr potential enables stable MD simulations under external electric fields.

36 MATERIALS SCIENCE↗

Superconducting magnets and devices for space vehicles and experiments

Superconductivity research has been oriented toward those problems that tend to restrict the greater application of superconducting devices in space research and technology. These include magnetic problems of high field magnets, increasing operating temperatures, and development of useful competitive superconducting instruments.

Urban, E. W.↗

Zeeman effect of As II.

Spectrograms of As electrodeless-discharge tubes operated in a field of 24,025 G have given Zeeman patterns for 232 As II spectral lines from 2361 to 10,556 A and yielded 80 Lande g factors, of which more than half are new. There is agreement between these and the g values calculated by least-squares fitting for single configurations or for multiconfigurations, where configuration interaction is noticeable. All of the measured g values as well as the energy levels are used in the fitting process.

Li, H.↗

The SAO lunar laser.

The SAO lunar-ranging system is currently being installed at the Agassiz Observatory, Harvard, Massachusetts, USA. It employs a high-radiance neodymium-glass laser and a transmitting telescope whose aperture diameter is only 0.2 m. This telescope is a coude refractor specially built for the purpose, with tracking accuracy 1 second of arc. The receiving instrument is the 1.5-m telescope at the Agassiz Observatory. However, the laser transmitting unit can be moved to other locations where telescopes of similar size are available. Since the large telescope does not transmit the laser radiation, it remains in a normal mode of operation and the regular observing schedule is not disrupted. During routine operation, the receiver field will be larger than that of the transmitter, thus imposing less of a constraint on the tracking capability of the large optical instrument.

Lehr, C. G.↗

Light shift and light broadening in the Rb-87 maser.

A description of measurements of light-shift and light-broadening parameters for an Rb-87 maser operating between the field independent levels is reported. A parallel study of the spectral profile of the D1 pumping line is described. Comparison between the experimental results and theoretical calculations, taking into account the spatial inhomogeneity of the pumping light in the absorption cell, is presented.

Busca, G.↗

Agricultural land use mapping

The author has identified the following significant results. Agricultural areas were selected or analysis in southeastern Pennsylvania, north central Montana, and southern Texas. These three sites represent a broad range of soils, soil parent materials, climate, modes of agricultural operation, crops, and field sizes. In each of these three sites, ERTS-1 digital data were processed to determine the feasibility of automatically mapping agricultural land use. In Pennsylvania, forest land, cultivated land, and water were separable within a 25,000 acre area. Four classes of water were also classified and identified, using ground truth. A less complex land use pattern was analyzed in Hill County, Montana. A land use map was prepared shown alternating patterns of summer fallow and stubble fields. The location of farmsteads could be inferred, along with that of a railroad line. A river and a creek flowing into the river were discernible. Six categories of water, related to sediment content and depth, were defined in the reservoir held by the Fresno dam. These classifications were completed on a 150 square mile area. Analysis of the data from Texas is in its formative stages. A test site has been selected and a brightness map has been produced.

Mcmurtry, G. J.↗

A star sensor for attitude determination

Description of the optical and electronic characteristics of a star sensor developed for the Small Astronomy Satellite B. The specified design goals of the star sensor included an accuracy of 3 arc minutes. Results from field tests and operation in orbit are presented.

Finkel, A.↗

Development and testing of a portable wind sensitive directional air sampler

A portable wind-sensitive directional air sampler has been developed as part of an air pollution source identification system. The system is designed to identify sources of air pollution based on the directional collection of field air samples and their analysis for TSP and trace element characteristics. Sources can be identified by analyzing the data on the basis of pattern recognition concepts. Functional testing of a prototype sampler is described; all items exhibited performance and life sufficient to carry out field performance test operations. Life testing of the wind direction sensor and the directional porting valves, which are critical to reliable operation, was emphasized with successful results.

Deyo, J.↗

Concentrating solar collector-installation package

Report contains general description of concentrating solar collector and tracking system kit, along with comprehensive drawings, instructions, and guidelines to assist in field assembly, installation, operation, and maintenance of system.

Source record↗