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NASA NTRS1975

A measurement of abundances of VVH nuclei above 0.6 GeV per nucleon

The abundance distribution of very very heavy (VVH) nuclei just beyond the iron group has been measured with a balloon-borne counter telescope flown in 1971 and 1972. While the statistical accuracy of these observations is limited, they are of considerable interest since very little work has so far been done to determine the abundance of nuclei with charge between 27 and 36. It is found that the element distribution in the cosmic rays arriving at the top of the atmosphere is quite similar to the solar-system abundance distribution in this interval.

Juliusson, E.↗

NASA NTRS1992

MRSR: Rationale for a Mars Rover/Sample Return mission

The Solar System Exploration Committee of the NASA Advisory Council has recommended that a Mars Rover/Sample Return mission be launched before the year 2000. The recommendation is consistent with the science objectives as outlined by the National Academy of Sciences committees on Planetary and Lunar Exploration, and Planetary Biology and Chemical Evolution. Interest has also focused on Mars Rover/Sample Return (MRSR) missions, because of their crucial role as precursors for human exploration. As a result of this consensus among the advisory groups, a study of an MRSR mission began early in 1987. The study has the following goals: (1) to assess the technical feasibility of the mission; (2) to converge on two or three options for the general architecture of the mission; (3) to determine what new technologies need to be developed in order to implement the mission; (4) to define the different options sufficiently well that preliminary cost estimates can be made; and (5) to better define the science requirements. This chapter briefly describes Mars Rover/Sample Return missions that were examined in the late 1980s. These missions generally include a large (1000 kg) rover and return of over 5 kg of sample.

Carr, Michael H.↗

NASA NTRS1995

Cadmium plating replacements

The Boeing Company has been searching for replacements to cadmium plate. Two alloy plating systems seem close to meeting the needs of a cadmium replacement. The two alloys, zinc-nickel and tin-zinc are from alloy plating baths; both baths are neutral pH. The alloys meet the requirements for salt fog corrosion resistance, and both alloys excel as a paint base. Currently, tests are being performed on standard fasteners to compare zinc-nickel and tin-zinc on threaded hardware where cadmium is heavily used. The Hydrogen embrittlement propensity of the zinc-nickel bath has been tested, and just beginning for the tin-zinc bath. Another area of interest is the electrical properties on aluminum for tin-zinc and will be discussed. The zinc-nickel alloy plating bath is in production in Boeing Commercial Airplane Group for non-critical low strength steels. The outlook is promising that these two coatings will help The Boeing Company significantly reduce its dependence on cadmium plating.

Nelson, Mary J.↗

NASA NTRS1993

An overview of the cosmic dust analogue material production in reduced gravity: the STARDUST experience

The formation, properties and chemical dynamics of microparticles are important in a wide variety of technical and scientific fields including synthesis of semiconductor crystals from the vapour, heterogeneous chemistry in the stratosphere and the formation of cosmic dust surrounding the stars. Gravitational effects on particle formation from vapors include gas convection and buoyancy and particle sedimentation. These processes can be significantly reduced by studying condensation and agglomeration of particles in microgravity. In addition, to accurately simulate particle formation near stars, which takes place under low gravity conditions, studies in microgravity are desired. We report here the STARDUST experience, a recent collaborative effort that brings together a successful American program of microgravity experiments on particle formation aboard NASA KC-135 Reduced Gravity Research Aircraft and several Italian research groups with expertise in microgravity research and astrophysical dust formation. The program goal is to study the formation and properties of high temperature particles and gases that are of interest in astrophysics and planetary science. To do so we are developing techniques that are generally applicable to study particle formation and properties, taking advantage of the microgravity environment to allow accurate control of system parameters.

NASA Discipline Exobiology↗

NASA NTRS1978

Body Building Boons From Apollo

The Exer-Genie program utilizes familiar types of exercise, such as isometrics (pushing or pulling against an immovable object) and isotonics (motive exercises such as calisthenics or weight lifting) but with the important added factor of controlled resistance. The device is an arrangement of hand grips and nylon cord wrapped around an aluminum shaft. Controlled friction determines the resistance and the user can set the amount of resistive force to his own physical conditioning needs. Since Apollo days, the Exer-Genie and a similar device called the Apollo Exerciser have found wide acceptance among professional, collegiate and high school athletic teams, and among the growing number of individuals interested in physical fitness. These devices are efficient and economical replacements for conventional conditioning equipment and extremely versatile, allowing more than 100 basic exercises for shaping up specific muscle groups.

Source record↗

NASA NTRS2010

Noninvasive Techniques for Intracranial Pressure Assessment: A Review from Aerospace Medicine Perspective

Microgravity-induced changes in fluid distribution and other physiological factors due to space flight have been implicated as the cause of increased intracranial pressure (ICP) in a number of space crewmembers. The modest levels of ICP elevation and absence of severe symptoms in this group do not warrant invasive diagnostic interventions. However, the long-term trends and residual or consequential changes secondary to the observed ICP elevation in this group are not yet known. Therefore, close attention is needed to evaluate the potential techniques of noninvasively assessing ICP, including those feasible for in-flight use. Of particular interest is continuity between ground and in-flight testing, whereby data from the same or different techniques allow reasonably dependable estimation of ICP trends and responses. Methods: A thorough review of current literature, analysis of NASA data, and interviews with subject matter experts were conducted to construct a presentation that reflects the state of the art for noninvasive ICP measurement and monitoring. Results: Multiple imaging and non-imaging modalities are available to assess ICP in terrestrial clinical and experimental environments. Imaging alternatives include magnetic resonance imaging (MRI) and high-resolution sonography. Non-imaging techniques include transcranial Doppler, certain audiological methods, and venous ophthalmodynamometry, among others. Special functional techniques have been proposed recently that allow the use of advanced MRI methods to calculate ICP in addition to the acquisition of high-resolution images. Our data include many of these applications, with several cases of correlation with lumbar puncture, the invasive "gold standard" measurement of ICP.

Hamilton, Douglas R.↗

DOE OSTI2016

Implementation Guide for the Revised Branch Technical Position on Concentration Averaging and Encapsulation - 16021

As a result of the research begun in 2007 to better understand the bases of the Branch Technical Position (BTP) on 'Concentration Averaging and Encapsulation' and 10 CFR 61 'Licensing Requirements for Land Disposal of Radioactive Waste', EPRI identified three regulatory initiatives that could be pursued to enhance disposal options for the industry. These initiatives directly follow the NRC strategic assessment. The first was to revise the BTP to allow broader blending of compatible waste types. The second was to examine how 10 CFR 61.58 'Alternative requirements for waste classification and characteristics' could be used to allow for an alternative disposal criterion based on site-specific hydro-geological characteristics and end land use scenarios. And, the third is to develop a technical basis for risk informed disposal regulations in anticipation of a 10CFR 61 rulemaking. By the summer of 2015 these initiatives had been broadly addressed and resulted in the NRC issuing Revision 1 to the BTP in February of 2015. Revision 1 of the BTP (BTP 2015) is a significant re-write of the draft issued in May 2012 and a significant improvement over the 1995 BTP (BTP 1995). The NRC has altered many of the positions in the interest of clarification. The development of an Implementation Guide for applying BTP 2015 to industry-specific waste streams that is vetted and supported by a EPRI sponsored working group consisting of industry participants (including utilities, disposal sites, NRC and Agreement State representatives and industry experts) will ensure compliant and consistent application during waste generation, packaging, processing and disposal activities. The Implementation Guide will provide for a comparison to previous BTP guidance and provide clarification and common understanding of the key concepts contained within the revised BTP. These include averaging constraints, hot spots, waste streams, waste types, discrete items, blending, solidification, encapsulation and alternative approaches. EPRI plans to publish the BTP Implementation Guide in the second quarter of 2016 and it will be available to the public. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2017

Proposed Semi-Analytic Benchmark for Coupled Neutronics/Thermal-Hydraulics Feedback in Multiphysics Simulations

The past decade has seen considerable advancements in multiscale and multiphysics simulations that account for nonlinear effects of feedback between different physical processes within a single calculation. One area of particular interest has been multiphysics simulations that include both neutronics and thermal-hydraulics effects to accurately model the thermal feedback effects present in nuclear reactors. During this time, many groups have successfully modeled thermal feedback effects by coupling a variety of different types of neutron transport and thermal-hydraulic solvers together. However, formal verification and validation of these coupled code systems has proven challenging due to a lack of benchmark problems with well-characterized reference solutions. One approach is to confirm gross energy balance using bulk coolant properties (outlet temperature/enthalpy) for code verification purposes. Alternatively, code-to-code comparisons of results for a predefined reference/challenge problem have been used to establish reasonability of local results (neutron flux, heating, enthalpy rise) for various implementations, for example the VERA Core Physics Progression Problems. While community solutions are valuable for assessing the relative performance and fidelity of different implementations, they are not guaranteed to provide a measure of the absolute accuracy of a given implementation. In fact, these code-to-code comparisons can give a false sense of confidence by masking the effects of errors or approximations that are common to all of the solution methods tested. This is a particular concern when many methods derive from a common approach, such as Picard iteration. To this end, an analytical benchmark would be very valuable for verifying individual coupled physics implementations, as well as for providing a formal assessment of algorithm accuracy and sensitivity to model approximations such as mesh size and number of convergence iterations. However, creation of an analytical benchmark is difficult due to the complex nature of the eigenvalue form of the neutron transport equation (which does not permit a simple analytical solution for non-trivial cases) as well as the variety of different empirical closure relationships used in thermal-hydraulic modeling. In this paper we propose a benchmark for coupled neutronics/thermal-hydraulics simulations. The proposed benchmark overcomes the challenges associated with a multiphysics benchmark problem by using a fixed-source (rather than eigenvalue) formulation of the neutron transport equation and limiting fluid properties to the single-phase regime where the density and temperature of the coolant are related to enthalpy by a known relationship, while still preserving significant nuclear/thermal feedback effects within the simplified problem. The new benchmark is easy to simulate using existing coupled physics implementations, and allows for a direct comparison with a reference solution, as provided in this summary.

42 ENGINEERING↗

DOE OSTI2026

Oxidation of Materials and Coatings at 1000°C and 250 bar for use in Oxy-Combustion Turbine

Combinations of materials and coatings were tested in supercritical CO2 (sCO2) to evaluate their reliability in an oxy-fuel turbine being designed to operate in the 150-300 MWe size range at inlet temperatures of 1,150 °C at 300 bar and exhaust temperatures in the 725-775 °C range. Nickel alloys and stainless steels were exposed to supercritical CO2 at 1,000 °C and 250 bar for a total of over 1,500 hours. The materials were tested bare, with a nanocrystalline MCrAlY bond coat only, or with one of two types of bond coat and a thermal barrier coating. A novel test facility using a localized heat zone generated by an induction heater inside an externally cooled autoclave was developed to perform those tests. The specimens were weighed before and after exposure to determine the oxidation rate. All specimens were inspected visually, and a smaller group of coated specimens were studied using secondary electron microscopy (SEM). The integrity of the coating, and the morphology and composition of the thermally grown oxide were especially of interest for the SEM investigation. This paper presents the up-to-date results of the testing coated and uncoated superalloys in sCO2 at up to 1150 °C and up to 300 bar performed at Southwest Research Institute.

Bocher, Florent [Southwest Research Institute, San↗

DOE OSTI2016

Resolving Electrode Morphology’s Impact on Platinum Group Metal-Free Cathode Performance Using Nano-CT of 3D Hierarchical Pore and Ionomer Distribution

This paper reports on the characterization of polymer electrolyte fuel cell (PEFC) cathodes featuring a platinum group metal-free (PGM-free) catalyst using nano-scale resolution X-ray computed tomography (nano-CT) and morphological analysis. PGM-free PEFC cathodes have gained significant interest in the past decade since they have the potential to dramatically reduce PEFC costs by eliminating the large platinum (Pt) raw material cost. However, several challenges remain before they are commercially viable. Since these catalysts have lower volumetric activity, the PGM-free cathodes are thicker and are subject to increased gas and proton transport resistances that reduce the performance. To better understand the efficacy of the catalyst and improve electrode performance, a detailed understanding the correlation between electrode fabrication, morphology, and performance is crucial. In this work, the pore/solid structure and the ionomer distribution was resolved in three dimensions (3D) using nano-CT for three PGM-free electrodes of varying Nafion® loading. The associated transport properties were evaluated from pore/particlescale simulations within the nano-CT imaged structure. These characterizations are then used to elucidate the microstructural origins of the dramatic changes in fuel cell performance with varying Nafion® ionomer loading. We show that this is primarily a result of distinct changes in ionomer’s spatial distribution. The significant impact of electrode morphology on performance highlights the importance of PGM-free electrode development in concert with efforts to improve catalyst activity and durability.

42 ENGINEERING↗

NASA NTRS1985

To catch a childs's imagination: Educational overview of CAN DO G-324

When a public school district is involved in the flight of a GAS package, they have a The desire to produce an serious responsibility, along with an unprecedented opportunity. experiment with real scientific validity must be tempered by the schools' primary mission to make the adventure educationally meaningful to the greatest possible number of students. Such a project can easily become the personal plaything of the select few that are highly scientifically motivated, and technologically gifted. A public school system must, in addition, insure that the resources invested in such a project also reach out to the average student, and those whose interests lie in other directions. Such a broad reach is only possible if the GAS canister is but one part of a comprehensive and ongoing educational effort that involves as many disciplines and levels of student interest as possible. The total program should include: 1) A background of previous programs which have trained teachers and prepared students to fully utilize special activities as part of the educational process. 2) Direct student involvement in the design of experimental packages to be flown, and in the evaluation of data derived. 3) Supplementary related activities that use a Get Away Special as a motivational catalyst to generate efforts in other disciplines, other schools and other student groups. 4) Future plans to fully exploit and maintain the momentum developed by this one dramatic event. The one overriding goal of all these activities as articulated by one of our leading classroom teachers: "TO CHOOSE AND DEVELOP HIGHLY MOTIVATION& ACTIVITIES WHICH WILL CAPTURE THE IMAGINATION AND INTEREST OF STUDENTS, AND TO TAKE ADVANTAGE OF THE "TEACHABLE MOMENT" WHICH IS SO ELUSIVE."

James H. Nicholson↗

DOE OSTI2012

On Perturbation Components Correspondence between Diffusion and Transport

We have established a correspondence between perturbation components in diffusion and transport theory. In particular we have established the correspondence between the leakage perturbation component of the diffusion theory to that of the group self scattering in transport theory. This has been confirmed by practical applications on sodium void reactivity calculations of fast reactors. Why this is important for current investigations? Recently, there has been a renewed interest in designing fast reactors where the sodium void reactivity coefficient is minimized. In particular the ASTRID8,9 reactor concept has been optimized with this goal in mind. The correspondence on the leakage term that has been established here has a twofold implication for the design of this kind of reactors. First, this type of reactor has a radial reflector; therefore, as shown before, the sodium void reactivity coefficient calculation requires the use of transport theory. The minimization of the sodium reactivity coefficient is normally done by increasing the leakage component that has a negative sign. The correspondence established in this paper allows to directly look at this component in transport theory. The second implication is related to the uncertainty evaluation on sodium void reactivity. As it has shown before, the total sodium void reactivity effect is the result of a large compensation (opposite sign) between the scattering (called often spectral) component and the leakage one. Consequently, one has to evaluate separately the uncertainty on each separate component and then combine them statistically. If one wants to compute the cross section sensitivity coefficients of the two different components, the formulation established in this paper allows to achieve this goal by playing on the contribution to the sodium void reactivity coming from the group self scattering of the sodium cross section.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

NASA NTRS2004

Prioritizing Scientific Data for Transmission

A software system has been developed for prioritizing newly acquired geological data onboard a planetary rover. The system has been designed to enable efficient use of limited communication resources by transmitting the data likely to have the most scientific value. This software operates onboard a rover by analyzing collected data, identifying potential scientific targets, and then using that information to prioritize data for transmission to Earth. Currently, the system is focused on the analysis of acquired images, although the general techniques are applicable to a wide range of data modalities. Image prioritization is performed using two main steps. In the first step, the software detects features of interest from each image. In its current application, the system is focused on visual properties of rocks. Thus, rocks are located in each image and rock properties, such as shape, texture, and albedo, are extracted from the identified rocks. In the second step, the features extracted from a group of images are used to prioritize the images using three different methods: (1) identification of key target signature (finding specific rock features the scientist has identified as important), (2) novelty detection (finding rocks we haven t seen before), and (3) representative rock sampling (finding the most average sample of each rock type). These methods use techniques such as K-means unsupervised clustering and a discrimination-based kernel classifier to rank images based on their interest level.

Castano, Rebecca↗

DOE OSTI2017

Increased chemo-sensitivity by knockdown coilin expression involved acceleration of premature cellular senescence in HeLa cells

Coilin is a marker protein of the Cajal body (CB). Cajal bodies, functional nuclear structure, play important roles for the maturation of telomerase mRNAs. However, whether CB participates in the process of cell senescence is unknown. Cisplatin is a frequently used drug for the chemotherapy for various cancers, which was recently reported to be able to induce premature senescence of tumor cells. In this study, we found that when HeLa cells were treated with 2 μg/ml cisplatin for 4 days, stagnant cell growth, especially in cells stained positive of SA-β-gal, was accompanied with significant changes in CB morphologies. The removal of cisplatin allowed the recovery of normal CB appearance, but was not able to restore cells from senescent states. Knocking down coilin expression by siRNA attenuated the growth and reduced the viability of treated cells, and the decreased rate of CB formation correlated with increased staining of SA-β-gal. Interestingly, when coilin knocked-down cells exposed to cisplatin, the drug sensitivity as shown by the reduction of cell viability was significantly increased compared to the control siRNA transfection groups. Overexpression of coilin phosphomutants increased SA-β-gal fluorescence following treatments with cisplatin as compared to the wild type coilin transfection. Our results indicated that coilin was an important functional player that involved in cisplatin-induced premature cell senescence. It suggested that the modulation of coilin expression could be considered as a potential anti-tumor strategy to increase the sensitivity of chemotherapy through which drug-induced cell senescence was accelerated. - Highlights: • The morphology of Cajal body change in cisplatin inducing premature cells. • The release from cisplatin treatments resulted in the recovery of CB morphology. • Knocking down coilin expression accelerated cisplatin induced senescence. • The overexpression of coilin phosphomutants induced premature senescence.

60 APPLIED LIFE SCIENCES↗

DOE OSTI2018

PBX1 promotes the cell proliferation via JAK2/STAT3 signaling in clear cell renal carcinoma

Highlights: • PBX1 is significantly upregulated in ccRCC tissues and cells, and associated with the overall survival in patients with ccRCC. • PBX1 mediates cell proliferation via JAK2/STAT3 signaling in ccRCC. • PBX1 acts as an oncogene in ccRCC by regulating the activation of JAK2/STAT3 signaling. PBX1 was abnormally overexpressed and its intracellular localization was found to be frequently amplified in many types of cancer, including renal clear cell carcinoma. PBX1 displays oncogenic activity in several different types of cells, but little is known about how signaling pathways are altered, and the function of PBX1 in renal clear cell carcinoma has not been well investigated. In this study, we demonstrate that the expression of PBX1 was significantly upregulated in 30 pairs of human tissues compared to adjacent normal tissues and the overall survival rate of PBX1-high group was significantly worse than that of PBX1-low group. Furthermore, JAK2 expression is significantly correlated to PBX1 expression in human clinical specimen and PBX1 knockdown inhibits STAT3 phosphorylation and reduced transcription of STAT3 target genes Cyclin D1. More interestingly, PBX1 knockdown inhibits ccRCC cell viability, proliferation and cell cycle progression in vivo and in vitro. Thus, our results demonstrate that PBX1 plays an oncogenic role in ccRCC via JAK2/STAT3 pathway and indicate its potential application for the treatment of human ccRCC in future.

60 APPLIED LIFE SCIENCES↗

DOE OSTI2018

Power lines and impacts on biodiversity: A systematic review

Highlights: • Transmission lines (TL) may cause at least 28 different biotic impacts. • Biotic impacts result from 13 abiotic impacts. • Most impacts persist during operation phase. • There are few studies on habitat loss and the response of lower-mobility species. • To guide Terms of Reference preparation for TL licensing we make an impact framework - Abstract: The growth of energy consumption demands a large expansion of transmission line (TL) networks worldwide. The reduction of the environmental impacts of these infrastructures will depend on the effectiveness of environmental impact assessments, that ultimately depend on the quality of the screening phase, the scoping phase, and the prioritization of potential environmental consequences. We conducted the first systematic review that encompasses all known potential impacts on biodiversity of the installation and operation of energy TLs, documented in the scientific literature and in a sample of Environmental Impact Studies (EIS). We examined 206 articles and 19 EIS and identified 28 impacts that correspond to biotic outcomes at the individual, population and community levels. Although scientific interest on TL impact evaluation is increasing, most studies have been focused on vertebrate taxa, especially birds. There are few published studies concerning habitat loss and the responses of functional groups with lower mobility or sensitive to physical alterations, such as amphibians. Most impacts appear in early stages of a project, during TL construction, but persist during operation. We summarized the biotic impacts in a framework that may guide the screening of relevant impacts to be included in the EIS and consequently improve the outcomes of the environmental licensing process of transmission line projects.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2020

Intramolecular Electrostatic Effects on O 2 , CO 2 , and Acetate Binding to a Cationic Iron Porphyrin

Noncovalent electrostatic interactions are important in many biological and chemical reactions, especially those that involve charged intermediates. There has been a growing interest in using electrostatic ligand designs—placing charges in the second coordination sphere—to improve molecular reactivity, catalysis, and electrocatalysis. For instance, an iron porphyrin bearing four cationic ortho -trimethylanilinium groups, Fe( o -TMA), has been reported to be an exceptional electrocatalyst for both the carbon dioxide reduction reaction (CO 2 RR) and the oxygen reduction reaction (ORR). These reactions involve many different steps, and it is not evident which steps are affected by the four positive charges, or why. By comparing Fe( o -TMA) with the related iron-tetraphenylporphyrin, this work examines how covalently positioned charged groups affect substrate binding and other key pre-equilibria of both the ORR and CO 2 RR, specifically acetate, dioxygen, and carbon dioxide binding. This study is among the first to directly measure the effects of electrostatics on ligand-binding. The results show that adding electrostatic groups to a catalyst design often results in a complex interplay of multiple effects, including changes in pre-equilibria prior to substrate binding, combinations of through-space and inductive contributions, and effects of ionic strength and solution dielectric. The inverse half-order dependence of binding constant on ionic strength is proposed as a clear marker for an electrostatic effect. Overall, the conclusions provide guidance for the increasingly popular electrostatic ligand designs in catalysis and other reactivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2021

Broadband light emitting zero-dimensional antimony and bismuth-based hybrid halides with diverse structures

Low-dimensional organic–inorganic metal halides have recently attracted extensive attention because of their various structures and distinguished photoelectric properties. Herein, we report a series of new zero-dimensional organic–inorganic hybrid metal halides: (TMEDA) 3 Bi 2 Cl 12 ·H 2 O, (TMEDA) 3 Bi 2 Br 12 ·H 2 O, (TMEDA) 3 Sb 2 Br 12 ·H 2 O, and (TMEDA) 5 Sb 6 Cl 28 ·2H 2 O [TMEDA = N,N,N'·trimethylethylenediamine]. (TMEDA) 3 M 2 X 12 ·H 2 O (M = Bi or Sb, X = Cl or Br) crystallizes in the monoclinic space group P2 1 /n, and (TMEDA) 5 Sb 6 Cl 28 ·2H 2 O crystallizes in the orthorhombic space group Pnma. (TMEDA) 3 M 2 X 12 possesses a zero-dimensional structure with the metal halide ions of [MBr 6 ] 3- isolated by the organic TMEDA 2+ cations. Interestingly, the (TMEDA) 5 Sb 6 Cl 28 ·2H 2 O structure consists of a combination of corner-connected octahedra [Sb 4 Cl 18 ] 6- and edge-shared [Sb 2 Cl 10 ] 4- , which is quite rare. The light emission of all these compounds was measured, and (TMEDA) 3 Sb 2 Br 12 ·H 2 O exhibits the most intense luminescence. Upon 400 nm ultraviolet light excitation, (TMEDA) 3 Sb 2 Br 12 ·H 2 O exhibited strong broadband yellow emission centered at 625 nm with a full-width at half-maximum of ~150 nm originating from self-trapped excitons. In conclusion, this work suggests the possibility of new types of hybrid halides by introducing different metal centers and probing the structural evolution and photoluminescent properties, serving as a reference for the relationship between structure and luminescent performance and demonstrating their potential use as phosphors in light-emitting diodes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗