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At least 1,081 records · Page 60

Diffusion kinetics of 3 He in pyroxene and plagioclase and applications to cosmogenic exposure dating and paleothermometry in mafic rocks

In this study, we investigate the diffusivity of cosmogenic 3 He in a variety of plagioclase and pyroxene compositions, and its application to paleothermometry and exposure dating in these minerals, through stepwise degassing experiments. While cosmogenic 3 He has been utilized for exposure dating in pyroxene for decades due to its retentivity, plagioclase, often found along with pyroxene in mafic rocks, is generally less retentive of cosmogenic noble gas. However, the diffusivity of 3 He in either plagioclase or pyroxene has not yet been measured quantitatively. A challenge in measuring diffusion kinetics by step-degassing experiments in poorly retentive minerals is the fact that significant amounts of He can be lost prior to the experiment. To address this issue, we apply a forward “multiple diffusion domain” (MDD) inversion model that includes model predictions of initial gas loss during irradiation and storage of the samples to account for this observation and add constraints to the diffusion parameters. We find that 3 He diffusivity in plagioclase appears to be highly variable. This variability can be explained by the MDD inversion models' inability to constrain the diffusion parameters when significant gas has been lost during irradiation and/or prolonged storage prior to experiment analysis, resulting in an overestimation of 3 He retentivity. Plagioclase samples that were kept frozen after irradiation, to limit this initial gas loss, yielded the most reliable estimate of diffusion kinetics. We find that 3 He in plagioclase is diffusively lost at Earth's surface temperatures on a timescale of 100 years and is therefore unsuitable for surface temperature paleothermometry. On the contrary, we find cosmogenic 3 He in pyroxene to be retentive at Earth's surface temperatures on a 1-million-year timescale.

Bergelin, Marie [Berkeley Geochronology Center (BG↗

Radiation-detector optical-imaging device is of simplified construction

A simplified radiation detector was designed which employs an activated continuous front surface consisting of either the diffused or barrier type of semiconducting material with a grid structure on the nonactivated side of the detector. Its form may be either a rectangular coordinate or a polar coordinate system.

Source record↗

Pitfalls in thermal emission studies

Attention is called to several pitfalls that often beset investigators who make thermal emittance studies. The pitfalls mentioned include the following: (1) conflicting meanings of several frequently used terms as found in the literature, each meaning having authoritative sponsorship; (2) incomplete and hence potentially misleading descriptions of specimens on which reported data arc based; (3) reference to emissivity or remittance as a property of a surface rather than a volume property (influenced by the surface); (4) occasional omission of diffuse reflection from analyses of the optical properties of inhomogeneous bodies; (5) failure to observe the restrictions upon conditions that are required for validity of basic equations; (6)uncertainties as to the effective temperature, peculiar to specimens having low absorption indices; and (7) lack of suitable physical standards. Several suggestions are made for avoid­ing or minimizing the consequences of the pitfalls discussed.

THERMAL RADIATION↗

Lineaments that are artifacts of lighting, part G

Apollo 15 orbital photographs, particularly those taken at low sun elevation angles, are examined revealing grid patterns of lineaments. Preliminary results of experiments demonstrate that spurious lineaments and grid patterns can be produced and that the directions are dependent in part upon the position of the light source. The experiments were designed to duplicate the effect of bright sunlight reflecting from a hummocky surface with little or no diffuse light in the shadowed areas.

Howard, K. A.↗

A new electric field effect in silicon solar cells.

The phenomenon of high-resistivity silicon solar cells manifesting high open-circuit voltages previously observed only for cells made from low-resistivity silicon is shown to be caused by the presence of a shallow diffused region at the back surface of the cell. The basic cell structure is either n+, p, p+ or p+, n, n+. The high open-circuit voltage arises from the injection and accumulation of excess majority carriers in the bulk upon illumination or application of forward bias to the structure. A working model for the cell, designated a back surface field (BSF) cell, is described, and recent developments are cited.

Mandelkorn, J.↗

The application of holography to the visualization of shock patterns in a transonic compressor

This paper describes an experiment in the application of holographic interferometry to the visualization of flow in a transonic compressor. The principal objective of the study was to visualize the shock waves created by the rotor blades and to determine their relative orientation in three dimensions. The technique employed double-pulse, double-exposure holography to record the flow field through a plastic window built into the outer case over the rotor blades. Illumination was by diffuse reflection from the interior surfaces of the compressor. No other optical components in or on the compressor were used. The resulting holograms successfully showed the upstream bow shocks and, at high speed, the outer-most portion of the leading edge passage shock. Techniques were devised for locating these shocks in three dimensions and the results were compared with theoretical predictions. In all cases, the shock angles were somewhat larger than predicted by theory, and a distinct increase in angle near the outer wall was observed, which may be attributed to end wall boundary layer effects.

Hantman, R. G.↗

Investigation of the environmental change pattern of Japan

The author has identified the following significant results. ERTS-1 imagery clearly identifies the relationships between the status of erosion, effluent patterns affected by the coastal current, and the cultural construction activities. Simple photographic techniques can be used for detecting water mass distribution separately from cloud cover and also noise caused by reflected sunlight from wave surfaces. Polluted water does not diffuse continuously into the oceanic water, but forms masses in the water in the Kuroshio area. The polluted or turbid water in the area just north of the Tomogashima Channel, the south outlet of the Osaka Bay, shows that the northward tidal current runs in a clockwise eddy at the tidal period when the imagery was taken. Such an eddy-like pattern of tidal current had never been revealed by conventional oceanographic data. A front between an oceanic water mass and a polluted water mass runs in a NW-SE direction in the central part of the Osaka Bay. The patterns of turbid water discharged from the Kii River and Yoshino River show a northward tidal current in the North Kii Straits. The pattern of lighter turbid or polluted water located in the northwest region of the North Kii straits suggests the existence of a clockwise eddy in the straits.

Maruyasu, T.↗

Development of Low Cost Contacts to Silicon Solar Cells

Commercial electroless Cu solutions were used. Satisfactory adhesion (and fairly good cell performance) resulted from the use of thin layers of barrier metals such as Au, Cr or Pd. In these tests, photoresist masks were used to contact silicon P-type slices with diffused N+ and alloyed P+ surfaces; and electrolytic Cu solution was used to build up the contact thickness to provide good cell behavior. In addition some cells with evaporated Cr-Cu contacts were also made (along with evaporated Ti-Pd-Ag contacts as controls), with the intention of subjecting cells to gradually increasing heat-treatments, to determine whether Cu causes the cells to be inherently unstable.

Iles, P. A.↗

Investigation of Proposed Process Sequence for the Array Automated Assembly Task, Phase 2

The technological readiness of the proposed process sequence was reviewed. Process steps evaluated include: (1) plasma etching to establish a standard surface; (2) forming junctions by diffusion from an N-type polymeric spray-on source; (3) forming a p+ back contact by firing a screen printed aluminum paste; (4) forming screen printed front contacts after cleaning the back aluminum and removing the diffusion oxide; (5) cleaning the junction by a laser scribe operation; (6) forming an antireflection coating by baking a polymeric spray-on film; (7) ultrasonically tin padding the cells; and (8) assembling cell strings into solar circuits using ethylene vinyl acetate as an encapsulant and laminating medium.

Mardesich, N.↗

Shield topology in lightning transient control

A formalism in which the interaction of a system with an electromagnetic source is described by sets of scattering, penetrations, and propagation functions is reviewed and interpreted in the context of the lightning interaction problem. In this formalism, the system is decomposed into simple volumes separated by closed shield surfaces. These surfaces are nested and interconnected to produce higher levels of shielding and subvolumes within a given level. The interaction analysis uses scattering theory to define current and charge densities on the shield surface in conjunction with the diffusion, apertures, and transmission line analysis to define penetration through shield imperfections and propagation within the protected volume.

Vance, E. F.↗

Advances in tunable diode laser technology

The improvement of long-term reliability, the purification of mode properties, and the achievement of higher-temperature operation were examined. In reliability studies a slow increase in contact resistance during room temperature storage for lasers fabricated with In-Au or In-Pt contacts was observed. This increase is actually caused by the diffusion of In into the surface layer of laser crystals. By using a three layered structure of In-Au-Pt or In-Pt-Au, this mode of degradation was reduced. In characterizing the mode properties, it was found that the lasers emit in a highly localized, filamentary manner. For widestripe lasers the emission occurs near the corners of the junction. In order to achieve single-mode operation, stripe widths on the order of 8-10 micrometers are needed. Also, it was found that room temperature electroluminescence is possible near 4.6 micrometers.

Lo, W.↗

Large area low-cost space solar cell development

A development program to produce large-area (5.9 x 5.9 cm) space quality silicon solar cells with a cost goal of 30 $/watt is descibed. Five cell types under investigation include wraparound dielectric, mechanical wraparound and conventional contact configurations with combinations of 2 or 10 ohm-cm resistivity, back surface reflectors and/or fields, and diffused or ion implanted junctions. A single step process to cut cell and cover-glass simultaneously is being developed. A description of cell developments by Applied Solar Energy Corp., Spectrolab and Spire is included. Results are given for cell and array tests, performed by Lockheed, TRW and NASA. Future large solar arrays that might use cells of this type are discussed.

Baraona, C. R.↗

Oscillating-Crucible Technique for Silicon Growth

Technique yields better mixing of impurities and superior qualiity crystals. Accellerated motion stirs melt which reduces temperature gradients and decreases boundary layer for diffusion of impurities near growing surface. Results better mixing of impurities into melt, decrease in tendency for dendritic growth or cellular growth and crystals with low dislocation density. Applied with success to solution growth and Czochralski growth, resulting in large crystals of superior quality.

Daud, T.↗

Large area low-cost space solar cell development

A development program to produce 5.9 x 5.9 cm space quality silicon solar cells with a cost goal of 30 $/W is described. Cell types investigated include wraparound dielectric, mechanical wraparound and conventional contact configurations with combinations of 2 or 10 ohm/cm resistivity, back surface reflectors and/or fields, and diffused or ion implanted junctions. A single step process to cut cell and cover glass simultaneously is being developed. Results for cell and array tests are given. Large solar arrays that might use cells of this type are discussed.

Barona, C. R.↗

Kinetics of copper ion absorption by cross-linked calcium polyacrylate membranes

The absorption of copper ions from aqueous copper acetate solutions by cross-linked calcium acrylate membranes was found to obey parabolic kinetics similar to that found for oxidation of metals that form protective oxide layers. For pure calcium polyacrylate membranes the rate constant was essentially independent of copper acetate concentration and film thickness. For a cross-linked copolymer film of polyvinyl alcohol and calcium polyacrylate, the rate constant was much greater and dependent on the concentration of copper acetate. The proposed mechanism in each case involves the formation of a copper polyacrylate phase on the surface of the membrane. The diffusion of the copper ion through this phase appears to be the rate controlling step for the copolymer film. The diffusion of the calcium ion is apparently the rate controlling step for the calcium polyacrylate. At low pH, the copper polyacrylate phase consists of the normal copper salt; at higher pH, the phase appears to be the basic copper salt.

Philipp, W. H.↗

Engineering correlations of variable-property effects on laminar forced convection mass transfer for dilute vapor species and small particles in air

A simple engineering correlation scheme is developed to predict the variable property effects on dilute species laminar forced convection mass transfer applicable to all vapor molecules or Brownian diffusing small particle, covering the surface to mainstream temperature ratio of 0.25 T sub W/T sub e 4. The accuracy of the correlation is checked against rigorous numerical forced convection laminar boundary layer calculations of flat plate and stagnation point flows of air containing trace species of Na, NaCl, NaOH, Na2SO4, K, KCl, KOH, or K2SO4 vapor species or their clusters. For the cases reported here the correlation had an average absolute error of only 1 percent (maximum 13 percent) as compared to an average absolute error of 18 percent (maximum 54 percent) one would have made by using the constant-property results.

Gokoglu, S. A.↗

The Shuttle Orbiter high resolution accelerometer package experiment - Preliminary flight results

A description of the High Resolution Accelerometer Package (HiRAP) experiment, designed to measure rarefied flow aerodynamic accelerations, is given. The ground test calibration factors, as well as post-flight data processing techniques to extract aerodynamic accelerations, are discussed and applied to the recorded reentry data of the recent STS-6 Shuttle Orbiter flight. The ratio of the measured normal-to-axial aerodynamic accelerations during reentry is used to obtain the first flight measurement of the lift-to-drag ratio (L/D) of a winged entry vehicle in the rarefied flow flight regime. The preliminary result for the free-molecule flow L/D is 0.10 + or - 0.03. The initial flight results on L/D are compared with current predictions which are based upon theoretical and empirical considerations. The measured free-molecule flow L/D value is higher than predicted by a factor of about three, indicating that surface reflection is not completely diffuse as currently assumed. In the rarefied flow transition regime, the Shuttle data book-bridging formula fits the flight data adequately. Upper altitude density profiles are also deduced from the measurements and presented. The density profiles show a wave phenomena with amplitude of about 60 percent, relative to a standard model.

Blanchard, R. C.↗