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At least 1,081 records · Page 60

Solid-State Lighting Using Side-by-Side White Phosphorescent Organic Light-Emitting Diodes

White organic light-emitting diodes (WOLEDs) have become increasingly popular for use in solid-state illumination, where diffuse, large area light sources that achieve a high color rendering index and luminous power efficiency are desirable. Color-tunable emission, where the light source combines emission from multiple, separately addressed color elements, is conveniently provided by WOLEDs for the purpose of adapting the lighting source to a particular illumination requirement. In this work, we demonstrate a method for side-by-side positioning of monochromatic blue and yellow phosphorescent OLED stripes that are combined to create tunable white light, using a high resolution mechanical peel-off patterning method. We achieve a peak luminous power efficiency of 17.1 ± 0.3 lm W –1 and an external quantum efficiency of 11.8 ± 0.2% and demonstrate color tunability of the 1960 Commission Internationale d’Eclairage chromaticity coordinates from (u,v) = (0.33,0.36) to (0.12,0.32). This corresponds to a tuning rnge of the color rendering index from 74 ± 1 to 86 ± 1 and the correlated color temperature from 2000 to 8000 ± 500 K. Here, due to the nondestructive nature of the peel-off technique, patterned devices exhibit a lifetime comparable to conventional, shadow mask-patterned devices.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

A New Spin

The trouble was that the shuttle was still under development when that schedule was set. As time went on, the Shuttle had problems with its high pressure turbines, thermal protection tiles, engines, and more. The early launch dates had to be scrapped. NASA Headquarters told us, "We re going to delay your launch two years to allow more time for the Shuttle development to take place. You can slow your development accordingly." Right off the bat, we looked into the celestial mechanics and how they would affect us. The difficulty in launching a spacecraft to Jupiter changes on a year-to- year basis, in a cyclical pattern that repeats about every ten or twelve years. In order to achieve the velocity needed to get from low earth orbit to Jupiter, an upper stage is required in the Shuttle. For the 1982 launch the upper stage was adequate, but it could not provide the velocity we would need in 1984. This meant we would have to separate the Galileo probe from the Galileo orbiter before launch and put each of them on separate Shuttles with separate upper stages. When we told the folks at Headquarters this, they told us, "Okay we'll give you two Shuttle launches."

Casani, John↗

Photoluminescence Dynamics Defined by Exciton Trapping Potential of Coupled Defect States in DNA-Functionalized Carbon Nanotubes

Chemical reactions between semiconducting single-wall carbon nanotubes (SWCNTs) and single-stranded DNA (ssDNA) achieve spatially patterned covalent functionalization sites and create coupled fluorescent quantum defects on the nanotube surface, tailoring SWCNT photophysics for applications such as single-photon emitters in quantum information technologies. The evaluation of relaxation dynamics of photoluminescence (PL) from those coupled quantum defects is essential for understanding the nanotube electronic structure and beneficial to the design of quantum light emitters. Here, we measured the PL decay for ssDNA-functionalized SWCNTs as a function of the guanine content of the ssDNA oligo that dictates the red-shifting of their PL emission peaks relative to the band-edge exciton. We then correlate the observed dependence of PL decay dynamics on energy red-shifts to the exciton potential energy landscape, which is modeled using first-principles approaches based upon the morphology of ssDNA-altered SWCNTs obtained by atomic force microscopy (AFM) imaging. In this work, our simulations illustrate that the multiple guanine defects introduced within a single ssDNA strand strongly interact to create a deep exciton trapping well, acting as a single hybrid trap. The emission decay from the distinctive trapping potential landscape is found to be biexponential for ssDNA-modified SWCNTs. We attributed the fast time component of the biexponential PL decay to the redistribution of exciton population among the lowest energy bright states and a manifold of dark states emerging from the coupling of multiple guanine defects. The long lifetime component in the biexponential decay, on the other hand, is attributed to the redistribution of exciton population among different exciton trapping sites that arise from the binding of multiple ssDNA strands along the nanotube axis. AFM measurements indicate that those trapping sites are separated on average by ~8 nm along the nanotube axis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Characterization of applied fields for ion mobility separations in traveling wave based structures for lossless ion manipulations (SLIM)

Ion mobility (IM) is rapidly gaining attention for the analysis of biomolecules due to the ability to distinguish the shapes of ions. However, conventional constant electric field drift tube IM has limited resolving power, constrained by practical limitations on the path length and maximum applied voltage. The implementation of traveling waves (TW) in IM removes the latter limitation, allowing higher resolution to be achieved using extended path lengths. These can be readily obtainable in structures for lossless ion manipulations (SLIM), which are fabricated from electric fields that are generated by appropriate potentials applied to arrays of electrodes patterned on two parallel surfaces. In this work we have investigated the relationship between the various SLIM variables, such as electrode dimensions, inter-surface gap, and the TW applied voltages, that directly impact the fields experienced by ions. Ion simulation and theoretical calculations have been utilized to understand the dependence of SLIM geometry and effective electric field. The variables explored impact both ion confinement and the observed IM resolution in Structures for Lossless Ion Manipulations (SLIM) modules.

Hamid, Ahmed M.↗

Speech as a pilot input medium

The speech recognition system under development is a trainable pattern classifier based on a maximum-likelihood technique. An adjustable uncertainty threshold allows the rejection of borderline cases for which the probability of misclassification is high. The syntax of the command language spoken may be used as an aid to recognition, and the system adapts to changes in pronunciation if feedback from the user is available. Words must be separated by .25 second gaps. The system runs in real time on a mini-computer (PDP 11/10) and was tested on 120,000 speech samples from 10- and 100-word vocabularies. The results of these tests were 99.9% correct recognition for a vocabulary consisting of the ten digits, and 99.6% recognition for a 100-word vocabulary of flight commands, with a 5% rejection rate in each case. With no rejection, the recognition accuracies for the same vocabularies were 99.5% and 98.6% respectively.

Plummer, R. P.↗

Electron observations and ion flows from the Pioneer Venus Orbiter plasma analyzer experiment

Additional plasma measurements in the vicinity of Venus are presented. It is shown that (1) there are three distinct plasma electron populations - solar wind electrons, ionosheath electrons, and nightside ionosphere electrons; (2) the plasma ion flow pattern in the ionosheath is consistent with deflected flow around a blunt obstacle; (3) the plasma ion flow velocities near the downstream wake may, at times, be consistent with the deflection of plasma into the tail, closing the solar wind cavity downstream from Venus at a relatively close distance (within 5 Venus radii) to the planet; (4) there is a separation between the inner boundary of the downstream ionosheath and the upper boundary of the nightside ionosphere; and (5) during the first 4.5 months in orbit the measured solar wind plasma speed continued to vary, showing a number of high-speed, but generally nonrecurrent, streams.

Intriligator, D. S.↗

Correlation and analysis of oil flow data for an air-breathing missile model

This paper will present the results of an oil flow investigation on an airbreathing missile model. This oil flow study examined the flow around the model, which can be configured with both axisymmetric and two-dimensional inlets. Flow visualization analyses were conducted for both types of geometries by examining the surface flow patterns made visible by the oil flows for Mach numbers of 2.5 and 3.95. The analysis has shown the extent of flow spillage around the inlet which has helped explain the force and moment data collected during previous testing of the model. The oil flow data has also been used to develop guidelines for modeling the location of the crossflow separation line along inlet fairings. Finally, the oil flow analysis has been used to identify unique features of the boattail flow. These boattail flow characteristics have been correlated with previous oil flow analysis of noncircular body models. This paper demonstrates the use of this type of oil flow analysis in developing missile flow field analysis and aerodynamic predictions ranging from impact angle methods through Navier-Stokes methods.

Stoy, S. L.↗

Measurement Via Optical Near-Nulling and Subaperture Stitching

A subaperture stitching interferometer system provides near-nulling of a subaperture wavefront reflected from an object of interest over a portion of a surface of the object. A variable optical element located in the radiation path adjustably provides near-nulling to facilitate stitching of subaperture interferograms, creating an interferogram representative of the entire surface of interest. This enables testing of aspheric surfaces without null optics customized for each surface prescription. The surface shapes of objects such as lenses and other precision components are often measured with interferometry. However, interferometers have a limited capture range, and thus the test wavefront cannot be too different from the reference or the interference cannot be analyzed. Furthermore, the performance of the interferometer is usually best when the test and reference wavefronts are nearly identical (referred to as a null condition). Thus, it is necessary when performing such measurements to correct for known variations in shape to ensure that unintended variations are within the capture range of the interferometer and accurately measured. This invention is a system for nearnulling within a subaperture stitching interferometer, although in principle, the concept can be employed by wavefront measuring gauges other than interferometers. The system employs a light source for providing coherent radiation of a subaperture extent. An object of interest is placed to modify the radiation (e.g., to reflect or pass the radiation), and a variable optical element is located to interact with, and nearly null, the affected radiation. A detector or imaging device is situated to obtain interference patterns in the modified radiation. Multiple subaperture interferograms are taken and are stitched, or joined, to provide an interferogram representative of the entire surface of the object of interest. The primary aspect of the invention is the use of adjustable corrective optics in the context of subaperture stitching near-nulling interferometry, wherein a complex surface is analyzed via multiple, separate, overlapping interferograms. For complex surfaces, the problem of managing the identification and placement of corrective optics becomes even more pronounced, to the extent that in most cases the null corrector optics are specific to the particular asphere prescription and no others (i.e. another asphere requires completely different null correction optics). In principle, the near-nulling technique does not require subaperture stitching at all. Building a near-null system that is practically useful relies on two key features: simplicity and universality. If the system is too complex, it will be difficult to calibrate and model its manufacturing errors, rendering it useless as a precision metrology tool and/or prohibitively expensive. If the system is not applicable to a wide range of test parts, then it does not provide significant value over conventional null-correction technology. Subaperture stitching enables simpler and more universal near-null systems to be effective, because a fraction of a surface is necessarily less complex than the whole surface (excepting the extreme case of a fractal surface description). The technique of near-nulling can significantly enhance aspheric subaperture stitching capability by allowing the interferometer to capture a wider range of aspheres. More over, subaperture stitching is essential to a truly effective near-nulling system, since looking at a fraction of the surface keeps the wavefront complexity within the capability of a relatively simple nearnull apparatus. Furthermore, by reducing the subaperture size, the complexity of the measured wavefront can be reduced until it is within the capability of the near-null design.

Forbes, Greg↗

Effect of display update interval, update type, and background on perception of aircraft separation on a cockpit display on traffic information

The concept of a cockpit display of traffic information (CDTI) includes the integration of air traffic, navigation, and other pertinent information in a single electronic display in the cockpit. Concise display symbology was developed for use in later full-mission simulator evaluations of the CDTI concept. Experimental variables used included the update interval motion of the aircraft, the update type, (that is, whether the two aircraft were updated at the same update interval or not), the background (grid pattern or no background), and encounter type (straight or curved). Only the type of encounter affected performance.

Jago, S.↗

Nanoimprinted Chiral Plasmonic Substrates with Three-Dimensional Nanostructures

Here, we report a large-area fabrication method to prepare chiral substrates patterned with arrays of multilayer, three-dimensional nanostructures using a combination of nanoimprint lithography and glancing angle deposition. Several structures are successfully fabricated using this method, including L-shaped, twisted arc and trilayer twisted Au nanorod structures, demonstrating its generality. As one typical example, arrays of L-shaped nanostructures, consisting of two layers of orthogonally oriented Au nanorods separated by a Ge dielectric layer in the thickness direction, exhibit giant optical chirality in the infrared region with an experimentally achieved g-factor as high as 0.38. Electromagnetic simulations show that the optical chirality results from plasmon hybridization between the two orthogonal Au segments. To demonstrate scalability, a 1 cm 2 chiral substrate is fabricated with uniform chiral optical property. This method combines both high throughput and precise geometrical control and is therefore promising for applications of chiral metamaterials.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Designing Metabolic Division of Labor in Microbial Communities

ABSTRACT Microbes face a trade-off between being metabolically independent and relying on neighboring organisms for the supply of some essential metabolites. This balance of conflicting strategies affects microbial community structure and dynamics, with important implications for microbiome research and synthetic ecology. A “gedanken” (thought) experiment to investigate this trade-off would involve monitoring the rise of mutual dependence as the number of metabolic reactions allowed in an organism is increasingly constrained. The expectation is that below a certain number of reactions, no individual organism would be able to grow in isolation and cross-feeding partnerships and division of labor would emerge. We implemented this idealized experiment using in silico genome-scale models. In particular, we used mixed-integer linear programming to identify trade-off solutions in communities of Escherichia coli strains. The strategies that we found revealed a large space of opportunities in nuanced and nonintuitive metabolic division of labor, including, for example, splitting the tricarboxylic acid (TCA) cycle into two separate halves. The systematic computation of possible solutions in division of labor for 1-, 2-, and 3-strain consortia resulted in a rich and complex landscape. This landscape displayed a nonlinear boundary, indicating that the loss of an intracellular reaction was not necessarily compensated for by a single imported metabolite. Different regions in this landscape were associated with specific solutions and patterns of exchanged metabolites. Our approach also predicts the existence of regions in this landscape where independent bacteria are viable but are outcompeted by cross-feeding pairs, providing a possible incentive for the rise of division of labor. IMPORTANCE Understanding how microbes assemble into communities is a fundamental open issue in biology, relevant to human health, metabolic engineering, and environmental sustainability. A possible mechanism for interactions of microbes is through cross-feeding, i.e., the exchange of small molecules. These metabolic exchanges may allow different microbes to specialize in distinct tasks and evolve division of labor. To systematically explore the space of possible strategies for division of labor, we applied advanced optimization algorithms to computational models of cellular metabolism. Specifically, we searched for communities able to survive under constraints (such as a limited number of reactions) that would not be sustainable by individual species. We found that predicted consortia partition metabolic pathways in ways that would be difficult to identify manually, possibly providing a competitive advantage over individual organisms. In addition to helping understand diversity in natural microbial communities, our approach could assist in the design of synthetic consortia.

59 BASIC BIOLOGICAL SCIENCES↗

The use of ERTS-1 multispectral imagery for crop identification in a semi-arid climate

Crop identification using multispectral satellite imagery and multivariate pattern recognition was used to identify wheat accurately in Greeley County, Kansas. A classification accuracy of 97 percent was found for wheat and the wheat estimate in hectares was within 5 percent of the USDA's Statistical Reporting Service estimate for 1973. The multispectral response of cotton and sorghum in Texas was not unique enough to distinguish between them nor to separate them from other cultivated crops.

Stockton, J. G.↗

X-Ray Observations of Recurrence of Eruptive Flares and Active Regions

In a study of soft X-ray coronal images obtained with the Yohkoh spacecraft, two eruptive flares with remarkably similar X-ray structures were noted -- most remarkably because the flares occurred at the same solar location (approximately 10 degrees north latitude on the east limb) yet separated in time by three solar rotations. Between the times of the eruptions, the active region responsible for the first flare disappeared from Yohkoh images. An extremely similar X-ray active region replaced it by the third solar rotation. The recurring X-ray active region appearance and recurring flare activity after 86 days suggest that persistent subsurface flux emergence patterns might be responsible, and support previous arguments that 'active longitudes' exist.

Batchelor, David↗

Observational Evidence of Magnetic Reconnection in the Terrestrial Bow Shock Transition Region

We report evidence of magnetic reconnection in the transition region of the Earth's bow shock when the angle between the shock normal and the immediate upstream magnetic field is 65°. An ion‐skin‐depth‐scale current sheet exhibits the Hall current and field pattern, electron outflow jet, and enhanced energy conversion rate through the nonideal electric field, all consistent with a reconnection diffusion region close to the X‐line. In the diffusion region, electrons are modulated by electromagnetic waves. An ion exhaust with energized field‐aligned ions and electron parallel heating are observed in the same shock transition region. The energized ions are more separated from the inflowing ions in velocity above the current sheet than below, possibly due to the shear flow between the two inflow regions. The observation suggests that magnetic reconnection may contribute to shock energy dissipation.

Wang, Shan↗

Analysis of the Amplitude Response of a Two-Point and a Multi-Point Focused Laser Differential Interferometer

Experiments were performed with two different focused laser differential interferometer (FLDI) instruments to assess the relative amplitude response of each instrument to a traveling shockwave generated by a laser spark in air. The first FLDI instrument generated two slightly-separated measurement points, with each measurement point providing sensitivity to density fluctuations induced by the shockwave. By performing a cross-correlation between the signals obtained from each measurement point, the phase velocity of density fluctuations can be obtained. The second FLDI instrument generated a measurement line that was oriented parallel to the shockwave direction of travel with the resulting interference pattern sampled at multiple equally-spaced points along the line. As a result, this instrument provides density fluctuation measurement capability at multiple points simultaneously. When the measurement line is oriented parallel to the shockwave direction of travel, the phase velocity, rate of change of the phase velocity, and acceleration of density fluctuations traveling along each line can be obtained by performing a cross-correlation between points along the line. Numerical computations of the shockwave generated by the laser spark are used to simulate the response of each instrument and are compared to the experimental results. High-speed schlieren imaging has also been performed and is compared with the FLDI measurements and computational results.

Brett F. Bathel↗

Analysis of the Amplitude Response of a Two-Point and a Multi-Point Focused Laser Differential Interferometer

Experiments were performed with two different focused laser differential interferometer (FLDI) instruments to assess the relative amplitude response of each instrument to a traveling shockwave generated by a laser spark in air. The first FLDI instrument generated two slightly-separated measurement points, with each measurement point providing sensitivity to density fluctuations induced by the shockwave. By performing a cross-correlation between the signals obtained from each measurement point, the phase velocity of density fluctuations can be obtained. The second FLDI instrument generated a measurement line that was oriented parallel to the shockwave direction of travel with the resulting interference pattern sampled at multiple equally-spaced points along the line. As a result, this instrument provides density fluctuation measurement capability at multiple points simultaneously. When the measurement line is oriented parallel to the shockwave direction of travel, the phase velocity, rate of change of the phase velocity, and acceleration of density fluctuations traveling along each line can be obtained by performing a cross-correlation between points along the line. Numerical computations of the shockwave generated by the laser spark are used to simulate the response of each instrument and are compared to the experimental results. High-speed schlieren imaging has also been performed and is compared with the FLDI measurements and computational results.

Interferometry↗

Entropy production fluctuations encode collective behavior in active matter

We derive a general lower bound on distributions of entropy production in interacting active matter systems. The bound is tight in the limit that interparticle correlations are small and short-ranged, which we explore in four canonical active matter models. In all models studied, the bound is weak where collective fluctuations result in long-ranged correlations, which subsequently links the locations of phase transitions to enhanced entropy production fluctuations. We develop a theory for the onset of enhanced fluctuations and relate it to specific phase transitions in active Brownian particles. Furthermore, we also derive optimal control forces that realize the dynamics necessary to tune dissipation and manipulate the system between phases. In so doing, we uncover a general relationship between entropy production and pattern formation in active matter, as well as ways of controlling it.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Experimental study of three-dimensional separated flow surrounding a hemisphere-cylinder at incidence

Detailed experimental surface pressure coefficient measurements, obtained for a hemisphere-cylinder-flare model in a low supersonic flow (freestream M = 1.2) at various angles of attack (0 deg to 27.5 deg), have been analyzed. The pressure values for each angle of attack were smoothed and checked against their respective oil-flow photographs. The smoothed results were then used to validate a theory which relates the number and type of singular points observed in the oil-flow patterns with local surface-pressure extrema.

Meade, Andrew J., Jr.↗