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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,081 records · Page 60

Synthesis of Silicalite Membrane with an Aluminum-Containing Surface for Controlled Modification of Zeolitic Pore Entries for Enhanced Gas Separation

The separation of small molecule gases by membrane technologies can help performance enhancement and process intensification for emerging advanced fossil energy systems with CO 2 capture capacity. This paper reports the demonstration of controlled modification of zeolitic channel size for the MFI-type zeolite membranes to enhance the separation of small molecule gases such as O 2 and N 2 . Pure-silica MFI-type zeolite membranes were synthesized on porous α-alumina disc substrates with and without an aluminum-containing thin skin on the outer surface of zeolite membrane. The membranes were subsequently modified by on-stream catalytic cracking deposition (CCD) of molecular silica to reduce the effective openings of the zeolitic channels. Such a pore modification caused the transition of gas permeation from the N 2 -selective gaseous diffusion mechanism in the pristine membrane to the O 2 -selective activated diffusion mechanism in the modified membrane. The experimental results indicated that the pore modification could be effectively limited within the aluminum-containing surface of the MFI zeolite membrane to minimize the mass transport resistance for O 2 permeation while maintaining its selectivity. The implications of pore modification on the size-exclusion-enabled gas selectivity were discussed based on the kinetic molecular theory. In light of the theoretical analysis, experimental investigation was performed to further enhance the membrane separation selectivity by chemical liquid deposition of silica into the undesirable intercrystalline spaces

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Investigation of Extreme Leading-Edge Roughness on Thick Low-Drag Airfoils to Indicate Those Critical to Separation

Several airfoils, Including a conventional NACA 23021 and some low-drag airfoils for which the thickness had been increased to the point that they were considered doubtfully conservative with respect to separation, were investigated as smooth airfoils and after the application of a standard roughness. The results show some of the airfoils to be critical to separation resulting from such flow disturbances. It is concluded, pending the further investigation of separation difficulties, that airfoil sections falling definitely within the conservative range should be used.

AIRFOILS - NACA 65,3-418 - CHAR & MOMENTS - LOW-DR↗

He II Liquid/Vapor Phase Separator for Large Dynamic Range Operation

A phase separator, which separates helium vapor from liquid superfluid helium (He II), is an indispensable device for space cryogenics. The most recent approach to the Space Infrared Telescope Facility (SIRTF) uses a new design concept in which only the detector package is cold at launch, the remainder of the telescope being subsequently cooled to operating temperature on orbit. Therefore, a large dynamic operational range is required of the cryogen system. This is a report of initial laboratory test results with candidate porous plugs as phase separators. Mass flow rates and pressure and temperature differences across a porous plug were measured in this experiment. Relatively large mass flow rates were observed even at small pressure differences. In the high mass flow rate region, a hysteresis was observed with increases and decreases of the pressure difference. A linear theory is proposed and compared with experimental data to explain several phenomena observed in this system.

Phase Separator, Space Cryogenics↗

NASA Armstrong's Approach to Store Separation Analysis

Presentation will an overview of NASA Armstrong's store separation capabilities and how they have been applied recently. Objective of the presentation is to brief Generation Orbit and other potential partners on NASA Armstrong's store separation capabilities. It will include discussions on the use of NAVSEP and Cart3D, as well as some Python scripting work to perform the analysis, and a short overview of this methodology applied to the Towed Glider Air Launch System. Collaboration with potential customers in this area could lead to funding for the further development of a store separation capability at NASA Armstrong, which would boost the portfolio of engineering expertise at the center.

launch operations↗

The Two-Phase Flow Separator Experiment Breadboard Model: Reduced Gravity Aircraft Results

Life support systems in space depend on the ability to effectively separate gas from liquid. Passive cyclonic phase separators use the centripetal acceleration of a rotating gas-liquid mixture to carry out phase separation. The gas migrates to the center, while gas-free liquid may be withdrawn from one of the end plates. We have designed, constructed and tested a breadboard that accommodates the test sections of two independent principal investigators and satisfies their respective requirements, including flow rates, pressure and video diagnostics. The breadboard was flown in the NASA low-gravity airplane in order to test the system performance and design under reduced gravity conditions.

phase separation↗

Space Launch System Liftoff and Separation Dynamics Analysis Tool Chain

A flexible, hierarchical tool chain that is being applied to NASA’s Space Launch System (SLS) for critical dynamics phenomena is described. This tool chain, called CLVTOPS, is used to investigate lateral liftoff movement of the vehicle as it departs and clears the mobile launch tower and separation of the two solid rocket boosters without collision with the core stage and payload. The toolset’s architecture was configured to take advantage of a modern software-engineering approach for maximum flexibility and utilization of open-source simulations and associated tools. As opposed to a “monolithic” approach, scripting languages were used to “bind” together a tool chain to configure and organize input data, execute and produce analysis results, and post-process these results to facilitate a rapid iterative analysis process to quickly address issues and pursue alternatives with emphasis on analysis automation. Key capabilities in the tool chain include processing and mining of very large data sets, a wide range of graphical depictions, and high-fidelity, physics-based simulations. The paper begins with a problem description and the motivation for liftoff and separation dynamics analysis followed by a historical survey of dynamics analyses for previous NASA human-rated launch vehicles. Details of the tool chain and its components are then introduced divided, first, into description of the scripting language architecture used to “bind” the simulation tools, programs, and scripts together and, second, the physics models and simulations. Representative analyses and data products are shown for liftoff and booster separation dynamics that provide in-depth insight to the tool chain’s capabilities. Supporting activities such as simulation tool chain verification, version archiving and data management, and training are addressed. The paper concludes with case examples on how the tool chain can be tailored to related aerospace dynamics analyses, both large and small. These patterns and techniques for SLS dynamics tool construction can be applied for other aerospace simulations.

6DOF↗

Space Launch System Liftoff and Separation Dynamics Analysis Tool Chain

A flexible, hierarchical tool chain that is being applied to NASA’s Space Launch System (SLS) for critical dynamics phenomena is described. This tool chain, called CLVTOPS, is used to investigate lateral liftoff movement of the vehicle as it departs and clears the mobile launch tower and separation of the two solid rocket boosters without collision with the core stage and payload. The toolset’s architecture was configured to take advantage of a modern software engineering approach for maximum flexibility and utilization of open-source simulations and associated tools. As opposed to a “monolithic” approach, scripting languages were used to “bind” together a tool chain to configure and organize input data, execute and produce analysis results, and post-process these results to facilitate a rapid, iterative analysis process to quickly address issues and pursue alternatives with emphasis on analysis automation. Key capabilities in the tool chain include processing and mining of very large data sets, a wide range of graphical depictions, and high-fidelity, physics-based simulations. The paper begins with a problem description and the motivation for liftoff and separation dynamics analysis followed by a historical survey of dynamics analyses for previous NASA human-rated launch vehicles. Details of the tool chain and its components are then introduced and divided, first, into description of the scripting language architecture used to “bind” the simulation tools, programs, and scripts together and, second, the physics models and simulations. Representative analyses and data products for liftoff and booster separation dynamics are shown in order to provide in-depth insight into the tool chain’s capabilities. Supporting activities such as simulation tool chain verification, version archiving and data management, and training are addressed. The paper concludes with case examples on how the tool chain can be tailored to related aerospace dynamics analyses, both large and small. The flexibility and versatility of this tool chain in supporting analyses of such a diverse range of aerospace applications demonstrates the feasibility of applying these patterns and techniques for tool construction to other aerospace simulations.

6DOF↗

Mars Pathfinder Cruise Stage/Entry Vehicle Separation Dynamics

Prior to atmospheric entry, Mars Pathfinder flight system will separate its entry vehicle from its cruise stage, and establish the entry conditions for a passive and unconventional entry, descent, and landing approach. This paper summarizes a separation dynamics analysis conducted to demonstrate that the cruise separation system design is viable and ensure that adequate design margins exist with the effects from parameter uncertainty included.

Pathfinder↗

Functional Allocation Approach for Separation Assurance for Remotely Piloted Aircraft

A functional analysis framework is employed with the objective of exploring the separation assurance function for the remotely piloted aircraft system. The architecture of the remotely piloted aircraft system—highlighting several of the component systems and the functions resident onboard the remotely piloted aircraft and in the ground control station—is described to provide the context for understanding the complexity of the said system for a detailed functional analysis. The interactions between the agents of the separation assurance function belonging to the air traffic service provider, remotely piloted aircraft system operator and remotely piloted aircraft are described. Separation assurance by air traffic control, remain well clear by the remotely piloted aircraft system and collision avoidance onboard the remotely piloted aircraft are briefly discussed. The functional analysis framework is illustrated by relating the agents to the actions of (a) acquiring the surveillance information, (b) checking for conflicts, (c) creating the solutions for resolving conflicts and (d) implementing the conflict resolution solutions. This example is offered as a template by which a more detailed functional analysis of this and other functions could be developed. The architecture of the remotely piloted aircraft system is described to aid this process.

functional analysis↗

Functional Allocation Approach for Separation Assurance for Remotely Piloted Aircraft

A functional analysis framework is employed with the objective of exploring the separation assurance function for the remotely piloted aircraft system. The architecture of the remotely piloted aircraft system—highlighting several of the component systems and the functions resident onboard the remotely piloted aircraft and in the ground control station—is described to provide the context for understanding the complexity of the said system for a detailed functional analysis. The interactions between the agents of the separation assurance function belonging to the air traffic service provider, remotely piloted aircraft system operator and remotely piloted aircraft are described. Separation assurance by air traffic control, remain well clear by the remotely piloted aircraft system and collision avoidance onboard the remotely piloted aircraft are briefly discussed. The functional analysis framework is illustrated by relating the agents to the actions of (a) acquiring the surveillance information, (b) checking for conflicts, (c) creating the solutions for resolving conflicts and (d) implementing the conflict resolution solutions. This example is offered as a template by which a more detailed functional analysis of this and other functions could be developed. The architecture of the remotely piloted aircraft system is described to aid this process.

Functional analysis↗

Wake Disturbance-Based Separation Evaluation for Urban Air Mobility Aircraft

This paper builds upon previous research to evaluate Urban Air Mobility (UAM) flight dynamics in the presence of wake disturbances. A model for fixed-wing-generated wake effects is applied to a Revolutionary Vertical Lift Technology (RVLT) Lift+Cruise UAM trail aircraft operating in the fixed-wing Cruise configuration. The wake effects are evaluated at various longitudinal and latitudinal separation configurations to determine the most hazardous wake encounter situation. Trim calculations and closed-loop simulations show a trailing aircraft flying directly into a wake vortex as the most hazardous scenario. Furthermore, trailing behind a larger aircraft at similar speeds greatly increases the safe separation distance. These considerations indicate a need for dynamic pairwise separation criteria to enable dense Advanced Air Mobility (AAM) operations while maintaining safety.

Urban Air Mobility↗

Ligand-Assisted Separation of Rare Earth Elements via Capillary Electrophoresis

Rare earth elements (REEs) are a class of critical materials vital in applications such as EVs, batteries, and defense weapons systems. These elements are found primarily in ores, and due to their similar chemical behavior, the challenge remains to find an effective means of separation. The addition of ligands of varying charge, size, denticity, etc. can help to increase separation, yet the mechanistic behavior and factors influencing separation are still poorly understood. Here, iminodiacetic acid (IDA) is used to exploit and maximize differences in electrophoretic mobilities between adjacent REEs. Mobilities and diffusion coefficients of REEs in aqueous media are measured via CE and are compared to MD and FEM simulations.

36 MATERIALS SCIENCE↗

Economic and Sustainability Assessment on Bio-Based 2,3-BDO Separation Approaches for Sustainable Aviation Fuel Production

Sustainable aviation fuel (SAF) plays a critical role in aviation decarbonization. SAF can be derived from lignocellulosic biomass, such as corn stover, via 2,3-butanediol (BDO) intermediate. BDO undergoes downstream upgrading, including dehydration, oligomerization, and hydrotreating, to make the hydrocarbon blend stock like SAF. Separating BDO from a fermentation broth is challenging. Water is more volatile than BDO, so energy consumption for ordinary distillation is prohibitively high. For BDO to be a feasible intermediate for sustainable biofuels such as SAF, the total energy usage for the BDO separation target was set to be no greater than 30% of its lower heating value (LHV). We have developed and explored less energy intensive separation technologies for processing dilute fermentation BDO broth into suitable feed for downstream upgrading. The combined economic and sustainability assessment was performed to assess the feasibility of select cost-effective process designs and comparisons with baseline technology (i.e., cascade vacuum distillation).

BIOMASS FUELS↗

Advances in Integral and Separate Effects Experiments for Water Cooled Small Modular Reactors

This paper focuses on the progress being made in water-cooled small modular reactor (SMR) advanced integral effects and separate effects experiments for reactor licensing. SMRs, considered modular in design, are mostly factory-built and then shipped to the reactor site. Of the several types of SMR designs available, water-cooled SMRs are likely to receive regulatory approval faster than others, as most of the technologies involved (e.g., the fuel and coolant technologies) are matured. However, the unique safety systems of SMRs, which depend on specific SMR design features, require integral and separate effects experiments to achieve reactor licensing. Thus, of the many SMR designs being proposed, only a few have successfully undergone licensing and reached the final development and demonstration stage. Many nuclear vendors and newcomer companies are investing millions of dollars to develop integral and separate effects testing facilities for preparing final safety analysis reports to include in licensing applications. Development and analysis of these experimental facilities is costly and takes about four to five years. The unique challenges involved can be reduced when stakeholders synergistically apply lessons learned, knowing the critical role played by advancements in experiments that support the licensing of SMR safety systems. Identification of knowledge/research gaps with the phenomena identification and ranking table (PIRT) and designing experimental facilities focusing on the phenomena of interest (POI) and figures of merit (FOMs) are pivotal to select the critical path to successful design demonstration and licensing application.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Reduction of the Waste Occupied Area by Nuclide Separation and Horizontal Emplacement of the Waste Packages - 20422

Two of the key objectives for realizing the advanced nuclear fuel cycle are to reduce the volume of high-level radioactive waste and to reduce the foot-print of the geological repository. To achieve these objectives, research and development on nuclide separation technologies is a prerequisite. In this context, it is necessary to consider the vitrification conditions and the design of the geological repository where separation technologies would be implemented to achieve effective reductions in the volume of vitrified waste and the foot-print of the geological repository. In this study, the effects of the vitrification conditions on the number of vitrified waste units and the disposal area were evaluated, based on the assumption that separation of Cs and Sr from the spent nuclear fuel had been performed. In addition, with reference to the design of the geological repository, the impact on the foot-print of the repository for different emplacement methods of the waste packages was examined. As a result, it was clarified that the waste-occupied area could be reduced by horizontal emplacement of the vitrified waste with low heat generation. In addition, it was demonstrated that a low waste-loaded vitrified waste contributed to a reduction in the foot-print of the geological repository in the case of horizontal emplacement, although the number of vitrified waste units increased. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Fundamental Data Supporting Novel Radiochemical Separations

Rapid chemical separation of actinide, lanthanide, and other radioactive elements is an important pursuit in the field of radioanalytical and nuclear chemistry. Vital to the development of advanced systems to achieve such separations is the determination of elements’ distribution coefficients (Kd values) for chromatographic resins. In this study, batch contacts of 68 elements were performed with various commercially available resins, and the resulting distribution coefficients were determined by Inductively Coupled Plasma – Mass Spectrometry Analysis (ICP-MS). An evaluation of the resulting Kd data for elements on the resins was performed. Finally, this work presents prototype flowsheets for streamlined separation of radioisotopes from a variety of complex matrices.

Distribution Coefficient↗

Thermomechanical Separation of Biogenic and Non-biogenic Carbon from Non-Recyclable MSW

The effective separation of biogenic and non-biogenic carbon from non-recyclable municipal solid waste (n-MSW) presents a significant challenge in the United States. Currently, there are no efficient methods available to address this issue, hindering the potential for maximizing waste utilization and reducing landfilling rates. This project aims to develop and implement a combine thermomechanical separation techniques to separate biogenic and non-biogenic carbon within n-MSW, ultimately facilitating greater resource recovery and enhancing the efficiency and environmental impact of waste management practices.

09 - BIOMASS FUELS↗

A Machine Learning Method for the Forensics Attribution of Separated Plutonium

Plutonium (Pu) source attribution would be a powerful tool to support nuclear nonproliferation efforts. This capability to find the source of a Pu sample would act as a deterrent to smuggling efforts, and also help regulatory agencies verify declared nuclear activities. Work at Texas A&M University yielded a nuclear forensics methodology, which is capable of determining separated Pu’s reactor of origin, fuel burnup, and the time since irradiation (TSI)—three parameters of interest. The methodology used a set of ten intra-element isotopic ratios found in separated Pu, which was compared to a library of isotopic ratio values produced using neutronics simulations for reactors of interest. By calculating the probability that unknown Pu sample’s isotopic ratio set matched a set in the library, the methodology could predict the three parameters of interest of the sample. One shortcoming of this methodology was an inability to correctly attribute spoofed Pu, where Pu sourced from two different reactors or two different fuel burnup levels are mixed. A new methodology to rectify this vulnerability using machine learning (ML) technique is developed, instead of the maximum likelihood calculation previously used and the results are satisfactory. The ML approach leverages the existing simulated data for training the algorithm, but use them efficiently by only using intra-element isotope ratios that contribute to the attribution one of the three parameters at a time. Previously, all isotope ratios were used to attribute all three parameters together. The new methodology attributes the Pu parameters in three steps, one for each parameter, rather than resolving all of the three parameters simultaneously like the previous maximum likelihood approach. First, a support vector machine classifier with a set of seven isotopic ratios finds the reactor of origin and a set of regression models trained using gaussian process predicts the burnup with a different set of seven isotopes. Finally, TSI is calculated analytically using decay equations. Thus far, the new methodology is capable of attributing pure Pu samples and has been validated using experimental data. The next step will to be augment the classifier training data set with spoofed Pu data.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗