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DOE OSTI2022

Optimization of Residential Air Source Heat Pump using Low–Global Warming Potential Refrigerants

We report low–global warming potential refrigerants can significantly reduce the direct emissions of CO 2 originating from HVAC systems. However, high-efficiency systems are needed to reduce indirect CO 2 emissions. In this study, an R410A residential 5-Ton heat pump was optimized using R32, R454A, R454B, R454C, and R455A. Among these options, R455A and R454C have the lowest global warming potential but have lower volumetric capacity and high glide. Optimization results using 5 mm tube heat exchangers showed 12.4% to 19.1% efficiency improvements and 13% to 33% reduction in CO 2 emissions.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

NASA NTRS1985

Observations of potential ultra high energy gamma-ray sources above 10(15) eV

The Haverah Park 50 m water-Cerenkov array has been used to examine a number of periodic sources for ultra high energy gamma-ray emission above 10 to the 15th power eV. The data, recorded between 1 Jan. 1979 and 31 Dec. 1984, feature a modest angular resolution of approx 3 deg with millisecond arrival time resolution post 1982. The sources investigated include the Crab pulsar, Her X-1, Au0115 + 63 and Geminga. All objects have been detected by workers in the TeV region, with varying degrees of confidence.

Lambert, A.↗

NASA NTRS2016

Genesis Solar Wind Science Canister Components Curated as Potential Solar Wind Collectors and Reference Contamination Sources

The Genesis mission collected solar wind for 27 months at Earth-Sun L1 on both passive and active collectors carried inside of a Science Canister, which was cleaned and assembled in an ISO Class 4 cleanroom prior to launch. The primary passive collectors, 271 individual hexagons and 30 half-hexagons of semiconductor materials, are described in. Since the hard landing reduced the 301 passive collectors to many thousand smaller fragments, characterization and posting in the online catalog remains a work in progress, with about 19% of the total area characterized to date. Other passive collectors, surfaces of opportunity, have been added to the online catalog. For species needing to be concentrated for precise measurement (e.g. oxygen and nitrogen isotopes) an energy-independent parabolic ion mirror focused ions onto a 6.2 cm diameter target. The target materials, as recovered after landing, are described in. The online catalog of these solar wind collectors, a work in progress, can be found at: http://curator.jsc.nasa.gov/gencatalog/index.cfm This paper describes the next step, the cataloging of pieces of the Science Canister, which were surfaces exposed to the solar wind or component materials adjacent to solar wind collectors which may have contributed contamination.

Allton, J. H.↗

DOE OSTI2025

Precision gyroscope from the helicity of light

We describe a gyroscope that measures rotation based on the effects of the rotation on the polarization of light. Rotation induces a differential phase shift in the propagation of left- and right-circularly polarized light and this phase shift can be measured in suitably designed interferometric setups. The signal in this setup is independent of the frequency of light, unlike various sources of noise such as vibrations, which cause phase shifts that depend on the frequency. Such vibrations are the practical limit on the sensitivity of conventional Sagnac-style optical interferometers that are typically used as gyroscopes. In the proposed setup, one can potentially mitigate this source of noise by simultaneously using two (or more) sources of light that have different frequencies. The signal in this setup scales with the total storage time of the light. Due to its frequency independence, it is thus most optimal to measure the signal using superconducting radio-frequency systems where the high finesse of the available cavities enables considerably longer storage times than is possible in an optical setup.

47 OTHER INSTRUMENTATION↗

NASA NTRS1991

Sources and geochemical evolution of cyanide and formaldehyde

The major source of cyanide has, in current paleoatmospheric models, been assumed to be the reaction of photodissociated thermospheric nitrogen with a limiting supply of stratospheric methane. Formaldehyde may be produced with more ease from an atmosphere of carbon dioxide as the dominant carbon species, and from carbonate in solution or sorbed in double layer hydroxide minerals. Potentially more important sources for cyanide and other carbon containing molecules are the partially photoprotected northern and southern auroral ovals where continuous currents reaching several mega-amperes induce ion-molecule reactions, extending into the lower stratosphere. In simulated environments of this kind, the cyanide ion is known to be produced from oxidized carbon species potentially more abundant than methane. Rainout of cyanide and formaldehyde place them in two different geochemical reaction reservoirs. In the anoxic Archean hydrosphere, about 1mM in Fe2(+), the cyanide ion would have been efficiently converted to the stable ferrocyanide complex Fe(CN) sub 6(4-), protecting it from the commonly considered fate of decomposition by hydrolysis, and eventually incorporating it in pyroaurite type minerals, most efficiently in green rust where it converts to insoluble ferriferrocyanide, prussian blue.

Arrhenius, G.↗

DOE OSTI2021

The metabolic origins of non-photorespiratory CO 2 release during photosynthesis: a metabolic flux analysis

Respiration in the light (R L ) releases CO 2 in photosynthesizing leaves and is a phenomenon that occurs independently from photorespiration. Since R L lowers net carbon fixation, understanding R L could help improve plant carbon-use efficiency and models of crop photosynthesis. Although R L was identified more than 75 years ago, its biochemical mechanisms remain unclear. To identify reactions contributing to R L , we mapped metabolic fluxes in photosynthesizing source leaves of the oilseed crop and model plant camelina (Camelina sativa). We performed a flux analysis using isotopic labeling patterns of central metabolites during 13 CO 2 labeling time course, gas exchange, and carbohydrate production rate experiments. To quantify the contributions of multiple potential CO 2 sources with statistical and biological confidence, we increased the number of metabolites measured and reduced biological and technical heterogeneity by using single mature source leaves and quickly quenching metabolism by directly injecting liquid N 2 ; we then compared the goodness-of-fit between these data and data from models with alternative metabolic network structures and constraints. Our analysis predicted that R L releases 5.2 μmol CO2 g –1 FW h –1 of CO 2 , which is relatively consistent with a value of 9.3 μmol CO 2 g –1 FW h –1 measured by CO 2 gas exchange. The results indicated that ≤10% of R L results from TCA cycle reactions, which are widely considered to dominate R L . Further analysis of the results indicated that oxidation of glucose-6-phosphate to pentose phosphate via 6-phosphogluconate (the G6P/OPP shunt) can account for >% of CO 2 released by R L .

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2021

Potential of Utilizing Thermal Energy Storage Integrated Ground Source Heat Pump System to Reshape Electricity Demand in the United States

Each year, more than 20% of electricity generated in the United States is consumed for meeting the thermal demands (e.g., space cooling, space heating, and water heating) in residential and commercial buildings. Integrating thermal energy storage (TES) with building’s HVAC systems has the potential to reshape the electric load profile of the building and mitigate the mismatch between the renewable generation and the demand of buildings. A novel ground source heat pump (GSHP) system integrated with underground thermal energy storage (UTES) has been proposed to level the electric demand of buildings while still satisfying their thermal demands. This study assessed the potential impacts of the proposed system with a bottom-up approach. The impacts on the electricity demand in various electricity markets were quantified. The results show that, within the capacity of the existing electric grids, the maximum penetration rate of the proposed system in different wholesale markets could range from 51% to 100%. Altogether, about 46 million single-family detached houses can be retrofitted into the proposed system without increasing the annual peak demand of the corresponding markets. By implementing the proposed system at its maximum penetration rate, the grid-level summer peak demand can be reduced by 9.1% to 18.2%. Meanwhile, at the grid level, the annual electricity consumption would change by –12% to 2%. The nationwide total electricity consumption would be reduced by 9%.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

DOE OSTI2024

Towards the Development of Molten Salt Reactor Multiphysics Modeling Capabilities: Depletion, Thermochemistry, Reactor Dynamics, and Species Tracking

This report documents the simulation and modeling work performed under the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program, utilizing the tools and codes developed under the program. The focus in this Fiscal Year (FY) is on the depletion, thermochemistry, reactor dynamics, and species transport in MSRs. The fission products travelling in the entire primary loop is unique in MSRs. There are many physical/chemical mechanisms that can significantly affect the fission products concentration in the fuel salt, e.g., diffusion into gas bubbles, diffusion in the core moderators, deposition on the surface of structures/pipes, etc. The fission product concentration in the fuel salt can potentially affect the neutronics, system dynamics, chemical potentials, etc., so accurately predicting the fission products distribution in the primary loop is important. Under the main objective, different activities are pursued to assess the NEAMS tools applicability for a variety of areas on species transport, including the depletion analyses using Griffin (fission product source), the redox potential assessment at different depletion points, the assessment of xenon transport effect on the neutronics and reactor dynamics, a survey of correlations for calculating the mass transfer coefficient of different fission products, etc.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

NASA NTRS1975

Preliminary evaluation of the contaminant induced environment for the space shuttle orbiter

A preliminary evaluation of the on-orbit induced environment from identified major sources of contamination for the STS shuttle orbiter is presented. A contamination computer mathematical model is discussed that was used to develop the description and predictions of the induced environment along with the extent and physical makeup of the molecular induced environment from these sources. The predicted induced molecular environment from each source is evaluated against current Space Shuttle Program on-orbit contamination control criteria. The flash evaporator vents and the VCS 25-lb thrust engines are shown to significantly exceed applicable contamination control criteria and were the subject of extensive evaluation. Preliminary conclusions concerning the contaminant potential of these sources along with recommendations for various measures of contamination control regarding the shuttle orbiter design and operational activities are made.

Bareiss, L. E.↗

DOE OSTI2020

Survey and Assessment of the Ocean Renewable Energy Resources in the US Gulf of Mexico

This study was conducted by the National Renewable Energy Laboratory (NREL) and funded by the Bureau of Ocean Energy Management (BOEM). It provides a comprehensive feasibility assessment of multiple offshore renewable energy technologies in the Gulf of Mexico (GoM) to inform BOEM's strategic plans related to possible Outer Continental Shelf alternative energy leasing activities in the GoM. In coordination with Gulf Coast states, the study includes some information on offshore renewable energy potential in state waters for future energy planning. The goal of the study is to survey potential offshore renewable energy sources in the GoM and quantify their feasibility relating to resource adequacy, technology maturity, and the potential for competitive cost. The study provides a review of available technologies and concepts for generating offshore renewable energy, including a high-level assessment of the current state of each technology and its potential for future advances. It provides a breakdown of resource capacity for each renewable energy technology and a recommendation that offshore wind be pursued for future study as the most promising technology. The renewable technologies that were considered include offshore wind, wave energy, tidal energy, ocean current energy, offshore solar energy, ocean thermal energy conversion (OTEC), cold water source cooling, and hydrogen (as a storage medium to utilize existing pipeline infrastructure). The resource capacity for each of these renewable energy sources was quantified for both the gross resource capacity potential (gross resource) and the technical resource capacity potential (technical resource) using the methodology described in an earlier NREL report. Many of these sources are very immature from a commercial perspective, which makes some of the comparisons difficult. In many cases, new methods were developed to estimate nominal power density for each technology type, which were necessary to convert the resource areas into deployable gross and technical resource capacity potentials.

17 WIND ENERGY↗

DOE OSTI2019

Sources and Assessment of Mercury and Other Heavy Metal Contamination in Soils Surrounding the Wuda Underground Coal Fire Area, Inner Mongolia, China

Concentrations of mercury and other heavy metals were measured in soils surrounding the Wuda Coalfield, Inner Mongolia where underground coal fires are regarded as an important contamination source. Soil samples at the downwind direction were nearly all enriched mercury in surface layers, with their concentrations ~ 10 times higher than those from upwind soils. Mercury concentrations generally increased along soil profiles upward, indicative of increasing atmospheric mercury deposition in recent decades. We suggest that underground coal fire emissions were the potential mercury contamination source and the key factor controlling mercury enrichment in soils. Other heavy metals showed no clear spatial and vertical trends, suggesting that underground coal fire emissions may not the main factor for their enrichment in soils. Antimony showed the highest enrichment followed by tin, while chromium, mercury and cadmium only exhibited slight enrichment. Risk evaluation indicated that heavy metals in the studied soils pose no ecological threats.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRSDate not supplied

Excess Water in Astronaut Helmet During EVA on ISS: Mitigations with Flight Demonstrations

Following a second crew report of excess water inexplicably accumulating in the helmet during EVA-80 on March 23, 2022, NASA initiated an aggressive effort to identify, mitigate, and/or eliminate all sources of the potentially life-threatening water. Our narration highlights demonstrations of microgravity flow expectations using terrestrial scale models, mitigations to dangerous water migration within the helmet, low-g two-phase flow separations for the flow entering the helmet, and an investigation of the nature of liquid carry-over from the EMU condensing heat exchanger source. Fast-to-flight demonstrations of each aspect of the work are carried out during hands-on crew interaction with flight scale hardware on ISS during the 2022-2023 timeframe. The results of the tests are described with a focus on the rarely observed, and thus rarely studied, large length scale air-driven wall-bound droplet and rivulet twophase flows in microgravity. The success of the mitigations and directions for continued work is discussed in summary.

spacesuit↗

NASA NTRS2023

Excess Water in Astronaut Helmet During EVA on ISS: Mitigations with Flight Demonstrations

spacesuit↗

DOE OSTI2018

Thermodynamic performance and cost optimization of a novel hybrid thermal-compressed air energy storage system design

Compressed Air Energy Storage (CAES) can potentially allow renewable energy sources to meet electricity demands as reliably as coal-fired power plants. However, conventional CAES systems rely on the combustion of natural gas, require large storage volumes, and operate at high pressures, which possess inherent problems such as high costs, strict geological locations, and the production of greenhouse gas emissions. A novel and patented hybrid thermal-compressed air energy storage (HT-CAES) design is presented which allows a portion of the available energy, from the grid or renewable sources, to operate a compressor and the remainder to be converted and stored in the form of heat, through joule heating in a sensible thermal storage medium. The HT-CAES design incudes a turbocharger unit that provides supplementary mass flow rate alongside the air storage. The hybrid design and the addition of a turbocharger have the beneficial effect of mitigating the shortcomings of conventional CAES systems and its derivatives by eliminating combustion emissions and reducing storage volumes, operating pressures, and costs. Storage efficiency and cost are the two key factors, which upon integration with renewable energies would allow the sources to operate as independent forms of sustainable energy. The potential of the HT-CAES design is illustrated through a thermodynamic optimization study, which outlines key variables that have a major impact on the performance and economics of the storage system. The optimization analysis quantifies the required distribution of energy between thermal and compressed air energy storage, for maximum efficiency, and for minimum cost. This study provides a roundtrip energy and exergy efficiency map of the storage system and illustrates a trade off that exists between its capital cost and performance.

25 ENERGY STORAGE↗

DOE OSTI2021

Taylor dispersion in osmotically driven laminar flows in phloem

Sucrose is among the main products of photosynthesis that are deemed necessary for plant growth and survival. It is produced in the mesophyll cells of leaves and translocated to different parts of the plant through the phloem. Progress in understanding this transport process remains fraught with experimental difficulties, thereby prompting interest in theoretical approaches and laboratory studies. The Münch pressure and mass flow model is one of the accepted hypotheses describing the physics of sucrose transport in the phloem. It is based on osmosis creating an energy potential difference between the source and the sink. The flow responding to this energy potential is assumed laminar and described by the Hagen–Poiseuille equation. This study revisits such osmotically driven flows in tubes with membrane walls by including the effects of Taylor dispersion on mass transport. This effect has been overlooked in phloem flow studies. Taylor dispersion can increase the effective transport of solutes by increasing the apparent diffusion coefficient. It is shown that, in addition to the conventional diffusive correction derived for impermeable tube walls, a new adjustment to the mean advective terms arises because of osmotic effects. Because the molecular Schmidt number is very large for sucrose in water, the sucrose front speed and travel times have a direct dependence on the Péclet number for different ranges of the Münch number. Fially, this study establishes upper limits on expected Taylor dispersion enhancement of sucrose transport.

42 ENGINEERING↗

NASA NTRS1990

The potential for ductility enhancement from surface and interface dislocation sources in NiAl

Limited ductility and toughness of NiAl and related aluminides near room temperature pose major problems in their potential application as structural materials. An analysis of these problems is presented as part of a review of the flow and fracture behavior of binary NiAl. Following this discussion is a demonstration that conditions of elastic and plastic constraint associated with phase boundaries afforded by surface films, internal lamellae, or precipitates may introduce sufficient densities of mobile dislocations to enhance the ductility of NiAl-based materials by significant amounts. Examples of this behavior are presented for several model materials, including 001- and 123-oriented single crystals of oxide-coated NiAl, directionally solidified beta-gamma-prime (Ni70Al30) and beta-gamma (Ni50Fe30Al20) in situ composites, and several NiAl/precipitate systems. The nature of the resulting dislocation substructures and the effects of several materials variables are described.

Noebe, R. D.↗

DOE OSTI2018

Understanding and quantifying the systematic effects of clutter within a radiation detection scene

Because of low signal-to-noise ratios, the main difficultly in real-world detection scenarios is distinguishing between benign sources and potentially-threatening radioactive materials. The variability in observed signal during a radiation detection search operation can be contributed to the stochastic nature of the underlying physics and the systematic errors inherent to the detection systems employed. This variability is compounded for dynamic detection scenarios, where objects, referred to as clutter, traverse through the primary detection scene, introducing potential suppressions in the observed signal due to the attenuation of background radiation. This study examines the impact that clutter, namely automobiles such as small utility vehicles, sedans, and trucks, produces on the observed signal in a 2 in. × 4 in. × 16 in. NaI(Tl) detector. The clutter is identified and tracked in the detection scene using a time-synced video camera and a 2-D light distance and ranging contextual sensors. Two experiments were performed on the Oak Ridge National Laboratory reservation: one using a distributed source within the scene to understand the systematics of detecting and analyzing the clutter, and the second experiment mimicking an urban environment with large buildings positioned on either side of a roadway. The experiments exhibited unique results in the amount of signal suppression and variability of the cluttered signal, both demonstrating an observable suppression from the clutter-free background. These results reveal a new potential category of signal noise intrinsic to real-world detection scenarios that should be considered when establishing detection thresholds based on expected values.

Stewart, Ian R.↗

DOE OSTI2024

The QCD axion sum rule

Abstract We demonstrate that the true QCD axion that solves the strong CP problem can be found in all generality outside the customary standard QCD band, with QCD being the sole source of Peccei-Quinn breaking. The essential reason is that the basis of axion-gluon interactions does not need to coincide with the mass basis. Specifically, we consider the case in which the QCD axion field is not the only singlet scalar in Nature but it mixes with other singlet scalars (besides theη′). We determine the exact mathematical condition for an arbitraryN-scalar potential to be Peccei-Quinn invariant. Such potentials provide extra sources of mass for the customary axion without enlarging the Standard Model gauge symmetry. The contribution to the axion mass stemming from the QCD topological susceptibility is shown to be shared then among theNaxion eigenstates through a precise sum rule. Their location can only be displaced to the right of the standard QCD band. We demonstrate that the axion closest to this band can be displaced from it by a factor of$$ \sqrt{N} $$ N at most, and this corresponds to the case in which all axion signals are maximally deviated. Conversely, if one axion is found on the standard QCD band, the other eigenstates will be out of experimental reach. Our results imply that any ALP experiment which finds a signal to the right of the standard QCD axion band can be solving the strong CP problem within QCD, with the associatedN− 1 excitations to be found in an area of parameter space that we determine. We illustrate the results and phenomenology in some particular cases.

Physics↗