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At least 1,081 records · Page 60

Mars - Photodesorption from mineral surfaces and its effects on atmospheric stability

Kinetic constraints are employed to identify the reactive chemisorbed complexes, to describe the mechanism of UV-accelerated desorption from Fe (+2) on mineral surfaces, and to estimate the photodesorption rate on Mars. In particular, it is proposed that gases such as O2, CO2, CO, H2O and N2 undergo an adsorption-desorption process at octahedrally coordinated Fe (+2) surface sites to produce seven-coordinate transition-state complexes. The ligand field stabilization energy acquired by these complexes lies between 16 and 18 kcal per mole. Published photocatalysis data are used to assess the role of photodesorption in Martian atmospheric chemistry and stability.

Huguenin, R. L.↗

Computing Incompressible Flows With Free Surfaces

RIPPLE computer program models transient, two-dimensional flows of incompressible fluids with surface tension on free surfaces of general shape. Surface tension modeled as volume force derived from continuum-surface-force model, giving RIPPLE both robustness and accuracy in modeling surface-tension effects at free surface. Also models wall adhesion effects. Written in FORTRAN 77.

Kothe, D.↗

A study of real jet effects on the surface pressure distribution induced by a jet in a crossflow

A study of jet exit profile, exit Mach number, swirl and turbulence level on jet-induced loadings for jets exhausting from a surface into a crossflow is presented. The importance of each of these real jet characteristics is assessed using available data. Where adequate surface pressure distribution data are available, a correlation method to predict surface pressure for a jet exhausting from an infinite flat plate is used either to attempt to develop a correlation based on the real jet characteristics or to model the effects of that characteristic. Data comparisons are presented for selected cases. Also, a summary of information on surface pressure distribution data for jet exhausting from flat plates into a subsonic crossflow is presented.

Perkins, S. C., Jr.↗

Mach number effects on conical surface features of swept shock boundary-layer interactions

A joint experimental and computational study is made of the shock-wave turbulent boundary-layer interaction generated by sharp fins, with emphasis on Mach-number effects. The Mach number range is from 2 to 4 and the unit Reynolds number is from 50 to 80 million per meter. Fin angles are varied from 4 to 22 deg. Surface-flow patterns are obtained using a color surface-flow-visualization technique. The results show that the upstream-influence response in the conical far-field region is a function of the freestream Mach number and the shock strength. A new interpretation of the behavior of the upstream influence with changes of the inviscid shock angle is given. Agreement between the experimental and the computed upstream-influence lines becomes poorer for stronger interactions, with the computations underpredicting the upstream-influence line.

Lu, F. K.↗

Effects of temperature-dependent molecular absorption coefficients on the thermal infrared remote sensing of the earth surface

The effect of temperature-dependent molecular absorption coefficients on thermal infrared spectral signatures measured from satellite sensors is investigated by comparing results from the atmospheric transmission and radiance codes LOWTRAN and MODTRAN and the accurate multiple scattering radiative transfer model ATRAD for different atmospheric profiles. The sensors considered include the operational NOAA AVHRR and two research instruments planned for NASA's Earth Observing System (EOS): MODIS-N (Moderate Resolution Imaging Spectrometer-Nadir-Mode) and ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer). The difference in band transmittance is as large as 6 percent for some thermal bands within atmospheric windows and more than 30 percent near the edges of these atmospheric windows. The effect of temperature-dependent molecular absorption coefficients on satellite measurements of sea-surface temperature can exceed 0.6 K. Quantitative comparison and factor analysis indicate that more accurate measurements of molecular absorption coefficients and better radiative transfer simulation methods are needed to achieve SST accuracy of 0.3 K, as required for global numerical models of climate, and to develop land-surface temperature algorithms at the 1-K accuracy level.

Wan, Zhengming↗

Effect of Tail Surfaces on the Base Drag of a Body of Revolution at Mach Numbers of 1.5 and 2.0

Wind-tunnel tests were performed at Mach numbers of 1.5 and 2.0 to investigate the influence of tail surfaces on the base drag of a body of revolution without boattailing and having a turbulent boundary layer. The tail surfaces were of rectangular plan form of aspect ratio 2.33 and has symmetrical, circular-arc airfoil section. The results of the investigation showed that the addition of these tail surfaces with the trailing edges at or near the body base incurred a large increase in the base-drag coefficient. For a cruciform tail having a 10-percent-thick airfoil section, this increase was about 70 percent at a Mach number of 1.5 and 35 percent at a Mach number of 2.0. As the trailing edge of the tail was moved forward or rearward of the base by about one tail-chord length, the base-drag increment was reduced to nearly zero. The increments in base-drag coefficient due to the presence of 10-percent-thick tail surfaces were generally twice those for 5-percent-thick surfaces. The base-drag increments due to the presence of a cruciform tail were less than twice those for a plane tail. An estimate of the change in base pressure due to the tail surfaces was made, based on a simple superposition of the airfoil-pressure field onto the base-pressure field behind the body. A comparison of the results with the experimental values indicated that in most cases the trend in the variation of the base-drag increment with changes in tail position could be predicted by this approximate method but that the quantitative agreement at most tail locations was poor.

BOUNDARY LAYER - BODIES OF REVOLUTION↗

Thermo-Oxidative Stability of Graphite/PMR-15 Composites: Effect of Fiber Surface Modification on Composite Shear Properties

Experiments were conducted to establish a correlation between the weight loss of a polyimide (PMR- 15) matrix and graphite fibers and the in-plane shear properties of their unidirectional composites subjected to different isothermal aging times up to 1000 hr at 316 C. The role of fiber surface treatment on the composite degradation during the thermo-oxidative aging was investigated by using A4 graphite fibers with three surface modifications: untreated (AU-4), surface treated (AS-4), and surface treated and sized with an epoxy-compatible sizing (AS-4G). The weight loss of the matrix fibers, and composites was determined during the aging. The effect of thermal aging was seen in all the fiber samples in terms of weight loss and reduction in fiber diameter. Calculated values of weight loss fluxes for different surfaces of rectangular unidirectional composite plates showed that the largest weight loss occurred at those cut surfaces where fibers were perpendicular to the surface. Consequently, the largest amount of damage was also noted on these cut surfaces. Optical observation of the neat matrix and composite plates subjected to different aging times revealed that the degradation (such as matrix microcracking and void growth) occurred in a thin surface layer near the specimen edges. The in-plane shear modulus of the composites was unaffected by the fiber surface treatment and the thermal aging. The shear strength of the composites with the untreated fibers was the lowest and it decreased with aging. A fracture surface examination of the composites with untreated fibers suggested that the weak interface allowed the oxidation reaction to proceed along the interface and thus expose the inner material to further oxidation. The results indicated that the fiber-matrix interface affected the composite degradation process during its thermal aging and that the the weak interface accelerated the composite degradation.

Madhukar, Madhu S.↗

Surface and bulk effects of K in highly efficient Cu 1-x K x InSe 2 solar cells

To advance knowledge of the beneficial effects of K in Cu(In,Ga)(Se,S) 2 (CIGS) photovoltaic (PV) absorbers, recent Cu-K-In-Se phase growth studies have been extended to PV performance. First, the effect of distributing K throughout bulk Cu 1-x K x InSe 2 absorbers at low K/(K+Cu) compositions (0 = x = 0.30) was studied. Efficiency, open-circuit voltage (VOC), and fill factor (FF) were greatly enhanced for x ~ 0.07, resulting in an officially-measured 15.0%-efficient solar cell, matching the world record CuInSe 2 efficiency. The improvements were a result of reduced interface and bulk recombination, relative to CuInSe 2 (x ~ 0). However, higher x compositions had reduced efficiency, short-circuit current density (J SC ), and FF due to greatly increased interface recombination, relative to the x ~ 0 baseline. Next, the effect of confining K at the absorber/buffer interface at high K/(K+Cu) compositions (0.30 = x = 0.92) was researched. Previous work showed that these surface layer growth conditions produced CuInSe 2 with a large phase fraction of KInSe 2 . After optimization (75 nm surface layer with x ~ 0.41), these KInSe 2 surface samples exhibited increased efficiency (officially 14.9%), VOC, and FF as a result of decreased interface recombination. The KInSe 2 surfaces had features similar to previous reports for KF post-deposition treatments (PDTs) used in world record CIGS solar cells - taken as indirect evidence that KInSe 2 can form during these PDTs. Both the bulk and surface growth processes greatly reduced interface recombination. However, the KInSe 2 surface had higher K levels near the surface, greater lifetimes, and increased inversion near the buffer interface, relative to the champion bulk Cu 1-x K x InSe 2 absorber. These characteristics demonstrate that K may benefit PV performance by different mechanisms at the surface and in the absorber bulk.

14 SOLAR ENERGY↗

Lower Temperature Annealing of Vapor Diffused Nb₃Sn for Accelerator Cavities

Nb₃Sn is a next-generation superconducting material for the accelerator cavities with higher critical temperature and superheating field, both twice compared to Nb. It promises superior performance and higher operating temperature than Nb, resulting in significant cost reduction. So far, the Sn vapor diffusion method is the most preferred and successful technique to coat niobium cavities with Nb₃Sn. Although several post-coating techniques (chemical, electrochemical, mechanical) have been explored to improve the surface quality of the coated surface, an effective process has yet to be found. Since there are only a few studies on the post-coating heat treatment at lower temperatures, we annealed Nb₃Sn-coated samples at 800 C - 1000 C to study the effect of heat treatments on surface properties, primarily aimed at removing surface Sn residues. This paper discusses the systematic surface analysis of coated samples after annealing at temperatures between 850 C and 950 C.

43 PARTICLE ACCELERATORS↗

An experimental investigation of silicon wafer surface roughness and its effect on the pull-strength of plated metals

Plated silicon wafers with surface roughness ranging from 0.4 to 130 microinches, subjected to tensile pull-strength tests, were analyzed. Results show that the measured pull-strength of plated metals decrease with increasing silicon surface roughness, effecting a weakening of the cohesive strength of the wafer, possibly caused by microcracks or 'etch pits' in the silicon surface. The mean value of pull-strength for all wafers plated with the Ni-Cu-Cu sequence exceeded the required 450 g/0.02 sq cm, and at Ra = 0.4 microinches, the mean pull-strength for the Ni-Cu-Cu and Ni-Cu wafers were 2290 and 850 g/0.02 sq cm, respectively. The development of standardized methods for measuring contact pull-strength is suggested. These results may have some bearing on solar cell arrays problems.

Spiers, G. D.↗

Numerical study of the effect of propped surface area and fracture conductivity on shale gas production: Application for multi-size proppant pumping schedule design

Hydraulic fracturing is a technique extensively used in the oil and gas industry, where water, proppant (sand) and additives are injected into unconventional reservoirs to enhance the recovery of shale hydrocarbon. Although some previous studies have developed pumping schedules that maximize gas production for a single-size proppant, there are very few studies that consider the effect of varying proppant diameters across pumping stages on shale gas production. Motivated by this, we carried out an extensive sensitivity analysis to determine the effect of different proppant diameters on the average fracture conductivity (FC), average propped surface area (PSA) and cumulative shale gas production volume. We found out that the cumulative shale gas production volume depends on both the average PSA and average FC. We also found out that small-diameter proppant resulted in higher average PSA and lower average FC, whereas large-diameter proppant resulted in lower average PSA and higher average FC. Hence, we designed a multi-size proppant pumping schedule considering both of these parameters into account for simultaneously propagating multiple fractures to maximize shale gas production from unconventional reservoirs. Since the size of injected proppant particles determines the average PSA and average FC for the propped hydraulic fractures, we developed a novel framework called Sequentially Interlinked Modeling Structure (SIMS) to predict the average PSA, average FC and cumulative shale gas production volume at the end of 10 years for a given pumping schedule. Then, we used this SIMS framework to obtain a multi-size proppant pumping schedule that maximizes shale gas production. In closing, we demonstrated that the obtained pumping schedule gives a cumulative shale gas production volume greater than the values obtained from the existing pumping schedules.

03 NATURAL GAS↗

Effect of Blade-surface Finish on Performance of a Single-stage Axial-flow Compressor

A set of modified NACA 5509-34 rotor and stator blades was investigated with rough-machine, hand-filed, and highly polished surface finishes over a range of weight flows at six equivalent tip speeds from 672 to 1092 feet per second to determine the effect of blade-surface finish on the performance of a single-stage axial-flow compressor. Surface-finish effects decreased with increasing compressor speed and with decreasing flow at a given speed. In general, finishing blade surfaces below the roughness that may be considered aerodynamically smooth on the basis of an admissible-roughness formula will have no effect on compressor performance.

COMPRESSORS - AXIAL FLOW↗

Experimental Study of the Effects of Finite Surface Disturbances and Angle of Attack on the Laminar Boundary Layer of an NACA 64A010 Airfoil with Area Suction

A Langley low-turbulence wind-tunnel investigation of a porous NACA 64A010 airfoil section has been made to determine the effectiveness of area suction in maintaining full-chord laminar flow behind finite disturbances and at angles of attacks other than 0 degrees. Aero suction resulted in only a small increase in the size of a finite disturbance required to cause premature boundary-layer transition as compared with that for the airfoil without suction. Combined wake and suction drags lower than the drag of the plain airfoil were obtained through a range of low lift coefficient by the use of area suction.

FLOW, LAMINAR↗

An efficient computational method for characterizing the effects of random surface errors on the average power pattern of reflectors

Based on the works of Ruze (1966) and Vu (1969), a novel mathematical model has been developed to determine efficiently the average power pattern degradations caused by random surface errors. In this model, both nonuniform root mean square (rms) surface errors and nonuniform illumination functions are employed. In addition, the model incorporates the dependence on F/D in the construction of the solution. The mathematical foundation of the model rests on the assumption that in each prescribed annular region of the antenna, the geometrical rms surface value is known. It is shown that closed-form expressions can then be derived, which result in a very efficient computational method for the average power pattern. Detailed parametric studies are performed with these expressions to determine the effects of different random errors and illumination tapers on parameters such as gain loss and sidelobe levels. The results clearly demonstrate that as sidelobe levels decrease, their dependence on the surface rms/wavelength becomes much stronger and, for a specified tolerance level, a considerably smaller rms/wavelength is required to maintain the low sidelobes within the required bounds.

Rahmat-Samii, Y.↗