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At least 1,099 records · Page 61

Metal versus rare-gas ion irradiation during Ti{sub 1-x}Al{sub x}N film growth by hybrid high power pulsed magnetron/dc magnetron co-sputtering using synchronized pulsed substrate bias

Metastable NaCl-structure Ti{sub 1-x}Al{sub x}N is employed as a model system to probe the effects of metal versus rare-gas ion irradiation during film growth using reactive high-power pulsed magnetron sputtering (HIPIMS) of Al and dc magnetron sputtering of Ti. The alloy film composition is chosen to be x = 0.61, near the kinetic solubility limit at the growth temperature of 500 Degree-Sign C. Three sets of experiments are carried out: a -60 V substrate bias is applied either continuously, in synchronous with the full HIPIMS pulse, or in synchronous only with the metal-rich-plasma portion of the HIPIMS pulse. Alloy films grown under continuous dc bias exhibit a thickness-invariant small-grain, two-phase nanostructure (wurtzite AlN and cubic Ti{sub 1-x}Al{sub x}N) with random orientation, due primarily to intense Ar{sup +} irradiation leading to Ar incorporation (0.2 at. %), high compressive stress (-4.6 GPa), and material loss by resputtering. Synchronizing the bias with the full HIPIMS pulse results in films that exhibit much lower stress levels (-1.8 GPa) with no measureable Ar incorporation, larger grains elongated in the growth direction, a very small volume fraction of wurtzite AlN, and random orientation. By synchronizing the bias with the metal-plasma phase of the HIPIMS pulses, energetic Ar{sup +} ion bombardment is greatly reduced in favor of irradiation predominantly by Al{sup +} ions. The resulting films are single phase with a dense competitive columnar structure, strong 111 orientation, no measureable trapped Ar concentration, and even lower stress (-0.9 GPa). Thus, switching from Ar{sup +} to Al{sup +} bombardment, while maintaining the same integrated incident ion/metal ratio, eliminates phase separation, minimizes renucleation during growth, and reduces the high concentration of residual point defects, which give rise to compressive stress.

36 MATERIALS SCIENCE↗

Residual Stress Measurements in Extreme Environments for Hazardous, Layered Specimens

In nuclear fuel plates of low-enriched U-10Mo (LEU) clad with aluminum by hot isostatic pressing (HIP), post-irradiation stresses arising during reactor shutdown are a major concern for safe reactor operations. Measurement of those residual stresses has not previously been possible because the high radioactivity of the plates requires handling only by remote manipulation in a hot cell. The incremental slitting method for measuring through-thickness stress profiles was modified, and a system for automated, remote operation was built and tested. Experimental modifications consisted of replacing electric-discharge machining (EDM) with a small end mill and strain-gauge measurements with cantilever displacement measurements. The inverse method used to calculate stresses was the pulse-regularization method modified to allow discontinuities across material interfaces. The new system was validated by comparing with conventional slitting on a depleted U-10Mo (DU) fuel plate. The new system was applied to two measurements each on six as-fabricated (pre-irradiation) LEU miniature fuel plates. Variations between the measurements at two locations in the same plate were strongly correlated with measured geometrical heterogeneity in the plate—a tilt in the fuel foil. Compressive stresses in the U-10Mo were shown to increase from 20 to 250 MPa as the ratio of aluminum thickness to U-10Mo thickness increased causing increased constraint during cooling. Faster cooling rates during processing also increased stress magnitudes. The measurements trends agreed with data in the literature from similar plates made with DU, which further validates the method. Because other methods are impractical in a hot cell, the modified slitting method is now poised for the first measurements of post-irradiation stresses.

36 MATERIALS SCIENCE↗

Geomechanical characterization of Rock Valley carbonates

In Rock Valley, Nevada, the USA, past earthquake sequences and shallow faulting in Paleozoic carbonates remain poorly understood. Carbonates are typically more ductile rocks that do not experience large stress drops or fracture coalescence, which contradicts previous observations in the region. As part of the Source Physics Experiment, an effort has been made to experimentally characterize the petrophysical and geomechanical properties of carbonates from Rock Valley. Well core and outcrop samples were used to determine the difference between shallow-buried Tertiary limestones and deeply buried Paleozoic limestones and dolostones. The carbonates possessed porosities between 3 and 9%, with V P and V S in the Tertiary carbonates around 2700 and 1800 m/s, respectively, and 6000 and 3100 m/s, respectively, in the Paleozoic carbonates. Microstructural characterization revealed that the Paleozoic carbonates contained significantly more pre-existing damage and alteration than the Tertiary carbonates, though the deformation varies from localized to diffuse. Unconfined Brazilian tests and triaxial tests with confining pressures between 0 and 50 MPa showed that, although samples all experienced failure, the dolostones typically failed at greater stresses and possessed greater E/ν ratios than the limestones. Furthermore, the Hoek–Brown failure criterion was used to construct failure envelopes with the compressive and tensile failure tests. Velocity, density, and porosity measurements were used to construct a hypothetical velocity-depth profile and compare the results with the theoretical petrophysical measurements. Using brittleness analysis, the likely failure conditions were determined to be low-porosity dolomitic rock for fault nucleation in the Paleozoic basement.

Brittleness↗

Microstructural Characterization and High Strain Rate Plastic Flow Behavior of SMAW Armox500T Steel Joints from Spherical Indentation Experiments

Static indentation and uniaxial compression tests have been conducted on Armox500T steel and its weldments to predict the constraint factor (CF), i.e., ratio of Meyer’s hardness to uniaxial flow stress. Series of dynamic indentation experiments were carried out at impact velocities ranging from 5 to 300 m/s to estimate dynamic hardness as a function of average strain. Subsequently, dynamic indentation (DI) test data and CF determined under static indentation conditions have been used to study the high strain rate plastic flow behavior of Armox500T weldments in comparison with the base metal. It was observed that flow stress for Armox500T and its weldments under dynamic loading conditions (10{sup 4} s{sup −1}) are significantly higher than flow stress measured under static loading conditions (10{sup −3} s{sup −1}). The plastic flow behavior computed from DI is in good agreement with the data evaluated through conventional split Hopkinson pressure bar technique. Further, the study of the microstructure of base metal and weldments by optical microscopy and SEM revealed a considerable variation in the microstructure.

36 MATERIALS SCIENCE↗

Hydrogen-rich syngas production from the steam co-gasification of low-density polyethylene and coal refuse

Gasification provides a promising pathway for transforming waste materials into valuable products, such as fuels and chemicals. Here, this study investigates the steam co-gasification of low-density polyethylene (LDPE) and compressed thickener underflow, representative of coal refuse (CR), in a drop tube reactor. The effects of feed blend ratio (0–100 wt% LDPE) and temperature (800–1000 °C) on syngas composition, tar formation, and process efficiency are examined. The high volatility of LDPE makes it more reactive than CR but also promotes the formation of 2–7 ring aromatic tars. Increasing temperature improves carbon conversion efficiency (CCE), cold gas efficiency (CGE), and syngas yield, although the lower heating value (LHV) of syngas decreases. Hydrogen is the dominant gas product, reaching 59 vol% with the H 2 /CO molar ratio ranging from 2.27 to 4.74. Synergistic effects from alkali and alkali earth metals (AAEMs), particularly K and Ca, in CR ash enhance syngas yield by catalyzing char gasification and tar cracking. Hematite (Fe 2 O 3 ) and ash from sub-bituminous/bituminous coals are explored as tar reforming catalysts. Fe 2 O 3 achieves 100 % tar reforming efficiency, while coal ash, with a lower Fe 2 O 3 content (15 wt%), is less effective at cracking polycyclic aromatic hydrocarbons, particularly naphthalene. These findings demonstrate the flexibility of co-gasification, allowing precise tuning of syngas characteristics for specific downstream applications. Further optimization of waste-derived catalysts could enhance the economic viability of gasification in waste-to-energy processes.

01 COAL, LIGNITE, AND PEAT↗

Strain control of AlGaN/GaN high electron mobility transistor structures on silicon (111) by plasma assisted molecular beam epitaxy

This paper reports on the use of plasma assisted molecular beam epitaxy of AlGaN/GaN-based high electron mobility transistor structures grown on 4 in. Si (111) substrates. In situ measurements of wafer curvature during growth proved to be a very powerful method to analyze the buffer layer's thickness dependent strain. The Ga/N ratio at the beginning of growth of the GaN buffer layer is the critical parameter to control the compressive strain of the entire grown structure. An engineered amount of compressive strain must be designed into the structure to perfectly compensate for the tensile strain caused by differences in the thermal expansion coefficient between the epi-layer and substrate during sample cool down from growth temperatures. A maximum film thickness of 4.2 {mu}m was achieved without the formation of any cracks and a negligible bow of the wafers below 10 {mu}m. Measurement of the as-grown wafers revealed depth profiles of the charge carrier concentration comparable to values achieved on SiC substrates and mobility values of the two dimensional electron gas in the range 1230 to 1350 cm{sup 2}/Vs at a charge carrier concentration of 6.5-7 10{sup 12}/cm{sup 2}. First results on processed wafers with 2 {mu}m thick buffer layer indicate very promising results with a resistance of the buffer, measured on 200 {mu}m long contacts with 15 {mu}m pitch, in the range of R > 10{sup 9}{Omega} at 100 V and breakdown voltages up to 550 V.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Ion-acoustic cnoidal waves in a quantum plasma

Nonlinear ion-acoustic cnoidal wave structures are studied in an unmagnetized quantum plasma. Using the reductive perturbation method, a Korteweg-de Vries equation is derived for appropriate boundary conditions and nonlinear periodic wave solutions are obtained. The corresponding analytical solution and numerical plots of the ion-acoustic cnoidal waves and solitons in the phase plane are presented using the Sagdeev pseudo-potential approach. The variations in the nonlinear potential of the ion-acoustic cnoidal waves are studied at different values of quantum parameter H{sub e} which is the ratio of electron plasmon energy to electron Fermi energy defined for degenerate electrons. It is found that both compressive and rarefactive ion-acoustic cnoidal wave structures are formed depending on the value of the quantum parameter. The dependence of the wavelength and frequency on nonlinear wave amplitude is also presented.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Ply-level failure analysis of a graphite/epoxy laminate under bearing-bypass loading

A combined experimental and analytical study was conducted to investigate and predict the failure modes of a graphite/epoxy laminate subjected to combined bearing and bypass loading. Tests were conducted in a test machine that allowed the bearing-bypass load ratio to be controlled while a single-fastener coupon was loaded to failure in either tension or compression. Onset and ultimate failure modes and strengths were determined for each test case. The damage-onset modes were studied in detail by sectioning and micrographing the damaged specimens. A two-dimensional, finite-element analysis was conducted to determine lamina strains around the bolt hole. Damage onset consisted of matrix cracks, delamination, and fiber failures. Stiffness loss appeared to be caused by fiber failures rather than by matrix cracking and delamination. An unusual offset-compression mode was observed for compressive bearing-bypass laoding in which the specimen failed across its width along a line offset from the hole. The computed lamina strains in the fiber direction were used in a combined analytical and experimental approach to predict bearing-bypass diagrams for damage onset from a few simple tests.

Naik, R. A.↗

Ply-level failure analysis of a graphite/epoxy laminate under bearing-bypass loading

A combined experimental and analytical study was conducted to investigate and predict the failure modes of a graphite/epoxy laminate subjected to combined bearing and bypass loading. Tests were conducted in a test machine that allowed the bearing-bypass load ratio to be controlled while a single-fastener coupon was loaded to failure in either tension or compression. Onset and ultimate failure modes and strengths were determined for each test case. The damage-onset modes were studied in detail by sectioning and micrographing the damaged specimens. A two-dimensional, finite-element analysis was conducted to determine lamina strains around the bolt hole. Damage onset consisted of matrix cracks, delamination, and fiber failures. Stiffness loss appeared to be caused by fiber failures rather than by matrix cracking and delamination. An unusual offset-compression mode was observed for compressive bearing-bypass loading in which the specimen failed across its width along a line offset from the hole. The computed lamina strains in the fiber direction were used in a combined analytical and experimental approach to predict bearing-bypass diagrams for damage onset from a few simple tests.

Naik, R. A.↗

Using cylindrical implosions to investigate hydrodynamic instabilities in convergent geometry

Hydrodynamic instabilities such as the Rayleigh–Taylor (RT) and Richtmyer–Meshkov instabilities disrupt inertial confinement fusion (ICF) implosions through the growth of 3D perturbations. Growth of these 3D imperfections at the interfaces of an ICF capsule during implosion lead to mixing between materials that is detrimental to performance. These instabilities have been studied extensively in planar geometry, but such experiments lack the effects of convergence in spherical implosions. While several studies have been performed in spherical geometry, these often lack a direct means to measure perturbation growth. Experiments in cylindrical geometry include convergence effects while maintaining direct diagnostic access. Although cylinders have less compression than spheres, they do provide an excellent platform to validate modeling for convergent geometries. The problem with previous cylindrical implosion experiments was that the convergence ratios were limited to ~4. With the National Ignition Facility (NIF), larger cylindrical targets can be driven to convergences of 10–15 while maintaining a large enough final diameter to measure perturbation growth. This paper reviews the design process used to both benchmark radiation hydrodynamics codes and enable 1D post-processed simulations to explore design space to separate compression effects from acceleration/deceleration RT instability. Results from 1D simulations suggest that cylindrical implosions on the NIF can produce high-convergence experiments to validate RT instability growth for ICF implosions.

36 MATERIALS SCIENCE↗

Polar symmetric flow of a viscous compressible atmosphere; an application to Mars

The atmosphere is assumed to be driven by a polar symmetric temperature field and the equations of motion in pressure ratio coordinates are linearized by considering the zero order in terms of a thermal Rossby number R delta I/(2a omega) sq where delta T is a measure of the latitudinal temperature gradient. When the eddy viscosity is greater than 1 million sq cm/sec, the boundary layer extends far up into the atmosphere, making the geostrophic approximation invalid for the bulk of the atmosphere. A temperature model for Mars was used which was based on Mariner 9 infrared spectral data with a 30% increase in the depth averaged temperature from the winter pole to the subsolar point. The results obtained for the increase in surface pressure from the subsolar point to the winter pole, as a function of eddy viscosity and with no-slip conditions imposed at the surface, are given.

Pirraglia, J. A.↗

A compressed cloud in the Vela supernova remnant

Strong interstellar absorption lines of C I, arising from the two excited fine-structure levels, are found in IUE observations of HD 72350 (type B4 III). An analysis of the excited-level populations of C I gives local temperature and pressure limits, and auxiliary data on the limit of column density for excited O I and the carbon ionization help to establish that (1) the local temperature is within the limits of 25-100 K, and (2) the pressure/Boltzmann's constant ratio is at least 10 to the 4.3/cu cm K, despite its small size. This high-pressure cloud is discussed in terms of shock compression by the Vela supernova blast wave, along with the relationship of this kind of cloud compression to star formation and to the origin of the characteristic filamentary emission arcs seen in Vela and other supernova remnants

Jenkins, E. B.↗

Geometric transformations for video compression and human teleoperator display

A method for bandwidth-efficient processing of video imagery to be viewed by the teleoperator of a remotely-operated vehicle on which the camera is mounted is described. The method comprises image coding, transmission, and reconstruction. It is assumed that the transmission bandpass is the limiting factor rather than encoding/decoding schemata; that image coding and reconstruction will be done within the general abilities of the NASA/TI Programmable Remapper; and that the ratio of retained local detail to the operator's visual resolution is held constant throughout the large-field image that is seen. Novel features include that the compression and reconstruction address certain characteristics of the human visual system, that two-way communication controls a moving 'fovea' in the transformation, and that resolution varies over the image. Conventional motivations accommodated include the Cartesian raster-scan nature of available imagers and display devices and a need for low bandwidth in the image transmission. Unique image processing hardware, NASA's Programmable Remapper, allows demonstration of the method. Once refined, the technology could be adapted to special purpose imagers and display devices, or otherwise to dedicated image processing hardware.

Juday, Richard D.↗

Effect of Particle Shape on Mechanical Behaviors of Rocks: A Numerical Study Using Clumped Particle Model

Since rocks are aggregates of mineral particles, the effect of mineral microstructure on macroscopic mechanical behaviors of rocks is inneglectable. Rock samples of four different particle shapes are established in this study based on clumped particle model, and a sphericity index is used to quantify particle shape. Model parameters for simulation in PFC are obtained by triaxial compression test of quartz sandstone, and simulation of triaxial compression test is then conducted on four rock samples with different particle shapes. It is seen from the results that stress thresholds of rock samples such as crack initiation stress, crack damage stress, and peak stress decrease with the increasing of the sphericity index. The increase of sphericity leads to a drop of elastic modulus and a rise in Poisson ratio, while the decreasing sphericity usually results in the increase of cohesion and internal friction angle. Based on volume change of rock samples during simulation of triaxial compression test, variation of dilation angle with plastic strain is also studied.

54 ENVIRONMENTAL SCIENCES↗

The "limiting line" in mixed subsonic and supersonic flow of compressible fluids

It is well known that the vorticity for any fluid element is constant if the fluid is non-viscous and the change of state of the fluid is isentropic. When a solid body is placed in a uniform stream, the flow far ahead of the body is irrotational. Then if the flow is further assumed to be isentropic, the vorticity will be zero over the whole filed of flow. In other words, the flow is irrotational. For such flow over a solid body, it is shown by Theodorsen that the solid body experiences no resistance. If the fluid has a small viscosity, its effect will be limited in the boundary layer over the solid body and the body will have a drag due to the skin friction. This type of essentially isentropic irrotational flow is generally observed for a streamlined body placed in a uniform stream, if the velocity of the stream is kept below the so-called "critical speed." At the critical speed or rather at a certain value of the ratio of the velocity of the undisturbed flow and the corresponding velocity of sound, shock waves appear. This phenomenon is called the "compressibility bubble." Along a shock wave, the change of state of the fluid is no longer isentropic, although still adiabatic. This results in an increase in entropy of the fluid and generally introduces vorticity in an originally irrotational flow. The increase in entropy of the fluid is, of course, the consequence of changing part of the mechanical energy into heat energy. In other words, the part of fluid affected by the shock wave has a reduced mechanical energy. Therefore, with the appearance of shock waves, the wake of the streamline body is very much widened, and the drag increases drastically. Furthermore, the accompanying change in the pressure distribution over the body changes the aerodynamic moment acting on it and in the case of an airfoil decreases the lift force. All these consequences of the breakdown of isentropic irrotational flow are generally undesirable in applied aerodynamics. Its occurrence should be delayed as much as possible by modifying the shape or contour of the body. However, such endeavor will be very much facilitated if the cause or the criterion for the breakdown can be found first.

MACH NUMBER↗

Bright, Mechanosensitive Upconversion with Cubic-Phase Heteroepitaxial Core–Shell Nanoparticles

Lanthanide-doped nanoparticles are an emerging class of optical sensors, exhibiting sharp emission peaks, high signal-to-noise ratio, photostability, and a ratiometric color response to stress. The same centrosymmetric crystal field environment that allows for high mechanosensitivity in the cubic-phase (α), however, contributes to low upconversion quantum yield (UCQY). In this work, we engineer brighter mechanosensitive upconverters using a core–shell geometry. Sub-25 nm α-NaYF 4 :Yb,Er cores are shelled with an optically inert surface passivation layer of ~4.5 nm thickness. Using different shell materials, including NaGdF 4 , NaYF 4 , and NaLuF 4 , we study how compressive to tensile strain influences the nanoparticles’ imaging and sensing properties. All core–shell nanoparticles exhibit enhanced UCQY, up to 0.14% at 150 W/cm 2 , which rivals the efficiency of unshelled hexagonal-phase (β) nanoparticles. Additionally, strain at the core–shell interface can tune mechanosensitivity. In particular, the compressive Gd shell results in the largest color response from yellow-green to orange or, quantitatively, a change in the red to green ratio of 12.2 ± 1.2% per GPa. For all samples, the ratiometric readouts are consistent over three pressure cycles from ambient to 5 GPa. Furthermore, heteroepitaxial shelling significantly improves signal brightness without compromising the core’s mechano-sensing capabilities and further, promotes core–shell cubic-phase nanoparticles as upcoming in vivo and in situ optical sensors.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Compressibility effects on rotor forces in the leakage path between a shrouded pump impeller and its housing

A modified approach to Childs' previous work on fluid-structure interaction forces in the leakage path between an impeller shroud and its housing is presented in this paper. Three governing equations consisting of continuity, path-momentum, and circumferential-momentum equations were developed to describe the leakage path inside a pump impeller. Radial displacement perturbations were used to solve for radial and circumferential force coefficients. In addition, impeller-discharge pressure disturbances were used to obtain pressure oscillation responses due to precessing impeller pressure wave pattern. Childs' model was modified from an incompressible model to a compressible barotropic-fluid model (the density of the working fluid is a function of the pressure and a constant temperature only). Results obtained from this model yielded interaction forces for radial and circumferential force coefficients. Radial and circumferential forces define reaction forces within the impeller leakage path. An acoustic model for the same leakage path was also developed. The convective, Coriolis, and centrifugal acceleration terms are removed from the compressible model to obtain the acoustics model. A solution due to impeller discharge pressure disturbances model was also developed for the compressible and acoustics models. The results from these modifications are used to determine what effects additional perturbation terms in the compressible model have on the acoustic model. The results show that the additional fluid mechanics terms in the compressible model cause resonances (peaks) in the force coefficient response curves. However, these peaks only occurred at high values of inlet circumferential velocity ratios greater than 0.7. The peak pressure oscillation was shown to occur at the wearing ring seal. Introduction of impeller discharge disturbances with n = 11 diametral nodes showed that maximum peak pressure oscillations occurred at nondimensional precession frequencies of f = 6.4 and f = 7.8 for this particular pump. Bolleter's results suggest that for peak pressure oscillations to occur at the wearing ring seal, the nondimensional excitation frequency should be on the order of f = 2.182 for n = 11. The resonances found in this research do not match the excitation frequencies predicted by Bolleter. At the predicted peak excitation frequencies given by Bolleter, the compressible model shows an attenuation of the pressure oscillations at the seal exit. The compressibility of the fluid does not have a significant influence on the model at low values of nondimensional excitation frequency. At high values of nondimensional frequency, the effects of compressibility become more significant. For the acoustic analysis, the convective, Coriolis, and centrifugal acceleration terms do affect the results to a limited extent for precession excitation and to a large extent for a pressure excitation when the fluid operates at relatively high Mach numbers.

Cao, Nhai The↗

An Informative Interpretation of Decision Theory: The Information Theoretic Basis for Signal-to-Noise Ratio and Log Likelihood Ratio

The signal processing concept of signal-to-noise ratio (SNR), in its role as a performance measure, is recast within the more general context of information theory, leading to a series of useful insights. Establishing generalized SNR (GSNR) as a rigorous information theoretic measure inherent in any set of observations significantly strengthens its quantitative performance pedigree while simultaneously providing a specific definition under general conditions. This directly leads to consideration of the log likelihood ratio (LLR): first, as the simplest possible information-preserving transformation (i.e., signal processing algorithm) and subsequently, as an absolute, comparable measure of information for any specific observation exemplar. Furthermore, the information accounting methodology that results permits practical use of both GSNR and LLR as diagnostic scalar performance measurements, directly comparable across alternative system/algorithm designs, applicable at any tap point within any processing string, in a form that is also comparable with the inherent performance bounds due to information conservation.

97 MATHEMATICS AND COMPUTING↗