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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,099 records · Page 61

CHIRP-Like Signals: Estimation, Detection and Processing A Sequential Model-Based Approach

Chirp signals have evolved primarily from radar/sonar signal processing applications specifically attempting to estimate the location of a target in surveillance/tracking volume. The chirp, which is essentially a sinusoidal signal whose phase changes instantaneously at each time sample, has an interesting property in that its correlation approximates an impulse function. It is well-known that a matched-filter detector in radar/sonar estimates the target range by cross-correlating a replicant of the transmitted chirp with the measurement data reflected from the target back to the radar/sonar receiver yielding a maximum peak corresponding to the echo time and therefore enabling the desired range estimate. In this application, we perform the same operation as a radar or sonar system, that is, we transmit a “chirp-like pulse” into the target medium and attempt to first detect its presence and second estimate its location or range. Our problem is complicated by the presence of disturbance signals from surrounding broadcast stations as well as extraneous sources of interference in our frequency bands and of course the ever present random noise from instrumentation. First, we discuss the chirp signal itself and illustrate its inherent properties and then develop a model-based processing scheme enabling both the detection and estimation of the signal from noisy measurement data.

42 ENGINEERING↗

Advancing Theory and Modeling Efforts in Heliophysics

Heliophysics theory and modeling build understanding from fundamental principles to motivate, interpret, and predict observations. Together with observational analysis, they constitute a comprehensive scientific program in heliophysics. As observations and data analysis become increasingly detailed, it is critical that theory and modeling develop more quantitative predictions and iterate with observations. Advanced theory and modeling can inspire and greatly improve the design of new instruments and increase their chance of success. In addition, in order to build physicsbased space weather forecast models, it is important to keep developing and testing new theories, and maintaining constant communications with theory and modeling. Maintaining a sustainable effort in theory and modeling is critically important to heliophysics. We recommend that all funding agencies join forces and consider expanding current and creating new theory and modeling programs–especially, 1. NASA should restore the HTMS program to its original support level to meet the critical needs of heliophysics science; 2. a Strategic Research Model program needs to be created to support model development for next-generation basic research codes; 3. new programs must be created for addressing mission-critical theory and modeling needs; and 4. enhanced programs are urgently required for training the next generation of theorists and modelers.

79 ASTRONOMY AND ASTROPHYSICS↗

Laboratory-Based Micro-X-ray Computed Tomography of Energy Materials at Idaho National Laboratory

Abstract The Idaho National Laboratory (INL) has implemented laboratory-based micro-X-ray computed tomography in a laboratory equipped for the examination of highly radioactive samples. This capability provides nondestructive three-dimensional volumetric information on samples to inform subsequent traditional destructive examinations as well as real-world inputs for high-fidelity scientific modeling. Samples can be imaged with spatial resolutions ranging from several hundred nm/voxel up to ~ 100 µm/voxel. The best usable spatial resolution achieved to date is 384 nm/voxel with this instrument, while the highest radiological dose rate of a sample imaged is ~ 60 R/h β/γ on contact. Advanced data analysis, including custom tomographic reconstruction and segmentation methods, have also been developed to support this capability. In addition to traditional digital X-ray radiography and tomography, this instrument is also able to visualize in situ tensile and compression testing as well as perform diffraction contrast tomography. This work describes the X-ray computed tomography post-irradiation examination capabilities at INL, as well as detailing a variety of applications this instrument has examined.

36 MATERIALS SCIENCE↗

Acoustic Techniques for Density and Mass Flow in Enrichment Plants

In recent years, the IAEA has pursued innovative techniques and an integrated suite of safeguards measures to address the verification challenges posed by advanced centrifuge technologies and the growth in capacity at gaseous centrifuge enrichment plants (GCEPs) [1; 2]. A prominent theme in the development of a new generation of safeguards measures for GCEPs is the use of permanently installed, unattended instruments that can provide continuous monitoring of facility activities, while also reducing the need for on-site inspections [3]. For example, the U.S. Support Program to the IAEA leads the development of an On-Line Enrichment Monitor (OLEM) [4; 5] and an Unattended Cylinder Verification Station (UCVS) [6]. OLEM units will provide continuous enrichment measurement for 100% of the declared gas flowing through unit header pipes, thereby improving the IAEA’s capabilities to verify operator declarations of enrichment. The OLEM concept requires an accurate determination of gas density in order to produce accurate enrichment calculations (Fig. 1). The current OLEM design assumes that this gas density is derived from a pressure transducer signal shared with the operator. The IAEA has expressed the desire for a technology that can independently and noninvasively measures gas density, in support of a next-generation OLEM design.

IAEA, Enrichment Plants, Acoustic Techniques, OLEM↗

ARM Cloud Radar Simulator Package for Global Climate Models Value-Added Product

It has been challenging to directly compare U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facility ground-based cloud radar measurements with climate model output because of limitations or features of the observing processes and the spatial gap between model and the single-point measurements. To facilitate the use of ARM radar data in numerical models, an ARM cloud radar simulator was developed to converts model data into pseudo-ARM cloud radar observations that mimic the instrument view of a narrow atmospheric column (as compared to a large global climate model [GCM] grid-cell), thus allowing meaningful comparison between model output and ARM cloud observations. The ARM cloud radar simulator value-added product (VAP) was developed based on the CloudSat simulator contained in the community satellite simulator package, the Cloud Feedback Model Intercomparison Project (CFMIP) Observation Simulator Package (COSP) (Bodas-Salcedo et al., 2011), which has been widely used in climate model evaluation with satellite data (Klein et al., 2013, Zhang et al., 2010). The essential part of the CloudSat simulator is the QuickBeam radar simulator that is used to produce CloudSat-like radar reflectivity, but is capable of simulating reflectivity for other radars (Marchand et al., 2009; Haynes et al., 2007). Adapting QuickBeam to the ARM cloud radar simulator within COSP required two primary changes: one was to set the frequency to 35 GHz for the ARM Ka-band cloud radar, as opposed to 94 GHz used for the CloudSat W-band radar, and the second was to invert the view from the ground to space so as to attenuate the beam correctly. In addition, the ARM cloud radar simulator uses a finer vertical resolution (100 m compared to 500 m for CloudSat) to resolve the more detailed structure of clouds captured by the ARM radars. The ARM simulator has been developed following the COSP workflow (Figure 1) and using the capabilities available in COSP wherever possible. The ARM simulator is written in Fortran 90, just as is the COSP. It is incorporated into COSP to facilitate use by the climate modeling community. In order to evaluate simulator output, the observational counterpart of the simulator output, radar reflectivity-height histograms (CFAD) is also generated from the ARM observations. This report includes an overview of the ARM cloud radar simulator VAP and the required simulator-oriented ARM radar data product (radarCFAD) for validating simulator output, as well as a user guide for operating the ARM radar simulator VAP.

54 ENVIRONMENTAL SCIENCES↗

Crosslinked Polyacrylamide Composite Hydrogels Impregnated with Fly Ash: Synthesis, Characterization and Their Application as Fractures Sealant for High Water Producing Zones in Oil and Gas Wells

Polymeric hydrogels are designed to serve many purposes in various fields of human endeavor. Herein, crosslinked polyacrylamide (PAM) composite hydrogels impregnated with coal fly ash (CFA) were synthesized, characterized and tested as fracture sealing agents in high water producing permeable zones in petroleum industry. The concept of utilizing CFA as an inorganic additive in the matrix of hydrogel emanates from the fact that CFA constitutes majorly alumina and silica. Both chemical oxides can induce the CFA to promote the inherent properties of hydrogel. Polyethyleneimine (PEI) was chosen as the crosslinking agent. Neat PAM/PEI hydrogel and PAM/PEI–CFA hydrogels at various CFA loadings (0.5, 1 and 2 wt%) were synthesized via a transamidation reaction pathway. The developed hydrogels were characterized by hybrid rheometer, FTIR, SEM and XRD instruments. Rheological results reveal that the PAM/PEI–CFA composite hydrogels embedded with various CFA quantities were more elastic than the neat PAM/PEI hydrogel, indicating the dispersion and reinforcing effect of CFA. The functional groups of these hydrogels were confirmed by the FTIR while SEM analysis show that the surface micrographs of neat PAM/PEI hydrogel and PAM/PEI–CFA1 hydrogel were porous in several regions. In contrast, the micrographs of PAM/PEI–CFA2 and PAM/PEI–CFA3 hydrogels demonstrated dense and “net-like” structural patterns. Further, XRD analysis revealed that CFA impregnation has a significant effect on the bulk structural properties of the fabricated hydrogels. The swelling rates of these hydrogels were determined by the gravimetric method and their diffusion parameters evaluated using Fickian diffusion and Schott-order kinetic models. Efficacy of the PAM/PEI–CFA composite hydrogel as fractures sealant in oil and gas wells was conducted at a typical reservoir temperature, 90 °C, and the outcome demonstrated considerable sealing potency.

36 MATERIALS SCIENCE↗

Thermal-shock experiments for separate-effects validation of UO 2 fuel fracture models

Because of the important role that fracture plays in the behavior of ceramic UO2 fuel in a nuclear reactor environment, fracture models are a major component of fuel performance codes. As with any aspect of fuel performance, it is crucial to validate these fracture models against experimental data; however, obtaining well-controlled data for conditions representative of a reactor environment is difficult. Quenching is proposed here as a relatively simple approach for using a laboratory environment to achieve conditions that approximate those of a reactor environment. In this paper, an experimental apparatus containing a single instrumented fuel pellet in a sealed section of copper tubing is developed. It is then applied to a series of seven experiments in which the apparatus is first heated to a high temperature (580-680°C) by immersion in a molten salt bath, then quenched in a cold bath (-10-4 °C). Development of these experiments was guided by numerical simulations, and post-test simulations were performed to aid in understanding the experimental behavior and assessing the accuracy of the predictions of fracture initiation and propagation. In addition, similar experiments were performed on solid copper rods to provide temperature-dependent heat transfer coefficients for use in simulations of these experiments. Here, this study demonstrates that quenching is a viable approach for generating thermal gradients representative of those in prototypical light-water reactor conditions at powers of about 5–10 kW/m. Fracture is expected to begin at these power levels, and moderate amounts of radial and axial cracking was observed in these quenching tests.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A facile pathway to prepare VO{sub 2} and V{sub 2}O{sub 3} powders via a carbothermal reduction process

The development of a highly efficient and low cost production process is instrumental for the wide application of VO{sub 2} and V{sub 2}O{sub 3}. In this paper, VO{sub 2} and V{sub 2}O{sub 3} powders are successfully prepared via carbothermal reduction of V{sub 2}O{sub 5} in a flowing Ar atmosphere at 973 K and 1423 K, respectively. Compared with the traditional methods, graphite is used as a reductant, which resulted in a low cost. The experimental results show that a high temperature assists in improving the kinetic rate. The phase transformation during the low-temperature reduction process between 948 K and 973 K occurs in the following sequential order: V{sub 2}O{sub 5}→V{sub 6}O{sub 13}→VO{sub 2}. When the temperature is 1423 K or 1473 K, the phase transformation can be described as follows: V{sub 2}O{sub 5}→V{sub 3}O{sub 5}→V{sub 2}O{sub 3}. Owing to the shrink of the volume, the as-prepared VO{sub 2} and V{sub 2}O{sub 3} particles could not maintain the original micro-morphology of V{sub 2}O{sub 5}. Relative to VO{sub 2}, the as-prepared V{sub 2}O{sub 3} particles are porous. It is also concluded that the V{sub 2}O{sub 3} can be easily oxidized to VO{sub 2}, when the partial pressure of O{sub 2} is in the range of 10{sup −8} atm to 10{sup −1} atm. Therefore, a reasonable reaction temperature and reaction time are important to prepare high purity V{sub 2}O{sub 3}.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Handheld readout electronics to fully exploit the particle discrimination capabilities of elpasolite scintillators

In this study, a new class of elpasolite scintillators has garnered recent attention due to the ability to perform as simultaneous gamma spectrometers and thermal neutron detectors. Such a dual-mode capability is made possible by pulse-shape discrimination (PSD), whereby the emission waveform profiles of gamma and neutron events are fundamentally unique. To take full advantage of these materials, we have developed the Compact Advanced Readout Electronics for Elpasolites (CAREE). This handheld instrument employs a multi-channel PSD-capable ASIC, custom micro-processor board, front-end electronics, power supplies, and a 2 in. photomultiplier tube for readout of the scintillator. The unit is highly configurable to allow for performance optimization amongst a wide sample of elpasolites which provide PSD in fundamentally different ways. We herein provide an introduction to elpasolites, then describe the motivation for the work, mechanical and electronic design, and preliminary performance results.

42 ENGINEERING↗

East Asian Study of Tropospheric Aerosols and their Impact on Regional Clouds, Precipitation, and Climate (EAST-AIR CPC )

Aerosols have significant and complex impacts on regional climate in East Asia. Cloud-aerosol-precipitation interaction (CAPI) remains most challenging in climate studies. The quantitative understanding of CAPI requires good knowledge of aerosols, ranging from their formation, composition, transport, as well as their radiative, hygroscopic, and microphysical properties. A comprehensive review is presented here centered on the CAPI based chiefly, but not limited to, publication in the special section named as EAST-AIRcpc, concerning (1) observation of aerosol loading and properties; (2) any relationships between aerosols and meteorological variables affecting CAPI; (3) mechanisms behind CAPI; and (4) quantification of CAPI and their impact on climate. Heavy aerosol loading in East Asia has significant radiative effects by reducing surface radiation, increasing air temperature, and lowering the boundary layer height. A key factor is aerosol absorption which is particularly strong in central China. This absorption can have a wide range of impacts such as creating an imbalance of aerosol radiative forcing at the top and bottom of the atmosphere, leading to inconsistent retrievals of cloud variables from space-borne and ground-based instruments. Aerosol radiative forcing can delay or suppress the initiation and development of convective clouds whose microphysics can be further altered by the microphysical effect of aerosols. For the same cloud thickness, the likelihood of precipitation is influenced by aerosol: suppressing light rain and enhancing heavy rain, delaying but intensifying thunderstorms, and reducing the onset of isolated showers in most parts of China. Rainfall has become more inhomogeneous and more extreme in the heavily polluted urban regions.

54 ENVIRONMENTAL SCIENCES↗

Design and first plasma measurements of the ITER-ECE prototype radiometer

On ITER, second harmonic optically thick electron cyclotron emission (ECE) in the range of 220-340 GHz will supply the electron temperature (T{sub e}). To investigate the requirements and capabilities prescribed for the ITER system, a prototype radiometer covering this frequency range has been developed by Virginia Diodes, Inc. The first plasma measurements with this instrument have been carried out on the DIII-D tokamak, with lab bench tests and measurements of third through fifth harmonic ECE from high T{sub e} plasmas. At DIII-D the instrument shares the transmission line of the Michelson interferometer and can simultaneously acquire data. Comparison of the ECE radiation temperature from the absolutely calibrated Michelson and the prototype receiver shows that the ITER radiometer provides accurate measurements of the millimeter radiation across the instrument band.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Dynamic high energy density plasma environments at the National Ignition Facility for nuclear science research

We present the generation of dynamic high energy density plasmas in the pico- to nano-second time domain at high-energy laser facilities affords unprecedented nuclear science research possibilities. At the National Ignition Facility (NIF), the primary goal of inertial confinement fusion research has led to the synergistic development of a unique high brightness neutron source, sophisticated nuclear diagnostic instrumentation, and versatile experimental platforms. These novel experimental capabilities provide a new path to investigate nuclear processes and structural effects in the time, mass and energy density domains relevant to astrophysical phenomena in a unique terrestrial environment. Some immediate applications include neutron capture cross-section evaluation, fission fragment production, and ion energy loss measurement in electron-degenerate plasmas. More generally, the NIF conditions provide a singular environment to investigate the interplay of atomic and nuclear processes such as plasma screening effects upon thermonuclear reactivity. Lastly, achieving enhanced understanding of many of these effects will also significantly advance fusion energy research and challenge existing theoretical models.

42 ENGINEERING↗

Image-based pupil plane characterization via a space-domain basis

© 2017 Society of Photo-Optical Instrumentation Engineers (SPIE). Aberration characterization plays a critical role in the development of any optical system. State-of-the-art lithography systems have the tightest aberration tolerances. We present an approach to image-based pupil plane amplitude and phase characterization using models built with a space-domain basis, in which aberration effects are separable. A polynomial model is constructed between the projections of the image intensity for chosen binary mask targets onto this basis and pupil amplitude or phase variation. This method separates model building and pupil characterization into two distinct steps, thus enabling rapid pupil characterization following data collection. The basis is related to both the transmission cross-coefficient function and the principal components of the image intensity. The pupil plane variation of a zone-plate lens from the Semiconductor High-NA Actinic Reticle Review Project (SHARP) at Lawrence Berkeley National Laboratory is examined using this method. Results are compared to pupil plane characterization using a previously proposed methodology where inverse solutions are obtained through an iterative process involving least-squares regression.

Levinson, Zac↗

Final Scientific Report - Electromagnetic Interactions in Self-Assembled Metallo-Dielectric Biomaterials

Achievements which resulted from previous DOE funding include: templated virus-like particle assembly thermodynamics, development of single particle photothermal absorption spectroscopy and dark- field spectroscopy instrumentation for the measurement of optical properties of virus-like nanoparticles, electromagnetic simulations of coupled nanoparticle cluster systems, virus contact mechanics, energy transfer and fluorescence quenching in multichromophore systems supported on biomolecular templates, and photo physical work on virus-aptamer systems. A current total of eight published research articles and a book chapter are acknowledging DOE support for the period 2013-2016.

36 MATERIALS SCIENCE↗

Sensitivity Analysis in Xyce

Parametric sensitivities of dynamic system responses are very useful in a variety of applications, including circuit optimization and uncertainty quantification. Sensitivity calculation methods fall into two related categories: direct and adjoint methods. Effective implementation of such methods in a production circuit simulator poses a number of technical challenges, including instrumentation of device models. This report documents several years of work developing and implementing direct and adjoint sensitivity methods in the Xyce circuit simulator. Much of this work sponsored by the Laboratory Directed Research and Development (LDRD) Program at Sandia National Laboratories, under project LDRD 14-0788.

42 ENGINEERING↗

Mutual Inductance Level Sensor for Use in Liquid Metals

Electromagnetic instrumentation capable of measuring the level of liquid metal has been developed at Argonne National Laboratory’s (ANL) Mechanisms Engineering Test Loop (METL). The mutual inductance level sensor (MILS) utilizes the electromagnetic coupling between two coil conductors and a surrounding liquid metal to determine the level of the liquid metal. Mineral insulated cables wrapped on a stainless steel core provide a durable sensor construction. The use of a sealed stainless steel thimble isolates the sensor from the high-temperature liquid metal, allowing for easy sensor maintenance. Modern digital electronics allow for reliable and accurate operation of the sensor. Two sensor variations have been designed and fabricated, and the first variation has seen extensive testing in a non-sodium testing stand as well as in the high-temperature sodium environment of METL. Electromagnetic finite-element analysis studies have been performed using the COMSOL Magnetic Fields Solver. Regular operation of the MILS will commence following in-situ calibration of the sensors in the METL environment.

36 MATERIALS SCIENCE↗

LLNL Macroscopic Anisotropic Explosives Research At INL National Security Test Range: Shot Narrative

This series of experiments is exploring new frontiers in explosives science, technology, and engineering. The extensive list of experiment shots is necessary to sort out what works and what does not work in searching for an environment that supports anisotropic detonation properties in explosives. These experiments have been designed to serve as an economical and efficient first-cut determination as to whether there is any validity to an explosive analog to a series circuit of electrical diodes. That is, the detonation moves more easily in the “forward” direction than the “backward” direction. The basic data gleaned from these experiments will be used to design experiments that will be shot in the 10 kg tank at the High Explosives Application Facility (HEAF) at the Lawrence Livermore National Laboratory. In turn, those shots that will be heavy in diagostics and instrumentation, providing basic data that will be used by simulation code developers in creating high explosive models that account for air gap and oblique explosive surfaces undergoing sympathetic detonation.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗