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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,099 records · Page 61

Pilot-Scale Modular Research Facility for Acidic Water Pollution Cleanup and Domestic Production of Critical Minerals for National Security

A recent study by Penn State researchers revealed that Pennsylvania AMD streams originate from abandoned mines, with coal refuse piles of the lower Kittanning coal seam containing the most valuable heavy rare earth elements. Penn State has developed a three-stage process to recover these critical minerals, tested it for proof of concept, and secured a patent. Funded by the US DOE, a modular pilot-scale research and development unit has been designed and built to process 1,000 gallons per day of AMD from a site managed by the Pennsylvania Department of Environmental Protection (PA DEP). The system will selectively recover iron, aluminum, rare earth elements, and cobalt-nickel-manganese concentrates from AMD, followed by a proprietary downstream purification process. These operations aim to produce concentrates of critical minerals while treating acid mine drainage to meet environmental standards and evaluate different feedstocks. This presentation will describe the design, operation, and innovations of the proposed process and pilot facility, emphasizing its role in promoting sustainable recovery of critical minerals from legacy waste streams.

Pisupati, Sarma V [Center for Critical Minerals, T↗

Microbial community response and SDS-PAGE reveal possible mechanism of waste activated sludge acidification enhanced by microaeration coupled thermophilic pretreatment

Aiming to strengthen the performance of waste activated sludge digestion, pretreatment is a prerequisite for keeping operations within an industrially acceptable time- frame. The performance of microaeration coupled with thermophilic (MT) pretreatment on waste activated sludge solubilization and acidification was investigated. The results showed that the maximum soluble organics concentrations, including soluble proteins and carbohydrates, reached 2290 mg COD/L in 24 h when the ventilation rate and temperature were 0.05 vvm and 70 °C. SDS-polyacrylamide gel electrophoresis (SDS-PAGE) test on pure-culture (E.coli) and scanning electron microscopy analysis indicated that MT pretreatment effectively destroyed microbial cell wall and resulted in an increase in soluble proteins. Polymerase chain reaction-denaturing gradient gel electrophoresis (PCR-DGGE) analysis revealed that MT pretreatment reduced the diversity of the bacterial community during pretreatment. Along with the dissolution of a large quantity of organic matter, microbial species such as Lactococcus and Methyloversatilis bloomed at the end of acidification period, which contributed to SCFAs production. Finally, this study revealed that MT pretreatment facilitated the WAS hydrolysis efficiency and enhanced SCFAs (3149 mg COD/L with fermentation for 96 h) production, especially for acetic acid (50%) accumulation, which provides a new perspective for the application and recovery of sludge resources.

59 BASIC BIOLOGICAL SCIENCES↗

Characterization of a Fast-Framing X-Ray Camera With Wide Dynamic Range for High-Energy Imaging

We present first characterization results, with a focus on high-flux measurements, of a fast-framing, wide-dynamic-range x-ray camera intended for high-energy imaging. The MM-PAD-2.1 uses an integrating pixel front-end with a charge removal architecture and in-pixel counter to extend the pixel well depth while maintaining low read noise across the full dynamic range. The charge-removal mechanism is dead-time-less (i.e., incoming signal continues to be integrated by the front-end while charge removal is taking place). The purpose of the highflux characterization was to determine the maximum sustained incident flux that could be measured while still exhibiting linear behavior. To this end, a 16 x 16 pixel prototype was tested at the Advanced Photon Source at Argonne National Laboratory using 10 keV photons generated by an undulator source. The intensity of the incident beam was varied over 3 orders of magnitude using a series of attenuators, and the signal integrated by the MM-PAD-2.1 prototype was compared to that measured by a He-filled ion chamber directly upstream. Initial results indicate linear performance up to ca. 10(10) ph/s in a spot spanning approximately 2 x 1.5 pixels (FWHM). The onset of transient radiation damage was observed during these measurements, characterized primarily by failure of digital readout from the detector ASIC. These effects were observed to reverse after annealing at 30 degrees C for several hours, with full recovery of the detector readout.

Shanks, Katherine S.↗

Water Recovery From Cooling Tower Plumes

According to studies by the UN and the US State Department, we are on the path to an extreme freshwater shortage by 2030. The US’s largest water withdrawal source is power plants, which account for 39% of total US freshwater withdrawals, mostly for cooling. Cooling towers are the most common cooling system. To solve these problems and enable efficient water- based cooling – Infinite Cooling’s novel technology uses electric fields to ionize the air, charge the escaping water leaving cooling towers and direct the water toward mesh collectors where it collects and gets recycled for use in the cooling system. This technology was developed at MIT and was reduced to practice on a lab-scale prototype, and a prototype at the MIT Cogeneration Power Plant. This DOE award funded taking this technology from a lab-scale prototype to TRL 5 on an operating cooling tower in the field at the MIT Nuclear Research Laboratory. The funding helped to design and optimize an electrostatic plume collection system and test it in high-fidelity lab setting and in actual field conditions on a cooling tower. Throughout the award, Infinite Cooling investigated the formation of plumes on cooling towers, used that information to optimize the design, material and electrical properties of the collection device and quantified the collection yield via flow rate and water quality.

20 FOSSIL-FUELED POWER PLANTS↗

The combined effects of hydrogen and aging condition on the deformation and fracture behavior of a precipitation-hardened nickel-base superalloy

The effect of hydrogen (H) on the deformation behavior of Monel K-500 in various isothermal heat treatment conditions (non-aged, under-aged, peak-aged, and over-aged) was assessed via uniaxial mechanical testing. H-charged and non-charged specimens were strained to failure to facilitate a comparison of ductility, fracture surface morphology, strength, and work hardening behavior. For all examined heat treatment conditions, H charging leads to a significant reduction in ductility, which is accompanied by a consistent change in fracture surface morphology from ductile microvoid coalescence to brittle intergranular fracture. While H charging led to a systematic enhancement in the yield strength of all heat treatments, the three age-hardened conditions exhibited a more than 2-fold increase relative to the non-aged heat treatment. This suggests that H modifies the dislocation–precipitate interactions, which also manifest themselves through changes in work hardening metrics related to the dislocation storage and recovery rates. In particular, the H-charged peak-aged specimen exhibited a significant increase in initial hardening (dislocation storage) rate relative to the H-charged under-aged specimen. Transmission electron microscopy of these samples revealed the onset of widespread dislocation looping in the H-charged peak-aged sample, in addition to the planar slip bands characteristic of the non-charged condition. This result suggests that hydrogen induces the particle shearing-to-looping transition at smaller particle sizes. Possible mechanistic explanations for this observed behavior are presented.

36 MATERIALS SCIENCE↗

A Dynamically-Reconfigurable Burst-Mode Link Using a Nanosecond Photonic Switch

Fast optical circuit switching has great potential to solve scaling issues with traditional packet-switch based networks and improve bandwidth and power efficiency in datacenter and high-performance computing applications. One difficultly in utilizing a fast optical switch is that the optical signal must be rapidly reacquired after each switching event so as to not significantly impact the overall throughput of the system. In this work we present a system-level integration of a nanosecond-scale $2 \times 2$ silicon photonic switch with a 25-Gbps burst-mode receiver that can lock in 31 ns. A novel FPGA-based control plane was used to generate test data, control the silicon photonic switch and burst-mode receiver, and measure bit errors at 12.5 and 20 Gbps. Error-free links (BER $< 10^{-12}$ ) with system-level reconfiguration times below 60 ns (at 20 Gbps) and 90 ns (at 12.5 Gbps) including bit- and frame-synchronization are demonstrated.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Risk-Aware Measurement Synchronization and Recovery for DSSE With Heterogeneous Data Sources

Power distribution systems are increasingly integrating heterogeneous sensors with varying data reporting rates and types, which pose challenges to achieving observability at the desired temporal resolution of distribution system state estimation (DSSE). Multisensor failures caused by extreme events exacerbate these issues, introducing substantial uncertainties into DSSE. This article proposes a novel solution to these challenges by ensuring high-resolution system observability despite heterogeneous data sources and multisensor failures. First, a deep learning architecture combining long short-term memory (LSTM) and graph convolutional network (GCN) is employed to synchronize meters with different reporting rates, aiming to achieve system observability. A random-walk-model-based approach is introduced to generate pseudo-measurements while properly characterizing their uncertainties under multisensor failures. Finally, a disaster-risk-informed observability metric (RiOM) is defined to quantify the uncertainty associated with state estimation results. The proposed framework offers deeper insights into the system observability on the fly compared with conventional analysis. The effectiveness of the framework is demonstrated on an IEEE standard test case and a large-scale real-world distribution feeder in mid-Minnesota in the U.S.

97 MATHEMATICS AND COMPUTING↗

Recrystallization Behavior and Super-Elasticity of a Metastable β-Type Ti-21Nb-7Mo-4Sn Alloy During Cold Rolling and Annealing

Based on the d-electron alloy design theory, a new metastable β-type titanium alloy for biomedical applications, Ti-21Nb-7Mo-4Sn (wt.%) was designed in this article. This theory predicted this alloy was a metastable single β-type titanium alloy with low elastic modulus at room temperature, and the β-phase transition (β to α″) would be easy to occur during the cold rolling. The evolution of microstructure and mechanical properties of this alloy during cold rolling plus annealing were investigated by means of x-ray diffraction, optical microscope, transmission electron microscope and mechanical properties test. The results indicate that only β phase can be identified in this alloy before cold rolling, while a large amount of lath martensite (α″ phase) appears after cold rolling due to stress-induced martensitic transformation, which is in accordance with the prediction of the d-electron alloy design theory. The recrystallization nucleation occurs preferentially in the martensite lath region during the subsequent annealing process, and this region forms a large number of nano-crystals and microcrystals, showing that cold rolling plus annealing can become a new process for refining grains. Compared with casting and cold rolling samples, the annealing materials at 923 K for 10 min have excellent comprehensive mechanical properties with lower elastic modulus (58 GPa) and higher elastic recovery rate (35.39%).

36 MATERIALS SCIENCE↗

Capture of volatile RuO 4 from oxidized simulated used nuclear fuel solutions

Ruthenium is a challenging fission product in used nuclear fuel (UNF) reprocessing due to its complex redox chemistry, variable speciation in nitric acid, partial extractability, and volatility. This work presents a strategy for Ru removal based on the volatilization of RuO 4 using the strong oxidant sodium bismuthate, followed by RuO 2 deposition onto various substrates. Among the materials tested, polymer-based substrates such as polyolefin wax film (Parafilm®), exhibited superior performance, achieving up to near-quantitative Ru removal from solution. After dissolution of the substrate, 99.6% of the Ru was recovered as RuO 2 . The deposition mechanism onto the polyolefin wax film involves both physisorption and chemical reaction through oxidative cleavage of olefinic bonds within the polymer. In contrast, on inorganic substrates such as Al foil, RuO 4 undergoes incomplete surface adsorption and reduction, as confirmed by FTIR and XPS analyses. This approach remains effective under conditions of simulated oxidation of UNF solutions, selectively removing Ru while leaving other fission products in solution. As a result, capture of RuO 4 offers a practical and efficient strategy for ruthenium decontamination and recovery, offering a route for integration into existing UNF reprocessing flowsheets to enhance overall process safety and performance.

Ruthenium↗

Improved characterization of heterogeneous permeability in saline aquifers from transient pressure data during freshwater injection

Managing recharge of freshwater into saline aquifers requires accurate estimation of the heterogeneous permeability field for maximizing injection and recovery efficiency. Here we present a methodology for subsurface characterization in saline aquifers that takes advantage of the density difference between the injected freshwater and the ambient saline groundwater. We combine high-resolution forward modeling of density-driven flow with an efficient Bayesian geostatistical inversion algorithm. In the presence of a density difference between the injected and ambient fluids due to differences in salinity, the pressure field is coupled to the spatial distribution of salinity. This coupling renders the pressure field transient: the time evolution of the salinity distribution controls the density distribution which then leads to a time-evolving pressure distribution. We exploit this coupling between pressure and salinity to obtain an improved characterization of the permeability field without multiple pumping tests or additional salinity measurements. We show that the inversion performance improves with an increase in the mixed convection ratio—the relative importance between viscous forces from injection and buoyancy forces from density difference. Thus, our work shows that measuring transient pressure data at multiple sampling points during freshwater injection into saline aquifers can be an effective strategy for aquifer characterization, key to the successful management of aquifer recharge.

54 ENVIRONMENTAL SCIENCES↗

Optimal Network Reconfiguration and Scheduling With Hardware-in-the-Loop Validation for Improved Microgrid Resilience

With the increased occurrence of various major extreme weather events, power outages and prompt power system restorations have recently drawn more attention to the resilience and recovery of power systems. From the perspective of a more resilient power delivery at the distribution grid, system restoration using network topology reconfiguration together with optimal scheduling of distributed energy resources are adopted in this paper. The proposed optimization model aims at minimizing the total load shedding cost and other operational costs, in which linearized topological constraints borrowed from graph theory and linearized DistFlow models are respectively used to maintain the radial network topology and power flow balance after system contingencies. To demonstrate the applicability of the proposed strategy, a real-world case study of a networked three-microgrid system in Adjuntas, Puerto Rico, is used with the consideration of different independent/interconnected microgrid scenarios, contingencies, and fairness settings. Furthermore, hardware-in-the-loop testing is conducted for the same three-microgrid network, where the closely matched results with the simulated ones have validated the effectiveness of the proposed restoration strategy, which is now ready to move one step forward towards field deployment. Finally, to test the proposed restoration strategy in a larger networked system, the modified IEEE-33 bus test distribution system is considered, and the results show a more resilient power delivery for critical loads under three and four line outages.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Development of Two-Phase Dense Fluid Expander for Advanced Cryogenic Air Separation and Low-Grade Heat Recovery

Cryogenic air separation represents the state-of-the-art technology to produce oxygen to feed coal gasification units. Given the maturity of this technology, it is difficult to identify opportunities to improve process efficiency and reduce the cost of the oxygen produced. However, Air Products conducted research and a feasibility investigation into the use of a two-phase (liquid-vapor) dense fluid expander (DFE) to improve the overall efficiency of cryogenic air separation. Demonstration of this novel concept was intended to allow two important process improvements: 1) elimination of the need for the DFE discharge to be single phase 2) expansion of the operating region of expanders in ASU service. Expanding the scope of turboexpander application beyond current application limits and traditional device designs would allow an increase in power recovery, and application of refrigeration and power recovery at new locations in process cycles would also enable the implementation of new process concepts. These new process concepts include power recovery from compression waste heat and refrigeration extraction and power recovery by replacing let-down valves with two-phase DFEs. Considering the maturity of cryogenic air separation, these new process options could represent a step change in power reduction and provide significant savings in operating costs. These new concepts would be particularly well-suited to large-scale oxygen production by cryogenic air separation and would enhance the economics of producing oxygen for use in coal gasification processes. Rotoflow, an Air Products business unit, manufactures dense fluid expanders in Pennsylvania for sites around the world. This project was executed in two phases, which are illustrated in Figure 1 below. Phase 1 consisted of a feasibility investigation of multiple applications of two-phase DFEs. In Phase 2, devices were identified, designed, fabricated and tested to explore the feasibility of commercial applications of DFEs operating in two-phase service. Engineering and testing were performed by personnel in Air Products’ Rotoflow business unit, with coordination with other Air Products business units.

01 COAL, LIGNITE, AND PEAT↗

Characterization of a fluvial aquifer at a range of depths and scales: the Triassic St Bees Sandstone Formation, Cumbria, UK

Fluvial sedimentary successions represent porous media that host groundwater and geothermal resources. Additionally, they overlie crystalline rocks hosting nuclear waste repositories in rift settings. The permeability characteristics of an arenaceous fluvial succession, the Triassic St Bees Sandstone Formation in England (UK), are described, from core-plug to well-test scale up to ~1 km depth. Within such lithified successions, dissolution associated with the circulation of meteoric water results in increased permeability (K~10{sup −1}–10{sup 0} m/day) to depths of at least 150 m below ground level (BGL) in aquifer systems that are subject to rapid groundwater circulation. Thus, contaminant transport is likely to occur at relatively high rates. In a deeper investigation (> 150 m depth), where the aquifer has not been subjected to rapid groundwater circulation, well-test-scale hydraulic conductivity is lower, decreasing from K~10{sup −2} m/day at 150–400 m BGL to 10{sup −3} m/day down-dip at ~1 km BGL, where the pore fluid is hypersaline. Here, pore-scale permeability becomes progressively dominant with increasing lithostatic load. Notably, this work investigates a sandstone aquifer of fluvial origin at investigation depths consistent with highly enthalpy geothermal reservoirs (~0.7–1.1 km). At such depths, intergranular flow dominates in unfaulted areas with only minor contribution by bedding plane fractures. However, extensional faults represent preferential flow pathways, due to presence of high connective open fractures. Therefore, such faults may (1) drive nuclear waste contaminants towards the highly permeable shallow (< 150 m BGL) zone of the aquifer, and (2) influence fluid recovery in geothermal fields.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Navigating Urban Mobility: Evaluating Infrastructure Strategies for Enhanced Energy-Efficient Access for Micromobility

Cities and communities continue to expand pedestrian and bicycle infrastructure as part of their sustainable mobility and post-pandemic recovery plans. However, the emergence of micro-mobility (e.g., electric bicycles) has created new challenges for urban transport planning. As the popularity of micro-mobility modes has grown, so have safety concerns due to rising injuries, thus challenging many cities to come up with regulatory measures that enable efficient access while minimizing negative impacts from micro-mobility. Leveraging the Open-Source Tool (Mobility Energy Productivity metric), powered by an open-source dataset (OpenStreetMap), and enhanced through the incorporation of perceived discomfort (level-of-traffic stress), this research study focuses on evaluating the accessibility implications of infrastructure planning and regulatory measures for micro-mobility. Five scenarios pertaining to level of traffic stress, sidewalk access, traffic calming, and bike lane coverage were tested in the Denver-Aurora region in Colorado. Maximum improvements in energy-efficient access are realized when allowing sidewalks for micro-mobility use. Cities and planning agencies could leverage this information to assess sidewalk use policies for micro-mobility, while ensuring pedestrian safety and ADA access. Results indicate that expansion of bicycle lane coverage yields 11% accessibility benefits for micro-mobility compared to implementing traffic calming measures yielding 3% accessibility improvements. Further, it was observed most of the population in the Denver-Aurora region is experiencing lower accessibility in-part due to presence of a high-stress connections in the network. Although not generalizable, the use of open-source data and access calculation methodology, make this analysis reproducible and transferable to other locations.

ADVANCED PROPULSION SYSTEMS↗

Recovery of Natural Gas Equipment Emissions into Gas Compression Engines for the Reduction of Potential Greenhouse Gas Emissions

Since the turn of the millennium, the United States (U.S.) oil and natural gas (ONG) industry has nearly doubled its natural gas production rate. As a result, the ONG industry has recently come under increasing scrutiny for its contributions to greenhouse gas (GHG) emissions. Consequently, various solutions to this problem have been proposed and formulated to reduce the impacts of GHG emissions on the environment. West Virginia University (WVU) have found it important to research the impacts of recovering vented gas streams into prime-mover engines. The U.S. Department of Energy (DOE) and National Energy Technology Laboratory (NETL) have granted WVU funding to research and develop a “Methane Mitigator” (M2) - a “Scalable Vent Mitigation Strategy to Simultaneously Reduce Methane Emissions and Fuel Consumption from the Compression Industry.” One of the main areas of interest for this research was the collection of emissions from natural gas equipment into a Caterpillar G3508J natural gas compression engine. The parameters being analyzed from the engine were brake-specific emissions and power output. The emissions sources considered for this research were pneumatic controllers (PCs), reciprocating compressor vents, and the engine’s open crankcase breather. The compressor vent and PC emissions were simulated using a mass flow controller (MFC) and flowed into the engine using two separate methods: (1) directly into the air intake, and (2) through a retrofitted closed crankcase ventilation system (CCV), serving as a buffer volume. The crankcase emissions were quantified without the CCV, and the impact on exhaust emissions from circulating the crankcase gases into the intake was measured. The simulated compressor vent and PC flows from the MFC had limited effect on the steady state operation of the engine and resulting performance. When the simulated flows were fed directly into the engine’s air intake, the changes within the engine’s continuous performance and emission parameters were larger but lasted for shorter durations. Conversely, when the simulated flows were fed into the CCV before entering the air intake, the changes in the engine’s performance and emission parameters were less pronounced for continuous analysis but lasted for longer durations. In either case, the continuous emission changes in both emissions and performance varied in size depending on the test scenario being run, but the cycle average changes in emissions and performance showed little impact overall compared to the engine’s baseline operation. As a result, the inclusion of a CCV shows a decrease in baseline carbon dioxide equivalent (CO2-eq.) engine emissions (from combined exhaust and open crankcase) of almost 4%. Likewise, the CCV inclusion reduced baseline total methane (CH4) from combined exhaust and open crankcase by upwards of 16%. These atmospheric emissions only decreased further with the inclusions of collected PC and compressor vent flows. The resulting changes in time-averaged rated exhaust behavior (or lack thereof) prove that the proposed M2 system could likely be deployed at sites with modern lean-burn natural gas engines as a viable option for reducing and eliminating potential GHG sources that would have otherwise been unutilized as energy sources.

03 NATURAL GAS↗

Using post-processing heat treatments to elucidate precipitate strengthening of additively manufactured superalloy 718

The poor machinability and extensive work hardening of Ni-based superalloys makes additive manufacturing an attractive option for producing geometrically complex components with distinct microstructures. Although previous studies show recovery of high strength at room temperature, very few studies demonstrate successful properties at elevated temperatures required for industrial applications. Here, the objectives of this study are to present a post-build heat treatment for high strength across a wide temperature range, determine the strength contribution of nanoscale precipitating phases to the overall mechanical properties of superalloy 718, and from these, provide a comprehensive microstructure-property relationship for wrought and AM 718 to guide efforts to simulate the properties of AM components. Laser powder bed fusion–produced superalloy 718 was characterized at multiple length scales using scanning electron microscopy and transmission electron microscopy in the as-built condition and with multiple heat treatments designed to form combinations of γ', γ", and δ precipitates. Uniaxial tensile tests performed from room temperature to 600 °C on subsize specimens determined the yield strength, elastic modulus, ultimate tensile strength, fracture stress, and uniform elongation. Precipitates in this work proved to be weak barriers to dislocation motion through a dispersed barrier model, but they provided strength to the alloy through their consistent high density. The relative contribution to the yield strength from γ" remained consistent between 48% and 57% of the total strength up to 600 °C, the primary influence on the high temperature strength of superalloy 718. The strength factors for γ" and δ precipitates were found to trend inversely with tensile test temperature and may be attributable to the differences in precipitate coherency. A post-build heat treatment is recommended to maintain high strength at elevated temperatures. A quantitative microstructure-property relationship, dependent on precipitate size, density, and morphology, was derived and can estimate the yield strength across a wide temperature range applicable to the operational regimes for superalloy 718.

36 MATERIALS SCIENCE↗

Atmospheric and Long-term Aging Effects on the Electrical Properties of Variable Thickness WSe 2 Transistors

Atmospheric and long-term aging effects on electrical properties of WSe 2 transistors with various thicknesses are examined. While countless published studies report electrical properties of transition-metal dichalcogenide materials, many are not attentive to testing environment or to age of samples, which we have found significantly impacts results. Our as-fabricated exfoliated WSe 2 pristine devices are predominantly n-type, which is attributed to selenium vacancies. Transfer characteristics of as-fabricated devices measured in air then vacuum reveal physisorbed atmospheric molecules significantly reduced n-type conduction in air. First-principles calculations suggest this short-term reversible atmospheric effect can be attributed primarily to physisorbed H 2 O on pristine WSe 2 , which is easily removed from the pristine surface in vacuum due to the low adsorption energy. Devices aged in air for over 300 h demonstrate irreversibly increased p-type conduction and decreased n-type conduction. Moreover, they develop an extended time constant for recovery of the atmospheric adsorbents effect. Short-term atmospheric aging (up to approximately 900 h) is attributed to O 2 and H 2 O molecules physisorbed to selenium vacancies where electron transfer from the bulk and adsorbed binding energies are higher than the H 2 O-pristine WSe2. The residual/permanent aging component is attributed to electron trapping molecular O 2 and isoelectronic O chemisorption at selenium vacancies, which also passivates the near-conduction band gap state, p-doping the material, with very high binding energy. All effects reflected have the expected thickness dependence, namely, thinner devices are more sensitive to atmospheric and long-term aging effects.

36 MATERIALS SCIENCE↗

Dynamic flow stress of pure polycrystalline aluminum: Pressure-shear plate impact experiments and extension of dislocation-based modeling to large strains

The dynamic thermo-mechanical behavior of pure aluminum has attracted renewed interest lately due to experimental observations of an anomalous increase in Hugoniot Elastic Limit (HEL) at incipient plasticity and elevated temperatures in polycrystalline pure metals. In context of current dislocation-mediated plasticity models for metals, this increase in dynamic strength is indicative of a transition in the rate controlling mechanism for dislocation glide from being thermally assisted to phonon-drag restricted due to increase in phonon viscosity at elevated temperatures. Though these studies have helped to shed light on these important mechanisms operative in FCC metals at incipient plasticity, the extent to which they contribute to flow stress, particularly at larger strains, remains unclear. Here, we address these questions through a combined experimental and modeling effort focused on investigating the evolution of dynamic flow stress in polycrystalline aluminum using experimental data gathered from a series of combined pressure-and-shear plate impact (PSPI) experiments designed to reveal the flow stress of pure aluminum at strain rates ~ 10 5 /s, plastic strains of up to 40% and temperatures ranging from room to 866 K. In all cases, the flow stress of aluminum, as inferred from the measured transverse particle velocity histories at the free surface of an elastic tungsten carbide target plate, reveals saturation with increasing plastic strains at stress levels that decrease with increasing test temperatures. Numerical simulations are performed to correlate the experimentally observed temperature and strain rate dependence of flow stress at small and large plastic strains using the Austin-McDowell dislocation-mediated plasticity model parametrized to normal plate impact experiments conducted in an earlier study by Zaretsky and Kanel (2012). Extensions to the model are made to better represent dynamic behavior of pure aluminum at larger plastic strains as observed in elevated temperature split Hopkinson Pressure bar (SPHB) experiments of Samanta (1971) and Lindholm and Yeakly (1965), and the combined pressure-and-shear plate-impact experiments conducted in the present study. The main theoretical extension to the Austin-McDowell model made in this paper is the introduction of a new rate- and temperature- dependent dynamic recovery function, which can potentially allow for an effective reduction in the rate of accumulation of dislocations at large plastic strains. The numerical predictions of the revised and re-calibrated plasticity model are brought into agreement with the experimental observations, correlating sufficiently well with dynamic yield stress at incipient plasticity and the flow stress levels at larger plastic strains, plastic strain rates in the range 10 3 – 10 6 /s, and elevated temperatures up to near melt. The model, in concert with the experimental measurements, suggests that at incipient plasticity the rate governing mechanism for plastic flow is phonon-drag restricted dislocation glide, whereas, at higher magnitudes of plastic strain, it transitions to stress-assisted thermally activated glide. The transition between these two rate governing mechanisms is controlled by the evolution of dislocations throughout the deformation process.

36 MATERIALS SCIENCE↗