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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,099 records · Page 61
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

The Stable Solar Analyzer

Progress in the development of an instrument with very high (1:10 billion) wavelength stability designed to measure solar surface velocities and magnetic fields is reported. The instrument determines Doppler and Zeeman shifts in solar spectral lines by a 6-point weighted average. It is built around an electrically tunable solid lithium-niobate Fabry-Perot etalon that is stabilized against a diode laser which itself is locked to a resonance line of cesium 133. Key features are the etalon, which acts as a wide-angle 0.017-nm solar filter, the camera with a specially stabilized shutter, and the instrument control and data collection system. Use of the instrument in helioseismological research is emphasized.

Rust, D. M.↗
DOE OSTI2024

Interdependence of Support Wettability - Electrodeposition Rate- Sodium Metal Anode and SEI Microstructure

Here, this study examines how current collector support chemistry (sodiophilic intermetallic Na 2 Te vs. sodiophobic baseline Cu) and electrodeposition rate affect microstructure of sodium metal and its solid electrolyte interphase (SEI). Capacity and current (6 mAh cm -2 , 0.5–3 mA cm -2 ) representative of commercially relevant mass loading in anode-free sodium metal battery (AF-SMBs) are analyzed. Synchrotron X-ray nanotomography and grazing-incidence wide-angle X-ray scattering (GIWAXS) are combined with cryogenic ion beam (cryo-FIB) microscopy. Highlighted are major differences in film morphology, internal porosity, and crystallographic preferred orientation e.g. (110) vs. (100) and (211) with support and deposition rate. Within the SEI, sodium fluoride (NaF) is more prevalent with Te-Cu versus sodium hydride (NaH) and sodium hydroxide (NaOH) with baseline Cu. Due to competitive grain growth the preferred orientation of sodium crystallites depends on film thickness. Mesoscale modeling delineates the role of SEI (ionic conductivity, morphology) on electrodeposit growth and onset of electrochemical instability.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Grain Boundary Engineering for Achieving High Thermoelectric Performance in n-Type Skutterudites

Grain or phase boundaries play a critical role in the carrier and phonon transport in bulk thermoelectric materials. Previous investigations about controlling boundaries primarily focused on the reducing grain size or forming nanoinclusions. Herein, liquid phase compaction method is first used to fabricate the Yb–filled CoSb 3 with excess Sb content, which shows the typical feature of low–angle grain boundaries with dense dislocation arrays. Seebeck coefficients show a dramatic increase via energy filtering effect through dislocation arrays with little deterioration on the carrier mobility, which significantly enhances the power factor over a broad temperature range with a high room–temperature value around 47 μW cm –2 K –1 . Simultaneously, the lattice thermal conductivity could be further suppressed via scattering phonons via dense dislocation scattering. As a result, the highest average figure of merit ZT of ≈1.08 from 300 to 850 K could be realized, comparable to the best reported result of single or triple–filled Skutterudites. Furthermore, this work clearly points out that low–angle grain boundaries fabricated by liquid phase compaction method could concurrently optimize the electrical and thermal transport properties leading to an obvious enhancement of both power factor and ZT .

36 MATERIALS SCIENCE↗
DOE OSTI2025

Water-In-Glass: A Self-Supporting Inorganic Aqueous Electrolyte

Aqueous rechargeable sodium-ion batteries (ARNIBs) are emerging as cost-effective and safe candidates for large-scale energy storage applications. However, their advancement has been constrained by the narrow electrochemical stability window (ESW) of conventional aqueous electrolytes (1.23 V). Here, in this study, we present a transformative approach using an inexpensive and rapidly dissolvable inorganic glass material, water glass (W-glass), to significantly enhance the ESW and enable the development of solid-state, self-supporting aqueous film (SSA film) electrolytes. These SSA film electrolytes exhibit an extended ESW of up to 3.5 V and a conductivity of ∼10 –4 S/cm at room temperature. Structural analysis using magic-angle spinning nuclear magnetic resonance (NMR) and solution-state NMR reveals that the dissolution of W-glass in water is driven by the interdependent hydrolysis of P–O–P linkages and Na + –H + ion exchange. This work offers a cost-effective and scalable solution for advancing high-performance ARNIB technology, addressing critical barriers to commercial adoption.

Electrochemical stability window↗
DOE OSTI2019

Active Microheology, Hall Effect, and Jamming in Chiral Fluids

We investigate the motion of a probe particle driven through a chiral fluid composed of circularly swimming disks. We find that the probe particle travels in both the longitudinal direction, parallel to the driving force, and in the transverse direction, perpendicular to the driving force, giving rise to a Hall angle. Under constant driving force, we show that the probe particle velocity in both the longitudinal and transverse directions exhibits nonmonotonic behavior as a function of the activity of the circle swimmers. The Hall angle is maximized when a resonance occurs between the frequency of the chiral disks and the motion of the probe particle. As the density of the chiral fluid increases, the Hall angle gradually decreases before reaching zero when the system enters a jammed state. We demonstrate that the onset of jamming depends on the chiral particle swimming frequency, with a fluid state appearing at low frequencies and a jammed solid occurring at high frequencies.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1974

An experimental investigation of jet plume simulation with solid circular cylinders

An investigation has been conducted in the Langley 16-foot transonic tunnel to determine the effectiveness of utilizing solid circular cylinders to simulate the jet exhaust plume for a series of four isolated circular arc afterbodies with little or no flow separation. This investigation was conducted at Mach numbers from 0.40 to 1.30 at 0 deg angle of attack. Plume simulators with simulator diameter to nozzle exit diameter ratios of 0.82, 0.88, 0.98, and 1.00 were investigated with one of the four configurations while the 0.82 and 1.00 simulators were investigated with the other three. Reynolds number based on maximum model diameter varied from approximately 1.50 to 2.14 million.

Reubush, D. E.↗
NASA NTRS1987

Combustion/particle sizing experiments at the Naval Postgraduate School Combustion Research Laboratory

Particle behavior in combustion processes is an active research area at NPS. Currently, four research efforts are being conducted: (1) There is a long standing need to better understand the soot production and combustion processes in gas turbine combustors, both from a concern for improved engine life and to minimize exhaust particulates. Soot emissions are strongly effected by fuel composition and additives; (2) A more recent need for particle sizing/behavior measurements is in the combustor of a solid fuel ramjet which uses a metallized fuel. High speed motion pictures are being used to study rather large burning particles; (3) In solid propellant rocket motors, metals are used to improve specific impulse and/or to provide damping for combustion pressure oscillations. Particle sizing experiments are being conducted using diode arrays to measure the light intensity as a function of scattering angle; (4) Once a good quality hologram is attained, a need exists for obtaining the particle distributions from hologram in a short period of time. A Quantimet 720 Image Analyzer is being used to reconstruct images.

Powers, John↗
NASA NTRS1951

Empirical relation between induced velocity, thrust, and rate of descent of a helicopter rotor as determined by wind-tunnel tests on four model rotors

The empirical relation between the induced velocity, thrust, and rate of vertical descent of a helicopter rotor was calculated from wind tunnel force tests on four model rotors by the application of blade-element theory to the measured values of the thrust, torque, blade angle, and equivalent free-stream rate of descent. The model tests covered the useful range of C(sub t)/sigma(sub e) (where C(sub t) is the thrust coefficient and sigma(sub e) is the effective solidity) and the range of vertical descent from hovering to descent velocities slightly greater than those for autorotation. The three bladed models, each of which had an effective solidity of 0.05 and NACA 0015 blade airfoil sections, were as follows: (1) constant-chord, untwisted blades of 3-ft radius; (2) untwisted blades of 3-ft radius having a 3/1 taper; (3) constant-chord blades of 3-ft radius having a linear twist of 12 degrees (washout) from axis of rotation to tip; and (4) constant-chord, untwisted blades of 2-ft radius. Because of the incorporation of a correction for blade dynamic twist and the use of a method of measuring the approximate equivalent free-stream velocity, it is believed that the data obtained from this program are more applicable to free-flight calculations than the data from previous model tests.

Castles, Walter, Jr.↗
NASA NTRS1951

Empirical Relation Between Induced Velocity, Thrust, and Rate of Descent of a Helicopter Rotor as Determined by Wind-tunnel Tests on Four Model Rotors

The empirical relation between the induced velocity, thrust, and rate of vertical descent of a helicopter rotor was calculated from wind tunnel force tests on four model rotors by the application of blade-element theory to the measured values of the thrust, torque, blade angle, and equivalent free-stream rate of descent. The model tests covered the useful range of C(sub t)/sigma(sub e) (where C(sub t) is the thrust coefficient and sigma(sub e) is the effective solidity) and the range of vertical descent from hovering to descent velocities slightly greater than those for autorotation. The three bladed models, each of which had an effective solidity of 0.05 and NACA 0015 blade airfoil sections, were as follows: (1) constant-chord, untwisted blades of 3-ft radius; (2) untwisted blades of 3-ft radius having a 3/1 taper; (3) constant-chord blades of 3-ft radius having a linear twist of 12 degrees (washout) from axis of rotation to tip; and (4) constant-chord, untwisted blades of 2-ft radius. Because of the incorporation of a correction for blade dynamic twist and the use of a method of measuring the approximate equivalent free-stream velocity, it is believed that the data obtained from this program are more applicable to free-flight calculations than the data from previous model tests.

Castles, Walter, Jr↗
NASA NTRS1999

Combustion and Flammability Characteristics of Solids at Microgravity in very Small Velocity Flows

Fires still remain as one of the most important safety risks in manned spacecraft. This problem will become even more important in long endurance non orbital flights in which maintenance will be non existing or very difficult. The basic process of a fire is the combustion of a solid at microgravity conditions in O2/N2 mixtures. Although a large number of research programs have been carried out on this problem, especially on flame spreading, several aspects of these processes are not yet well understood. It may be mentioned, for example, the temperature and characteristic of low emissivity flames in the visual range that take place in some conditions at microgravity; and there exists a lack of knowledge on the influence of key parameters, such as convective flow velocities of the order of magnitude of typical oxygen diffusion velocities. The "Departamento de Motopropulsion y Termofluidodinamica" of the "Universidad Politecnica de Madrid, Escuela Tecnica Superior de Ingenieros Aeronauticos" is conducting a research program on the combustion of solids at reduced gravity conditions within O2/N2 mixtures. The material utilized has been polymethylmethacrylate (PMMA) in the form of rectangular slabs and hollow cylinders. The main parameters of the process have been small convective flow velocities (including velocity angle with the direction of the spreading flame) and oxygen concentration. Some results have also been obtained on the influence of material thickness and gas pressure.

Sanchez-Tarifa, C.↗
DOE OSTI2019

Effect of Zn, Ga and Gd Doping on Structural and Magnetic Properties of Nanonickel Ferrite Prepared by Two Different Methods

Zn/Ga/Gd-substituted NiFe{sub 2}O{sub 4} was formed by solid state reaction and citrate methods. The influence of substitutions on phase formation, the strain, crystallize size, cations distribution and magnetic properties have been examined by X-ray diffraction, Mössbauer effect spectrometer, Fourier-transform infrared, and vibrating sample magnetometer. Zn/Ga/Gd substituted NiFe{sub 2}O{sub 4} samples prepared by solid state method showed that as gadolinium introduced into the system, a second phase was formed with a small percentage while samples prepared by citrate method exhibited a single phase. The distributions of different cations between different sites were determined by both Mössbauer effect spectroscopy, modified Bertaut and Rietveld analysis. Mössbauer technique at room temperature showed that samples synthesized by the ceramic method have a magnetic order while samples prepared by citrate method have a superparamagnetic nature. The canting angle between magnetic ions was increased by increased the amount of Zn in samples prepared by both methods.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Quantifying Twist Angles in Cuprate Heterostructures with Anisotropic Raman Signatures

Artificially engineered twisted van der Waals (vdW) heterostructures have unlocked new pathways for exploring emergent quantum phenomena and strongly correlated electronic states. Many of these phenomena are highly sensitive to the twist angle, which can be deliberately tuned to tailor the interlayer interactions. This makes the twist angle a critical tunable parameter, emphasizing the need for precise control and accurate characterization during device fabrication. In particular, twisted cuprate heterostructures based on Bi 2 Sr 2 CaCu 2 O 8 + x (BSCCO) have demonstrated angle-dependent superconducting properties, positioning the twist angle as a key tunable parameter. However, the twisted interface is highly unstable under ambient conditions and vulnerable to damage from conventional characterization tools such as electron microscopy or scanning probe techniques. In this work, a fully non-invasive, polarization-resolved Raman spectroscopy approach is introduced for determining twist angles in artificially stacked BSCCO heterostructures. By analyzing twist-dependent anisotropic vibrational Raman modes, particularly utilizing the out-of-plane A 1g vibrational mode of Bi/Sr at ≈116 cm −1 , clear optical fingerprints of the rotational misalignment between cuprate layers are identified. The high-resolution confocal Raman setup, equipped with polarization control and RayShield filtering down to 10 cm −1 , allows for reliable and reproducible measurements without compromising the material's structural integrity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Polymer Nanogels as Reservoirs To Inhibit Hydrophobic Drug Crystallization

Herein the effects of cross-link density and composition on the loading and in vitro dissolution of the drug phenytoin as amorphous solid dispersions in emulsion polymerized poly(N-isopropylacrylamide) (PNIPAm) and poly(N-isopropylacrylamide-co-N,N-dimethylacrylamide) nanogels were investigated near the lower critical solution temperature (LCST). Nanogel size and particle density in phosphate buffered saline were quantified by dynamic light scattering (DLS) and viscometry experiments, while drug–nanogel interactions were revealed by cross peaks in aqueous-state nuclear Overhauser effect spectroscopy measurements. Spray-dried dispersions (SDDs) of drug-loaded PNIPAm nanogel particles (R ≈ 43 nm) were directly visualized by cryogenic transmission electron microscopy and further quantified by small-angle X-ray scattering during in vitro dissolution. SDD dissolution profiles were highly dependent on the nanogel cross-link density and directly correlated with the state of dispersion of the drug-loaded nanogel particles. A balance between net particle hydrophobicity and hydrophilicity along with the distance in temperature from the LCST are shown to dictate the in vitro dissolution of the amorphous solid dispersions. Solubility enhancement mechanisms disclosed in this study provide essential guidance for the design of effective nanogels for oral drug delivery applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Fabrication of Al-Zn solid solution via friction stir processing

Highlights: • Thermomechanical nature of FSP was utilized for mechanical alloying. • Zn particles dissolved in Al during FSP to form solid solution. • Second pass of FSP lead to homogenization and partial decomposition of the solid solution. • Processed alloy exhibited improved hardness over base and FSPed metal. • The process can be adopted for site specific property enhancement. - Abstract: The present study demonstrates that friction stir processing (FSP) can be used as a mechanical alloying tool to process solid solution. Zn was incorporated in commercially pure aluminium by multi-pass FSP leading to its dissolution and formation of supersaturated solid solution which was confirmed by X-ray diffraction and scanning electron microscopy. The hardness across the stir zone matched with the distribution of Zn and was significantly improved compared to the base metal. The supersaturated solid solution that formed in the first pass, partially decomposed during the second pass, leading to the formation of fine Al-Zn precipitates. Thermal stability of the microstructure against abnormal grain growth was also improved after the second pass due to the pinning effect of the grain boundary precipitates. FSP also caused grain refinement of the alloy yielding fine equiaxed grains in the range of 4–6 μm with a high fraction (> 67%) of high angle grain boundaries. Such microstructure is conducive for isotropic properties and the fact that the microstructure is stable against thermal cycles make the process suitable for selective alloying for location specific property enhancement.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Complex Chern–Simons Theory at Level k via the 3d–3d Correspondence

Herein, we use the 3d–3d correspondence together with the DGG construction of theories T n [ M ] labelled by 3-manifolds M to define a non-perturbative state-integral model for \({SL(n,\mathbb{C})}\) Chern–Simons theory at any level k , based on ideal triangulations. The resulting partition functions generalize a widely studied k = 1 state-integral, as well as the 3d index, which is k = 0. The Chern–Simons partition functions correspond to partition functions of T n [ M ] on squashed lens spaces L ( k , 1). At any k , they admit a holomorphic-antiholomorphic factorization, corresponding to the decomposition of L ( k , 1) into two solid tori, and the associated holomorphic block decomposition of the partition functions of T n [ M ]. A generalization to L ( k , p ) is also introduced. Convergence of the state integrals, for any k , requires triangulations to admit a positive angle structure; we propose that this is also necessary for the DGG gauge theory T n [ M ] to flow to a desired IR SCFT.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2022

Structure of Sulfuric Acid Solutions Using Pair Distribution Function Analysis

Solvation and mesoscale ordering of sulfuric acid and other strong acid solutions leads to suppressed freezing points and strong rheological changes with varying concentration. While the solid-state structures are well-understood, studies focused on the evolving solvation structure in the solution phase have probed a limited concentration range (~1–6 M). This study applies a total scattering approach in both the wide-angle X-ray scattering (WAXS) and pair distribution function (PDF) regimes to elucidate the evolving solvation structure over its full range of acid concentration (0–18 M). The emergence of a prepeak in the WAXS regime at intermediate concentrations indicates a transition from noninteracting sulfate molecules in the dilute limit to sterically limited sulfates at concentrations near its deep eutectic point. Fits to the PDF data quantify this trend, showing a transition from octahedrally hydrated sulfates up to 6–7 M concentrations, followed by gradual dehydration, and eventually reaching a solution structure similar to that of water-in-salt electrolyte systems at high acid concentrations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Observing Framework Expansion of Ordered Mesoporous Hard Carbon Anodes with Ionic Liquid Electrolytes via in Situ Small-Angle Neutron Scattering

Here, the reversible capacity of materials for energy storage, such as battery electrodes, is deeply connected with their microstructure and any major changes in the microstructure that occur during cycling can cause a dramatic loss in capacity. Here, we address the fundamental mechanism by which hard mesoporous carbons, which exhibit high capacities versus Li, achieve stable cycling during the initial “break-in” cycles. Using in-situ small angle neutron scattering we show that hard carbon anodes that exhibit reversible Li + cycling typically expand in volume up to 5% during the first discharge cycle, with only relatively minor expansion and contraction in subsequent cycles after a suitable solid electrolyte interphase (SEI) has formed. Reversible carbon framework expansion is observed in the electrolyte lithium bis(trifluoro-methanesulfonyl)imide (LiTFSI)/1-ethyl-3-methyl-imidazolium bis(trifluoromethanesulf-onyl)imide (EMIM.TFSI) related to EMIM + intercalation before a stable SEI is formed. However, intercalation by 1-methyl-1-propypyrrolidinium bis-(trifluoromethanesulfonyl)imide (MPPY.TFSI) and lithium result in irreversible framework expansion. Irreversible framework ex-pansion in conjunction with SEI formation is found to be essential for the stable cycling of hard carbon electrodes.

25 ENERGY STORAGE↗