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At least 1,099 records · Page 61

Radiative interaction of atmosphere and surface: write up with elements of code

In passive satellite remote sensing of the Earth, separation of the path radiance (atmosphere-only contribution) from the surface reflection remains a “significant challenge”. Recent literature names it among the gaps in radiative transfer (RT) topics that “require continued research in the near future”. The challenge comes from multiple reflections (bouncing) between the atmosphere and surface – radiative interaction. In this paper we use a known RT technique, the matrix-operator method (MOM), and a new modification of the monochromatic vector RT (vRT) code IPOL (Intensity and POLarization) to simulate the interaction of a plane-parallel atmosphere and a few widely used surface reflection models. Following the idea of the Green’s function method, IPOL no longer takes the surface model parameters on input. Instead, it provides the path radiance, and the atmospheric reflection and transmission matrices as output. Despite many RT codes use the MOM formalism, this output does not seem common. The surface reflection matrix is computed externally. Therefore, this paper extends the Green’s function atmospheric correction technique to the case of polarized light. Aiming clarity rather than performance, we explain in Python the structure of the surface matrices for the isotropic (Lambertian), directional unpolarized, and polarized ocean reflection models. We then combine these surface matrices and the precomputed IPOL output to get numerically accurate signal at the top of atmosphere (TOA) and test it vs. published benchmarks. Then, for each benchmark scenario we show how to get the surface from the TOA signal, i.e. perform the RT-based atmospheric correction.

radiative transfer↗

Morphology, Modification and Characterisation of Electrospun Polymer Nanofiber Adsorbent Material Used in Metal Ion Removal

Among a wide range of technologies available to separate metal ions, adsorption is a major treatment technique for removing or recovering metals from aqueous solutions. Electrospun nanofiber adsorbents have attracted research consideration due to the distinctive properties such as their high surface area, high porosity and high adsorption capacity which makes nanofibers a good choice for selective metal recovery applications. Thus, the modification of electrospun nanofiber adsorbents by functionalisation with suitable ligands for selective metal extraction is a growing area of scientific research aiming to improve the selectivity of the adsorption process. This study reviews and summarises available information related to the different nanofiber modification processes for increasing adsorption efficiency, functionality and selectivity of modified nanofiber adsorbents as well as improving their durability and stability during use. The surface properties of an adsorbent is an essential control factor for its metal ion adsorption efficiency. The various techniques available for characterisation of specific properties of nanofiber adsorbents are also considered. Lastly, the recovery of the metal ions after adsorption by regenerating adsorbent materials and understanding the kinetics of nanofiber adsorption processes is summarised and recommendations made for further studies in order to address existing weaknesses of these materials.

36 MATERIALS SCIENCE↗

Investigation of Ni catalyst activation during plasma-assisted methane oxidation

Atmospheric pressure plasma has shown promise in improving thermally activated catalytic reactions through a process termed plasma-catalysis synergy. In this work, we investigated atmospheric pressure plasma jet (APPJ)-assisted CH 4 oxidation over a Ni/SiO 2 .Al 2 O 3 catalyst. Downstream gas-phase products from CH 4 conversion were quantified by Fourier transform infrared spectroscopy. The catalyst near-surface region was characterized by in-situ diffuse reflectance infrared Fourier transform spectroscopy. The catalyst was observed to be activated at elevated temperature (500 °C) if it was exposed to the APPJ operated at large plasma power. 'Catalyst activation' signifies that the purely thermal conversion of CH 4 using catalysts which had been pre-exposed to plasma became more intense and produced consistently CO product, even if the plasma was extinguished. Without the application of the APPJ to the Ni catalyst surface this was not observed at 500 °C. The study of different exposure conditions of the activated catalyst indicates that the reduction of the catalyst by the APPJ is likely the cause of the catalyst activation. We also observed a systematic shift of the vibrational frequency of adsorbed CO on Ni catalyst when plasma operating conditions and catalyst temperatures were varied and discussed possible explanations for the observed changes. Furthermore, this work provides insights into the plasma-catalyst interaction, especially catalyst modification in the plasma catalysis process, and potentially demonstrates the possibility of utilizing the surface CO as a local probe to understand the plasma-catalyst interaction and shed light on the complexity of plasma catalysis.

methane oxidation↗

Thermo-Oxidative Aging of LDPE/Stearoyl Chloride-Grafted Cellulose Nanocrystals Blown Films

The effect of the incorporation of pristine and stearoyl chloride grafted CNCs on the chemical, mechanical, thermal and microstructural properties, during the thermo-oxidative aging, of LDPE blown films at 60 °C was studied. The success of the pristine CNCs grafting was assessed by Fourier transform infrared (FT-IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), Thermal-gravimetric analysis (TGA), Atomic Force Spectroscopy (AFM) and contact angle measurements. The results show that chemical modification decreases both, the CNCs thermal stability and the polar component of surface energy, i.e. increases the nanocrystals hydrophobicity. Also, it was found that neither CNCs crystalline structure nor its dimensions changed with grafting. The changes on the blown film properties during thermo-oxidative aging were monitored using FT-IR, DSC, DRX and tensile testing. It was found that the CNCs catalyzed the production of carboxylic acids as a final degradation by-product, whereas the CNC-g-C{sub 18} inhibits its formation, i.e. in presence of CNCs grafted with stearoyl chloride the catalytic effect attributed to the pristine CNCs was partially inhibited. The DSC, DRX and tensile testing results show the microstructural arrangements due to the annealing and the chains oxidation predominated during the first 30 days of aging and then chain scissions prevail. These findings suggest an analogous reduction in molecular weight at the end thermo-oxidative aging. In addition, the presence of a high concentration of carboxylic acid and the drop in molecular weight after LDPE aging will facilitate the biodegradation of these oxo-degradable films.

36 MATERIALS SCIENCE↗

Exploring the binding properties and activities of ancestral expansins

Bacterial expansins are non-lytic proteins capable of loosening cellulose networks, offering promising applications in agriculture, biotechnology, and material science. Their ability to disrupt noncovalent interactions in biopolymer matrices such as cellulose and chitin positions them as valuable tools for upgrading abundant natural materials. However, their industrial use remains limited due to their relatively low wall-loosening activity compared to plant expansins. To address this limitation, we applied Ancestral Sequence Resurrection (ASR) to reconstruct and characterize ancient variants of the Bacillus subtilis expansin BsEXLX1. ASR is a powerful evolutionary tool that enables the inference and synthesis of ancestral proteins, allowing researchers to explore functional traits that may have been lost over time. This approach not only provides insights into protein evolution but also facilitates the design of proteins with enhanced properties, such as improved substrate affinity or structural stability. In this study, we combined biochemical and biophysical assays to evaluate the activity and binding behavior of ancestral expansins. Our results reveal that ancestral variants exhibit increased cellulose affinity, reduced binding to acidic polysaccharides, and greater salt resistance. Furthermore, these traits enhance their wall-loosening activity and demonstrate the utility of ASR in engineering surface-active proteins for industrial applications, particularly in biomass processing and cellulose modification.

09 BIOMASS FUELS↗

Unravelling Adsorbate-Metal-Oxide Interactions: Water Vapor Chemistry on the Growth and Sintering of Ni over Reducible CeO2(111) Thin Films

The role of water in the growth and sintering of Ni particles over well-ordered CeOx(111) (1.5 < x < 2) thin films was investigated through scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS) studies, considering ceria-supported Ni attracts great attention as a promising catalyst for reactions such as steam reforming of ethanol and water gas shift reaction, in which water vapor is used as a key reactant. In the study, both fully oxidized CeO2 and partially reduced CeO1.75 thin films were prepared to examine the effect of the oxygen vacancies/Ce3+ sites in ceria supports. Our STM results revealed that dosing water before or after Ni deposition over the CeOx(111) surfaces at room temperature influenced the sintering behavior of Ni nanoparticles with further heating. Exposure of water to Ni nanoparticles that were deposited over both CeO2 and CeO1.75 at 300 K causes the formation of flatter particles with significantly reduced height when heating to the same temperatures compared to Ni/ceria with no water adsorbates. The flatter Ni particles were also observed when water was first dosed over CeO2 at 300 K followed by Ni deposition at room temperature and further heating. Over a partially reduced CeO1.75 surface with predosed water at 300 K, there is an extensive decrease in the particle density upon subsequent Ni deposition at room temperature and a significant increase in the height for Ni nanoparticles with further heating to higher temperatures compared to Ni over a pristine CeO1.75 surface. This is due to the filling of oxygen vacancies caused by the dissociation of water. This creates fewer nucleation sites for Ni on ceria, weakening the metal-oxide interaction and causing significant metal sintering. Our experimental findings suggest distinct adsorbate-metal-oxide interactions are key to the tuning of sintering of Ni nanoparticles over the CeOx(111) surface caused by water exposure. Such interactions are essential for the further modification of Ni-based catalysts for improved reactivity and stability.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Causes of Reduced Climate Sensitivity in E3SM From Version 1 to Version 2

The effective climate sensitivity in the Department of Energy's Energy Exascale Earth System Model (E3SM) has decreased from 5.3 K in version 1 to 4.0 K in version 2. This reduction is mainly due to a weaker positive cloud feedback that leads to a stronger negative radiative feedback. Present-day atmosphere-only experiments with uniform 4 K sea surface temperature warming are used to separate the contributions of individual model modifications to the reduced cloud feedback. We find that the reduced cloud feedback is mostly driven by changes over the tropical marine low cloud regime, mainly related to a new trigger function for the deep convection scheme and modifications in the cloud microphysics scheme. The new trigger function helps weaken the low cloud reduction by increasing the cloud water detrainment at low levels from deep convection under warming. Changes to the formula of autoconversion rate from liquid to rain and an introduced minimum cloud droplet number concentration threshold in cloud microphysical calculations help sustain clouds against dissipation by suppressing precipitation generation with warming. In the midlatitudes, the increased Wegener-Bergeron-Findeisen (WBF) efficiency strongly reduces present-day liquid water and leads to a stronger negative cloud optical depth feedback. The reduced trade cumulus cloud feedback in v2 is closer to estimates from recent observational and large-eddy modeling studies but might not be due to the right physical reasons. The reduced mid-latitude cloud feedback may be more plausible because more realistic present-day mixed-phase clouds are produced through the change in the WBF efficiency.

54 ENVIRONMENTAL SCIENCES↗

Functionally critical residues in the aminoglycoside resistance-associated methyltransferase RmtC play distinct roles in 30S substrate recognition

Methylation of the small ribosome subunit rRNA in the ribosomal decoding center results in exceptionally high-level aminoglycoside resistance in bacteria. Enzymes that methylate 16S rRNA on N7 of nucleotide G1405 (m 7 G1405) have been identified in both aminoglycoside-producing and clinically drug-resistant pathogenic bacteria. Using a fluorescence polarization 30S-binding assay and a new crystal structure of the methyltransferase RmtC at 3.14 Å resolution, here we report a structure-guided functional study of 30S substrate recognition by the aminoglycoside resistance-associated 16S rRNA (m 7 G1405) methyltransferases. We found that the binding site for these enzymes in the 30S subunit directly overlaps with that of a second family of aminoglycoside resistance-associated 16S rRNA (m 1 A1408) methyltransferases, suggesting that both groups of enzymes may exploit the same conserved rRNA tertiary surface for docking to the 30S. Within RmtC, we defined an N-terminal domain surface, comprising basic residues from both the N1 and N2 subdomains, that directly contributes to 30S-binding affinity. In contrast, additional residues lining a contiguous adjacent surface on the C-terminal domain were critical for 16S rRNA modification but did not directly contribute to the binding affinity. The results from our experiments define the critical features of m 7 G1405 methyltransferase–substrate recognition and distinguish at least two distinct, functionally critical contributions of the tested enzyme residues: 30S-binding affinity and stabilizing a binding-induced 16S rRNA conformation necessary for G1405 modification. Our study sets the scene for future high-resolution structural studies of the 30S-methyltransferase complex and for potential exploitation of unique aspects of substrate recognition in future therapeutic strategies.

(ribosomal RNA) ribosome RNA methylation↗

The regulation of the cell wall by glycosylphosphatidylinositol-anchored proteins in Arabidopsis

A polysaccharides-based cell wall covers the plant cell, shaping it and protecting it from the harsh environment. Cellulose microfibrils constitute the cell wall backbone and are embedded in a matrix of pectic and hemicellulosic polysaccharides and glycoproteins. Various environmental and developmental cues can regulate the plant cell wall, and diverse glycosylphosphatidylinositol (GPI)-anchored proteins participate in these regulations. GPI is a common lipid modification on eukaryotic proteins, which covalently tethers the proteins to the membrane lipid bilayer. Catalyzed by a series of enzymic complexes, protein precursors are post-translationally modified at their hydrophobic carboxyl-terminus in the endomembrane system and anchored to the lipid bilayer through an oligosaccharidic GPI modification. Ultimately, mature proteins reach the plasma membrane via the secretory pathway facing toward the apoplast and cell wall in plants. In Arabidopsis, more than three hundred GPI-anchored proteins (GPI-APs) have been predicted, and many are reported to be involved in diverse regulations of the cell wall. In this review, we summarize GPI-APs involved in cell wall regulation. GPI-APs are proposed to act as structural components of the cell wall, organize cellulose microfibrils at the cell surface, and during cell wall integrity signaling transduction. Besides regulating protein trafficking, the GPI modification is potentially governed by a GPI shedding system that cleaves and releases the GPI-anchored proteins from the plasma membrane into the cell wall.

59 BASIC BIOLOGICAL SCIENCES↗

Shear flow beneath oceanic plates - Local nonsimilarity boundary layers for olivine rheology

The principle of local similarity, which has been used to model the two-dimensional boundary layers in the oceanic upper mantle, permits calculation of the temperature, velocity, and stress fields with essentially analytic techniques. Finite difference numerical methods are hard pressed to resolve the detail required by the large variation of viscosity between the lithosphere and the asthenosphere. In this paper the local similarity approximation has been justified by quantitatively evaluating the effect of nonsimilarity due to viscous heating, nonlinear temperature- and pressure-dependent rheology, buoyancy, adiabatic cooling, etc. Nonsimilar effects produce only small modifications of the locally similar boundary layers; important geophysical observables such as surface heat flux and ocean floor topography are given to better than 10 percent by the locally similar solution. A posteriori evaluations of the terms neglected in the boundary layer simplification of the complete equations have been conducted on the locally similar temperature and velocity profiles close to the spreading ridge. The boundary layer models are valid to depths of 100 km at 3 m.y. and 10 km at 0.3 m.y.

Yuen, D. A.↗

Numerical simulation of supersonic cone flow at high angle of attack

A conical symmetry assumption is applied to the full Navier-Stokes equations resulting in an equation set containing time and two coordinate directions as independent variables. The set is integrated by use of a finite difference technique for the particular case of sharp cones at incidence. Solutions are obtained and compared with experiment for auxiliary conditions corresponding to both laminar and turbulent flows. Closure for the turbulent flow case is provided by use of a scalor eddy viscosity model based on the mixing length hypothesis. Modifications to the eddy viscosity model were found which led to excellent surface pressure and surface flow direction agreement for turbulent flow at low supersonic Mach numbers. It is apparent that further work on the turbulence model is necessary for agreement at higher supersonic Mach numbers.

Mcrae, D. S.↗

Particle contamination from Martin Optical Black

The design of the barrel baffle of the Infrared Astronomical Satellite (IRAS) Optical Subsystem to minimize production of particulate contamination is described. The configuration of the 50-inch long, 28.5-inch diameter baffle required pop-rivet assembly after coating with Martin Optical Black for stray light suppression. An experiment to determine the contamination produced at assembly led to the modification of the baffle construction to preclude such damage to the coated surfaces.

Young, P. J.↗

Precipitation measurements from space - Workshop summary 28 April-1 May 1981, Greenbelt, MD

The goals and methods for global precipitation measurements from space are examined. Records currently exist only for visible and IR scans of cloud properties, and are applied from GEO for detecting diurnal variations in precipitation. Microwave radiometry is noted to be a suitable method for supplementing the visible and IR data for measuring stratiform oceanic precipitation, and when used at up to 3 microns can detect areas, if not amounts, of precipitation from GEO. Applications of radar altimeters are proposed in terms of modifications to the Seasat-type 2.2 cm radar, the use of surface target attentuation radar, of frequency agile rain radar, or of adaptive pointing radar. Soil moisture sensing is available with passive microwave radiometry in the 20-50 cm bands, or active sensing in the 5-8 cm bands. The utilization of GARP ground truth data is explored, along with statistical methods for treating the data samples.

Atlas, D.↗

A Numerical Study of Anti-Vortex Film Cooling Designs at High Blowing Ratio

A concept for mitigating the adverse effects of jet vorticity and liftoff at high blowing ratios for turbine film cooling flows has been developed and studied at NASA Glenn Research Center. This "anti-vortex" film cooling concept proposes the addition of two branched holes from each primary hole in order to produce a vorticity counter to the detrimental kidney vortices from the main jet. These vortices typically entrain hot freestream gas and are associated with jet separation from the turbine blade surface. The anti-vortex design is unique in that it requires only easily machinable round holes, unlike shaped film cooling holes and other advanced concepts. The anti-vortex film cooling hole concept has been modeled computationally for a single row of 30deg angled holes on a flat surface using the 3D Navier-Stokes solver Glenn-HT. A modification of the anti-vortex concept whereby the branched holes exit adjacent to the main hole has been studied computationally for blowing ratios of 1.0 and 2.0 and at density ratios of 1.0 and 2.0. This modified concept was selected because it has shown the most promise in recent experimental studies. The computational results show that the modified design improves the film cooling effectiveness relative to the round hole baseline and previous anti-vortex cases, in confirmation of the experimental studies.

Heidmann, James D.↗

Fluvial Volumes, Timescales, and Intermittency in Milna Crater, Mars

Ancient lake deposits and valley networks on Mars provide strong evidence that its surface was once modified by liquid water, but the extent of that modification is still debated. Ancient lacustrine deposits in Milna Crater provide insight into the timescale and fluid volume required to construct fluvially derived sedimentary deposits near the Noachian-Hesperian boundary. Placing the lacustrine deposits their regional context in Paraná Valles provides a quantitative measurement of the intermittency of large, water-mediated sediment transport events in that region.

Buhler, P.↗

Science of the Moon

Science of the Moon discusses the present state of knowledge of the Moon, as well as the scientific questions remaining about the Moon's history and current attributes. This chapter covers events in lunar history, the geology of the Moon, properties and modification of the lunar regolith, the effects of radiation on the lunar surface, volatiles including those in the lunar Permanently Shadowed Regions, as well as the lunar seismic environment and what it indicates about the lunar interior. The chapter also lists instruments that, when deployed on the Moon or utilized in a lunar sample analysis facility in a lunar base, contribute to knowledge of the Moon. Presented within the chapter are unanswered questions regarding cratering on the lunar surface, the transition from bedrock to regolith, lunar tectonism, the crustal structure and composition of the Moon, reserve potential for in-situ resources, and the nature of the volatiles on the Moon.

Lunar science, Moon, geology, geophysics↗

A Combined Computational, Experimental, and Technology Development Approach to In-Space Laser Manufacturing Maturation at NASA Marshall Space Flight Center

In-space manufacturing (ISM) is emerging as a field vital to continued access and capabilities in the space environment. NASA Marshall Space Flight Center (MSFC) is advancing the frontier of in-space laser manufacturing (ISLM) techniques through work initially focused on maturing laser beam welding (LBW) and laser forming (LF) for use in space. Such techniques proffer the ability to assemble and join structures in space from sheet metal or other stock – extant satellites, in situ resource utilization of Lunar regolith, etc. – by forming to desired shapes and then joining via in-space welding (ISW). ISLM processes are useful for assembly, joining, modification, and repair of structures in free space and on the Lunar surface such as large observatories, antennas, trusses, blast/thermal/radiation shields, pressure vessels, and more. However, these techniques are not yet qualified & certified (Q&C) for regular application in space. It would be prohibitively expensive, laborious, and time-consuming to perform Q&C via traditional experimental approaches as data collection & experimentation in space is resource-intensive. As such, benchmark experiments and focused, properly instrumented technology demonstration efforts in space can collect sufficient data that – when combined with verified computational models in an integrated computational materials engineering (ICME) approach – can validate ICME tools capable of translating more readily obtained ground data to in-space, in situ, computationally informed Q&C of ISLM techniques. Several ISLM projects at MSFC are obtaining the data required to validate ICME tools through both ground and flight experiments. A parabolic flight experiment of LBW under vacuum is manifested for August 2024, including both microgravity and Lunar gravity profiles. This collaboration with the Ohio State University is investigating common aerospace alloys such as 316L stainless steel, 2219 aluminum alloy, and Ti64 titanium alloy. In situ data collection includes videography, thermography, and reference thermocouples to build a thermal model of the welds. This will elucidate the relevant physics when combined with post-flight microstructural examination and mechanical testing. MSFC is also progressing towards a suborbital flight experiment of LBW under vacuum, which could provide reams of data on ISW during sustained, high-quality reduced gravity. The effect of combined thermal (cryogenic and high-temperature) and vacuum exposure on both LBW (NASA-funded) and LF (DARPA-funded) is being investigated through ground experiments. In addition to the copious data collected during these ground experiments, ruggedization of LBW hardware will also be pursued. The datasets from these experiments will be used to validate computational models which will inform future ISLM efforts in an ICME framework. A variety of techniques across lengths scales, from CALPHAD-driven thermodynamics & kinetics to phase field modeling of solidification to kinetic Monte Carlo simulations of grain evolution at the mesoscale, will be employed to accelerate the infusion and eventual Q&C of LBW and LF for use in space. The development of data-driven surrogate models to bridge ground to flight experiments and thereby reduce the need for resource-intensive experiments in space will also be investigated. These ICME techniques, surrogate models, and datasets from ground testing can also be employed to advance manufacturing in terrestrial environments.

in-space welding↗

Algorithms for High-Speed Noninvasive Eye-Tracking System

Two image-data-processing algorithms are essential to the successful operation of a system of electronic hardware and software that noninvasively tracks the direction of a person s gaze in real time. The system was described in High-Speed Noninvasive Eye-Tracking System (NPO-30700) NASA Tech Briefs, Vol. 31, No. 8 (August 2007), page 51. To recapitulate from the cited article: Like prior commercial noninvasive eyetracking systems, this system is based on (1) illumination of an eye by a low-power infrared light-emitting diode (LED); (2) acquisition of video images of the pupil, iris, and cornea in the reflected infrared light; (3) digitization of the images; and (4) processing the digital image data to determine the direction of gaze from the centroids of the pupil and cornea in the images. Most of the prior commercial noninvasive eyetracking systems rely on standard video cameras, which operate at frame rates of about 30 Hz. Such systems are limited to slow, full-frame operation. The video camera in the present system includes a charge-coupled-device (CCD) image detector plus electronic circuitry capable of implementing an advanced control scheme that effects readout from a small region of interest (ROI), or subwindow, of the full image. Inasmuch as the image features of interest (the cornea and pupil) typically occupy a small part of the camera frame, this ROI capability can be exploited to determine the direction of gaze at a high frame rate by reading out from the ROI that contains the cornea and pupil (but not from the rest of the image) repeatedly. One of the present algorithms exploits the ROI capability. The algorithm takes horizontal row slices and takes advantage of the symmetry of the pupil and cornea circles and of the gray-scale contrasts of the pupil and cornea with respect to other parts of the eye. The algorithm determines which horizontal image slices contain the pupil and cornea, and, on each valid slice, the end coordinates of the pupil and cornea. Information from multiple slices is then combined to robustly locate the centroids of the pupil and cornea images. The other of the two present algorithms is a modified version of an older algorithm for estimating the direction of gaze from the centroids of the pupil and cornea. The modification lies in the use of the coordinates of the centroids, rather than differences between the coordinates of the centroids, in a gaze-mapping equation. The equation locates a gaze point, defined as the intersection of the gaze axis with a surface of interest, which is typically a computer display screen (see figure). The expected advantage of the modification is to make the gaze computation less dependent on some simplifying assumptions that are sometimes not accurate

Talukder, Ashit↗