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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS2001

Thermal Conductivity of Ceramic Thermal Barrier and Environmental Barrier Coating Materials

Thermal barrier and environmental barrier coatings (TBC's and EBC's) have been developed to protect metallic and Si-based ceramic components in gas turbine engines from high temperature attack. Zirconia-yttria based oxides and (Ba,Sr)Al2Si2O8(BSAS)/mullite based silicates have been used as the coating materials. In this study, thermal conductivity values of zirconia-yttria- and BSAS/mullite-based coating materials were determined at high temperatures using a steady-state laser heat flux technique. During the laser conductivity test, the specimen surface was heated by delivering uniformly distributed heat flux from a high power laser. One-dimensional steady-state heating was achieved by using thin disk specimen configuration (25.4 mm diam and 2 to 4 mm thickness) and the appropriate backside air-cooling. The temperature gradient across the specimen thickness was carefully measured by two surface and backside pyrometers. The thermal conductivity values were thus determined as a function of temperature based on the 1-D heat transfer equation. The radiation heat loss and laser absorption corrections of the materials were considered in the conductivity measurements. The effects of specimen porosity and sintering on measured conductivity values were also evaluated.

Zhu, Dong-Ming↗

DOE OSTI2018

Well-Posedness and Spectral Analysis of Integrodifferential Equations Arising in Viscoelasticity Theory

We study the well-posedness of initial-value problems for abstract integrodifferential equations with unbounded operator coefficients in Hilbert spaces and provide a spectral analysis of operator functions that are symbols of the specified equations. These equations represent an abstract form of linear partial integrodifferential equations arising in viscoelasticity theory and other important applications. For the said integrodifferential equations, we obtain well-posedness results in weighted Sobolev spaces of vector functions defined on the positive semiaxis and valued in a Hilbert space. For the symbols of the said equations, we find the localization and the structure of the spectrum.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2021

Two-bond 13 C– 13 C spin-coupling constants in saccharides: dependencies on exocyclic hydroxyl group conformation

Seven doubly 13 C-labeled isotopomers of methyl β-D-glucopyranoside, methyl β-D-xylopyranoside, methyl β-D-galactopyranoside, methyl β-D-galactopyranosyl-(1→4)-β-D-glucopyranoside and methyl β-D-galactopyranosyl-(1→4)-β-D-xylopyranoside were prepared, crystallized, and studied by single-crystal X-ray crystallography and solid-state 13 C NMR spectroscopy to determine experimentally the dependence of 2 J C1,C3 values in aldopyranosyl rings on the C1–C2–O2–H torsion angle, θ 2 , involving the C2 carbon of the C1–C2–C3 coupling pathway. Using X-ray crystal structures to determine θ 2 in crystalline samples and by selecting compounds that exhibit a relatively wide range of θ 2 values in the crystalline state, 2 J C1,C3 values measured in crystalline samples were plotted against θ 2 and the resulting plot compared to that obtained from density functional theory (DFT) calculations. For θ 2 values ranging from ~90° to ~240°, very good agreement was observed between the experimental and theoretical plots, providing strong validation of DFT-calculated spin-coupling dependencies on exocyclic C–O bond conformation involving the central carbon of geminal C–C–C coupling pathways. we report that these findings provide new experimental evidence supporting the use of 2 J CCC values as non-conventional spin-coupling constraints in MA'AT conformational modeling of saccharides in solution, and the use of NMR spin-couplings not involving coupled hydroxyl hydrogens as indirect probes of C–O bond conformation. Solvomorphism was observed in crystalline βGal-(1→4)-βGlcOCH 3 wherein the previously-reported methanol solvate form was found to spontaneously convert to a monohydrate upon air-drying, leading to small but discernible conformational changes in, and a new crystalline form of, this disaccharide.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1985

Airborne lidar measurements of El Chichon stratospheric aerosols, October 1982 to November 1982

A coordinated flight mission to determine the spatial distribution and aerosol characteristics of the El Chichon produced stratospheric aerosol was flown in October to November 1982. The mission covered 46 deg N to 46 deg S and included rendezvous between balloon-, airplane-, and satellite-borne sensors. The lidar data from the flight mission are presented. Representative profiles of lidar backscatter ratio, plots of the integrated backscattering function versus latitude, and contours of backscatter mixing ratio versus altitude and latitude are given. In addition, tables containing numerical values of the backscatter ratio and backscattering functions versus altitude are supplied for each profile. The bulk of the material produced by the El Chichon eruptions of late March 10 to early April 1982 resided between latitudes from 5 to 7 deg S to 35 to 37 deg N and was concentrated above 21 km in a layer that peaked at 23 to 25 km. In this latitude region, peak scattering ratios at a wavelength of 0.6943 micron were approximately 24. The results of this mission are presented in a ready-to-use format for atmospheric and climatic studies.

Mccormick, M. P.↗

NASA NTRS1985

Airborne lidar measurements of El Chichon stratospheric aerosols

A NASA Electra airplane, outfitted with a lidar system, was flown in January to February 1983 between the latitudes of 27 deg N and 76 deg N. One of the primary purposes of this mission was to determine the spatial distribution and aerosol characteristics of the El Chichon-produced stratospheric material. This report presents the lidar data from that flight mission. Representative profiles of lidar backscatter ratio, plots of the integrated backscattering function versus latitude, and contours of backscatter mixing ratio versus altitude and latitude are given. It addition, tables containing numerical values of the backscatter ratio and backscattering function versus altitude are supplied for each profile. The largest amount of material produced by the El Chichon eruptions of late March to early April 1982, which was measured by this flight, resided between 35 deg N and 52 deg N. Peak backscatter ratios at a wavelength of 0.6943 micro m decreased from 8 to 10 at the lower latitudes to 3 at the higher latitudes. Backscatter ratio profiles taken while crossing the polar vortex show that the high-altitude material from El Chichon arrived at the north polar region sometime after the winter polar vortex was established. This report presents the results of this mission in a ready-to-use format for atmospheric and climatic studies.

Mccormick, M. P.↗

NASA NTRS1986

Airborne lidar measurements of El Chichon stratospheric aerosols, May 1983

An experimental survey flight to determine the spatial distribution and aerosol characteristics of the El Chichon-produced stratospheric aerosol was conducted in May 1983. The mission included several different sensors flown abroad the NASA Convair 990 at latitudes between 72 deg. and 56 deg. S. This report presents the lidar data from that flight mission. Representative profiles of lidar backscatter ratio, plots of integrated backscattering function versus latitude, and contours of backscatter mixing ratio versus altitude and latitude are given. In addition, tables containing numerical values of the backscatter ratio and backscattering function versus altitude are supplied for each profile. By May 1983, material produced by the El Chichon eruptions of late March-early April 1982 had spread throughout the latitudes covered by this mission. However, the most massive portion of the material resided north of 33 deg. N and was concentrared below 21 km. In this latitude region (33 deg. N to 72 deg. N), peak backscatter ratios at a wavelength of 0.6943 microns varied between 3.5 and 4.5, and the peak integratred backscattering function was about 18 X 10 to the -4 power/sr, corresponding to a peak optical depth calculated to be approximately 0.08. This report presents the results of this mission in a ready-to-use format for atmospheric and climatic studies.

Mccormick, M. P.↗

NASA NTRS1987

Airborne lidar measurements of El Chichon stratospheric aerosols, January 1984

A lidar-equipped NASA Electra aircraft was flown in January 1984 between the latitude of 38 and 90 deg N. One of the primary purposes of this mission was to determine the spatial distribution and aerosol characteristics of El Chichon produced stratospheric material. Lidar data from that portion of the flight mission between 38 deg N and 77 deg N is presented. Representative profiles of lidar backscatter ratio, a plot of the integral backscattering function versus latitude, and contours of backscatter mixing ratio versus altitude and latitude are given. In addition, tables containing numerical values of the backscatter ratio and backscattering function versus altitude are applied for each profile. These data clearly show that material produced by the El Chichon eruptions of late March-early April 1982 had spread throughout the latitudes covered by this mission, and that the most massive portion of the material resided north of 55 deg N and was concentrated below 17 km in a layer that peaked at 13 to 15 km. In this latitude region, peak backscatter ratios at a wavelength of 0.6943 microns were approximately 3 and the peak integrated backscattering function was about 15 X 10 to the -4/sr corresponding to a peak optical depth of approximately 0.07. This report presents the results of this mission in a ready-to-use format for atmospheric and climatic studies.

Mccormick, M. Patrick↗

NASA NTRS1947

An Anaylsis of Control Requirements and Control Parameters for Direct-Coupled Turbojet Engines

Requirements of an automatic engine control, as affected by engine characteristics, have been analyzed for a direct-coupled turbojet engine. Control parameters for various conditions of engine operation are discussed. A hypothetical engine control is presented to illustrate the use of these parameters. An adjustable speed governor was found to offer a desirable method of over-all engine control. The selection of a minimum value of fuel flow was found to offer a means of preventing unstable burner operation during steady-state operation. Until satisfactory high-temperature-measuring devices are developed, air-fuel ratio is considered to be a satisfactory acceleration-control parameter for the attainment of the maximum acceleration rates consistent with safe turbine temperatures. No danger of unstable burner operation exists during acceleration if a temperature-limiting acceleration control is assumed to be effective. Deceleration was found to be accompanied by the possibility of burner blow-out even if a minimum fuel-flow control that prevents burner blow-out during steady-state operation is assumed to be effective. Burner blow-out during deceleration may be eliminated by varying the value of minimum fuel flow as a function of compressor-discharge pressure, but in no case should the fuel flow be allowed to fall below the value required for steady-state burner operation.

Novik, David↗

NASA NTRS1978

Far-infrared absorption in H2 and H2-He mixtures

Collision-induced absorption in the translation-rotation band of H2 and H2-He mixtures has been measured from 20 to 900 kaysers at 77.4, 195, and 292 K. To establish the accuracy of the results, various sources of error are investigated. The zeroth and first spectral moments are evaluated from experiment and theory for H2 at the various temperatures. To obtain theoretical moments consistent with the experimental values, the quantum pair-distribution function must be used. The major portion of the experimental moments can be accounted for by quadrupole-induced dipoles in H2 pairs. The remaining portion is attributable to an anisotropic overlap interaction, although its magnitude depends on the value of the molecular parameters required to calculate the quadrupole contribution.

Birnbaum, G.↗

NASA NTRS1990

Neuromorphic learning of continuous-valued mappings from noise-corrupted data. Application to real-time adaptive control

The ability of feed-forward neural network architectures to learn continuous valued mappings in the presence of noise was demonstrated in relation to parameter identification and real-time adaptive control applications. An error function was introduced to help optimize parameter values such as number of training iterations, observation time, sampling rate, and scaling of the control signal. The learning performance depended essentially on the degree of embodiment of the control law in the training data set and on the degree of uniformity of the probability distribution function of the data that are presented to the net during sequence. When a control law was corrupted by noise, the fluctuations of the training data biased the probability distribution function of the training data sequence. Only if the noise contamination is minimized and the degree of embodiment of the control law is maximized, can a neural net develop a good representation of the mapping and be used as a neurocontroller. A multilayer net was trained with back-error-propagation to control a cart-pole system for linear and nonlinear control laws in the presence of data processing noise and measurement noise. The neurocontroller exhibited noise-filtering properties and was found to operate more smoothly than the teacher in the presence of measurement noise.

Troudet, Terry↗

NASA NTRS1981

Theoretical studies of solar-pumped lasers

Estimates of the absorption and emission characteristics of molecules required to develop materials for solar-pumped lasers are addressed. These characteristics are described in terms of the Franck Condon factors, which are calculated from the molecular wave functions. Wave functions for vibrational levels in the lower and upper electronic states of I2 and NSe are calculated numerically and methods of checking errors discussed. Errors arise when the vibrational quantum numbers are high; but, using a calculated rather than measured value of the dissociation energy, wave functions up to the fiftieth vibrational level are obtained. A numerical method of evaluating the wave functions is given, which should be more accurate in the region of electronic transitions during absorption. Franck Condon factors, plotted versus the wavelength of the absorbed photons, are shown, and a check on the Franck Condon factors is made using the vibrational sum rule.

Harries, W. L.↗

NASA NTRS1991

Optical phase-locked loop (OPLL) for free-space laser communications with heterodyne detection

Several advantages of coherent free-space optical communications are outlined. Theoretical analysis is formulated for an OPLL disturbed by shot noise, modulation noise, and frequency noise consisting of a white component, a 1/f component, and a 1/f-squared component. Each of the noise components is characterized by its associated power spectral density. It is shown that the effect of modulation depends only on the ratio of loop bandwidth and data rate, and is negligible for an OPLL with loop bandwidth smaller than one fourth the data rate. Total phase error variance as a function of loop bandwidth is displayed for several values of carrier signal to noise ratio. Optimal loop bandwidth is also calculated as a function of carrier signal to noise ratio. An OPLL experiment is performed, where it is shown that the measured phase error variance closely matches the theoretical predictions.

Win, Moe Z.↗

DOE OSTI2017

RG flow from Φ 4 theory to the 2D Ising model

We study 1+1 dimensional Φ 4 theory using the recently proposed method of conformal truncation. Starting in the UV CFT of free field theory, we construct a complete basis of states with definite conformal Casimir, C. We use these states to express the Hamiltonian of the full interacting theory in lightcone quantization. After truncating to states with C≤C max , we numerically diagonalize the Hamiltonian at strong coupling and study the resulting IR dynamics. We compute non-perturbative spectral densities of several local operators, which are equivalent to real-time, infinite-volume correlation functions. These spectral densities, which include the Zamolodchikov C-function along the full RG flow, are calculable at any value of the coupling. Near criticality, our numerical results reproduce correlation functions in the 2D Ising model.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2017

Concentration dependence of the wings of a dipole-broadened magnetic resonance line in magnetically diluted lattices

The singularities of the time autocorrelation functions (ACFs) of magnetically diluted spin systems with dipole–dipole interaction (DDI), which determine the high-frequency asymptotics of autocorrelation functions and the wings of a magnetic resonance line, are studied. Using the self-consistent fluctuating local field approximation, nonlinear equations are derived for autocorrelation functions averaged over the independent random arrangement of spins (magnetic atoms) in a diamagnetic lattice with different spin concentrations. The equations take into account the specificity of the dipole–dipole interaction. First, due to its axial symmetry in a strong static magnetic field, the autocorrelation functions of longitudinal and transverse spin components are described by different equations. Second, the long-range type of the dipole–dipole interaction is taken into account by separating contributions into the local field from distant and near spins. The recurrent equations are obtained for the expansion coefficients of autocorrelation functions in power series in time. From them, the numerical value of the coordinate of the nearest singularity of the autocorrelation function is found on the imaginary time axis, which is equal to the radius of convergence of these expansions. It is shown that in the strong dilution case, the logarithmic concentration dependence of the coordinate of the singularity is observed, which is caused by the presence of a cluster of near spins whose fraction is small but contribution to the modulation frequency is large. As an example a silicon crystal with different {sup 29}Si concentrations in magnetic fields directed along three crystallographic axes is considered.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NASA NTRS1979

Assessment at full scale of exhaust nozzle to wing size on STOL-OTW acoustic characteristics

On the basis of static aero/acoustic data obtained at model scale, the effect of exhaust nozzle size on flyover noise is evaluated at full scale for different STOL-OTW nozzle configurations. Three types of nozzles are evaluated: a circular/deflector nozzle mounted above the wing; a slot/deflector nozzle mounted on the wing; and a slot nozzle mounted on the wing. The nozzle exhaust plane location, measured from the wing leading edge, was varied from 10 to 46 percent of the wing chord (flaps retracted). Flap angles of 20 deg (takeoff) and 60 deg (approach) are included in the study. Initially, perceived noise levels (PNL) are calculated as a function flyover distance at 152m altitude. From these plots, static EPNL values (defined as flyover relative noise levels), are obtained as functions of nozzle size for equal aerodynamic performance (lift and thrust). The acoustic benefits attributable to nozzle size relative to a given wing chord size are assessed.

Vonglahn, U.↗

NASA NTRS1991

Helicopter flight-control design using an H(2) method

Rate-command and attitude-command flight-control designs for a UH-60 helicopter in hover are presented and were synthesized using an H(2) method. Using weight functions, this method allows the direct shaping of the singular values of the sensitivity, complementary sensitivity, and control input transfer-function matrices to give acceptable feedback properties. The designs were implemented on the Vertical Motion Simulator, and four low-speed hover tasks were used to evaluate the control system characteristics. The pilot comments from the accel-decel, bob-up, hovering turn, and side-step tasks indicated good decoupling and quick response characteristics. However, an underlying roll PIO tendency was found to exist away from the hover condition, which was caused by a flap regressing mode with insufficient damping.

Takahashi, Marc D.↗

DOE OSTI2017

On the nonoscillatory phase function for Legendre's differential equation

We express a certain complex-valued solution of Legendre's differential equation as the product of an oscillatory exponential function and an integral involving only nonoscillatory elementary functions. By calculating the logarithmic derivative of this solution, we show that Legendre's differential equation admits a nonoscillatory phase function. Moreover, we derive from our expression an asymptotic expansion useful for evaluating Legendre functions of the first and second kinds of large orders, as well as the derivative of the nonoscillatory phase function. Our asymptotic expansion is not as efficient as the well-known uniform asymptotic expansion of Olver; however, unlike Olver's expansion, it coefficients can be easily obtained. Numerical experiments demonstrating the properties of our asymptotic expansion are presented.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

DOE OSTI2021

A Multi-Objective Bayesian Optimization Approach Using the Weighted Tchebycheff Method

Abstract Bayesian optimization (BO) is a low-cost global optimization tool for expensive black-box objective functions, where we learn from prior evaluated designs, update a posterior surrogate Gaussian process model, and select new designs for future evaluation using an acquisition function. This research focuses upon developing a BO model with multiple black-box objective functions. In the standard multi-objective (MO) optimization problem, the weighted Tchebycheff method is efficiently used to find both convex and non-convex Pareto frontiers. This approach requires knowledge of utopia values before we start optimization. However, in the BO framework, since the functions are expensive to evaluate, it is very expensive to obtain the utopia values as a prior knowledge. Therefore, in this paper, we develop a MO-BO framework where we calibrate with multiple linear regression (MLR) models to estimate the utopia value for each objective as a function of design input variables; the models are updated iteratively with sampled training data from the proposed MO-BO. These iteratively estimated mean utopia values are used to formulate the weighted Tchebycheff MO acquisition function. The proposed approach is implemented in two numerical test examples and one engineering design problem of optimizing thin tube geometries under constant loading of temperature and pressure, with minimizing the risk of creep-fatigue failure and design cost, along with risk-based and manufacturing constraints. Finally, the model accuracy with frequentist, Bayesian and without MLR-based calibration are compared to true Pareto solutions.

Engineering↗