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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,117 records · Page 62
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Discrete One-Dimensional Coverage Process on a Renewal Process

Consider the following coverage model on ℕ, for each site i∈ℕ associate a pair (ξ{sub i},R{sub i}) where (ξ{sub i}){sub i≥0} is a 1-dimensional undelayed discrete renewal point process and (R{sub i}){sub i≥0} is an i.i.d. sequence of ℕ-valued random variables. At each site where ξ{sub i}=1 start an interval of length R{sub i}. Coverage occurs if every site of ℕ is covered by some interval. We obtain sharp conditions for both, positive and null probability of coverage. As corollaries, we extend results of the literature of rumor processes and discrete one-dimensional Boolean percolation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1993

Interstellar grains in primitive meteorites - Diamond, silicon carbide, and graphite

Primitive meteorites contain a few parts per million (ppm) of pristine interstellar grains that provide information on nuclear and chemical processes in stars. Their interstellar origin is proven by highly anomalous isotopic ratios, varying more than 1000-fold for elements such as C and N. Most grains isolated thus far are stable only under highly reducing conditions (C/O greater than 1), and apparently are 'stardust' formed in stellar atmospheres. Microdiamonds, of median size about 10 A, are most abundant (about 400-1800 ppm) but least understood. They contain anomalous noble gases including Xe-HL, which shows the signature of the r- and p-processes. Silicon carbide, of grain size 0.2-10 microns and abundance about 6 ppm, shows the signature of the s-process and apparently comes mainly from red giant carbon (AGB) stars of 1-3 solar masses. Some grains appear to be not less than 10 exp 9 a older than the solar system. Graphite spherules of grain size 0.8-7 microns and abundance less than 2 ppm contain highly anomalous C and noble gases, as well as large amounts of fossil Mg-26 from the decay of extinct Al-26. They seem to come from at least three sources, probably AGB stars, novae, and Wolf-Rayet stars.

Anders, Edward↗
DOE OSTI2021

Data for "Soil carbon dynamics during drying vs. rewetting: Importance of antecedent moisture conditions"

This dataset contains data used for the paper "Soil carbon dynamics during drying vs. rewetting: importance of antecedent moisture conditions". The Related References field will be updated with a full citation when available.Soil moisture influences soil carbon dynamics, including microbial growth and respiration. The response of such ‘soil respiration’ to moisture changes is generally assumed to be linear and reversible, i.e. to depend only on the current moisture state. Current models thus do not account for antecedent soil moisture conditions when determining soil respiration or the available substrate pool. We conducted a laboratory incubation to determine how the antecedent conditions of drought and flood influenced soil organic matter (SOM) chemistry, bioavailability, and respiration. We sampled soils from an upland coastal forest, Beaver Creek, WA USA, and subjected them to drying and rewetting treatments. For the drying treatment, field moist soils were saturated and then dried to 75, 50, 35, and 5 % saturation. In the rewetting treatment, field moist soils were air-dried and then rewet to 35, 50, 75, and 100 % saturation. We measured respiration and water extractable organic carbon (WEOC) concentrations and used 1H-NMR and FT-ICR-MS to characterize the WEOC pool across the treatments. The drying vs. wetting treatment strongly influenced SOM bioavailability, as rewet soils (with antecedent drought) had greater WEOC concentrations and respiration fluxes compared to the drying soils (with antecedent flood). In addition, air-dry soils had the highest WEOC concentrations, and the NMR-resolved peaks showed a strong contribution of protein groups in these soils. Both NMR and FT-ICR-MS analyses indicated increased contribution of complex aromatic groups/molecules in the rewet soils, compared to the drying soils. We suggest that drying introduced organic matter into the WEOC pool via desorption of aromatic molecules and/or by microbial cell lysis, and this stimulated microbial mineralization rates. Our work indicates that even short-term shifts in antecedent moisture conditions can strongly influence soil C dynamics at the core scale. The predictive uncertainties in current soil models may be reduced by a more accurate representation of soil water and C persistence that includes a mechanistic and quantitative understanding of the impact of antecedent moisture conditions.This dataset contains a compressed (.zip) archive of the data and R scripts used for this manuscript. The dataset includes files in .csv and .txt format, which can be accessed and processed using MS Excel or R. NMR data are provided as raw output data (accessed in Bruker TopSpin or MestreNova) as well as the MestreNova-processed files. This archive can also be accessed on GitHub at https://github.com/kaizadp/hysteresis_and_soil_carbon (DOI: 10.5281/zenodo.4432885).

1H-NMR↗
DOE OSTI2019

Improving Microstructural Quantification in 3D FIB-SEM Tomography

A detailed understanding of 3D microstructural features is crucial during postprocessing of the acquired data, while determining microstructural properties. Focused ion beam and scanning electron microscopy (fib-sem) is an ideal technique for the acquisition and quantification of 3D microstructures in subsurface features. In this work, we evaluated and implemented approaches to quantify 3D morphological features of plutonium oxalate and oxide particles. Image analysis, as well as statistical analysis were utilized to study the effect of process variables on the pore morphology of plutonium oxalate and oxide particles. The primary results were the creation of morphological maps of particles and identify indicators that correlated parameters allowing for discrimination between direct and reverse strike processes. This enabled us to properly quantify and map particles with their images obtained via sem. For this project, the highest correlation was found to be between Volume and Sphericity (R 2 = 0.7432) for the Revere Strike process, and Volume % and Sphericity (R 2 = 0.7450) for the Direct Strike process.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Cold crucible deployment in La Hague facility: the feedback from the first four years of operation - 15119

In April 2010, a Cold Crucible Induction Melter (CCIM) started hot operation for the first time ever in an existing very high active facility (R7) at La Hague. This was the culmination of more than two decades of R and D involving progressive process and technological development. The industrial deployment included extensive cleaning of the hot cell, removal of the previous melter, exchange of several mechanical and process components in the cell, and implementation of the various additional utilities and components necessary for operation of the new CCIM. The design and implementation phases for this deployment were described in a previous paper at WM. The CCIM has now been operated for more than four years, essentially processing active effluents from D and D operations and high-level liquid waste from reprocessed U-Mo-Sn-Al spent fuel. During this period, many data have been collected to confirm the process parameters that were defined during the qualification of this innovating process. Even if some difficulties occurred, the experience of the operating teams with the support of engineering and R and D allow managing them. This paper presents the start-up methodology and history of the cold crucible deployment in La Hague facility with the feedback from the first years of operation. The production records with the different liquid solutions treated in the process are itemized. The lessons learned during the first four years of operation of the CCIM are presented with the difficulties encountered and the solutions implemented, emphasizing the benefits of a close integration between RD, engineering, and operation teams. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2018

Measurements of Wet Deposition of Black Carbon in the Arctic Field Campaign Report

We measured BC number and mass concentrations (CNBC and CMBC) in snow and rain samples using a single-particle soot photometer (SP2) combined with a nebulizer (Nebulizer-SP2). The effect of the coagulation of BC particles suspended in water on the measurement of BC size distribution has been shown to be negligible under typical BC number concentrations in water based on theoretical calculations and laboratory experiments (Moteki and Mori 2015; Mori et al., 2016). The stability of the CMBC values during the storage of water samples was evaluated using rainwater samples (Ohata et al., 2013; Mori et al., 2016). The diameter range of BC measured by SP2 used to be about 70-4170 nm (Mori et al., 2016). The size distributions of BC are very useful for detailed studies of the microphysical processes of wet removal of BC particles (Moteki et al., 2012; Kondo et al., 2016; Ohata et al., 2016) and for understanding the microphysical properties of BC in snow and rain. Size distributions are also needed to calculate the radiative effects of airborne BC particles and of those deposited on snow (Schwarz et al., 2013; Moteki et al., 2017). We calculated CNBC and CMBC by integrating the number and mass size distributions.

Arctic processes, black carbon, aerosol transport,↗
DOE OSTI2019

Event-related brain potentials reveal how multiple aspects of semantic processing unfold across parafoveal and foveal vision during sentence reading

Recent event–related brain potential (ERP) experiments have demonstrated parafoveal N400 expectancy and congruity effects, showing that semantic information can be accessed from words in parafoveal vision (a conclusion also supported by some eye–tracking work). At the same time, it is unclear how higher–order integrative aspects of language comprehension unfold across the visual field during reading. In the current study, we recorded ERPs in a parafoveal flanker paradigm, while readers were instructed to read passively for comprehension or to judge the plausibility of sentences in which target words varied in their semantic expectancy and congruity. We directly replicated prior work showing graded N400 effects for parafoveal viewing, which are then not duplicated when the target words are processed foveally. Critically, although N400 effects were not modulated by task goals, a posteriorly distributed late positive component thought to reflect semantic integration processes was observed to semantic incongruities only in the plausibility judgment task. Furthermore, this effect was observed at a considerable delay, appearing only after words had moved into foveal vision. Our findings thus suggest that semantic access can be initiated in parafoveal vision, whereas central foveal vision may be necessary to enact higher–order (and task–dependent) integrative processing.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2017

Fleet Feedback and Fleet Efficiency Metrics

The Marine Corps have 10 years of experience implementing a telematics program and several lessons to share with partner agencies. This presentation details results of a Marine Corps survey as well as methods of using telematics to promote fleet efficiency and optimize the vehicle acquisition process.

33 ADVANCED PROPULSION SYSTEMS↗
NASA NTRS2001

Dispersal of Disks Around Young Stars

We review the evidence pertaining to the lifetimes of planet-forming disks and discuss possible disk dispersal mechanisms: 1) viscous accretion of material onto the central source, 2) close stellar encounters, 3) stellar winds, and 4) photoevaporation by ultraviolet radiation. We focus on 3) and 4) and describe the quasi-steady state appearance and the overall evolution of disks under the influence of winds and radiation from the central star and of radiation from external OB stars. Viscous accretion likely dominates disk dispersal in the inner disk (r < or approx. equals 10 AU), while photoevaporation is the principal process of disk dispersal outside of r > or approx. equals 10 AU for low mass stars. Disk dispersal timescales are compared and discussed in relation to theoretical estimates for planet formation timescales. Photoevaporation may explain the large differences in the hydrogen content of the giant planets in the solar system. The commonly held belief that our early sun's stellar wind dispersed the solar nebula is called into question. Finally, we model the small bright objects ("proplyds") observed in the Orion Nebula as disks around young, low mass stars which are externally illuminated by the UV photons from the nearby massive star Theta(sup 1)C.

Hollenbach, David↗
DOE OSTI2014

Energy-Saving Melting and Revert Reduction Technology (E-SMARRT): Final Summary Report

Energy-Saving Melting and Revert Reduction Technology (E-SMARRT) is a balanced portfolio of R&D tasks that address energy-saving opportunities in the metalcasting industry. E-SMARRT was created to: • Improve important capabilities of castings • Reduce carbon footprint of the foundry industry • Develop new job opportunities in manufacturing • Significantly reduce metalcasting process energy consumption and includes R&D in the areas of: • Improvements in Melting Efficiency • Innovative Casting Processes for Yield Improvement/Revert Reduction • Instrumentation and Control Improvement • Material properties for Casting or Tooling Design Improvement The energy savings and process improvements developed under E-SMARRT have been made possible through the unique collaborative structure of the E-SMARRT partnership. The E-SMARRT team consisted of DOE’s Office of Industrial Technology, the three leading metalcasting technical associations in the U.S: the American Foundry Society; the North American Die Casting Association; and the Steel Founders’ Society of America; and SCRA Applied R&D, doing business as the Advanced Technology Institute (ATI), a recognized leader in distributed technology management. This team provided collaborative leadership to a complex industry composed of approximately 2,000 companies, 80% of which employ less than 100 people, and only 4% of which employ more than 250 people. Without collaboration, these new processes and technologies that enable energy efficiencies and environment-friendly improvements would have been slow to develop and had trouble obtaining a broad application. The E-SMARRT R&D tasks featured low-threshold energy efficiency improvements that are attractive to the domestic industry because they do not require major capital investment. The results of this portfolio of projects are significantly reducing metalcasting process energy consumption while improving the important capabilities of metalcastings. Through June 2014, the E-SMARRT program predicts an average annual estimated savings of 59 Trillion BTUs per year over a 10 year period through Advanced Melting Efficiencies and Innovative Casting Processes. Along with these energy savings, an estimated average annual estimate of CO2 reduction per year over a ten year period is 3.56 Million Metric Tons of Carbon Equivalent (MM TCE).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
NASA NTRS2014

Novel Catalysts and Processing Technologies for Production of Aerospace Fuels from Non-Petroleum Raw Materials

Transportation fuels production (including aerospace propellants) from non-traditional sources (gases, waste materials, and biomass) has been an active area of research and development for decades. Reducing terrestrial waste streams simultaneous with energy conversion, plentiful biomass, new low-cost methane sources, and/or extra-terrestrial resource harvesting and utilization present significant technological and business opportunities being realized by a new generation of visionary entrepreneurs. We examine several new approaches to catalyst fabrication and new processing technologies to enable utilization of these nontraditional raw materials. Two basic processing architectures are considered: a single-stage pyrolysis approach that seeks to basically re-cycle hydrocarbons with minimal net chemistry or a two-step paradigm that involves production of supply or synthesis gas (mainly carbon oxides and H2) followed by production of fuel(s) via Sabatier or methanation reactions and/or Fischer-Tröpsch synthesis. Optimizing the fraction of product stream relevant to targeted aerospace (and other transportation) fuels via modeling, catalyst fabrication and novel reactor design are described. Energy utilization is a concern for production of fuels for either terrestrial or space operations; renewable sources based on solar energy and/or energy efficient processes may be mission enabling. Another important issue is minimizing impurities in the product stream(s), especially those potentially posing risks to personnel or operations through (catalyst) poisoning or (equipment) damage. Technologies being developed to remove (and/or recycle) heteroatom impurities are briefly discussed as well as the development of chemically robust catalysts whose activities are not diminished during operation. The potential impacts on future missions by such new approaches as well as balance of system issues are addressed.

space processing↗
DOE OSTI2022

Data for: Patel et al. Carbon flux estimates are sensitive to data source: A comparison of field and lab temperature sensitivity data

This dataset contains data and code used for the paper "Carbon flux estimates are sensitive to data source: A comparison of field and lab temperature sensitivity data" [DOI COMING SOON]A large literature exists on mechanisms driving soil production of the greenhouse gases CO2 and CH4. Measurements of these gases’ fluxes are often performed using closed-chamber incubations in the laboratory or in situ, i.e., in the field. Although it is common knowledge that measurements obtained through field studies vs. laboratory incubations can diverge because of the vastly different conditions of these environments, few studies have systematically examined these patterns. It is crucial to understand the magnitude and reasons for any differences, as these data are used to parametrize and benchmark ecosystem- to global-scale models, which are then susceptible to the biases of the source data. Here, we specifically examine how greenhouse gas measurements may be influenced by whether the measurement/incubation was conducted in the field vs. laboratory, focusing on CO2 and CH4 measurements. We use Q10 of greenhouse gas flux (temperature sensitivity) for our analyses, because of the ubiquity of this metric in biological and Earth system sciences and its importance to many modeling frameworks. We predicted that laboratory measurements would be less variable, but also less representative of true field conditions. However, there was greater variability in the Q10 values calculated from lab-based measurements of CO2 fluxes, because lab experiments explore extremes rarely seen in situ, and reflect the physical and chemical disturbances occurring during sampling, transport, and incubation. Overall, respiration Q10 values were significantly greater in laboratory incubations (mean = 4.19) than field measurements (mean = 3.05), with strong influences of incubation temperature and climate region/biome. However, this was in part because field measurements typically represent total respiration (Rs), whereas lab incubations typically represent heterotrophic respiration (Rh), making direct comparisons difficult to interpret. Focusing only on Rh-derived Q10, these values showed almost identical distributions across laboratory (n = 1110) and field (n = 581) experiments, providing strong support for using the former as an experimental proxy for the latter, although we caution that geographic biases in the extant data make this conclusion tentative. Due to a smaller sample size of CH4 Q10 data, we were unable to perform a comparable robust analysis, but we expect similar interactions with soil temperature, moisture, and environmental/climatic variables. Our results here suggest the need for more concerted efforts to document and standardize these data, including sample and site metadata. This dataset contains a compressed (.zip) archive of the data and R scripts used for this manuscript. The dataset includes files in .csv format, which can be accessed and processed using MS Excel or R. This archive can also be accessed on GitHub at https://github.com/kaizadp/field_lab_q10 (DOI: 10.5281/zenodo.7106554).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Topography and canopy cover influence soil organic carbon composition and distribution across a forested hillslope in the discontinuous permafrost zone

This dataset contains data used for the paper "Topography and canopy cover influence soil organic carbon composition and distribution across a forested hillslope in the discontinuous permafrost zone". The Related References field will be updated with a full citation when available. Topography and canopy cover influence ground temperature in warming permafrost landscapes, yet soil temperature heterogeneity introduced by meso-topographic slope positions, microtopographic differences in vegetation cover, and the subsequent impact of contrasting temperature conditions to soil organic carbon (SOC) dynamics are understudied. Buffering of permafrost-affected soils against warming air temperatures in boreal forests can reflect surface soil characteristics (e.g., thickness of organic material) as well as the degree and type of canopy cover (e.g., open cover vs closed cover). Both landscape and soil properties interact to determine meso- and micro-scale heterogeneity of ground warming. We sampled a hillslope catena transect in a discontinuous permafrost zone near Fairbanks, Alaska to test the small-scale (1 to 3 meter) impacts of slope position and cover type on soil organic matter composition. Mineral active layer samples were collected from backslope, low backslope, and footslope positions at depths spanning 19 to 60 cm. We examined soil mineralogical composition, soil moisture, total carbon and nitrogen content, and organic mat thickness in conjunction with an assessment of SOC composition using Fourier-transform ion Cyclotron Resonance Mass Spectrometry (FT-ICR-MS). Soils in the footslope position had a higher relative contribution of lignin-like compounds while backslope soils had more aliphatic and condensed aromatic compounds as determined by FT-ICR-MS. The effect of open versus closed tree canopy cover varied with slope position. On the backslope, we found higher oxidation of molecules under open cover compared with closed cover, indicating an effect of warmer soil temperature on decomposition. Little to no effect of canopy was observed for soils at the footslope position, which we attributed, in part, to the strong impact of soil moisture content in SOC dynamics in the water-gathering footslope position. The thin organic mat under open cover on the backslope position may have contributed to differences in soil temperature and thus SOC oxidation under open and closed canopy. Here, the thinner organic mat did not appear to buffer the underlying soil against warm season air temperatures and thus increased SOC decomposition as indicated by higher oxidation of SOC molecules and a lower contribution of simple molecules under open cover compared with the closed canopy sites. Our findings suggest that the role of canopy cover in SOC dynamics varies as a function of landscape position and soil properties, namely organic mat thickness and soil moisture. Condition-specific heterogeneity of SOC composition under open and closed canopy cover highlights the protective effect of canopy cover for soils on backslope positions. This dataset contains a compressed (.zip) archive of the data and R scripts used for this manuscript. The dataset includes files in .csv format, which can be accessed and processed using MS Excel or R. This archive can also be accessed on GitHub at https://github.com/Erin-Rooney/Y1_fairbanks (DOI: 10.5281/zenodo.8071247).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Data for: Time to anoxia: Observations and predictions of oxygen drawdown following coastal flood events

This dataset contains data and code associated with the paper Patel et al. "Time to anoxia: Observations and predictions of oxygen drawdown following coastal flood events".The coastal terrestrial-aquatic interface (TAI) is a highly dynamic system characterized by strong physical, chemical, and biological gradients. In particular, shifting soil redox conditions and consumption of terminal electron acceptors, due in part to dynamic hydrologic conditions, is a strong driver of carbon availability and transformations across TAIs. However, while redox dynamics are well described, our ability to quantitatively forecast rates of oxic to anoxic shifts in soils with different characteristics and inundation regimes is limited. We integrated field measurements, laboratory incubations, and model simulations to improve mechanistic understanding of oxygen consumption dynamics in coastal soils. Continuous in situ monitoring unexpectedly revealed that flooding caused temporary spikes in subsurface dissolved oxygen followed by rapid consumption in the wetlands. To further investigate these mechanisms in a controlled setting, we performed laboratory incubations using surface and subsurface soils from a TAI gradient (defined here as upland forest to transitional forest to wetland) in Western Lake Erie to measure oxygen consumption rates in TAI soils during flood events. In our experiments, wetland soils reached anoxia the fastest, in ∼ 9 h on average, whereas upland soils turned anoxic in ∼ 18 h. Subsurface upland soils did not turn anoxic even after two weeks of saturation in the lab, and their oxygen consumption patterns suggested carbon and/or nutrient limitation. These results are consistent with in-situ groundwater redox and oxygen measurements in the field, where wetland soils exhibited the highest rates of oxygen consumption along the TAI. Model simulations of oxygen consumption suggested that oxygen consumption had stronger abiotic controls in wetland soils but stronger biotic controls in upland soils, providing a useful framework for future incubation experiments. Microbial activity is a strong driver of oxygen consumption in TAI soils, although it is constrained by the availability of dissolved carbon in subsurface soils.This dataset contains a compressed (.zip) archive of the data and R scripts used for this manuscript. The dataset includes files in .csv format, which can be accessed and processed using MS Excel or R. This archive can also be accessed on GitHub at https://github.com/COMPASS-DOE/cmps-time_to_anoxia (DOI: 10.5281/zenodo.10815374).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Examples of Disposition Alternatives for WTP Solid Secondary Waste

The Hanford Waste Treatment and Immobilization Plant is planned to produce a variety of solid secondary wastes that will require disposal at the Integrated Disposal Facility on the Hanford Site. Solid secondary wastes include a variety of waste streams that are a result of waste treatment and processing activities.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS2015

Electric Field Generation in Martian Dust Devils

Terrestrial dust devils are known to generate electric fields from the vertical separation of charged dust particles. The particles present within the dust devils on Mars may also be subject to similar charging processes and so likely contribute to electric field generation there as well. However, to date, no Marsin situ instrumentation has been deployed to measure electric field strength. In order to explore the electric environment of dust devils on Mars, the triboelectric dust charging physics from the MacroscopicTriboelectric Simulation (MTS) code has been coupled to the Mars Regional Atmospheric ModelingSystem (MRAMS). Using this model, we examine how macroscopic electric fields are generated within martian dust disturbances and attempt to quantify the time evolution of the electrodynamical system.Electric fields peak for several minutes within the dust devil simulations. The magnitude of the electric field is a strong function of the size of the particles present, the average charge on the particles and the number of particles lifted. Varying these parameters results in peak electric fields between tens of millivolts per meter and tens of kilovolts per meter.

Aeolian processes↗
DOE OSTI2018

Crystal structure of the human NK 1 tachykinin receptor

The NK 1 tachykinin G-protein–coupled receptor (GPCR) binds substance P, the first neuropeptide to be discovered in mammals. Through activation of NK 1 R, substance P modulates a wide variety of physiological and disease processes including nociception, inflammation, and depression. Human NK 1 R (hNK 1 R) modulators have shown promise in clinical trials for migraine, depression, and emesis. However, the only currently approved drugs targeting hNK 1 R are inhibitors for chemotherapy-induced nausea and vomiting (CINV). To better understand the molecular basis of ligand recognition and selectivity, we solved the crystal structure of hNK 1 R bound to the inhibitor L760735, a close analog of the drug aprepitant. Our crystal structure reveals the basis for antagonist interaction in the deep and narrow orthosteric pocket of the receptor. We used our structure as a template for computational docking and molecular-dynamics simulations to dissect the energetic importance of binding pocket interactions and model the binding of aprepitant. Furthermore, the structure of hNK 1 R is a valuable tool in the further development of tachykinin receptor modulators for multiple clinical applications.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2016

Analysis of Legacy {sup 85}Kr Waste Form Samples - 16319

In the late 1970's, the Idaho Chemical Processing Plant conducted an R and D program on krypton encapsulation. Legacy samples composed of {sup 85}Kr incorporated in solid zeolite 5A material, and five small metal tubes containing a mixture of the zeolite combined with a glass matrix resulting from hot isostatic pressing, have been preserved. These samples were shipped to Oak Ridge National Laboratory (ORNL) in mid-FY 2014. After receipt and repackaging, the samples were examined by x-ray imaging and x-ray tomography. Two of the capsules appear to contain an amorphous mass within the capsules. An image of one capsule clearly shows the saw marks on the capsule and a quantity of loose pellet or bead-like material remaining in the capsule. An image of another capsule shows similar bead-like material within the intact capsule. One of the capsules was previously opened. The end of this capsule appears to have been cut off, and there are additional saw marks on the side of the capsule. X-ray tomography allowed the capsules to be viewed along the three axes. Of most interest was determining whether there was any residual material in the closed end of this capsule. The images confirmed the presence of residual material within this capsule. The material appears to be compacted but still retains some of the bead-like morphology. Based on the initial nondestructive assay (NDA) and the fact that there are two obviously breached samples, a plan was developed for exploratory tests that would be conducted with the breached specimens before opening the three intact capsules. Preparations are being made to determine the fraction of krypton/xenon remaining in the waste form matrix and the amount of rubidium remaining in the waste form matrix. The inner surface of the breached capsules will be examined for corrosion. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗