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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,117 records · Page 62

Detailed thermodynamic investigation of an ICE-driven, natural gas-fueled, 1 kWe micro-CHP generator

Here, the purpose of this work is to record the baseline performance of a state-of-the-art micro-combined heat and power (mCHP) system. A second goal of this work is to provide detailed thermodynamic first and second law performance measurements of the internal combustion engine and generator subsystems. A global technology survey was conducted to identify the leading mCHP systems in the 1 kW electric range. The Honda ECOWILL was identified as the state-of-the-art system in the United States, and an unused unit was procured. The ECOWILL underwent round-robin performance testing at three independent laboratories. First law (energy) and second law (exergy) analyses were conducted on the steady state data. Analysis revealed the ECOWILL operated at a first law electrical efficiency of 23.5 ± 0.4% and a utilization factor of 74.5 ± 3.2%. The primary energy loss was heat transfer from the device, followed by chemical and thermal energy in the exhaust stack. The second law analysis showed the ECOWILL operated at a second law electrical efficiency of 23.1 ± 0.4% and total (including exergy in both the electrical and recovered waste heat streams) second law efficiency of 30.2 ± 2.3%. Key areas of exergy destruction were, in decreasing magnitude, heat transfer, combustion irreversibility, and generator and friction losses.

42 ENGINEERING↗

Online monitoring of lanthanide species with combined spectroscopy in flowing aqueous aerosol systems

Combined spectroscopic analysis through absorption and laser-induced breakdown spectroscopy (LIBS) was used to monitor Nd and Pr concentrations in a flowing aqueous system. A unique, online sampling approach was employed that allowed for an approximately closed analysis loop of liquids from a reservoir. Absorption spectroscopy was performed with an optical flow cell, and LIBS was performed on an aerosol stream. Multivariate calibrations based on combined absorption and LIBS signals were built for Nd and Pr and then used to monitor concentrations in mixed solutions in a series of spiking tests. In these tests, the concentrations of Nd and Pr in solution were intermittently changed while spectroscopic signals were monitored in real-time. The combined spectroscopic signals and multivariate models were successful in monitoring changing concentrations of lanthanide species with high accuracy and minimal latency. Root-mean squared error of predictions were 0.015 mol L −1 and 0.019 mol L −1 for Nd and Pr respectively, and these lanthanides were able to be monitored to an accuracy of < 0.2 wt%. This work demonstrates both the capabilities of a sampling system for online analysis of liquids and the capabilities of multimodal spectroscopic characterization for real-time, continuous tracking of species in potentially hazardous liquid systems.

absorbance spectroscopy↗

Comparative life cycle analysis for value recovery of precious metals and rare earth elements from electronic waste

There is an ever-increasing concern regarding the electronic waste (e-waste), which is the fastest growing waste stream in the world. Incentivized by various legislations and the intrinsic value of critical metals inside, recycling of e-waste is becoming an attractive business opportunity that also benefits the environment. We report a novel electrochemical recovery (ER) process has been developed as a promising alternative to the existing pyrometallurgical and hydrometallurgical processes based technologies to recover base metals, precious metals, and rare earth elements (REEs) from e-waste. Experimental results indicate that the ER process has lower chemical consumption, enhanced control, and reduced energy demand compared to the pyrometallurgical and the hydrometallurgical processes. To quantify and compare the environmental performances of the three technologies, life cycle analysis has been conducted. Results show that the ER process outperforms the other two processes in almost all impact categories adopted in TRACI and ILCD while there is no clear winner between the hydrometallurgical and the pyrometallurgical processes. The highest impactful input for the ER method is hydrochloric acid, and for the pyrometallurgical method is copper scrap, while for the hydrometallurgical method, it is hydrogen peroxide, an oxidizer that accelerates base metal extraction process, that dominates the overall environmental footprint. The environmental viability of the ER process warrants the further development of ER process at industrial scale.

36 MATERIALS SCIENCE↗

Final Report for the Project Characterization and Valorization of Aqueous Phases Derived from Liquefaction and Upgrading of Bio-Oils

The Characterization and Valorization of Aqueous Phases Derived from Liquefaction and Upgrading of Bio-Oils project developed processes to extract value from the organics within aqueous streams derived from biomass direct liquefaction processes. The focus of the project was twofold. First, we characterized a diverse set of aqueous streams from numerous processes and feedstocks. The characterization effort served to inform this project toward development around the most prevalent compounds to maximize versatility and impact. We analyzed diverse streams from hydrothermal liquefaction of lignocellulosic, algal, and waste feedstocks; catalytic fast-pyrolysis aqueous phases; fast-pyrolysis aqueous phases; and aqueous phases produced by hydroprocessing of fast-pyrolysis bio-oil. Second, thermochemical catalytic processes were developed to convert aqueous-phase organics into useful products. These processes focused mostly on organic acids and specifically acetic acid, which was found to be ubiquitous from the characterization effort. A La x Zr y O z catalyst was discovered and developed for the ketonization of acids to ketones in the condensed aqueous phase. A dual-bed steam reforming process was developed to convert acids and other organics to hydrogen for bio-oil hydroprocessing. The dual-bed reforming process consisted of a ketonization step followed by a steam reforming step with Co as the active metal. The dual-bed process significantly reduced the rate of coke deposition versus direct steam reforming of the organic acids and beneficially produced CH 4 below the equilibrium value. Finally, we demonstrated direct conversion of aqueous-phase organics to olefins over a Zn x Zr y O z catalyst. Each thermochemical catalytic process was demonstrated with process-derived aqueous mixtures. Model compounds were used to benchmark performance and optimize conditions, but emphasis was placed on utilizing “real” aqueous streams whenever possible. A liquid-liquid extraction process using methyl tert-butyl ether as the solvent was developed to segregate dissolved inorganic species and sugars from desirable light oxygenates such as acids and alcohols. Furthermore, a carbon treatment to remove color bodies was employed after it was found the presumably heavy organic chromophore species deactivated catalysts. These economic separation processes allowed for the successful demonstration of stable catalytic processing in the condensed-phase ketonization, dual-bed reforming, and direct olefin production processes for tens to hundreds of hours, which were limited only by the quantity of feed available. Techno-economic analysis of these processes demonstrated the impact possible when capturing “waste” organics as valuable products. The condensed-phase ketonization process for converting aqueous stream acids to ketones followed by reduction and dehydration to olefins sold as a co-product resulted in the reduction of the minimum fuel selling price by about 13% compared to the anaerobic-digestion, aqueous-phase treatment base case (3.74 to 4.29/GGE). The dual-bed reforming process was commensurate in price to the anaerobic digestion base case (4.24 versus 4.29/GGE). However, the need for external natural gas to produce hydrogen for bio-oil hydroprocessing was eliminated, thereby lowering the carbon impact of the process.

09 BIOMASS FUELS↗

Validation of Loci-Stream for Autogenous Pressurization of Cryogenic Propellant Tank

Autogenous pressurization of cryogenic propellant tanks eliminates the need to have an additional pressurant tank on the space vehicle, which is highly advantageous due to reduced vehicle mass and design complexity. Autogenous pressurization therefore is one of the key technologies for deep space exploration and long-term space missions. The complex interaction of thermal gradients, turbulence and phase change near the interface make the problem a challenging one to model. Nodal analysis tools and reduced order models are unable to capture the necessary physics. 3-D CFD analyses are necessary to fully characterize autogenous pressurization. CFD analyses pose their own difficulties. The requisite CFD tool to tackle this problem need to be modular with the ability to incorporate various physics models, efficient, and computationally scalable for simulating flight size tanks. NASA MSFC's Loci-Stream CFD tool along with the VOF module is a great candidate to fit this mold. We demonstrate our modeling approach and validation of Loci-Stream for predicting autogenous pressurization of a flight scale propellant tank in order for the solver to serve as a reliable design and analysis tool for NASA's CFM application needs. Liquid hydrogen tank pressurization tests carried out at the MSFC test stand 300 facilities provide reliable validation data for this purpose. These tests were modeled using the Loci-Stream solver with a newly implemented two-phase sharp interface treatment. We show that our modeling approach and CFD solver predict the autogenous pressurization phenomena satisfactorily, and document challenging aspects of modeling this problem.

cryogenic fluid management↗

Validation of Loci-Stream for Autogenous Pressurization of Cryogenic Propellant Tank

Autogenous pressurization of cryogenic propellant tanks eliminates the need to have an additional pressurant tank on the space vehicle, which is highly advantageous due to reduced vehicle mass and design complexity. Autogenous pressurization therefore is one of the key technologies for deep space exploration and long-term space missions. The complex interaction of thermal gradients, turbulence and phase change near the interface make the problem a challenging one to model. Nodal analysis tools and reduced order models are unable to capture the necessary physics. 3-D CFD analyses are necessary to fully characterize autogenous pressurization. CFD analyses pose their own difficulties. The requisite CFD tool to tackle this problem need to be modular with the ability to incorporate various physics models, efficient, and computationally scalable for simulating flight size tanks. NASA MSFC's Loci-Stream CFD tool along with the VOF module is a great candidate to fit this mold. We demonstrate our modeling approach and validation of Loci-Stream for predicting autogenous pressurization of a flight scale propellant tank in order for the solver to serve as a reliable design and analysis tool for NASA's CFM application needs. Liquid hydrogen tank pressurization tests carried out at the MSFC test stand 300 facilities provide reliable validation data for this purpose. These tests were modeled using the Loci-Stream solver with a newly implemented two-phase sharp interface treatment. We show that our modeling approach and CFD solver predict the autogenous pressurization phenomena satisfactorily, and document challenging aspects of modeling this problem.

CFM↗

CLARA: CLAS12 Reconstruction and Analysis Framework

In this paper we present SOA based CLAS12 event Reconstruction and Analyses (CLARA) framework. CLARA design focus is on two main traits: real-time data stream processing, and service-oriented architecture (SOA) in a flow based programming (FBP) paradigm. Data driven and data centric architecture of CLARA presents an environment for developing agile, elastic, multilingual data processing applications. The CLARA framework presents solutions capable of processing large volumes of data interactively and substantially faster than batch systems.

Gyurjyan, Vardan↗

Research on miniature gas analysis systems

Technology for fabricating very small valves, whose function will be to introduce a small sample of the gas to be analyzed into the main carrier gas stream flowing through the chromatograph column is described. In addition, some analyses were made of the factors governing the resolution of gas chromatographs, particularly those with miniature columns. These analyses show how important the column lining thickness is in governing the ability of a miniature column to separate components of an unknown gas. A brief description of column lining factors is included. Preliminary work on a super small thermistor detector is included.

Angell, J. B.↗

Experimental analysis and computation of the onset and development of the boundary layer transition

The transition of an incompressible boundary layer, with zero pressure gradient and low free-stream turbulence is studied. Mean velocity, turbulence and Reynolds shear stress profiles are presented. The development of the Tollmien-Schlichting waves is clearly shown until the turbulent spots appear. The intermittency phenomenon is studied by conditional sampling of the hotwire signal. The comparison with calculation results obtained by resolution of a set of transport equations shows a good agreement for the mean characteristics of the flow; discrepancies observed for the turbulent quantities evolution are due to the intermittency phenomenon.

Arnal, D.↗

Photometric analysis of a space shuttle water venting

Presented here is a preliminary interpretation of a recent experiment conducted on Space Shuttle Discovery (Mission STS 29) in which a stream of liquid supply water was vented into space at twilight. The data consist of video images of the sunlight-scattering water/ice particle cloud that formed, taken by visible light-sensitive intensified cameras both onboard the spacecraft and at the AMOS ground station near the trajectory's nadir. This experiment was undertaken to study the phenomenology of water columns injected into the low-Earth orbital environment, and to provide information about the lifetime of ice particles that may recontact Space Shuttle orbits later. The findings about the composition of the cloud have relevance to ionospheric plasma depletion experiments and to the dynamics of the interaction of orbiting spacecraft with the environment.

Viereck, R. A.↗

Progress in the development of advanced computational models for the analysis of generalized supersonic jet flowfields

This paper describes two three-dimensional computational codes (PARCH and CRAFT) for computing a generalized supersonic jet flowfields with subsonic external streams, which solve the Reynolds-averaged Navier-Stokes equations in a time asymptotic manner. The application of these codes to an imperfectly expanded jet flowfield is demonstrated. Special attention is given to numerical issues and to turbulence modeling. The application of the PARCH and CRAFT codes to other related flowfield problems, such as gas turbine and nozzle flows, and to generalized missile-plume flowfields is discussed.

Dash, S. M.↗

Griffin: A MOOSE-based reactor physics application for multiphysics simulation of advanced nuclear reactors

Griffin is a Multiphysics Object-Oriented Simulation Environment (MOOSE) based reactor physics application for multiphysics simulations of advanced reactor designs jointly developed by Idaho National Laboratory and Argonne National Laboratory. This paper summarizes the motivation, significance, architecture, design, and features of Griffin. Griffin offers flexible and extensible features to address the challenges associated with advanced reactor designs. These features range from fundamental particle transport to specific reactor physics tasks. The features cover a wide range including on-the-fly and traditional two-step cross-section generation methods, steady-state and transient transport solvers suitable for both heterogeneous and homogeneous models, high-fidelity depletion where thousands of isotopes can be tracked and low-fidelity depletion characterized by burnup, etc. The most fundamental aspect that sets Griffin apart from other reactor analysis codes is that it is developed based on the MOOSE framework. A modular development approach is strongly enforced, with multiphysics being an essential element considered since the beginning of Griffin’s development. Griffin links various MOOSE physics modules and couples to other MOOSE-based applications and non-MOOSE-based applications for multiphyiscs simulations. Griffin includes three modules: ISOXML for preparing and managing multigroup cross sections, radiation transport for solving the neutron transport equation, and reactor analysis for user-oriented reactor physics analysis functionalities. Griffin uses various finite element methods for spatial discretization, multigroup approximation for energy discretization and discrete ordinates method, spherical harmonics expansion method, and diffusion approximation for streaming direction discretization to solve the neutron transport equation. Griffin’s flexibility is evidenced through Griffin’s various applications to fast reactor, high-temperature reactor, pebble bed reactor, molten salt reactor, and microreactor designs. Griffin development follows the software quality assurance procedure for MOOSE-based applications and with software requirements consistent with the ASME NQA-1 standard. Griffin has been adopted into the reactor analysis system for the U.S. NRC and is in use at U.S. companies, universities and national laboratories.

97 MATHEMATICS AND COMPUTING↗

Preliminary utilization of Iran's ERTS-1 data in the field of geology and water resources

Preliminary analysis of a number of selected ERTS-1 images undertaken in the fields of geology and water resources for the purpose of testing its applicability and usefulness for mapping the natural resources of Iran identified a number of geologic and hydrologic phenomena, such as previously unknown faults, streams, and lakes. Due to a number of limiting factors, the results of this study are by no means conclusive; yet, the encouraging results obtained demonstrate the importance of satellite imagery for multidisciplinary resource analysis purposes in Iran.

Akhavi, M. S.↗

Validation of Two Phase Flow Modeling Techniques in Loci-Stream using Axial Jet Pressure Control and Autogenous Pressurization Experiment

Autogenous pressurization of cryogenic propellant tanks eliminates the need to have an additional pressurant tank on the space vehicle, which is highly advantageous due to reduced vehicle mass and design complexity. Autogenous pressurization therefore is one of the key technologies for deep space exploration and long-term space missions. The complex interaction of thermal gradients, turbulence and phase change near the interface make the problem a challenging one to model. Nodal analysis tools and reduced order models are unable to capture the necessary physics. 3-D CFD analyses are necessary to fully characterize autogenous pressurization. CFD analyses pose their own difficulties. The requisite CFD tool to tackle this problem need to be modular with the ability to incorporate various physics models, efficient, and computationally scalable for simulating flight size tanks. NASA MSFC's Loci-Stream CFD tool along with the VOF module is a great candidate to fit this mold. We demonstrate our modeling approach and validation of Loci-Stream for predicting autogenous pressurization of a flight scale propellant tank in order for the solver to serve as a reliable design and analysis tool for NASA's CFM application needs. Liquid hydrogen tank pressurization tests carried out at the MSFC test stand 300 facilities provide reliable validation data for this purpose. These tests were modeled using the Loci-Stream solver with a newly implemented two-phase sharp interface treatment. We show that our modeling approach and CFD solver predict the autogenous pressurization phenomena satisfactorily, and document challenging aspects of modeling this problem.

cryogenic fluid management↗

The solar wind neon abundance observed with ACE/SWICS and ULYSSES/SWICS

Using in situ ion spectrometry data from ACE/SWICS, we determine the solar wind Ne/O elemental abundance ratio and examine its dependence on wind speed and evolution with the solar cycle. We find that Ne/O is inversely correlated with wind speed, is nearly constant in the fast wind, and correlates strongly with solar activity in the slow wind. In fast wind streams with speeds above 600 km s{sup –1}, we find Ne/O = 0.10 ± 0.02, in good agreement with the extensive polar observations by Ulysses/SWICS. In slow wind streams with speeds below 400 km s{sup –1}, Ne/O ranges from a low of 0.12 ± 0.02 at solar maximum to a high of 0.17 ± 0.03 at solar minimum. These measurements place new and significant empirical constraints on the fractionation mechanisms governing solar wind composition and have implications for the coronal and photospheric abundances of neon and oxygen. The results are made possible by a new data analysis method that robustly identifies rare elements in the measured ion spectra. The method is also applied to Ulysses/SWICS data, which confirms the ACE observations and extends our view of solar wind neon into the three-dimensional heliosphere.

79 ASTRONOMY AND ASTROPHYSICS↗

PREPARING FOR ADVANCED LIGO: A STAR–GALAXY SEPARATION CATALOG FOR THE PALOMAR TRANSIENT FACTORY

The search for fast optical transients, such as the expected electromagnetic counterparts to binary neutron star mergers, is riddled with false positives (FPs) ranging from asteroids to stellar flares. While moving objects are readily rejected via image pairs separated by ∼1 hr, stellar flares represent a challenging foreground, significantly outnumbering rapidly evolving explosions. Identifying stellar sources close to and fainter than the transient detection limit can eliminate these FPs. Here, we present a method to reliably identify stars in deep co-adds of Palomar Transient Factory (PTF) imaging. Our machine-learning methodology utilizes the random forest (RF) algorithm, which is trained using >3×10{sup 6} sources with Sloan Digital Sky Survey (SDSS) spectra. When evaluated on an independent test set, the PTF RF model outperforms the SExtractor star classifier by ∼4%. For faint sources (r{sup ′}⩾21 mag), which dominate the field population, the PTF RF model produces a ∼19% improvement over SExtractor. To avoid false negatives in the PTF transient-candidate stream, we adopt a conservative stellar classification threshold, corresponding to a galaxy misclassification rate of 0.005. Ultimately, ∼1.70×10{sup 8} objects are included in our PTF point-source catalog, of which only ∼10{sup 6} are expected to be galaxies. We demonstrate that the PTF RF catalog reveals transients that otherwise would have been missed. To leverage its superior image quality, we additionally create an SDSS point-source catalog, which is also tuned to have a galaxy misclassification rate of 0.005. These catalogs have been incorporated into the PTF real-time pipelines to automatically reject stellar sources as non-extragalactic transients.

79 ASTRONOMY AND ASTROPHYSICS↗

Modeling Orifice Pulse Tube Coolers

We have developed a calculational model that treats all the components of an orifice pulse tube cooler. We base our analysis on 1-dimensional thermodynamic equations for the regenerator and we assume that all mass flows, pressure oscillations and temperature oscillations are small and sinusoidal. Non-linear pressure drop effects are included in the regenerator to account for finite pressure amplitude effects. The resulting mass flows and pressures are matched at the boundaries with the other components of the cooler: compressor, aftercooler, cold heat exchanger, pulse tube, hot heat exchanger, orifice and reservoir. The results of the calculation are oscillating pressures, mass flows and enthalpy flows in the main components of the cooler. By comparing with the calculations of other available models, we show that our model is very similar to REGEN 3 from NIST and DeltaE from Los Alamos National Lab. Our model is much easier to use than other available models because of its simple graphical interface and the fact that no guesses are required for the operating pressures or mass flows. In addition, the model only requires a few minutes of running time allowing many parameters to be optimized in a reasonable time. A version of the model is available for use over the World Wide Web at http://irtek.arc.nasa.gov. Future enhancements include adding a bypass orifice and including second order terms in steady mass streaming and steady heat transfer. A two-dimensional anelastic approximation of the fluid equations will be used as the basis for the latter analysis. Preliminary results are given in dimensionless numbers appropriate for oscillating compressible flows. The model shows how transverse heat transfer reduces enthalpy flow, particularly for small pulse tubes. The model also clearly shows mass recirculation in the open tube on the order of the tube length. They result from the higher order Reynolds stresses. An interesting result of the linearized approach is that the steady mass streaming does not affect the enthalpy flow at second order. The major effect of recirculating mass streaming is to increase transverse temperature gradients, which leads to higher entropy production and reduced efficiency.

Roach, Kittel P.↗

Impact of Fission Products Impurity on the Plutonium Content in PWR MOX Fuels

This report presents the results of a neutronics analysis done in response to the charter IFCA-SAT-2 entitled 'Fuel impurity physics calculations'. This charter specifies that the separation of the fission products (FP) during the reprocessing of UOX spent nuclear fuel assemblies (UOX SNF) is not perfect and that, consequently, a certain amount of FP goes into the Pu stream used to fabricate PWR MOX fuel assemblies. Only non-gaseous FP have been considered (see the list of 176 isotopes considered in the calculations in Appendix 1). This mixture of Pu and FP is called Pu FP . Note that, in this preliminary analysis, the FP losses are considered element-independent, i.e., for example, 1% of FP losses mean that 1% of all non-gaseous FP leak into the Pu stream.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗