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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,135 records · Page 63

Automated On-board Terrain Analysis for Precision Landings

Advances in space robotics technology hinge to a large extent upon the development and deployment of sophisticated new vision-based methods for automated in-space mission operations and scientific survey. To this end, we have developed a new concept for automated terrain analysis that is based upon a generic image enhancement platform-multi-scale Retinex (MSR) and visual servo (VS) processing. This pre-conditioning with the MSR and the VS produces a "canonical" visual representation that is largely independent of lighting variations, and exposure errors. Enhanced imagery is then processed with a biologically inspired two-channel edge detection process, followed by a smoothness based criteria for image segmentation. Landing sites can be automatically determined by examining the results of the smoothness-based segmentation which shows those areas in the image that surpass a minimum degree of smoothness. Though the MSR has proven to be a very strong enhancement engine, the other elements of the approach, the VS, terrain map generation, and smoothness-based segmentation, are in early stages of development. Experimental results on data from the Mars Global Surveyor show that the imagery can be processed to automatically obtain smooth landing sites. In this paper, we describe the method used to obtain these landing sites, and also examine the smoothness criteria in terms of the imager and scene characteristics. Several examples of applying this method to simulated and real imagery are shown.

Rahman, Zia-ur↗

Elevated temperature biaxial fatigue

A 3 year experimental program for studying elevated temperature biaxial fatigue of a nickel based alloy Hastelloy-X has been completed. A new high temperature fatigue test facility with unique capabilities has been developed. Effort was directed toward understanding multiaxial fatigue and correlating the experimental data to the existing theories of fatigue failure. The difficult task of predicting fatigue lives for nonproportional loading was used as an ultimate test for various life prediction methods being considered. The primary means of reaching improved understanding were through several critical nonproportional loading experiments. The direction of cracking observed on failed specimens was also recorded and used to guide the development of the theory. Cyclic deformation responses were permanently recorded digitally during each test. It was discovered that the cracking mode switched from primarily cracking on the maximum shear planes at room temperature to cracking on the maximum normal strain planes at 649 C. In contrast to some other metals, loading path in nonproportional loading had little effect on fatigue lives. Strain rate had a small effect on fatigue lives at 649 C. Of the various correlating parameters the modified plastic work and octahedral shear stress were the most successful.

Jordan, E. H.↗

Preliminary Steps in Developing Rapid Aero Modeling Technology

The Rapid Aero Modeling (RAM) approach is a method to efficiently and automatically obtain aerodynamic models during testing, significantly saving time and resources. Motivation for this technology results from demand for experimental efficiency and model fidelity that has increased with growing aircraft complexity and aerodynamic nonlinearities. These issues are typical in the responses presented by a class of vehicles categorized as Urban Air Mobility aircraft where many features from both airplane and rotorcraft are present. For UAM configurations, with typically many more factors than conventional aircraft, traditional test methods can lead to increased costs and missed interactions. RAM guides the test to obtain high-fidelity, statistically rigorous aircraft models, and the approach is applicable to computational, ground, or flight-test experiments. It combines concepts from Design of Experiment theory and Aircraft System Identification theory that allow the user the freedom to choose, in advance of the test, a specific level of fidelity typically, in terms of prediction error. RAM only collects data required to meet the user-specified fidelity and fidelity is only limited by the facility and test article capabilities. An initial wind tunnel test to support development of RAM was conducted to assess potential metrics, algorithms, and procedures. This paper presents results from initial tests for the development of RAM technology and highlights some of the unique features of RAM applied toa conventional configuration during a ground-based, static, wind-tunnel test.

Patrick C Murphy↗

A review of experimental methods to determine bioaerosol transfer in energy recovery ventilators

Increasing ventilation is an effective method to reduce indoor airborne disease transmission. An Energy recovery ventilator (ERV) is a passive energy recovery device used to reduce the energy consumption of heating, ventilation and air-conditioning (HVAC) systems for conditioning the ventilation air. It preconditions the ventilation air by transferring energy from building exhaust air. Therefore, the ventilation and exhaust air streams interact directly/indirectly in the ERV for energy transfer. It is surmised that the ERV may transfer bioaerosols (with pathogens) from the exhaust air to ventilation air, resulting in the spread of infectious diseases. Consequently, many pandemic HVAC guidelines recommend that the use of ERVs be limited. This is a highly unsustainable direction given the increased energy requirements associated with the high ventilation provision advocated for pandemic operation. It must be noted that no validated experimental evidence exists in literature for bioaerosol transfer in ERVs. Hence, it is necessary to conduct extensive bioaerosol transfer research before adopting the unsustainable practice of limiting the utilization of ERVs. The main objective of this review study is to summarize the experimental methods and instrumentation for bioaerosol transfer research in ERVs. This comprehensive article provides a detailed overview of the generation, sampling, and analysis of bioaerosols for conducting the experiments. Further, it explains the possible mechanisms for bioaerosol transfer in various types of ERVs based on which the ERVs that need immediate attention are identified. The main contribution of this research paper is that it provides a novel experimental method which encompasses the biosafety aspects, instrumentation, performance parameters and uncertainties in conducting virus contained bioaerosol transfer study in ERVs. The findings from this review will be helpful in designing bioaerosol transfer experiments and developing future ERV test standards for such experiments.

42 ENGINEERING↗

Developing a space-filling mixture experiment design when the components are subject to linear and nonlinear constraints

This article presents a case study of developing a space-filling design (SFD) for a constrained mixture experiment when the experimental region is specified by single-component constraints (SCCs), linear multiple-component constraints (LMCCs), and nonlinear multiple-component constraints (NMCCs). Traditional methods and software for designing constrained mixture experiments with SCCs and LMCCs (using either optimal design or SFD approaches) are not directly applicable because of the NMCCs. A SFD algorithm in the JMP software was modified to accommodate the nonlinear MCCs; the modification is described in this article. The case study involves high-level waste (HLW) glass that is subject to the formation of nepheline crystals as the glass cools. This can significantly reduce the durability of HLW glass (which is undesirable). The goal of the study was to develop a SFD for the HLW glass compositional region where nepheline may form, and generate data for modeling nepheline formation as a function of HLW glass composition. The HLW glass composition region was specified in terms of eight components with SCCs, two LMCCs, and two NMCCs. The NMCCs were based on a nonlinear logistic regression model for a binary-response nepheline response that was developed from previous data. This article discusses the HLW glass example, the constraints specifying the experimental composition region, and how an existing algorithm for generating SFDs was modified to accommodate the NMCCs. The methodology discussed in this article can be applied to any example in which the experimental region is specified by one or more nonlinear constraints in addition to linear constraints on mixture components and/or non-mixture variables.

Mixture experiment, space-filling experimental des↗

Physics of debris clouds from hypervelocity impacts

The protection scheme developed for long duration space platforms relies primarily upon placing thin metal plates or 'bumpers' around flight critical components. The effectiveness of this system is highly dependent upon its ability to break up and redistribute the momentum of any particle which might otherwise strike the outer surface of the spacecraft. Therefore it is of critical importance to design the bumpers such that maximum dispersion of momentum is achieved. This report is devoted to an in-depth study into the design and development of a laboratory instrument which would permit the in-situ monitoring of the momentum distribution as the impact event occurs. A series of four designs were developed, constructed and tested culminating with the working instrument which is currently in use. Each design was individually tested using the Space Environmental Effects Facility (SEEF) at the Marshall Space Flight Center in Huntsville, Alabama. Along with the development of the device, an experimental procedure was developed to assist in the investigation of various bumper materials and designs at the SEEF. Preliminary results were used to compute data which otherwise were not experimentally obtainable. These results were shown to be in relative agreement with previously obtained values derived through other methods. The results of this investigation indicated that momentum distribution could in fact be measured in-situ as the impact event occurred thus giving a more accurate determination of the effects of experimental parameters on the momentum spread. Data produced by the instrument indicated a Gaussian-type momentum distribution. A second apparatus was developed and it was placed before the shield in the line of travel utilized a plate to collect impact debris scattered backwards. This plate had a passage hole in the center to allow the particle to travel through it and impact the proposed shield material. Applying the law of conservation of angular momentum a backward momentum vector was determined from the angular velocity of the plate. The forward scattered and backward scattered momentum values were then analyzed to judge the distribution of debris. Loss of momentum was attributed to the inaccuracies of the means of measurement. Assumptions of symmetrical debris for the forward and backward scattered directions also contributed to this loss.

Zee, Ralph↗

Charge carrier mobility of halide perovskite single crystals for ionizing radiation detection

Halide perovskites have recently emerged as promising semiconductor materials for several applications including solar cells, light-emitting diodes (LEDs), and radiation detectors. The charge carrier transport properties, which could be evaluated by the mobility-lifetime (mu-tau or μ-г) product, serve an important role for the development of halide perovskites for radiation detection applications. In this perspective, we firstly explain the charge transport mechanism and the limiting factors that determine the intrinsic charge carrier mobility in halide perovskite single crystals. Then, we overview the techniques and methods that have been employed for evaluating the charge carrier mobility (for both electrons and holes). Lastly, we discuss the discrepancy between the experimentally determined carrier mobility from the literature for halide perovskite single crystals and a perspective on future developments for carrier mobility enhancement is provided.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

REBOUND: Reverse Engineering Bidirectional Outflow Under Non-Equilibrium Diffusion

Rare-earth elements (REEs) are essential for electronics, renewable energy, and defense technologies. However, the current supply of REEs relies on mining concentrated in a few countries and energy-intensive separations. DOE’s Basic Energy Sciences (BES) program has launched a grand challenge which aims to ensure a sustainable supply of critical REEs by developing innovative and environmentally friendly separation methods. As an alternative to costly and harmful traditional methods, the Non-Equilibrium Transport Driven Separations (NETS) initiative has created a microfluidic Y-channel co-flow method that applies external fields to exploit magneto- and electrohydrodynamic effects for separating dilute REE ions from complex feedstocks. Computational fluid dynamics (CFD) studies have identified a few operating conditions with promising ion selectivity and separation efficiency. However, challenges remain regarding Y-channel versatility across feedstocks and accurate incorporation of physical phenomena into CFD models. In this work, we develop a multi-fidelity modelling approach which integrates experimental results with CFD simulation to build a surrogate model for the dependence of separation efficiency to variation of design parameters. The surrogate model enables a reinforcement learning (RL) method to adaptively launch CFD and experimental runs, improving model fidelity around optimal Y-channel parameters.

36 MATERIALS SCIENCE↗

Small-Scale Drying: FY2020 Interim Report

This report documents the interim experimental status of small-scale drying tests currently being performed at Pacific Northwest National Laboratory. These small-scale drying tests are to develop the technical bases for sensors, techniques, and approaches that will be used to address the challenges faced when determining moisture content from gas samples taken at the North Anna Nuclear Generating Station for the High Burnup Demonstration Project. Specifically, the purpose of these tests is to support Sandia National Laboratories gas sample methods and analyses through a series of small-scale experiments. Key focus areas include performing tests to: • Correlate sample bottle measurements to in-cask conditions • Estimate the amount of trapped and absorbed water on cask features and surfaces that can contribute to water vapor • Assess the accuracy of the hygrometer used in the measurements under similar conditions • Identify additional methods for measuring humidity in casks easily and accurately using lessons-learned from Sandia National Laboratories, including direct gravimetric and isotopic tracer techniques. To address these topics this report outlines a series of five tests and any data collected to date that were planned for FY 2020 that include 1) humidity measurement method development, 2) gas bottle sampling tests, 3) surface drying tests on cladding, 4) small-scale drying of cladding, and 5) small-scale drying of guide-tube/dashpots. This interim report documents the experimental background, design and progress of these small-scale drying tests. Further data gathered will be summarized in the FY 2021 report.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Probing coherence in nanoscale energy transport with high spatial-temporal resolution. Final Technical Report for DOE Award Number DE-SC0019244

The overarching goal of this project is to understand how the phase coherence of phonons and the interaction of phonons with other microscopic degrees of freedom in nanomaterials, such as 2D materials, can affect the energy transport properties and eventually lead to control of energy transport by manipulating phonon interference and phonon scatterings. On the computational side, we are developing and applying first-principles methods to study emerging phonon properties in nanomaterials, including coherent phonons, resonant bonding and gate-tunable phonon-electron scatterings, which hold the promise of enabling significant tunability of energy transport processes with external fields for a wide range of applications. On the experimental side, we are developing ultrafast transient grating spectroscopy and scanning ultrafast electron microscopy (SUEM) to directly probe the coherent phonon transport and phonon-electron interaction processes in nanomaterials with high combined spatial-temporal resolutions. This program will not only provide new insights into the microscopic transport and interaction processes of fundamental energy carriers, but also open new venue towards energy-relevant applications such as thermal switches and coherent energy harvesters.

42 ENGINEERING↗

An index to characterize gas‐solid and solid‐solid mixing from average volume fraction fields

Abstract A mixing index based on solid volume fraction fields is developed for gas‐solid flows. Conventional mixing indices are based on particle realizations of granular mixing and are applicable to experimental data or discrete element method simulations. However, these indices cannot be used as‐is for multifluid models, and an index for characterizing mixing in gas‐solid flows from continuous fields is needed. The performance of the new mixing index is tested in two applications. The first is a 3D simulation of the mixing of biomass and sand in a fluidized bed reactor, and the second is a 2D simulation of binary particle segregation in a fluidized bed. The simulations are performed using OpenFOAM®. The mixing index is used to quantify gas‐solid mixing using solid volume fractions and solid‐solid mixing using solid fractions. The formulation of conventional mixing indices is extended to be used with solid volume fractions fields, and methods for performance improvement are presented.

09 BIOMASS FUELS↗

Ionic/electronic conductivity regulation of n-type polyoxadiazole lithium sulfonate conductive polymer binders for high-performance silicon microparticle anodes

Low-cost silicon microparticles (SiMP), as a substitute for nanostructured silicon, easily suffer from cracks and fractured during the electrochemical cycle. A novel n-type conductive polymer binder with excellent electronic and ionic conductivities as well as good adhesion, has been successfully designed and applied for high-performance SiMP anodes in lithium-ion batteries to address this problem. Its unique features are attributed to the strong electron-withdrawing oxadiazole ring structure with sulfonate polar groups. The combination of rigid and flexible components in the polymer ensures its good mechanical strength and ductility, which is beneficial to suppress the expansion and contraction of SiMP s during the charge/discharge process. By fine-tuning the monomer ratio, the conjugation and sulfonation degrees of the polymer can be precisely controlled to regulate its ionic and electronic conductivities, which has been systematically analyzed with the help of an electrochemical test method, filling in the gap on the conductivity measurement of the polymer in the doping state. The experimental results indicate that the cell with the developed n-type polymer binder and SiMP (~0.5 μm) anodes achieves much better cycling performance than traditional non-conductive binders. It has been considered that the initial capacity of the SiMP anode is controlled by the synergetic effect of ionic and electronic conductivity of the binder, and the capacity retention mainly depends on its electronic conductivity when the ionic conductivity is sufficient. Here, it is worth noting that the fundamental research of this work is also applicable to other battery systems using conductive polymers in order to achieve high energy density, broadening their practical applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Active and machine learning-based approaches to rapidly enhance microbial chemical production

In order to make renewable fuels and chemicals from microbes, new methods are required to engineer microbes more intelligently. Computational approaches, to engineer strains for enhanced chemical production typically rely on detailed mechanistic models (e.g., kinetic/stoichiometric models of metabolism)—requiring many experimental datasets for their parameterization—while experimental methods may require screening large mutant libraries to explore the design space for the few mutants with desired behaviors. To address these limitations, we developed an active and machine learning approach (ActiveOpt) to intelligently guide experiments to arrive at an optimal phenotype with minimal measured datasets. In this study, ActiveOpt was applied to two separate case studies to evaluate its potential to increase valine yields and neurosporene productivity in Escherichia coli. In both the cases, ActiveOpt identified the best performing strain in fewer experiments than the case studies used. This work demonstrates that machine and active learning approaches have the potential to greatly facilitate metabolic engineering efforts to rapidly achieve its objectives.

60 APPLIED LIFE SCIENCES↗

Dataset of low global warming potential refrigerant refrigeration system for fault detection and diagnostics

Abstract HVAC and refrigeration system fault detection and diagnostics (FDD) has attracted extensive studies for decades; however, FDD of supermarket refrigeration systems has not gained significant attention. Supermarkets consume around 50 kWh/ft 2 of electricity annually. The biggest consumer of energy in a supermarket is its refrigeration system, which accounts for 40%–60% of its total electricity usage and is equivalent to about 2%–3% of the total energy consumed by commercial buildings in the United States. Also, the supermarket refrigeration system is one of the biggest consumers of refrigerants. Reducing refrigerant usage or using environmentally friendly alternatives can result in significant climate benefits. A challenge is the lack of publicly available data sets to benchmark the system performance and record the faulted performance. This paper identifies common faults of supermarket refrigeration systems and conducts an experimental study to collect the faulted performance data and analyze these faults. This work provides a foundation for future research on the development of FDD methods and field automated FDD implementation.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Dynamic model-based feature extraction for fault detection and diagnosis of a supermarket refrigeration system

With the increasing concerns over climate change and carbon emissions, fault detection and diagnostics (FDD) of low–global warming potential (GWP) refrigerant supermarket refrigeration systems has gained great attention from academic and industrial sectors. Various FDD approaches have been developed to detect, identify, and diagnose faults to save energy, improve food quality, and protect the environment. Here, to mitigate the difficulty of collecting high-quality steady-state operational data in field operations faced by most model-based FDD methods, this study developed dynamic models of a low–GWP refrigerant (CO 2 ) supermarket refrigeration system. The model accuracy was validated using manufacturer data and experimental data. Simulations were conducted to predict the system dynamic response under two common operational faults—evaporator air path blockage fault and the display case door open fault—to identify fault patterns and define key dynamic behavior indexes for supporting FDD algorithm development.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Beta-Decay Half-Lives beyond 54 Ca: A Systematic Survey of Decay Properties Approaching the Neutron Dripline

In an experiment performed at the Facility for Rare Isotope Beams (FRIB) using the FRIB Decay Station initiator, 15 new half-lives of isotopes near 54 Ca were measured. A new method of extracting lifetimes from experimental data, taking into account the unknown 𝛽-delayed neutron emission branches of very neutron-rich nuclei, was developed to enable systematic uncertainty analysis. The experiment observed a dramatic change in the half-life systematics for the isotopes with neutron number 𝑁 = 34. Beyond 𝑁 = 34, the decline of nuclear lifetime is much slower, leading to longer than anticipated lifetimes for near-dripline nuclei. State-of-the-art shell-model calculations can explain the experimental results, revealing the imprint of shell effects and the need for modification of single-particle neutron states. In conclusion, the results from a newly developed quasiparticle random phase approximation model with potential for making global predictions were also tested against the experimental results and good agreement was found.

Physics - Nuclear physics and radiation physics↗

Master equation emulation and coherence preservation with classical control of a superconducting qubit

Open quantum systems are a topic of intense theoretical research. The use of master equations to model a system's evolution subject to an interaction with an external environment is one of the most successful theoretical paradigms. General experimental tools to study different open system realizations have been limited, and so it is highly desirable to develop experimental tools which emulate diverse master equation dynamics and give a way to test open systems theories. In this paper we demonstrate a systematic method for engineering specific system-environment interactions and emulating master equations of a particular form using classical stochastic noise in a superconducting transmon qubit. We also demonstrate that non-Markovian noise can be used as a resource to extend the coherence of a quantum system and counteract the adversarial effects of Markovian environments.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Gene regulatory networks for lignin biosynthesis in switchgrass (Panicum virgatum )

Summary Cell wall recalcitrance is the major challenge to improving saccharification efficiency in converting lignocellulose into biofuels. However, information regarding the transcriptional regulation of secondary cell wall biogenesis remains poor in switchgrass ( Panicum virgatum ), which has been selected as a biofuel crop in the United States. In this study, we present a combination of computational and experimental approaches to develop gene regulatory networks for lignin formation in switchgrass. To screen transcription factors ( TF s) involved in lignin biosynthesis, we developed a modified method to perform co‐expression network analysis using 14 lignin biosynthesis genes as bait (target) genes. The switchgrass lignin co‐expression network was further extended by adding 14 TF s identified in this study, and seven TF s identified in previous studies, as bait genes. Six TF s (Pv MYB 58/63, Pv MYB 42/85, Pv MYB 4, Pv WRKY 12, Pv SND 2 and Pv SWN 2) were targeted to generate overexpressing and/or down‐regulated transgenic switchgrass lines. The alteration of lignin content, cell wall composition and/or plant growth in the transgenic plants supported the role of the TF s in controlling secondary wall formation. RNA ‐seq analysis of four of the transgenic switchgrass lines revealed downstream target genes of the secondary wall‐related TF s and crosstalk with other biological pathways. In vitro transactivation assays further confirmed the regulation of specific lignin pathway genes by four of the TF s. Our meta‐analysis provides a hierarchical network of TF s and their potential target genes for future manipulation of secondary cell wall formation for lignin modification in switchgrass.

transcription factors↗