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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1975

Water vapor weathering of Taurus-Littrow orange soil - A pore-structure analysis

A pore-volume analysis was performed on water vapor adsorption data previously obtained on a fresh sample of Taurus-Littrow orange soil, and the analysis was repeated on the same sample after its exposure to moist air for a period of approximately six months. The results indicate that exposure of an outgassed sample to high relative pressures of water vapor can result in the formation of substantial micropore structure, the precise amount being dependent on the sample pretreatment, particularly the outgassing temperature. Micropore formation is explained in terms of water penetration into surface defects. In contrast, long-term exposure to moist air at low relative pressures appears to reverse the process with the elimination of micropores and enlargement of mesopores possibly through surface diffusion of metastable adsorbent material. The results are considered with reference to the storage of lunar samples.

Cadenhead, D. A.↗

NASA NTRS1992

The asymmetric distribution of satellite galaxy velocities

Companion galaxies tend to have redshifts that exceed that of their associated primary. We show that the latest sample of satellite galaxies (from Zaritsky et al.) corroborates this assertion. We examine whether selection biases and contamination by galaxies that are not physical satellites can create the observed velocity asymmetry. As shown by Valtonen and Byrd (1986) for previous samples, simple models of the selection process reproduce the sense of the asymmetry, but not its magnitude unless the samples are dominated by interlopers. We expand on this model by using numerical simulations that include a simple model of galaxy clustering, and demonstrate that clustering can increase the magnitude of the expected asymmetry for a particular level of contamination. Depending on input assumptions, these models imply 1 sigma lower limits on the contamination level in the Zaritsky et al. (1992) sample of between 8 and 20 percent. Using the results from the analysis of that sample and the models, we conclude that, for the type of satellite galaxy sample discussed, here, a moderate level of contamination (about 10 percent) is sufficient to account for the observed asymmetry.

Zaritsky, Dennis↗

NASA NTRS1979

Chemical processes involved in the initiation of hot corrosion of B-1900 and NASA-TRW VIA

Sodium sulfate induced hot corrosion of B-1900 and NASA-TRW VIA at 900 C was studied with special emphasis on the chemical reactions occurring during and immediately after the induction period. Thermogravimetric tests were run for set periods of time after which the samples were washed with water and water soluable metal salts and/or residual sulfates were analyzed chemically. Element distributions within the oxide layer were obtained from electron microprobe X-ray micrographs. A third set of samples were subjected to surface analysis by X-ray photoelectron spectroscopy. Evolution of SO2 was monitored throughout many of the hot corrosion tests. Results are interpreted in terms of acid-base fluxing mechanisms.

Fryburg, G. C.↗

NASA NTRS1992

High-temperature deformation and microstructural analysis for silicon nitride-scandium(III) oxide

It was indicated that Si3N4 doped with Sc2O3 may exhibit high temperature mechanical properties superior to Si3N4 systems with various other oxide sintered additives. High temperature deformation of samples was studied by characterizing the microstructures before and after deformation. It was found that elements of the additive, such as Sc and O, exist in small amounts at very thin grain boundary layers and most of them stay in secondary phases at tripple and multiple grain boundary junctions. These secondary phases are devitrified as crystalline Sc2Si2O7. Deformation of the samples was dominated by cavitational processes rather than movements of dislocations. Thus the excellent deformation resistance of the samples at high temperature can be attributed to the very small thickness of the grain boundary layers and the crystalline secondary phase.

Cheong, Deock-Soo↗

NASA NTRS2018

The Planetary Materials Database

NASA provides funds for a variety of research programs whose principal focus is to collect and analyze terrestrial analog materials. These data are used to (1) understand and interpret planetary geology; (2) identify and characterize habitable environments and pre-biotic/biotic processes; (3) interpret returned data from present and past missions; and (4) evaluate future mission and instrument concepts prior to selection for flight. Data management plans are now required for these programs, but the collected data are still not generally available to the community. There is also little possibility to re-analyze the collected materials by other techniques, since there is no requirement to archive collected samples. The Planetary Materials Database (PMD) is a central, high-quality, long-term data repository, which aims to promote the field of astrobiology and increase scientific returns from NASA funded research by enabling data sharing, collaboration and exposure of non-NASA scientists to NASA research initiatives and missions. The PMD is a linked collection of databases developed using the Open Data Repository (ODR) system. The PMD will include detailed descriptions of terrestrial analog planetary materials as well as data from the instruments used in their analysis. The goal is to provide example patterns/spectra/analyses, etc. and background information suitable for use by the Space Science community. An early example showing the utility of these databases (although not in the ODR format) is the RRUFF mineral database. RRUFF, comprising 4,000+ pure mineral standards, is the most popular and widely used dataset of minerals and receives more than 180,000 queries per week from geologists and mineralogists worldwide. The PMD will be patterned after the CheMin database [3], a resource that contains all of the data collected by the MSL CheMin XRD instrument on Mars. Raw and processed CheMin data can be viewed, downloaded, reprocessed and reanalyzed using cloud-based “applications” linked to the data.

Blake, David↗

NASA NTRS1978

Production and analysis of thermal decomposition products from polymeric materials

A description is presented of a strategy for analyzing the combustion process and the degradation products which are formed. One of three primary objectives in the study of polymer degradation is related to the characterization of the material to be studied and the investigation of the thermal behavior of the material. Another objective is concerned with the definition of the nature of the decomposition process by identification and quantitation of the degradation products. The third objective involves the determination of the mechanism and kinetics of the decomposition process. The methods of sample degradation include pyrolysis, oxidative degradation, flaming combustion, and the use of large-scale combustion chambers. Methods of chemical separation and identification are considered, taking into account low-boiling volatiles, high-boiling volatiles, and ancillary techniques.

Chatfield, D. A.↗

NASA NTRS1979

Neutron-gamma techniques for planetary exploration

Chemical analysis of planetary surfaces is necessary for the understanding of the origin and evolutionary processes of the solar system. Orbital lunar geochemical experiments performed during the Apollo 15 and 16 demonstrated that even with a low neutron flux (fast and thermal), reliable results could be extracted. The possibility of using a compact 14 MeV neutron generator for geochemical analysis of planetary surfaces, comets and asteroids is currently studied. This method allows the determination of bulk chemical composition, even in the presence of an atmosphere. This would be possible on the surface of Venus, for example, where alternate methods such as sample return are impractical. This method can be used for continuous monitoring of elemental abundances from a roving vehicle, for example, on the surface of Mars.

Johnson, R. G.↗

NASA NTRS2002

Ship Radar Observations of a Developing Hurricane in the East Pacific

During the recently completed East Pacific Investigation of Climate Processes in the Coupled Ocean-Atmosphere System (EPIC) field program, the NOAA research vessel Ronald H. Brown (RHB) was deployed in the east Pacific Inter Tropical Convergence Zone (ITCZ) for approximately 3 weeks near 10 deg. N, 95 deg. W. One of the principal objectives of the EPIC-ITCZ program was to observe the modulation of convection by synoptic-scale easterly waves and the air-sea coupling process in this poorly sampled region of the east Pacific. Data from the experiment will be used as validation to improve forecast models. The RHB carried a variety of platforms during EPIC to sample atmospheric and oceanic phenomena, including a scanning C-band Doppler radar, radiation flux instrumentation, air-sea flux system, Doppler lidar, 35 GHz cloud radar, UHF wind profiler, sea surface temperature (SST) sensors, as well as standard surface meteorological instrumentation and a suite of rain gauges. This presentation will focus on the analysis of C-band radar data that was collected on 10 September, 2001 as the ship passed through an easterly wave which later developed into hurricane Ivo. The ship captured approximately 12 hours of convection associated with the tropical disturbance. During this period, the domain sampled by the radar (approximately 71,000 sq km) contained a significant number of echo features. Specifically, the fraction of the domain containing radar echo above 10 dBZ reached 80% for over 2 hours and remained near 60% for a continuous six hour period. Animation of radar images showed distinct rotation in echo features associated with the easterly wave passage. Despite an approximate 4 C drop in surface air temperature and sustained winds approaching 20 m/ s, the SST remained nearly constant throughout the observation period (approx. 29.5 C). Peak values of latent and sensible heat flux exceeded 400 and 100 W /sq m, respectively. The radar documented the change in precipitation vertical structure as the ship passed through regions of significant convection with echo tops approaching 14 km and 30 dBZ echo tops extending to near 9 km embedded in regions that were predominantly stratiform in nature. Single Doppler retrievals (Extended Velocity Azimuth Display) were conducted continuously at 10-minute resolution for approximately 4 hours in the latter part of the observation period, and documented the transition from convection (low-level convergence, upper level divergence) to stratiform (mid-level convergence sandwiched between upper and lower level divergence) kinematic structure.

Cifelli, Robert↗

NASA NTRS2004

Direct Observation of Controlled Melting and Resolidification of Succinonitrile Mixtures in a Microgravity Environment

In support of the Pore Formation and Mobility Investigation (PFMI) direct observation of experiments on the controlled melting and subsequent resolidification of succinonitrile were conducted in the glovebox facility (GBX) of the International Space Station (ISS). Samples were prepared on ground by filling glass tubes, 1 cm ID and approximately 30 cm in length, with pure succinonitrile (SCN) and SCN-Water mixtures under 450 millibar of nitrogen. Experimental processing parameters of temperature gradient and translation speed, as well as camera settings, were remotely monitored and manipulated from the ground Telescience Center (TSC) at the Marshall Space Flight Center. Sample temperatures are monitored by six in situ thermocouples. Real time visualization during melt back revealed bubbles of different sizes initiating at the solid/liquid interface, their release, interactions, and movement into the temperature field ahead of them. Subsequent re-solidification examined planar interface breakdown and the transition to steady-state dendritic growth. A preliminary analysis of the observed phenomena and its implication to future microgravity experiments is presented and discussed.

Grugel, R. N.↗

NASA NTRS2007

Association between Randall's Plaque and Calcifying Nanoparticles

Randall initially described calcified subepithelial papillary plaques, which he hypothesized as nidi for kidney stone formation. The discovery of calcifying nanoparticles (CNP) in many calcifying processes of human tissues has raised another hypothesis about their possible involvement in urinary stone formation. This research is the first attempt to investigate the potential association of these two hypotheses. We collected renal papilla and blood samples from 17 human patients who had undergone laparoscopic nephrectomy due to neoplasia. Immunohistochemical staining (IHS) was applied on the tissue samples using monoclonal antibody 8D10 (mAb) against CNP. Homogenized papillary tissues and serum samples were cultured for CNP. Scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) analysis were performed on fixed papillary samples. Randall's plaques were visible on gross inspection in 11 out of 17 collected samples. IHS was positive for CNP antigen in 8 of these 11 visually positive samples, but in only 1 of the remaining 6 samples. SEM revealed spherical apatite formations in 14 samples, all of which had calcium and phosphate peaks detected by EDS analysis. From this study, there was some evidence of a link between the presence of Randall's plaques and the detection of CNP, also referred to as nanobacteria. Although causality was not demonstrated, these results suggest that further studies with negative control samples should be made to explore the etiology of Randall's plaque formation, thus leading to a better understanding of the pathogenesis of stone formation.

Citfcioglu, Neva↗

NASA NTRS2004

Nuclear Microprobe using Elastic Recoil Detection (ERD) for Hydrogen Profiling in High Temperature Protonic Conductors

The interaction between hydrogen and various high temperature protonic conductors (HTPC) has not been clearly understood due to poor densification and unreacted secondary phases. the melt-processing technique is used in producing fully dense simple SrCe(0.9)Y (0.10) O(3-delta) and complex Sr3Ca(1+x)Nb(2+x)O(9-delta) perovskites that can not be achieved by solid-state sintering. the possibilities of ion beam analysis have been investigated to quantify hydrogen distribution in HTPC perovskites subjected to water heat treatment. Nuclear microprobe technique is based on the interactions of a focused ion beam of MeV light ions (H-1, H-2, He-3, He-4,.) with the sample to be analyzed to determine local elemental concentrations at the cubic micrometer scale, the elastic recoil detection analysis technique (ERDA) has been carried out using He-4(+) microbeams and detecting the resulting recoil protons. Mappings of longitudinal sections of water treated SrCeO3 and Sr(Ca(1/3)Nb(2/3))O3 perovskites have been achieved, the water treatment strongly alters the surface of simple SrCe(0.9)Y(0.10)O(3-delta) perovskite. From Rutherford Back Scattering measurements (RBS), both Ce depletion and surface re-deposition is evidenced. the ERDA investigations on water treated Sr3Ca(1+x)Nb(2+x)O(9-delta) perovskite did not exhibit any spatial difference for the hydrogen incorporation from the surface to the centre. the amount of hydrogen incorporation for Sr3Ca(1+x)Nb(2+x)O(9-delta) was low and required further development of two less conventional techniques, ERDA in forward geometry and forward elastic diffusion H-1(p,p) H-1 with coincidence detection.

Berger, Pascal↗

NASA NTRS2014

Hot Hydrogen Testing of Tungsten-Uranium Dioxide (W-UO2) CERMET Fuel Materials for Nuclear Thermal Propulsion

CERMET fuel materials are being developed at the NASA Marshall Space Flight Center for a Nuclear Cryogenic Propulsion Stage. Recent work has resulted in the development and demonstration of a Compact Fuel Element Environmental Test (CFEET) System that is capable of subjecting depleted uranium fuel material samples to hot hydrogen. A critical obstacle to the development of an NCPS engine is the high-cost and safety concerns associated with developmental testing in nuclear environments. The purpose of this testing capability is to enable low-cost screening of candidate materials, fabrication processes, and further validation of concepts. The CERMET samples consist of depleted uranium dioxide (UO2) fuel particles in a tungsten metal matrix, which has been demonstrated on previous programs to provide improved performance and retention of fission products1. Numerous past programs have utilized hot hydrogen furnace testing to develop and evaluate fuel materials. The testing provides a reasonable simulation of temperature and thermal stress effects in a flowing hydrogen environment. Though no information is gained about radiation damage, the furnace testing is extremely valuable for development and verification of fuel element materials and processes. The current work includes testing of subscale W-UO2 slugs to evaluate fuel loss and stability. The materials are then fabricated into samples with seven cooling channels to test a more representative section of a fuel element. Several iterations of testing are being performed to evaluate fuel mass loss impacts from density, microstructure, fuel particle size and shape, chemistry, claddings, particle coatings, and stabilizers. The fuel materials and forms being evaluated on this effort have all been demonstrated to control fuel migration and loss. The objective is to verify performance improvements of the various materials and process options prior to expensive full scale fabrication and testing. Post test analysis will include weight percent fuel loss, microscopy, dimensional tolerance, and fuel stability.

Hickman, Robert↗

NASA NTRS2018

Chlorine Isotopic Compositions of Apatite in Apollo 14 Rocks: Evidence for Widespread Vapor-Phase Metasomatism on the Lunar Nearside ~4 Billion Years Ago

Compared to most other planetary materials in the Solar System, some lunar rocks display high delta (sup 37) Cl signatures. Loss of Cl in a H<<Cl environment has been invoked to explain the heavy signatures observed in lunar samples, either during volcanic eruptions onto the lunar surface or during large scale degassing of the lunar magma ocean. To explore the conditions under which Cl isotope fractionation occurred in lunar basaltic melts, five Apollo 14 crystalline samples were selected (14053,19, 14072,13, 14073,9, 14310,171 along with basaltic clast 14321,1482) for in situ analysis of Cl isotopes using secondary ion mass spectrometry. Cl isotopes were measured within the mineral apatite, with delta (sup 37) Cl values ranging from +14.6 ± 1.6 per mille to +40.0 ± 2.9 per mille. These values expand the range previously reported for apatite in lunar rocks, and include some of the heaviest Cl isotope compositions measured in lunar samples to date. The data here do not display a trend between increasing rare earth elements contents and delta (sup 37) Cl values, reported in previous studies. Other processes that can explain the wide inter- and intra-sample variability of delta (sup 37) Cl values are explored. Magmatic degassing is suggested to have potentially played a role in fractionating Cl isotope in these samples. Degassing alone, however, could not create the wide variability in isotopic signatures. Our favored hypothesis, to explain small scale heterogeneity, is late-stage interaction with a volatile-rich gas phase, originating from devolatilization of lunar surface regolith rocks ~4 billion years ago. This period coincides with vapor-induced metasomastism recorded in other lunar samples collected at the Apollo 16 and 17 landing sites, pointing to the possibility of widespread volatile-induced metasomatism on the lunar nearside at that time, potentially attributed to the Imbrium formation event.

apatit↗

NASA NTRS2016

Mapping of Spacecraft Atmosphere Monitor Signal to Major Constituent Abundances

The Spacecraft Atmosphere Monitor (S.A.M.) follows the JPL’s commitment to introduce and develop next-generation instrumentation concepts for sensing the air quality on manned space flights via continuous sampling, measuring, and reporting in 2s intervals on all gaseous pollutants. The S.A.M. will have two modes of operation: the Major Constituent Analysis (MCA) mode and the Trace Gas Analysis (TGA) mode. The MCA mode will report on molecular analytes such as CH4, H2O, N2, O2, Ar, and CO2 while the TGA mode will acquire minute amounts of volatile organic compounds. Both modes assess the composition of the ambient air with twenty full mass spectra per second giving rise to a substantial amount of data to be processed by a set of small footprint software stacks hosted by an on-board computer. Mass spectra will be accumulated as the number of counts recorded in a given mass-to-charge channel and converted into the absolute abundances of detected species using an efficient algorithm. The decomposition algorithm contains four units: peak identification, mass calibration, background and dead time correction, and an abundance analysis unit. The abundance analysis module identifies target species through their characteristic fragmentation patterns in the presence of molecular isobars, such as CO and N2. For example, in order to identify N2 analyte, the code will simultaneously monitor abundance ratios of the 14, 28 and 29 Th signals and will adapt to any instability caused by a decrease in ambient pressure or changes in humidity. This requirement becomes critical for instruments designed to monitor the near real-time quality of cabin air and promptly provide accurate feedbacks.

Nikolic, D.↗

NASA NTRSDate not supplied

Synthetic Failure Mode Generation for Resilience Analysis and Failure Mechanism Discovery

Traditional risk-based design processes seek to mitigate operational hazards by manually identifying possible faults and corresponding mitigation strategies—a tedious process which critically relies on the designer’s limited knowledge. Resilience-based design, on the other hand, seeks to embody generic hazard-mitigating properties in the system to mitigate unknown hazards, often by modelling the system's response to potential hazardous events. This work adapts this approach to the traditional risk-based design process to synthetically generate hazardous modes, by representing them as a unique combination of internal component health-states which can then be injected and simulated in a model of the system failure dynamics. The design process may then reduce the risk of unknown internal hazards by iteratively mitigating the effects of these modes. The performance of this approach is evaluated in a model of an autonomous rover, where cluster analysis shows that elaborating the space of synthetic faults in the drive system using this approach uncovers a wider range of possible hazardous trajectories and failure consequences within each trajectory. However, this increase in hazard information comes at a high computational expense, highlighting the need for advanced, efficient methods to search and sample the hazard space.

Simulation↗

NASA NTRSDate not supplied

Synthetic Failure Mode Generation for Resilience Analysis and Failure Mechanism Discovery

Simulation↗

NASA NTRS1972

A comparison of the capabilities of three finite element programs

Three finite element programs are compared to assess their capabilities as an analysis tool in a structural design process. Because of the need for repetitive analyses as an integral part of a design loop, a candidate program must be capable of handling large problems, operate efficiently, and be readily adaptable for use in computer-aided design. The three programs considered in the study, ELAS,SNAP, and NASTRAN, range from a relatively small finite element program limited to static structural analysis (ELAS) to a large complex general analysis system (NASTRAN). Results are given for comparative speeds and computer resources required for each program in the analysis of sample fuselage problems representative of practical aircraft design.

Loendorf, D. D.↗

NASA NTRS1991

Computational simulation of hot composites structures

Three different computer codes developed in-house are described for application to hot composite structures. These codes include capabilities for: (1) laminate behavior (METCAN); (2) thermal/structural analysis of hot structures made from high temperature metal matrix composites (HITCAN); and (3) laminate tailoring (MMLT). Results for select sample cases are described to demonstrate the versatility as well as the application of these codes to specific situations. The sample case results show that METCAN can be used to simulate cyclic life in high temperature metal matrix composites; HITCAN can be used to evaluate the structural performance of curved panels as well as respective sensitivities of various nonlinearities, and MMLT can be used to tailor the fabrication process in order to reduce residual stresses in the matrix upon cool-down.

Chamis, Christos C.↗