Search NASA⌕ Search

SEARCH · Search NASA

Results for “surface stability”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,153 records · Page 64
All sourcesNASA NTRSDOE OSTI
NASA NTRS2014

Comparison of Near-Surface Air Temperatures and MODIS Ice-Surface Temperatures at Summit, Greenland (2008-2013)

We have investigated the stability of the MODerate resolution Imaging Spectroradiometer (MODIS) infrared-derived ice surface temperature (IST) data from Terra for use as a climate quality data record. The availability of climate quality air temperature data (TA) from a NOAA Global Monitoring Division observatory at Greenlands Summit station has enabled this high temporal resolution study of MODIS ISTs. During a 5 year period (July 2008 to August 2013), more than 2500 IST values were compared with 3-minute average TA values derived from the 1-minute data from NOAAs primary 2 m air temperature sensor. These data enabled an expected small offset between air and surface temperatures at this the ice sheet location to be investigated over multiple annual cycles.

Greenland↗
NASA NTRS1979

Numerical simulation of VTPR temperature retrievals in a severe storm environment

Environmental conditions prior to convective development on the Great Plains of the U.S. on one case study day were investigated using the high-resolution infrared radiation sounder (HIRS) on Nimbus 6. A dual-retrieval scheme was developed to retrieve both lower tropospheric moisture and temperature parameters from the HIRS radiances. Total precipitable water, surface dew point temperatures, and stability indices were analyzed at a resolution of up to 30 Km on this day. Correlations with interpolated NES rawinsonde values were high and intrinsic noise levels were low. The true quality of the mesoscale analyses, however, is only seen by examining the small scale features at a scale of approximately 100 Km. Perturbations on the dry line feature for this day were seen in the satellite data, although the dry line position was just as easily picked up by surface observations. Convective development 2 1/2 hours later did seem to correlate well with the local maxima of moisture and instability seen in the satellite analyses.

Vonderhaar, T. H.↗
DOE OSTI2020

Continental-scale patterns of extracellular enzyme activity in the subsoil: an overlooked reservoir of microbial activity

Abstract Chemical stabilization of microbial-derived products such as extracellular enzymes (EE) onto mineral surfaces has gained attention as a possibly important mechanism leading to the persistence of soil organic carbon (SOC). While the controls on EE activities and their stabilization in the surface soil are reasonably well-understood, how these activities change with soil depth and possibly diverge from those at the soil surface due to distinct physical, chemical, and biotic conditions remains unclear. We assessed EE activity to a depth of 1 m (10 cm increments) in 19 soil profiles across the Critical Zone Observatory Network, which represents a wide range of climates, soil orders, and vegetation types. For all EEs, activities per mass of soil correlated positively with microbial biomass (MB) and SOC, and all three of these variables decreased logarithmically with depth ( p < 0.05). Across all sites, over half of the potential EE activities per mass soil consistently occurred below 20 cm for all measured EEs. Activities per unit MB or SOC were substantially higher at depth (soils below 20 cm accounted for 80% of whole-profile EE activity), suggesting an accumulation of stabilized (i.e. mineral sorbed) EEs in subsoil horizons. The pronounced enzyme stabilization in subsurface horizons was corroborated by mixed-effects models that showed a significant, positive relationship between clay concentration and MB-normalized EE activities in the subsoil. Furthermore, the negative relationships between soil C, N, and P and C-, N-, and P-acquiring EEs found in the surface soil decoupled below 20 cm, which could have also been caused by EE stabilization. This finding suggests that EEs may not reflect soil nutrient availabilities deeper in the soil profile. Taken together, our results suggest that deeper soil horizons hold a significant reservoir of EEs, and that the controls of subsoil EEs differ from their surface soil counterparts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Calorimetric metal vapor adsorption energies for characterizing industrial catalyst support materials

Many important catalysts and electro-catalysts for energy and environmental technologies involve late transition metal atoms and nanoparticles dispersed across the surface of high-surface-area support materials, for example, oxide nanoparticles. The surface reactivity and long-term stability against deactivation of these materials depends strongly on the strength of bonding of the metal atom and nanoparticles to the support surface. Here, we introduce a novel calorimetry method that implements a LiTaO 3 crystal for heat detection and extends metal adsorption calorimetry to surfaces of nanomaterials that are deposited from liquid solutions, as is typical when preparing industrial catalyst supports. This allows one to measure the strength of metal atom bonding and the adhesion energy of metal nanoparticles to clean surfaces of technologically relevant catalyst supports. We demonstrate that here by measuring the heat of Ag vapor adsorption onto the clean surfaces of high-surface-area TiO 2 anatase powdered support materials (i.e., 5-nm-diameter nanoparticles). These heats of adsorption show a pulse-to-pulse standard deviation of only 9.3 kJ/mol (3.3%) for pulses containing only 1% of a monolayer of Ag vapor, with potential for a 5-fold reduction in noise if used with another metal evaporator. The calorimeter was also proven to work well measuring heats of Ag adsorption on calcium niobate(001) nanosheets deposited as thin films from liquid solution. Here, this calorimeter opens up the possibility of using metal adsorption calorimetry to screen catalyst support materials for the strengths with which they bind metal atoms and metal nanoparticles, offering new opportunities to discover better support materials or for basic scientific study of structure / function relationships with respect to metal / support bond energies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Extreme fast charging characteristics of zirconia modified LiNi 0.5 Mn 1.5 O 4 cathode for lithium ion batteries

LiNi 0.5 Mn 1.5 O 4 is a promising high-voltage cathode for lithium-ion battery fast charging applications. Aware of its electrochemical stability issues, the material's surface is modified with small amounts of zirconia (ZrO 2 ) ranging from 0.5 to 2 wt% using a scalable ball milling process. The advantage of the coating has been demonstrated in electrochemical measurements performed at room temperature and 55 °C, and in cells discharged under high-rate conditions up to 80C. Of significance, the material coated with 1.0 wt% ZrO 2 has been cycled at the 40C rate for over a thousand cycles and retains 86% of its initial capacity. The material with 2.0 wt% ZrO 2 modification preserves 76% of its initial capacity when cycled at the 40C rate and 55 °C. The coated materials have shown excellent cycling stability when subjected to 6C (10-min) fast charging and C/3 discharging for 300 cycles. Compared to the uncoated material, the interfacial resistance of the zirconia modified LiNi 0.5 Mn 1.5 O 4 has been found to be much lower and does not significantly increase with increasing the coating amount. However, the electrochemical performances are still partly limited by both interfacial resistance at the beginning of charge and electrolyte diffusivity, particularly under higher rate cycling conditions. Altogether, the strategy of ZrO 2 surface modification applied to LiNi 0.5 Mn 1.5 O 4 unveils the potential that the material could play in extreme fast charged electric vehicles.

25 ENERGY STORAGE↗
DOE OSTI2022

Similarity of the turbulent kinetic energy dissipation rate distribution in the upper mixed layer of the tropical Indian Ocean

Turbulence within the upper ocean mixed layer plays a key role in various physical, biological, and chemical processes. Between September and November 2011, a dataset of 570 vertical profiles of the turbulent kinetic energy (TKE) dissipation rate, as well as conventional hydrological and meteorological data, were collected in the upper layer of the tropical Indian Ocean. These data were used to statistically analyze the vertical distribution of the TKE dissipation rate in the mixed layer. The arithmetic-mean method made the statistical TKE dissipation rate profile more scattered than the median and geometric-mean methods. The statistical TKE dissipation rate were respectively scaled by the surface buoyancy flux and the TKE dissipation rate at the mixed-layer base. It was found that the TKE dissipation rate scaled by that at the mixed-layer base exhibited better similarity characteristics than that scaled by the surface buoyancy flux, whether the stability parameter D/|L MO | was greater or less than 10, indicating that the TKE dissipation rate at the mixed-layer base is a better characteristic scaling parameter for reflecting the intrinsic structure of the TKE dissipation rate in the mixed layer, where D and L MO are respectively the mixed-layer thickness and the Monin-Obukhov length scale. The parameterization of the TKE dissipation rate at the mixed-layer base on the shear-driven dissipation rate and the surface buoyancy flux was further explored. It was found that the TKE dissipation rate at the mixed-layer base could be well fitted by a linear combination of three terms: the wind-shear-driven dissipation rate, the surface buoyancy flux, and a simple nonlinear coupling term of these two.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Synergistic effect of polyaniline on stabilizing Pt nanoparticles in PEMFCs†

The stability of Pt nanoparticles on a carbon support is crucial for the lifespan of polymer electrolyte membrane fuel cells as well as other electrocatalysis systems such as electrolyzers. Here we took the approach of utilizing the covalently grafted polyaniline on carbon to stabilize Pt nanoparticles by simultaneously alleviating the particle migration and mitigating the Ostwald ripening, which are two major mechanisms for loss of the catalyst stability. A comprehensive investigation of the stability and performance of Pt catalyst nanoparticles on these supports reveals that the polyaniline can shift the Pt L edge binding energy and the Pt 4f peak energy, leading to the increased redox potential of the Pt nanoparticles and making them more resistant to oxidation. Interestingly, the highest polyaniline density (50 wt%) does not show the best catalyst stability, rather, the second (33 wt%) demonstrates the best catalyst stability among these catalysts. Combining the XPS, XAS and fuel cell stability studies, we concluded that the locations of the Pt nanoparticles over the polyaniline layer on the carbon surface depend on the surface density of the polyaniline over the carbon surface. The Pt nanoparticles in the 50 wt% polyaniline catalyst are wrapped by the polyaniline polymer but do not sit directly on the carbon surface, while Pt nanoparticles in the 33 wt% polyaniline catalyst sit on the carbon surface and are densely surrounded by the polyaniline polymer. The results show that the mass activity loss is 12.5% while the ECSA (electrochemically active surface area) loss is 37.1% after 30k cycles of accelerating stress test for the 33 wt% polyaniline catalyst, far exceeding the DOE 2020 target for MEA (i.e., mass activity loss < 50%, and ECSA loss < 40%). Overall, the polyaniline has a synergistic effect on mitigating the surface migration and slowing down the Ostwald ripening to stabilize the Pt nanoparticles in fuel cells. The novel strategy to stabilize Pt nanoparticles using polyaniline opens a new pathway in the development of highly stable catalysts: relying on the functionalization group on the carbon support, instead of just focusing on the catalyst itself.

Li, Chenzhao↗
NASA NTRS1981

Microwave scatterometer measurements of oceanic wind vector

Results from Seasat-A scatterometer (SASS) remote sensing of oceanic wind vectors are reviewed, together with the theory of radar backscattering. The SASS was designed to measure the surface wind stress and neutral stability wind vector at 19.5 m altitude. Requirements included windspeeds from 4-24 m/sec to within 2 m/sec or 10%, a 1000 km swath, directions from 0-360 deg to within 20 deg, a 50 km resolution cell, and cross-track and along-track spacing between resolution cells of 100 km. The method was based on Bragg scattering of microwaves from cm-length capillary ocean waves. The strength of the backscatter is proportional to the capillary wave amplitude, which is in equilibrium with the ocean surface wind speed. The measurement grouping, least-squares estimator, and dB deviation model function table for the SASS geophysical algorithm are discussed. Comparisons of SASS, GOASEX, and ground truth wind data are made, and a 0.92 correlation between SASS and ground truth data is determined from regression analysis.

Jones, W. L.↗
DOE OSTI2019

Ternary CoPtAu Nanoparticles as a General Catalyst for Highly Efficient Electro‐oxidation of Liquid Fuels

Abstract Efficient electro‐oxidation of formic acid, methanol, and ethanol is challenging owing to the multiple chemical reaction steps required to accomplish full oxidation to CO 2 . Herein, a ternary CoPtAu nanoparticle catalyst system is reported in which Co and Pt form an intermetallic L1 0 ‐structure and Au segregates on the surface to alloy with Pt. The L1 0 ‐structure stabilizes Co and significantly enhances the catalysis of the PtAu surface towards electro‐oxidation of ethanol, methanol, and formic acid, with mass activities of 1.55 A/mg Pt , 1.49 A/mg Pt , and 11.97 A/mg Pt , respectively in 0.1 m HClO 4 . The L1 0 ‐CoPtAu catalyst is also stable, with negligible degradation in mass activities and no obvious Co/Pt/Au composition changes after 10 000 potential cycles. The in situ surface‐enhanced infrared absorption spectroscopy study indicates that the ternary catalyst activates the C−C bond more efficiently for ethanol oxidation.

Li, Junrui↗
NASA NTRS1986

Composition and stability of the condensate observed at the Viking Lander 2 site on Mars

Surface energy balance and near-surface temperature data from the Viking Lander 2 site taken during the first winter that condensated were observed and analyzed to determine the relative stability of CO2 and H2O frosts. The CO2 frost stability is calculated with an equilibrium surface energy balance model, i.e., the total energy incident on a frost surface is compared with the blackbody energy emitted by the surface. The energy sources considered were IR emission from the atmosphere, sunlight, and the sensible heat flux from the atmosphere. H2O stability was examined as a function of buoyant diffusion and turbulent mixing processes which could remove saturated near-surface gases. The CO2 frost is found to be sufficiently unstable at the time the condensate was observed on the ground, so all CO2 ice deposited at night would boil away in a few hours of sunlight. CO2 ice would not form during a dust storm. Water frost would be stable during the condensate observations, since sublimation would occur at a rate below 1 micron/day. A stable winter thickness of 10 microns is projected for the water ice.

Hart, H. M.↗
DOE OSTI2019

A New Type of Carbon Nanostructure on a Vicinal SiС(111)-8° Surface

The electronic properties of the Ba/SiC/Si(111)-8° nanointerface have been studied for the first time by photoelectron spectroscopy using synchrotron radiation. The experiments are conducted in situ in superhigh vacuum on submonolayer Ba coatings of SiC/Si(111)-8° samples grown by the method of substitution of atoms. It is found that the adsorption of Ba causes strong changes in the spectrum of the C 1s core level. It is shown that the effect is due to the formation of a new, previously unknown carbon nanostructure. It is found that the nanostructure is formed exclusively on the SiC vicinal surfaces in the presence of stabilizing adsorbed Ba metal atoms and consists of carbon rings, in which the chemical bonds are close in nature to the bonds characteristic of aromatic compounds.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1990

Growth morphology with anisotropic surface kinetics

The morphological evolution of crystals growing from an incongruent vapor phase is studied using a Monte Carlo model, and the full range of growth morphologies is recovered. The diffusion in the bulk nutrient and the anisotropy in the interface kinetics are morphologically destabilizing and stabilizing, respectively. For a given set of simulation parameters and lattice symmetries there is a critical size, which scales linearly with the mean free path in the vapor, beyond which a crystal cannot retain its stable, macroscopically faceted growth shape. Surface diffusion stabilizes faceted growth on the shorter scale of the mean surface diffusion length. In simulations with a uniform drift superimposed on the random walk nutrient transport, crystal faces oriented toward the drift show enhanced morphological stability compared to the purely diffusive situation. Rotational drifts with periodic reversal of direction are morphologically stabilizing for all crystal facets.

Xiao, Rong-Fu↗
NASA NTRS1992

Stability correction functions for the mean wind speed and temperature in the unstable surface layer

In accordance with a theoretical analysis by Kader and Yaglom, interpolation expressions are proposed for the Monin-Obukhov functions for the wind speed and temperature profiles under unstable conditions in the surface layer of the atmospheric boundary layer. The values of the parameters are adjusted to agree with earlier work under weak instability, as reviewed by Hogstrom. The resulting formulations are valid for considerably larger values of their argument than those that were hitherto available. Their advantage is that they yield concise and closed-form stability correction functions which can be readily applied in profile analysis and model calculations.

Brutsaert, Wilfried↗
NASA NTRS1981

Venus gravity - A high-resolution map

The Doppler data from the radio tracking of the Pioneer Venus Orbiter (PVO) have been used in a two-stage analysis to develop a high-resolution map of the gravitational potential of Venus, represented by a central mass and a surface mass density. The two-stage procedure invokes a Kalman filter-smoother to determine the orbit of the spacecraft, and a stabilized linear inverter to estimate the surface mass density. The resultant gravity map is highly correlated with the topographic map derived from the PVO radar altimeter data. However, the magnitudes of the gravity variations are smaller than would be expected if the topography were uncompensated, indicating that at least partial compensation has taken place.

Reasenberg, R. D.↗
NASA NTRS1945

Experimental verification of a simplified vee-tail theory and analysis of available data on complete models with vee tails

An analysis has been made of available data on vee tail surfaces. Previously published theoretical studies of vee tails have been extended to include the control effectiveness and control forces in addition to the stability. Tests of two isolated tail surfaces with various amounts of dihedral provided a check of the theory. Methods for designing vee tails were also developed and are given in the present paper.

Purser, Paul E↗
DOE OSTI2024

Atomic scale etching of diamond: insights from molecular dynamics simulations

Diamond is a promising material for multiple applications in quantum information processing and sensing as well as applications in microelectronics. However, diamond devices can be limited by surface defects that compromise charge stability and spin coherence, among others. Improved strategies in plasma etching of diamond could play an important role in minimizing or eliminating these defects. In this work, we explore plasma-assisted atomic scale etching of diamond using argon ions (Ar + ), hydrogen ions (H + ) and hydrogen atoms (H). We employ classical molecular dynamics (MD) simulations and test several interatomic potentials based on the Reactive Empirical Bond Order (REBO) form with comparisons to a variety of published experimental results. We performed MD simulations of low-energy hydrogen ($\leqslant$50 eV) and argon ( $\leqslant$200 eV) ion bombardment of diamond surfaces. Ar + bombardment can be used to locally smooth initially rough diamond surfaces via the formation of an amorphous C layer, the thickness of which increases with argon ion energy. Subsequent exposure with hydrogen ions (or fast neutrals) will selectively etch this amorphous C layer, leaving the underlying diamond layer mostly intact if the H energy is maintained below about 10 eV. The simulations suggest that combining Ar + smoothing with selective, near threshold energy H removal of amorphous C can be an effective strategy for diamond surface engineering, leading to more reliable and sensitive diamond color center devices.

74 ATOMIC AND MOLECULAR PHYSICS↗