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At least 1,153 records · Page 64

New Transformer Testing Approach Reduces Reactor Down Time

The ATR-774 transformer yard has been in operation for 57 years. It's old, outdated, and reaching end of life. Plant health has decided to construct a new transformer yard, which will require testing. I've explored the standards library and compiled a list of tests that need to be performed on the transformer yard. This effort led to a significant speed-up in the testing process.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Seismic Resilience of Large Power Transformer Bushings & Non-SF6 Industrial Base Scan Review

Large (high voltage) power transformers (LPT), and more specifically, their bushings, are known to be susceptible to seismic failure. With bushing failure, a transformer will have to be replaced, which has a considerable lead time, adding to the power outage duration. Cost-efficient, proven solutions are not currently available to mitigate this risk, which can persist for the more than 30-year life of a particular transformer. This work will focus on developing and demonstrating a hardware solution to address seismic vulnerabilities and reduce outage risks from LPT failure. Sulfur Hexafluoride (SF6) is a specialty gas with excellent electrical insulation properties which has been used extensively in the power industry. This gas is unfortunately also one of the most potent greenhouse gases known to humanity. A 2014 report by the Intergovernmental Panel on Climate Change found that SF6 has a global warming potential (GWP) 23,000 times higher than Carbon Dioxide, and has the highest GWP of all gases assessed (Myhre 2013). SF6 is almost exclusively man-made and is produced for use as an insulator in high voltage electrical equipment. This makes the production and use of SF6 one of the leading sources of anthropogenic climate change. To fully eliminate the environmental impacts of SF6, alternative technology is needed. The ideal replacement would be a technology that can fulfil the same role as SF6, at the same cost or cheaper, but without adverse environmental effects. Currently, no technology fits this description, however several promising technologies have begun to enter the market. An industry scan was performed to assess the state of industry adoption and manufacturing capability for SF6-free alternative technologies for use at the high-voltage level, and the primary barriers to broader adoption.

10 SYNTHETIC FUELS↗

Insulation Coordination Design for Grid-Connected Solid-State Transformers

The deployment of solid-state transformers (SSTs) in medium-voltage (MV) distribution systems is facing various challenges, especially the challenge of insulation coordination design against grid-originated lightning impulses. In this article, two challenges in existing insulation coordination designs for grid-connected SSTs are identified. One challenge is the mismatch between metal-oxide varistor (MOV) protective levels and SST insulation strength, the other challenge is the incompatibility of standard impulse test on SST protective structures. To address the MOV selection challenge, a novel lightning protection scheme is designed to protect a single-stage SST where the semiconductor modules are directly exposed to external lightning impulses. Here, the in-lab lightning impulse tests are performed to verify the overvoltage attenuation performance of the prototyped lightning protection scheme. To address the impulse test challenge, the surge withstand capability of the protected SST is comprehensively evaluated with a complete set of insulation coordination design procedures beyond the basic insulation level (BIL) test. After these two challenges are addressed, a discussion is presented on substituting conventional transformers with the protected SSTs into insulation-coordinated distribution systems to facilitate the field deployment of SSTs.

solid-state transformer (SST)↗

Stacked Low-Inertia Converter or Solid-State Transformer: Modeling and Model Predictive Priority-Shifting Control for Voltage Balance

This paper presents control challenges of stacked low-inertia converter (SLIC) or cascaded reduced dc-link solid-state transformer (SST) and proposes a novel model predictive priority-shifting (MPPS) control with implicit modulator and a discrete-time large-signal model for voltage balancing and dc-link regulation. Low-inertia converters, featuring small electrolytic capacitor-less dc links, dramatically reduce cost, size, and weight compared to conventional solutions. However, without a large dc-link buffer, the input and output are tightly coupled, leading to significant control challenges. The control becomes even more challenging with these converters stacked input-series output-parallel (ISOP) for medium-voltage (MV) grid, which causes coupling between the modules besides the coupling within each module. This paper analyzes the multi-objective, multi-degree of freedom control problem, using the modular soft-switching solid-state transformer (M-S4T) as an example of the SLIC. First, distribution of control efforts under controller saturation is critical because multiple control objectives can be conflicting, especially when the module voltages are unbalanced and are being restored. The MPPS can shift the priorities to address this issue. Second, due to the low inertia and high dc-link ripple, classic space vector pulse-width modulation (SVPWM), average model with small-ripple assumption, and control design based on small-signal model cannot accurately modulate, model, and control the nonlinear reduced dc link. Therefore, a discrete-time large-signal model of the M-S4T is established to derive the predictive control in the MPPS. The MPPS and the PI control are compared in MV simulations to show the issue of applying the PI to the SLIC and the effectiveness of the MPPS for voltage balancing and dc-link regulation in a deadbeat manner. Finally, the proposed control is tested on a 5 kV ISOP SiC SST prototype to verify priority shifting to address controller saturation issue and fast and robust voltage balancing.

14 SOLAR ENERGY↗

DC-Link Current Minimization Control for Current Source Converter-Based Solid-State Transformer

This article proposes a fast predictive control method and a small DC-link inductor to minimize the DC-link current in current-source converter (CSC)-based solid-state transformer. The DC-link current minimization can significantly reduce power loss and improve efficiency. The challenge of this problem is on improving both steady-state and dynamic performance. PI control methods and large DC-link inductors are conventionally used in the CSC but have limited dynamic performance. A model predictive control (MPC) method is proposed to achieve switching-cycle-level settling time, and the DC-link inductor is sized for 40% ripple to enable fast current change. Importantly, this article also proposes to minimize the DC-link current by varying the current even within a line cycle under single-phase load to improve the steady-state performance, in contrast with the reduction to a constant value in the literature. The proposed MPC features a constant switching frequency without weighting factors. The MPC does not have a high computational burden and is implemented in a regular digital controller for a prototype of soft-switching solid-state transformer (S4T) with reduced conduction loss. The effectiveness of the proposed method has been experimentally verified on the SiC S4T prototype during steady-state and dynamics under different multiport power flow conditions up to 2 kV peak. Here, the DC-link current in the experiments is close to the minimum current with a short zero-vector duration, which further verifies the performance of the proposed method.

14 SOLAR ENERGY↗

Grid Ready, Flexible Large Power Transformer

GE Research and its partner Prolec GE have proposed a novel and breakthrough concept to improve the flexibility and interchangeability of large power transformers (LPTs). LPTs refer in this report to transformers with a power rating equal or greater than 100 MVA. The concept consists of a 3-phase autotransformer bank having one specified high voltage side (HV) voltage and three configurable low voltage side (LV) voltage taps. Moreover, the leakage impedance is adjustable offline using taps which allows to accommodate short-circuit requirements for a wide range of LPTs applications. The research performed aimed to develop and validate a cost-effective design of a flexible LPT and to demonstrate its competitiveness with the LPT fleet currently in operation in the U.S. The concept is intended for the long-term replacement of existing LPTs. In this project, the U.S based population of LPTs was analyzed to determine their commonality in power, voltage classes, and impedance range. Up to 9,700 units, currently deployed in the NERC’s Eastern and Western interconnection regions, were evaluated. This analysis yielded the specifications of two flexible LPTs to be designed to demonstrate the manufacturability and competitiveness of the concept: a 345 kV, 230 MVA and a 230 kV, 100 MVA LPTs. The two LPTs are both configurable to 161 kV, 138 kV, and 115 kV on the LV side and allow leakage impedance variation between 4% and 14%. The design output showed that the flexible LPT is manufacturable and competitive with conventional LPT. The proposed design has a power efficiency of 99.5% and a total active part weight increase ranging only between 15% and 28% relative to conventional LPTs it can be substituted with. Indeed, for the flexible LPT, the higher the LV side voltage is, the higher is its power rating. Hence, flexible LPTs are more competitive when compared with the largest conventional LPT they can replace. Power systems analyses were carried out to evaluate the performance of the flexible LPT when replacing an existing conventional LPT. These analyses showed that short-circuit and inrush currents will remain respectively within 15% and 9.4% of their original levels suggesting that no substations equipment is likely to be replaced due the installation of the flexible LPT. In addition, the analyses showed that the transient overvoltage anticipated at the impedance configuration switch will be manageable and will not pose any particular risk during lightning or switching events. This research proved that the deployment of flexible LPTs in the U.S power grid can greatly improve the grid reliability and its resiliency especially in the event of the loss of multiple LPTs. Moreover, the concept can significantly help reduce LPTs’ spare inventory by providing a high spare coverage level. The performed analysis showed that the designed 345 kV flexible LPT can serve as a spare for up to 34 units currently in operation in the U.S while the designed 230 kV flexible LPT can replace up to 101 units. Flexible LPTs offer new opportunities to U.S utilities to improve interchangeability of LPTs in the transmission system and to better strategize the upcoming renewal of about 70% of the population of LPTs anticipated to retire within the next two decades.

24 POWER TRANSMISSION AND DISTRIBUTION↗

NASA Enterprise Digital Transformation Initiative Strategic Framework & Implementation Approach

Since 1958, NASA has delivered its enduring bold purpose, characterized in the 2022 NASA Strategic Plan as a mission to discover, explore, innovate, and advance solutions to the problems of flight, within and outside the Earth’s atmosphere, for the benefit of humankind. The NASA Strategic Plan also recognizes that this mission will be delivered differently as it looks to a future marked by radical global change, which is in part being driven by digital advances. For this reason, in late 2020 NASA established an Enterprise Digital Transformation (DT) agency-level strategic initiative to accelerate and coordinate leveraging digital advances to transform the way the Agency works, the experience of its workforce and the agility of its workplace. This paper documents NASA’s DT strategic framework and associated implementation approach, with the DT strategic initiative serving to ignite, connect, integrate, and facilitate DT progress across a federated organizational operating model.

digital transformation↗

Phase Transformation Contributions to Heat Capacity and Impact on Thermal Diffusivity, Thermal Conductivity, and Thermoelectric Performance

Abstract The accurate characterization of thermal conductivity κ, particularly at high temperature, is of paramount importance to many materials, thermoelectrics in particular. The ease and access of thermal diffusivity D measurements allows for the calculation of κ when the volumetric heat capacity, ρc p , of the material is known. However, in the relation κ = ρc p D , there is some confusion as to what value of c p should be used in materials undergoing phase transformations. Herein, it is demonstrated that the Dulong–Petit estimate of c p at high temperature is not appropriate for materials having phase transformations with kinetic timescales relevant to thermal transport. In these materials, there is an additional capacity to store heat in the material through the enthalpy of transformation Δ H . This can be described using a generalized model for the total heat capacity for a material where φ is an order parameter that describes how much latent heat responds “instantly” to temperature changes. Here, C pφ is the intrinsic heat capacity (e.g., approximately the Dulong–Petit heat capacity at high temperature). It is shown experimentally in Zn 4 Sb 3 that the decrease in D through the phase transition at 250 K is fully accounted for by the increase in c p , while κ changes smoothly through the phase transition. Consequently, reports of κ dropping near phase transitions in widely studied materials such as PbTe and SnSe have likely overlooked the effects of excess heat capacity and overestimated the thermoelectric efficiency, zT .

Agne, Matthias T.↗

Understanding Strain‐Induced Phase Transformations in BiFeO 3 Thin Films

Experiments demonstrate that under large epitaxial strain a coexisting striped phase emerges in BiFeO 3 thin films, which comprises a tetragonal‐like ( T ′) and an intermediate S ′ polymorph. It exhibits a relatively large piezoelectric response when switching between the coexisting phase and a uniform T ′ phase. This strain‐induced phase transformation is investigated through a synergistic combination of first‐principles theory and experiments. The results show that the S ′ phase is energetically very close to the T ′ phase, but is structurally similar to the bulk rhombohedral ( R ) phase. By fully characterizing the intermediate S ′ polymorph, it is demonstrated that the flat energy landscape resulting in the absence of an energy barrier between the T ′ and S ′ phases fosters the above‐mentioned reversible phase transformation. This ability to readily transform between the S ′ and T ′ polymorphs, which have very different octahedral rotation patterns and c / a ratios, is crucial to the enhanced piezoelectricity in strained BiFeO 3 films. Additionally, a blueshift in the band gap when moving from R to S ′ to T ′ is observed. These results emphasize the importance of strain engineering for tuning electromechanical responses or, creating unique energy harvesting photonic structures, in oxide thin film architectures.

36 MATERIALS SCIENCE↗

Quantification of High‐Temperature Transition Al 2 O 3 and Their Phase Transformations**

Abstract High‐temperature treatment of γ‐Al 2 O 3 can lead to a series of polymorphic transformations, including the formation of δ‐Al 2 O 3 and θ‐Al 2 O 3 . Quantification of the microstructure in the range where δ‐ and θ‐Al 2 O 3 are formed represents a formidable challenge, as both phases accommodate a high degree of structural disorder. In this work, we explore the use of an XRD recursive‐stacking formalism for the quantification of high‐temperature transition aluminas. We formulate the recursive‐stacking methodology for modelling of disorder in δ‐Al 2 O 3 and twinning in θ‐Al 2 O 3 and show that explicitly accounting for the disorder is necessary to reliably model the XRD patterns of high‐temperature transition alumina. We also use the recursive stacking approach to study phase transformation during high‐temperature (1050 °C) treatment. We show that the two different intergrowth modes of δ‐Al 2 O 3 have different transformation characteristics and that a significant portion of δ‐Al 2 O 3 is stabilized with θ‐Al 2 O 3 even after prolonged high‐temperature exposures.

Kovarik, Libor↗

Morphogenic Regulator-Mediated Transformation of Maize Inbred B73

Maize B73 is a reference genome and has long been a major resource for genetics and molecular biology research. We have developed an efficient B73 transformation protocol by enabling somatic embryogenesis through differential co-expression of maize morphogenic regulators BBM and WUS2. We describe a successful protocol that utilizes Agrobacterium tumefaciens strain AGL1 harboring binary vector PHP78891 that comprises a BBM and WUS2 expression cassette as well as a green fluorescent protein (GFP) reporter cassette. The PHP78891 vector also contains, within the T-DNA region, a CRE/lox recombination system flanking the CRE/BBM/WUS2 co-expression cassette driven by the desiccation inducible RAB17 promoter that allows removal of the BBM/WUS2 cassette. Introduction and co-expression of BBM and WUS2 induced direct somatic embryogenesis (SE) in non-regenerable maize B73 from immature embryo explants. Removal of the CRE/BBM/WUS2 cassette is essential to allow regeneration to fertile plants. The GFP expression cassette outside the lox excision sites is retained in the transgenic plant genome, allowing subsequent phenotypic analysis of calli and regenerated transgenic events. This transformation system enables a selectable marker-free transformation process by taking advantage of BBM/WUS2-induced SE as a developmental selection system.

59 BASIC BIOLOGICAL SCIENCES↗

Effects of Surface Orientation and Termination Plane on Glass‐to‐Crystal Transformation of Lithium Disilicate by Molecular Dynamics Simulations

Glass‐to‐crystal transformation of lithium disilicate is studied using molecular dynamics simulations using an effective partial charge potential. The structural evolution of the interface between glassy and crystalline lithium disilicate is analyzed to simulate crystallization of glass on pre‐existing crystal seeds. Besides previously used atomic number density, the distribution of Q n species (Si tetrahedra with n bridging oxygen) is shown to be an effective parameter for following this transformation quantitatively. The early stages of crystal growth are significantly affected by the orientation and termination of the surface of adjacent crystal, as indicated by calculated atomic density, partial ordering, atomic segregation, and an increase in Q 3 concentration. In particular, under‐coordinated Si within the outer crystal layer is found to be most effective in transforming the amorphous structure toward crystallinity. The increase in Q 3 in the glass close to interface region most clearly shows the initial stage of lithium disilicate crystal growth.

Sun, Wei↗

Theoretical and experimental evidence of conformational transformation in stereoisomers of nucleoside analogues

A theoretical and experimental characterization of N(1)-(2',3'-dihydroxypropil)thymine (DHPT), a potential prebiotic nucleoside analogue of 5-methyluridine, is performed. A proposed methodology based on a solvation method was used to study conformational transformations of the different low-energy conformers of DHPT according to time-dependent IR spectroscopy. NMR and CD spectroscopy provides additional evidence of these transformations. The conformational transformations appear to be due to solvent and DHPT interactions. This highlights the importance of experimental conditions on conformer ratio equilibrium, in particular, the interpretation of experimental conditions used for determining the stereoisomers' absolute configuration.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Recordings and Analysis of Atomic Ledge and Dislocation Movements in InGaAs to Nickelide Nanowire Phase Transformation

The formation of low resistance and self‐aligned contacts with thermally stable alloyed phases is a prerequisite for realizing reliable functionality in ultrascaled semiconductor transistors. Detailed structural analysis of the phase transformation accompanying contact alloying can facilitate contact engineering as transistor channels approach a few atoms across. Original in situ heating transmission electron microscopy studies are carried out to record and analyze the atomic scale dynamics of contact alloy formation between Ni and In 0.53 Ga 0.47 As nanowire channels. It is observed that the nickelide reacts on the In 0.53 Ga 0.47 As (111) || Ni 2 In 0.53 Ga 0.47 As (0001) interface with atomic ledge propagation along the Ni 2 In 0.53 Ga 0.47 As direction. Ledges nucleate as a train of strained single‐bilayers and propagate in‐plane as double‐bilayers that are associated with a misfit dislocation of . The atomic structure is reconstructed to explain this phase transformation that involves collective gliding of three Shockley partials in In 0.53 Ga 0.47 As lattice to cancel out shear stress and the formation of misfit dislocations to compensate the large lattice mismatch in the newly formed nickelide phase and the In 0.53 Ga 0.47 As layers. This work demonstrates the applicability of interfacial disconnection (ledge + dislocation) theory in a nanowire channel during thermally induced phase transformation that is typical in metal/III–V semiconductor reactions.

Chen, Renjie↗

Hydroxyl radical‐driven transformations of bisphenol A and 2,4‐dinitroanisole: Experimental and computational analysis

Abstract This study used experimental and computational analysis to investigate the advanced oxidation of bisphenol A (BPA) and 2,4‐dinitroanisole (DNAN). The pseudo first‐order reaction rate constants depended on the molar peroxide ratio and were between 0.13 and 0.28 min −1 for BPA and between 0.018 and 0.032 min −1 for DNAN. The kinetic differences appear to be due in part to the energy requirements for oxidation, which depended on the reaction mechanism but were typically lower for BPA than they were for DNAN. Density functional theory (DFT) was used to develop transformation pathways that included experimentally‐detected byproducts. The most energetically favored pathway for BPA oxidation begins with the formation of hydroxylated derivatives, while for DNAN, the most energetically favorable degradation pathway begins with the substitution of the methoxy group. Overall, these findings demonstrate the power of combining experimental and computational tools to reveal transformation mechanisms during water treatment. Practitioner Points Advanced oxidation transformations for two emerging water pollutants, bisphenol A and dinitroanisole, was investigated. The observed reaction kinetics depended on molar peroxide ratio in a manner that is in keeping with previous findings. Density functional theory‐based analysis revealed reaction energy requirements and degradation pathways.

Engineering↗

Application of Raman Spectroscopy for the Detection of Acetone Dissolved in Transformer Oil

The CLRS detection characteristics of acetone dissolved in transformer oil were analyzed. Raman spectral peak at 780 cm{sup –1} was used as the characteristic spectral peak for qualitative and quantitative analyses. The effect of the detection depth and the temperature was investigated in order to obtain good Raman signals. The optimal detection depth and temperature were set as 3 mm and room temperature. A quantitative model relation between concentration and the Raman peak intensity ratio I{sub 780}/I{sub 893} was constructed via the least-squares method. The results demonstrated that CLRS can quantitatively detect the concentration of acetone in transformer oil and CLRS has potential as a useful alternative for accelerating the in-situ analysis of the concentration of acetone in transformer oil.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Image Reconstruction from Under sampled Fourier Data Using the Polynomial Annihilation Transform

Fourier samples are collected in a variety of applications including magnetic resonance imaging and synthetic aperture radar. The data are typically under-sampled and noisy. In recent years, l 1 regularization has received considerable attention in designing image reconstruction algorithms from under-sampled and noisy Fourier data. The underlying image is assumed to have some sparsity features, that is, some measurable features of the image have sparse representation. The reconstruction algorithm is typically designed to solve a convex optimization problem, which consists of a fidelity term penalized by one or more l 1 regularization terms. The Split Bregman Algorithm provides a fast explicit solution for the case when TV is used for the l1l1 regularization terms. Due to its numerical efficiency, it has been widely adopted for a variety of applications. A well known drawback in using TV as an l 1 regularization term is that the reconstructed image will tend to default to a piecewise constant image. This issue has been addressed in several ways. Recently, the polynomial annihilation edge detection method was used to generate a higher order sparsifying transform, and was coined the “polynomial annihilation (PA) transform.” This paper adapts the Split Bregman Algorithm for the case when the PA transform is used as the l 1 regularization term. In so doing, we achieve a more accurate image reconstruction method from under-sampled and noisy Fourier data. Our new method compares favorably to the TV Split Bregman Algorithm, as well as to the popular TGV combined with shearlet approach.

97 MATHEMATICS AND COMPUTING↗

Production of Airy-related beams by an Airy transform optical system

Based on the process of Huygens–Fresnel diffraction integral, we investigate theoretically the characteristics of fields generated by diffracted controllable dark-hollow beams (CDHBs) through an Airy transform optical system. It is shown that the CDHB is transformed into Airy-related beams and the dark central spot is converted into peak intensity. The effects of the incident CDHB parameters such as the mode number N, central spot width w{sub 0} and ε as well as the phase pattern parameters of Airy transform optical system on the generated beam are analyzed in detail with numerical examples.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗