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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,171 records · Page 65
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Oscillating-Crucible Technique for Silicon Growth

Technique yields better mixing of impurities and superior qualiity crystals. Accellerated motion stirs melt which reduces temperature gradients and decreases boundary layer for diffusion of impurities near growing surface. Results better mixing of impurities into melt, decrease in tendency for dendritic growth or cellular growth and crystals with low dislocation density. Applied with success to solution growth and Czochralski growth, resulting in large crystals of superior quality.

Daud, T.↗
NASA NTRS1982

Large area low-cost space solar cell development

A development program to produce 5.9 x 5.9 cm space quality silicon solar cells with a cost goal of 30 $/W is described. Cell types investigated include wraparound dielectric, mechanical wraparound and conventional contact configurations with combinations of 2 or 10 ohm/cm resistivity, back surface reflectors and/or fields, and diffused or ion implanted junctions. A single step process to cut cell and cover glass simultaneously is being developed. Results for cell and array tests are given. Large solar arrays that might use cells of this type are discussed.

Barona, C. R.↗
NASA NTRS1983

Kinetics of copper ion absorption by cross-linked calcium polyacrylate membranes

The absorption of copper ions from aqueous copper acetate solutions by cross-linked calcium acrylate membranes was found to obey parabolic kinetics similar to that found for oxidation of metals that form protective oxide layers. For pure calcium polyacrylate membranes the rate constant was essentially independent of copper acetate concentration and film thickness. For a cross-linked copolymer film of polyvinyl alcohol and calcium polyacrylate, the rate constant was much greater and dependent on the concentration of copper acetate. The proposed mechanism in each case involves the formation of a copper polyacrylate phase on the surface of the membrane. The diffusion of the copper ion through this phase appears to be the rate controlling step for the copolymer film. The diffusion of the calcium ion is apparently the rate controlling step for the calcium polyacrylate. At low pH, the copper polyacrylate phase consists of the normal copper salt; at higher pH, the phase appears to be the basic copper salt.

Philipp, W. H.↗
NASA NTRS1984

Engineering correlations of variable-property effects on laminar forced convection mass transfer for dilute vapor species and small particles in air

A simple engineering correlation scheme is developed to predict the variable property effects on dilute species laminar forced convection mass transfer applicable to all vapor molecules or Brownian diffusing small particle, covering the surface to mainstream temperature ratio of 0.25 T sub W/T sub e 4. The accuracy of the correlation is checked against rigorous numerical forced convection laminar boundary layer calculations of flat plate and stagnation point flows of air containing trace species of Na, NaCl, NaOH, Na2SO4, K, KCl, KOH, or K2SO4 vapor species or their clusters. For the cases reported here the correlation had an average absolute error of only 1 percent (maximum 13 percent) as compared to an average absolute error of 18 percent (maximum 54 percent) one would have made by using the constant-property results.

Gokoglu, S. A.↗
NASA NTRS1984

The Shuttle Orbiter high resolution accelerometer package experiment - Preliminary flight results

A description of the High Resolution Accelerometer Package (HiRAP) experiment, designed to measure rarefied flow aerodynamic accelerations, is given. The ground test calibration factors, as well as post-flight data processing techniques to extract aerodynamic accelerations, are discussed and applied to the recorded reentry data of the recent STS-6 Shuttle Orbiter flight. The ratio of the measured normal-to-axial aerodynamic accelerations during reentry is used to obtain the first flight measurement of the lift-to-drag ratio (L/D) of a winged entry vehicle in the rarefied flow flight regime. The preliminary result for the free-molecule flow L/D is 0.10 + or - 0.03. The initial flight results on L/D are compared with current predictions which are based upon theoretical and empirical considerations. The measured free-molecule flow L/D value is higher than predicted by a factor of about three, indicating that surface reflection is not completely diffuse as currently assumed. In the rarefied flow transition regime, the Shuttle data book-bridging formula fits the flight data adequately. Upper altitude density profiles are also deduced from the measurements and presented. The density profiles show a wave phenomena with amplitude of about 60 percent, relative to a standard model.

Blanchard, R. C.↗
NASA NTRS1986

Release of noble gases and nitrogen from grain-surface sites in lunar ilmenite by closed-system oxidation

Noble gases and nitrogen were extracted from a 100 to 150 microns ilmenite separate from lunar soil 71501 by closed system stepped heating in approx. 10 torr O2 at 300 C, 400 C, 500 C, 600 C and 630 C, followed by stepped pyrolysis at ten temperatures between 680 C and approx. 1500 C. The five oxidation steps together liberated approx. 65% of the total He-4, 45% of the Ne-20, 23% of the N-14 and Ar-36, 12% of the Kr-84 and 8% of the Xe-132 in the sample; Ne-20/Ar-36 and Ne-20/Ne-22 ratios agree with the solar wind composition experiment, and Kr-84/Ar-36 and Xe-132/Ar-36 are within approx. 10% of Cameron's estimates for the sun and solar wind. The remaining gases, released above 630 C by pyrolysis, are strongly fractionated with respect to the SWC-Cameron solar wind elemental composition. Large concentrations of fractionated noble gases in grain interiors, their virtual absence in the relatively unfractionated surface gas reservoir, and the high N/noble gas ratio all imply that most of the solar wind noble gases initially implanted in grain surfaces are eventually lost by diffusion. Loss limits can be estimated by considering two given scenarios. It is concluded tat approx. 70 to 97% or more of the Ar implanted in 71501 ilmenite grains has diffusively escaped.

Frick, U.↗
NASA NTRS1985

High temperature oxidation of beta-NiAl

The oxidation of single crystal beta-NiAl has been studied primarily using electron microscopy. Oriented metastable Al2O3 phases form during transient oxidation at 800 C. Specific orientation relationships exist on all metal orientations studied and are a result of the small mismatch along aligned close-packed directions in the cation sublattices of the metal and oxide. Transformation of the metastable Al2O3 phases at 1100 C results in an oxide morphology described as the 'lacey' structure of alpha-Al2O3 scales. This structure results from impingement of oriented patches of alpha-Al2O3 as the transformation initiates and moves radially parallel to the surface. Scale growth occurs by diffusion along high angle grain boundaries. A drastic reduction in oxidation rate accompanies the change in oxide morphology.

Koychak, J. K.↗
NASA NTRS1988

Modelling ignition characteristics of rich H2/O2 mixture in a monolithic catalytic reactor

Ignition of rich hydrogen-oxygen mixture in a monolithic catalytic reactor is studied using a transient combustion model. The model assumes a quasi-steady gas phase and a thermally-thin substrate. The ignition time lag is due to the thermal inertia of the substrate. One-step global chemical reaction is assumed both on the surface and in the gas phase. An effectiveness factor is introduced to account for the transition from a kinetically-limited catalytic surface reaction to a diffusion-limit one during ignition. Results presented include a catalytic ignition boundary, ignition delay time and the transient response in the catalytic bed.

Tien, Ta-Ching↗
NASA NTRS1989

Raman intensity as a probe of concentration near a crystal growing in solution

The feasibility of using Raman spectral scattering signals for measurements of concentration profiles near a crystal interface during growth or dissolution is discussed. With KH2PO4 (KDP) as a test material, optical multichannel analyzer (OMA) detection of a solute Raman vibrational band provided direct quantification of solute concentration with band intensity. The intersection of incident laser and Raman collection optics provided 3-D selective point measurements of the solution concentration field. Unlike many other techniques, the Raman band intensity is not sensitive to the typical temperature variations. Precision calibration of Raman intensity versus KDP concentration with less than 1 pct standard deviation error levels was demonstrated. A fiber optic, which sampled incident laser intensity and coupled it to the OMA, provided a fully synchronized monitor of fluctuations in laser power to correlate with observed Raman signals. With 1 W of laser power at the sample, good data statistics required eight repeated data collections at approximately 2.5 min collection. The accumulated time represents the concentration measurement time at one spatial location. Photomicroscopy documented a 30 micrometer diameter by 200 micrometer of laser Raman scattering region in the solution near the crystal surface. The laser beam was able to approach up to 25 micrometer from the crystal surface. However, a crystal surface reflected intensity contribution was weakly detectable. Nucleated microcrystals were seen in the crystal-growing solution. These microcrystals convect right up to the crystal surface and indicate no quiet diffusion region under normal gravity conditions. Translation of the solution cell with respect to the optics caused systematic intensity errors.

Wilkinson, R. Allen↗
NASA NTRS1989

Isotopic study of oxygen diffusion in oxide coatings

Diffusion of oxygen in thin films of silicon dioxide was studied using oxygen isotopically enriched in oxygen of atomic mass 18 (O-18). This subject is of interest because thin films of dielectrics such as SiO2 are proposed for use as a protective coatings for solar mirrors in low Earth orbit, which is a strongly oxidizing environment. Films of this material were prepared with a direct current magnetron using reactive sputtering techniques. To produce (O-18)- enriched SiO2, a standard 3.5-in.-diameter silicon wafer was reactively sputtered using (O-18)-enriched (95 percent) oxygen as the plasma feed gas. The films were characterized using Rutherford backscattering and Secondary Ion Mass Spectrometer (SIMS) to establish stoichiometry and purity. Subsequently, the films were exposed to an air-derived oxygen plasma in a standard laboratory plasma reactor for durations of up to 10 hr. The concentration ratio of O-16 as a function of depth was determined using SIMS profiling and compared to a baseline, nonplasma exposed sample. A value for the diffusivity of oxygen near the surface of these films was obtained and found to be about 10(-15)sq cm/sec.

Gulino, Daniel A.↗
NASA NTRS1989

Application of a vectorized particle simulation in high-speed near-continuum flow

An efficient particle simulation technique, developed for use on vector architecture based supercomputers for studying hypersonic rarefied gas flows is employed to simulate the complex wake generated by Mach six flow over a 10 deg half-angle wedge for freestream Reynolds numbers of 1780 and 3560. Data obtained are compared against higher Reynolds number experimental results. Simulations utilized as many as 10 to the 5th computational cells and 10 to the 7th simulated particles having power-law interaction potentials. A code performance of 1.8-2.4 microsec of Cray-2 CPU time to process a single particle per timestep is achieved. Diffuse adiabatic and isothermal wedge surface models are used in this investigation. Although the wedge geometry is two-dimensional, the simulation incorporates a width-wise direction, resulting in a three-dimensional computation.

Woronowicz, Michael S.↗
NASA NTRS1989

Frequency response of electrochemical cells

Impedance concepts can be applied to the analysis of battery electrodes, yielding information about the structure of the electrode and the processes occurring in the electrode. Structural parameters such as the specific area (surface area per gram of electrode) can be estimated. Electrode variables such as surface overpotential, ohmic losses, and diffusion limitations may be studied. Nickel and cadmium electrodes were studied by measuring the ac impedance as a function of frequency, and the specific areas that were determined were well within the range of specific areas determined from BET measurements. Impedance spectra were measured for the nickel and cadmium electrodes, and for a 20 A-hr NiCd battery as functions of the state of charge. More work is needed to determine the feasibility of using frequency response as a nondestructive testing technique for batteries.

Thomas, Daniel L.↗
NASA NTRS1990

Submillimeter continuum emission from galaxies - Star formation and the interstellar medium in the local group dwarf IC 10

Far-infrared (95 and 160 micron) maps and visual broad-band and line images of the nearby, luminous irregular galaxy IC 10 are discussed. Observations of the dust emission make it possible to constrain the total mass of gas and the rate of star formation derived for the galaxy. The total star-formation rate is estimated to be about 0.15 solar mass/yr, and the e-folding time for exhaustion of the interstellar gas due to the star formation is only a few billion years. To determine the source of the cool dust in emission at approximately 100-250 microns from many galaxies, 60, 100, and 160 micron photometry, obtained previously, is compared; and CO, H I, and dust emission is correlated. Based on the correlation between the various cool components of the interstellar medium, it is concluded that the likely location of the dust that dominates the emission at about 160, and possibly 100, microns is within both the diffuse atomic gas and in surface layers of molecular clouds.

Thronson, Harley A., Jr.↗
NASA NTRS1991

Heat Transfer to a Thin Solid Combustible in Flame Spreading at Microgravity

The heat transfer rate to a thin solid combustible from an attached diffusion flame, spreading across the surface of the combustible in a quiescent, microgravity environment, was determined from measurements made in the drop tower facility at NASA-Lewis Research Center. With first-order Arrhenius pyrolysis kinetics, the solid-phase mass and energy equations along with the measured spread rate and surface temperature profiles were used to calculate the net heat flux to the surface. Results of the measurements are compared to the numerical solution of the complete set of coupled differential equations that describes the temperature, species, and velocity fields in the gas and solid phases. The theory and experiment agree on the major qualitative features of the heat transfer. Some fundamental differences are attributed to the neglect of radiation in the theoretical model.

Bhattacharjee, S.↗
NASA NTRS1991

Thermal modeling of comet Kopff: Implications for the CRAF mission

A thermal model of periodic comet Kopff was developed to aid in planning for the Comet Rendezvous Asteroid Flyby mission. The model is based on the comet nucleus model, which estimates the surface temperature distribution and sublimation rates on a rotating icy sphere in heliocentric orbit. The model results are compared with the observed gas production rates from Kopff in 1983. It is found that approximately 15 percent of the sunlit nucleus surface is active, a relatively high fraction for a typical short-period comet. This suggests that the actual nucleus radius may be larger than the model value. The slope of the observed gas production curve with heliocentric distance is steeper than that predicted by the thermal model. This may indicate the existence of a more complex process than direct sublimation of surface ices, such as gas diffusion through a nonvolatile insulating crust.

Weissman, Paul↗
NASA NTRS1994

The lithium content and other properties of F2-G5 giants in the Hertzsprung Gap

As stars of 2-5 solar mass evolve across the Hertzsprung Gap they should first deplete their surface lithium by convective dilution and then, when convection penetrates deeper, begin to bring CN processed material to their surfaces. To investigate this process we have observed 52 giants, 25 of which have known C/N ratios, for their Li abundances. After eliminating four stars that may actually be dwarfs and including the two components of Capella analyzed by Pilachowski and Sowell we have compared our (Li/Fe) ratios with models of Swenson. For stars showing v sin i greater than 50 km/s we find (Li/Fe) to be uneffected by mixing for B - V less than 0.7 as predicted. For stars cooler than B - V = 0.7 both v sin i and (Li/Fe) drop to smaller values. For the sharp lined stars (v sin i less than 50 km/s) we find a drop in Li between B - V = 0.45 and 0.60 which cannot be understood in terms of dilution by convection. Various possible causes of such an early depletion or dilution of surface Li are discussed including diffusion at the base of the convection zone, mass loss possibly enhanced by pulsation, and magnetic activity as in the magnetic A and B type stars. The models of Richer & Michaud (1993) with diffusion point toward a satisfactory solution. A few giants with low v sin i values stand out with much higher than expected (Li/Fe) values despite their cool effective temperatures. We do not understand why those stars have not depleted their lithium as have most giants of similar color. The correlation of (N/C) with (Li/Fe) follows expectations in so far as almost all stars with enhanced (N/C) have depleted their Li as well.

Wallerstein, George↗
NASA NTRS1992

Reflectance Spectroscopy of Palagonite and Iron-Rich Montmorillonite Clay Mixtures: Implications for the Surface Composition of Mars

Mixtures of a Hawaiian palagonite and an iron-rich, montmorillonite clay (15.8 +/- 0.4 wt% Fe as Fe2O3) were evaluated as Mars surface spectral analogs from their diffuse reflectance spectra. The presence of the 2.2 microns absorption band in the reflectance spectrum of clays and its absence in the Mars spectrum have been interpreted as indicating that highly crystalline aluminous hydroxylated clays cannot be a major mineral component of the soil on Mars. The palagonite sample used in this study does not show this absorption feature in its spectrum. In mixtures of palagonite and iron-rich montmorillonite, the 2.2 microns Al-OH clay lattice band is not seen below 15 wt% montmorillonite. This suggests the possibility that iron-rich montmorillonite clay may be present in the soil of Mars at up to 15 wt% in combination with palagonite, and remain undetected in remotely sensed spectra of Mars.

Orenberg, James↗
NASA NTRS2000

Wide-Field Imaging of Galactic Halos with a Near-Infrared Rocket-Borne Telescope

We successfully completed both of the proposed flights by May of 1998, on schedule and on budget. In both flights the instrument worked flawlessly, achieving sensitivities slightly better than the specification (1 nW/sq m sr per pixel). The payload was recovered with only minor damage after both flights. The results from the first flight, which targeted the nearby edge-on spiral NCG 4565, have been published. Analysis of the data failed to detect any significant emission, from the halo around the galaxy, and set a very stringent 2 sigma lower limit on the M/L ratio of the halo of greater than 260 in solar units. The results from the second flight, which targeted the infamous NGC 5907, have taken longer to analyze because of an offset in the absolute pointing of the payload which broke the symmetry of the scan pattern about the galaxy, thus complicating the analysis, After careful analysis, Caltech graduate student, Sarah Yost, has recovered the full sensitivity of the experiment, setting a 2 sigma lower limit on the M/L ratio of the halo of greater than 280 in solar units. This result rules out the hypothesis that a significant portion of the halo around NGC 5907 is composed of low-mass stars, as previous observations had suggested. NITE probes directly the halo at 10 to 30 kpc from the disk, a region far too dim for other experiments. Our conclusion is that observations of a significant IR signature associated with the halo at less than approximately 5kpc radius where contaminated by tidally disrupted disk population of stars. In order to test the idea that we could study faint surface-brightness fluctuations in the diffuse background using NITE, we have analyzed the data from the 1997 flight which targeted NCG 4565 (this target is in a region of lower stellar confusion than is NGC 5907). We have detected a significant correlation in the noise at zero-lag, with an amplitude that corresponds to brightness fluctuations of 3.04 plus or minus 0.16 nW/sq m sr. This work will be submitted for publication later this year. An important accomplishment of our sub-orbital program is the training graduate students and postdocs who will become future leaders in NASA's space astrophysics program. The PI has mentored 7 scientists that now hold tenure-track faculty positions or the equivalent at NASA research centers.

Lange, Andrew E.↗