Search NASA⌕ Search

SEARCH · Search NASA

Results for “diffusion processes”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,171 records · Page 65

Observations of energetic Jovian electrons and protons

The Goddard/University of New Hampshire experiment aboard Pioneers 10 and 11 used high and low energy telescopes to measure the nucleon and electron components of the Jupiter magnetosphere. Proton energy spectra are of the form E to the -4th in the outer region and become more complex in the inner region. Particle absorption by several of Jupiter's satellites is an important effect which clearly establishes that radial diffusion is the dominant acceleration process in this region. Observed electron bursts or increases were typically several hundred times the normal quiet-time electron flux, resulting in the quasi-continuous presence of these electrons in interplanetary space. It is suggested that Jupiter could be the source of most of the ambient low energy electrons in the heliosphere.

Mcdonald, F. B.↗

On a model of calculating bond strength

Diffusion bonding is a fabricating process to join the fibers and a matrix together forming a composite. The efficiency of the bonding process depends on temperature, time, and pressure. Based on a simplified pair potential model, an expression for the bond-energy at the fiber-matrix interface is formulated in terms of the above-mentioned three parameters. From this expression and the mean atomic distance, the bond-strength between the fibers and the matrix can be calculated.

Yue, A. S.↗

Investigation of proposed process sequence for the array automated assembly task, phases 1 and 2

Progress was made on the process sequence for module fabrication. A shift from bonding with a conformal coating to laminating with ethylene vinyl acetate and a glass superstrate is recommended for further module fabrication. The processes that were retained for the selected process sequence, spin-on diffusion, print and fire aluminum p+ back, clean, print and fire silver front contact and apply tin pad to aluminum back, were evaluated for their cost contribution.

Mardesich, N.↗

Influence of convection on free growth of dendrite crystals from solution

The free growth of dendrites in a uniformly supercooled solution was examined using cine photography with a Schlieren optical system. Crystals were grown in the bulk of the solution from a centrally located capillary tube, nucleated at the interface with a liquid nitrogen cooled wire. Crystals propagated along the tube, the slower growing orientations eliminated, and emerged at the tip, usually growing parallel to the tube direction. For both sodium sulfate decahydrate from its solution and ice from sodium chloride solution, growth rate and fineness of dendrites increased with supercooling. In sodium sulfate, upward convection of the less dense depleted solution occurs; downward convection was observed for the rejected, more concentrated sodium chloride solution. In both cases, there was a spatial and temporal delay in the release of the convective plume from the moving dendrite tip. The role of this convection on the growth characteristics and the production of secondary crystals is examined. A proposed low-g experiment to examine differences in growth rate, crystal texture, and secondary nucleation in a reduced convective regime where molecular diffusion is the dominant transfer process is discussed.

Hallett, J.↗

Day and night models of the Venus thermosphere

A model atmosphere of Venus for altitudes between 100 and 178 km is presented for the dayside and nightside. Densities of CO2, CO, O, N2, He, and O2 on the dayside, for 0800 and 1600 hours local time, are obtained by simultaneous solution of continuity equations. These equations couple ionospheric and neutral chemistry and the transport processes of molecular and eddy diffusion. Photodissociation and photoionization J coefficients are presented to facilitate the incorporation of chemistry into circulation models of the Venus atmosphere. Midnight densities of CO2 CO, O, N2, He, and N are derived from integration of the continuity equations, subject to specified fluxes. The nightside densities and fluxes are consistent with the observed airglow of NO and O2(1 Delta). The homopause of Venus is located near 133 km on both the dayside and nightside.

Massie, S. T.↗

Combustor flame flashback

Flashback, a problem that occurs in premixed-prevaporized combustors, is the upstream propagation of the flame from the combustor into the premixing tubes. Not only does flashback change the combustion process from premixed burning to diffusion burning, thus creating more pollutants, but it also inflicts considerable damage to the fuel injector, premixing tube and other equipment upstream. The conditions at which flashback occurs in steady burning and the mechanism that causes flashback in both steady and transient flow are studied. The equivalence ratio at which flashback occurs is being measured for inlet temperatures of 600-950 K, premixer wall temperatures of 450-1050 K and premixer velocities of 40-80 ft/s. These data are presented.

Proctor, M. P.↗

Excitation of turbulence by density waves

A nonlinear system describes the microdynamical state of turbulence that is excited by density waves. It consists of an equation of propagation and a master equation. A group-scaling generates the scaled equations of many interacting groups of distribution functions. The two leading groups govern the transport processes of evolution and eddy diffusivity. The remaining sub-groups represent the relaxation for the approach of diffusivity to equilibrium. In strong turbulence, the sub-groups disperse themselves and the ensemble acts like a medium that offers an effective damping to close the hierarchy. The kinetic equation of turbulence is derived. It calculates the eddy viscosity and identifies the effective damping of the assumed medium self-consistently. It formulates the coupling mechanism for the intensification of the turbulent energy at the expense of the wave energy, and the transfer mechanism for the cascade. The spectra of velocity and density fluctuations find the power law k sup-2 and k sup-4, respectively.

Tichen, C. M.↗

Cosmic-ray propagation in the Galaxy and in the heliosphere - The path-length distribution at low energy

The energy dependence of the path-length distribution of cosmic rays at low energies, below relativistic velocities, is studied, and its implications for models of cosmic-ray confinement and propagation in the Galaxy and Galactic halo, including the effects of a possible Galactic wind, are studied. It is found that the mean free path in Galactic propagation must be fully energy-dependent, with the mean of an exponential path-length distribution increasing with increasing energy below 1 GeV per nucleon and decreasing with increasing energy above 1 GeV per nucleon. This indicates that, at low energies, diffusion is not the controlling process. The path-length distribution is not purely exponential but is depleted in short path lengths at low energies. This depletion is energy-dependent, being largest at low energies and decreasing with increasing energy.

Garcia-Munoz, M.↗

Similarity solutions for phase-change problems

A modification of Ivantsov's (1947) similarity solutions is proposed which can describe phase-change processes which are limited by diffusion. The method has application to systems that have n-components and possess cross-diffusion and Soret and Dufour effects, along with convection driven by density discontinuities at the two-phase interface. Local thermal equilibrium is assumed at the interface. It is shown that analytic solutions are possible when the material properties are constant.

Canright, D.↗

Correlations and alloy properties - Growth, vacancies, surface segregation

The aspects of bonding interaction mechanisms which have an impact on the correlation state of alloy semiconductors are demonstrated. The effect of the correlation state on liquidus and solidus curves, on surface segregation, and on vacancy densities is deduced. Vacancy energies for several alloys are presented, and tentative conclusions are drawn about their effects on diffusion, doping, and ion beam processing. Features of the theory of surface segregation in semiconductor alloys are then presented.

Sher, A.↗

Composition of chondrule silicates in LL3-5 chondrites and implications for their nebular history and parent body metamorphism

The composition of 75 type-IA and type-II porphyritic olivine chondrules from nine LL type 3 to type 5 chondrites was determined and was compared with that of chondrules from the Semarkona type 3.0 meteorite. Chemical data for silicates in the LL3.3-5 chondrites indicated that porphyritic olivine chondrules in these chondrites could be derived from chondrules similar to those from the Semarkona LL3.0, the least metamorphosed one of the known LL chondrites. It is shown that the chemical trends defined by the minerals of type-IA and type-II chondrules can be satisfactorily accounted for by the process of solid-state diffusive equilibration between minerals in chondrules and the opaque matrix rather than by changes in conditions during chondrule crystallization.

Mccoy, Timothy J.↗

Vapor crystal growth studies of single crystals of mercuric iodide (3-IML-1)

A single crystal of mercuric iodide (HgI2) will be grown during the International Microgravity Lab. (IML-1) mission. The crystal growth process takes place by sublimation of HgI2 from an aggregate of purified material, transport of the molecules in the vapor from the source to the crystal, and condensation on the crystal surface. The objectives of the experiment are as follow: to grow a high quality crystal of HgI2 of sufficient size so that its properties can be extensively analyzed; and to study the vapor transport process, specifically the rate of diffusion transport at greatly reduced gravity where convection is minimized.

Vandenberg, Lodewijk↗

The O2 reduction at the IFC modified O2 fuel cell electrode

The International Fuel Corporation (IFC) state of the art (SOA) O2 electrode (Au-10 percent Pt electrocatalyst by weight) is currently being used in the alkaline H2-O2 fuel cell in the NASA Space Shuttle. Recently, IFC modified O2 electrode, as a possible replacement for the SOA electrode. In the present study, O2 reduction data were obtained for the modified electrode at temperatures between 23.3 and 91.7 C. BET measurements gave an electrode BET surface area of about 2070 sq. cm/sq. cm of geometric surface area. The Tafel data could be fitted to two straight line regions. The slope for the lower region, designated as the 0.04 V/decade region, was temperature dependent, and the transfer coefficient was about 1.5. The 'apparent' energy of activation for this region was about 19 kcal/mol. An O2 reduction mechanism for this 0.04 region is presented. In the upper region, designated as the 0.08 V/decade region, diffusion may be the controlling process. Tafel data are presented to illustrate the increase in performance with increasing temperature.

Fielder, William L.↗

A computer model for one-dimensional mass and energy transport in and around chemically reacting particles, including complex gas-phase chemistry, multicomponent molecular diffusion, surface evaporation, and heterogeneous reaction

Various chemically reacting flow problems highlighting chemical and physical fundamentals rather than flow geometry are presently investigated by means of a comprehensive mathematical model that incorporates multicomponent molecular diffusion, complex chemistry, and heterogeneous processes, in the interest of obtaining sensitivity-related information. The sensitivity equations were decoupled from those of the model, and then integrated one time-step behind the integration of the model equations, and analytical Jacobian matrices were applied to improve the accuracy of sensitivity coefficients that are calculated together with model solutions.

Cho, S. Y.↗

The effect of dissipative inhomogeneous medium on the statistics of the wave intensity

One of the main theoretical points in the theory of wave propagation in random medium is the derivation of closed form equations to describe the statistics of the propagating waves. In particular, in one dimensional problems, the closed form representation of the multiple scattering effects is important since it contributes in understanding such problems like wave localization, backscattering enhancement, and intensity fluctuations. In this the propagation of plane waves in a layer of one-dimensional dissipative random medium is considered. The medium is modeled by a complex permittivity whose real part is a constant representing the absorption. The one dimensional problem is mathematically equivalent to the analysis of a transmission line with randomly perturbed distributed parameters and a single mode lossy waveguide and the results can be used to study the propagation of radio waves through atmosphere and the remote sensing of geophysical media. It is assumed the scattering medium consists of an ensemble of one-dimensional point scatterers randomly positioned in a layer of thickness L with diffuse boundaries. A Poisson impulse process with density lambda is used to model the position of scatterers in the medium. By employing the Markov properties of this process an exact closed form equation of Kolmogorov-Feller type was obtained for the probability density of the reflection coefficient. This equation was solved by combining two limiting cases: (1) when the density of scatterers is small; and (2) when the medium is weakly dissipative. A two variable perturbation method for small lambda was used to obtain solutions valid for thick layers. These solutions are then asymptotically evaluated for small dissipation. To show the effect of dissipation, the mean and fluctuations of the reflected power are obtained. The results were compared with a lossy homogeneous medium and with a lossless inhomogeneous medium and the regions where the effect of absorption is not essential were discussed.

Saatchi, Sasan S.↗

Eddy mixing coefficient values derived from simulations with the NASA Ames Mars GCM

Values of eddy mixing coefficients, especially that for vertical mixing, are of particular importance for various photochemical models of the Mars atmosphere, which are either globally or zonally averaged. These models represent atmospheric transport processes in terms of eddy diffusion. While this is not appropriate for the advective transport by the mean meridional circulation (in general, a part of the eddy diffusion tensor actually does represent advection--a 'correction' to the Eulerian-mean circulation), it can be applied to simulate both the small- and larger-scale eddy transports of an atmospheric constituent. An effort is underway to estimate values of the eddy mixing coefficients for the Mars atmosphere using circulation data generated with the NASA Ames Mars GCM. This model simulates the three-dimensional winds in the atmosphere, and these are then used as inputs for a tracer transport model. The latter model has previously been used in interactive dust transport experiments with the Ames GCM. Idealized tracer transport experiments, with a conservative or nearly conservative hypothetical tracer, are performed to generate data from which the eddy diffusion coefficients can be estimated. Carrying out matched pairs of tracer experiments, using two very different initial states, permits all four components of the diffusion tensor to be determined. A large number of GCM experiments have been conducted, spanning a range of seasons and atmospheric dust loading, allowing the eddy mixing coefficients to be estimated for a variety of atmospheric conditions.

Barnes, J. R.↗

Mars atmospheric loss and isotopic fractionation by solar-wind-induced sputtering and photochemical escape

We examine the effects of loss of Mars atmospheric constituents by solar-wind-induced sputtering and by photochemical escape during the last 3.8 b.y. Sputtering is capable of efficiently removing all species from the upper atmosphere including the light noble gases; N is removed by photochemical processes as well. Due to diffusive separation (by mass) above the homopause, removal from the top of the atmosphere will fractionate the isotopes of each species with the lighter mass being preferentially lost. For C and O, this allows us to determine the size of nonatmospheric reservoirs that mix with the atmosphere; these reservoirs can be CO2 adsorbed in the regolith or H2O in the polar ice caps. We have constructed both simple analytical models and time-dependent models of the loss from and supply of volatiles to the Martian atmosphere.

Jakosky, B. M.↗

Modeling time-dependent corrosion fatigue crack propagation in 7000 series aluminum alloys

Stress corrosion cracking and corrosion fatigue experiments were conducted with the susceptible S-L orientation of AA7075-T651, immersed in acidified and inhibited NaCl solution, to provide a basis for incorporating environmental effects into fatigue crack propagation life prediction codes such as NASA FLAGRO. This environment enhances da/dN by five to ten-fold compared to fatigue in moist air. Time-based crack growth rates from quasi-static load experiments are an order of magnitude too small for accurate linear superposition prediction of da/dN for loading frequencies above 0.001 Hz. Alternate methods of establishing da/dt, based on rising-load or ripple-load-enhanced crack tip strain rate, do not increase da/dt and do not improve linear superposition. Corrosion fatigue is characterized by two regimes of frequency dependence; da/dN is proportional to f(exp -1) below 0.001 Hz and to F(exp 0) to F(exp -0.1) for higher frequencies. Da/dN increases mildly both with increasing hold-time at K(sub max) and with increasing rise-time for a range of loading waveforms. The mild time-dependence is due to cycle-time-dependent corrosion fatigue growth. This behavior is identical for S-L nd L-T crack orientations. The frequency response of environmental fatigue in several 7000 series alloys is variable and depends on undefined compositional or microstructural variables. Speculative explanations are based on the effect of Mg on occluded crack chemistry and embritting hydrogen uptake, or on variable hydrogen diffusion in the crack tip process zone. Cracking in the 7075/NaCl system is adequately described for life prediction by linear superposition for prolonged load-cycle periods, and by a time-dependent upper bound relationship between da/dN and delta K for moderate loading times.

Mason, Mark E.↗