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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,171 records · Page 65
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Electron beam injection from a hollow cathode plasma into a downstream reactive environment: Characterization of secondary plasma production and Si 3 N 4 and Si etching

A material etching system was developed by combining beam electron injection from a direct current (DC) hollow-cathode (HC) electron source with the downstream reactive environment of a remote CF 4 /O 2 low temperature plasma. The energy of the injected beam electrons is controlled using an acceleration electrode biased positively relative to the HC Argon discharge. For an acceleration voltage greater than the ionization potential of Ar, the extracted primary electrons can produce a secondary plasma in the process chamber. We characterized the properties of the secondary plasma by performing Langmuir probe measurements of the electron energy probability function (EEPF) 2.5 cm below the extraction ring. The data indicate the existence of two major groups of electrons, including electrons with a primary beam electron energy which varies as the acceleration voltage is varied, along with low energy electrons produced by ionization of the Ar gas atoms in the process chamber by the injected beam electrons. When combining the HC Ar beam electron with a remote CF 4 /O 2 electron cyclotron wave resonance (ECWR) plasma, the EEPF of both the low energy plasma electron and beam electron components decreases. Additionally, we studied surface etching of Si3N4 and poly-crystalline Si (poly-Si) thin films as a function of process parameters, including the acceleration voltage (0-70 V), discharge current of the HC discharge (1-2 A), pressure (2- 100 mTorr), source to substrate distance (2.5 to 5 cm), and feed gas composition (with or without CF 4 /O 2 ). The direction of the incident beam electrons was perpendicular to the surface. Si 3 N 4 and poly-crystalline silicon etching are seen and indicate an electronneutral synergy effect. No/little remote plasma spontaneous etching was observed for the conditions used in this study, and the etching is confined to the substrate area irradiated by the injected beam electrons. The electron etched Si 3 N 4 surface etching rate profile distribution is confined within a ~30 mm diameter circle, which is slightly broader than the area for which poly-Si etching is seen, and coincides closely with the spatial profile of beam electrons as determined by the Langmuir probe measurements. The magnitude of poly-Si etching rate is by a factor of two times smaller than the Si 3 N 4 etching rate. In this paper, we discuss possible explanations of the data and the role of surface charging.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Advanced Processing of Functional Magnetic Materials

Functional materials, specifically those which respond to external stimuli such as magnetic and electrical field, are increasingly important for many green energy technologies. Functional magnetic materials are increasingly been investigated from basic and applied sciences perspectives. Probably, the best-known of these are permanent magnets, they are used to supply a magnetic field and are widely applied in motors, generators, data storage, sensors, and actuators. Other examples of functional materials include soft magnets, magnetocalorics, and thermoelectrics.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Radiation effects on materials for electrochemical energy storage systems

Batteries and electrochemical capacitors (ECs) are of critical importance for applications such as electric vehicles, electric grids, and mobile devices. However, the performance of existing battery and EC technologies falls short of meeting the requirements of high energy/high power and long durability for increasing markets such as the automotive industry, aerospace, and grid-storage utilizing renewable energies. Therefore, improving energy storage materials performance metrics is imperative. In the past two decades, radiation has emerged as a new means to modify functionalities in energy storage materials. There exists a common misconception that radiation with energetic ions and electrons will always cause radiation damage to target materials, which might potentially prevent its applications in electrochemical energy storage systems. But in this review, we summarize recent progress in radiation effects on materials for electrochemical energy storage systems to show that radiation can have both beneficial and detrimental effects on various types of energy materials. Prior work suggests that fundamental understanding toward the energy loss mechanisms that govern the resulting microstructure, defect generation, interfacial properties, mechanical properties, and eventual electrochemical properties is critical. Here, we discuss radiation effects in the following categories: (1) defect engineering, (2) interface engineering, (3) radiation-induced degradation, and (4) radiation-assisted synthesis. We analyze the significant trends and provide our perspectives and outlook on current research and future directions in research seeking to harness radiation as a method for enhancing the synthesis and performance of battery materials.

25 ENERGY STORAGE↗
DOE OSTI2020

Electric and magnetic dipole strength in 112,114,116,118,120,124 Sn

Background: There is renewed interest in electric dipole strength distributions for a variety of reasons including the extraction of the dipole polarizability related to properties of the symmetry energy and a measure for the neutron skin thickness, understanding the structure of low-energy $\textit{E}$1 strength in nuclei with neutron excess, and establishing the systematics of the isovector giant dipole resonance (IVGDR). Inelastic proton scattering at energies of a few hundred MeV and very forward angles including 0° has been established as a tool for the study of electric and magnetic dipole strength distributions in nuclei. Purpose: The present work aims at a systematic investigation of the electric and magnetic dipole strength distributions in the chain of stable even-mass tin isotopes. Methods: Inelastic proton scattering experiments were performed at the Research Center for Nuclear Physics, Osaka, with a 295-MeV beam covering laboratory angles 0°–6° and excitation energies 6–22 MeV. Cross sections due to $\textit{E}$1 and $\textit{M}$1 excitations were extracted with a multipole decomposition analysis (MDA) and then converted to reduced transition probabilities with the “virtual photon method” for $\textit{E}$1 and the “unit cross section method” for $\textit{M}$1 excitations, respectively. Including a theory-aided correction for the high-excitation-energy region not covered experimentally, the electric dipole polarizability was determined from the $\textit{E}$1 strength distributions. Results: In this work, total photoabsorption cross sections derived from the $\textit{E}$1 and $\textit{M}$1 strength distributions show significant differences compared to those from previous ($\textit{γ, xn}$) experiments in the energy region of the IVGDR. The widths of the IVGDR deduced from the present data with a Lorentz parametrization show an approximately constant value of about 4.5 MeV in contrast to the large variations between isotopes observed in previous work. The IVGDR centroid energies are in good correspondence to expectations from empirical systematics of their mass dependence. Furthermore, a study of the dependence of the IVGDR energies on bulk matter properties is presented. The $\textit{E}$1 strengths below neutron threshold show fair agreement in this work with results from ($\textit{γ, γ'}$) experiments on 112,116,120,124 Sn in the energy region between 6 and 7 MeV, where also isoscalar $\textit{E}$1 strength was found for 124 Sn. At higher excitation energies, large differences are observed, pointing to a different nature of the excited states with small ground-state branching ratios. The isovector spin-$\textit{M}$1 strengths exhibit a broad distribution between 6 and 12 MeV in all studied nuclei. Conclusions: The present results contribute to the solution of a variety of nuclear structure problems including the systematics of the energy and width of the IVGDR, the structure of low-energy $\textit{E}$1 strength in nuclei, new constraints to energy density functionals (EDFs) aiming at a systematic description of the dipole polarizability across the nuclear chart, from which properties of the symmetry energy can be derived, and the systematics of the isovector spin-$\textit{M}$1 strength in heavy nuclei.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2013

Advection of passive magnetic field by the Gaussian velocity field with finite correlations in time and spatial parity violation

Using the field theoretic renormalization group technique the model of passively advected weak magnetic field by an incompressible isotropic helical turbulent flow is investigated up to the second order of the perturbation theory (two-loop approximation) in the framework of an extended Kazantsev-Kraichnan model of kinematic magnetohydrodynamics. Statistical fluctuations of the velocity field are taken in the form of a Gaussian distribution with zero mean and defined noise with finite correlations in time. The two-loop analysis of all possible scaling regimes is done and the influence of helicity on the stability of scaling regimes is discussed and shown in the plane of exponents ɛ − η, where ɛ characterizes the energy spectrum of the velocity field in the inertial range E ∞ k{sup 1−2ε}, and η is related to the correlation time at the wave number k which is scaled as k {sup −2+η}. It is shown that in non-helical case the scaling regimes of the present vector model are completely identical and have also the same properties as those obtained in the corresponding model of passively advected scalar field. Besides, it is also shown that when the turbulent environment under consideration is helical then the properties of the scaling regimes in models of passively advected scalar and vector (magnetic) fields are essentially different. The results demonstrate the importance of the presence of a symmetry breaking in a given turbulent environment for investigation of the influence of an internal tensor structure of the advected field on the inertial range scaling properties of the model under consideration and will be used in the analysis of the influence of helicity on the anomalous scaling of correlation functions of passively advected magnetic field.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1975

Relative and absolute level populations in beam-foil-excited neutral helium

Relative and absolute populations of 19 levels in beam-foil-excited neutral helium at 0.275 MeV have been measured. The singlet angular-momentum sequences show dependences on principal quantum number consistent with n to the -3rd power, but the triplet sequences do not. Singlet and triplet angular-momentum sequences show similar dependences on level excitation energy. Excitation functions for six representative levels were measured in the range from 0.160 to 0.500 MeV. The absolute level populations increase with energy, whereas the neutral fraction of the beam decreases with energy. Further, the P angular-momentum levels are found to be overpopulated with respect to the S and D levels. The overpopulation decreases with increasing principal quantum number.

Davidson, J.↗
DOE OSTI2019

Chicken fat for catalysis: a scaffold is as important for molecular complexes for energy transformations as it is for enzymes in catalytic function

Metalloenzymes are remarkably active, specific, and efficient catalysts.Mimicking the active sites with organometallic complexes based on crystal structures has been a focus for many synthetic chemists. These surrogates have provided significant mechanistic insight into both the molecular complexes as well as the enzymes, however, one of the principle findings has been that just reproducing the active site is not adequate in reproducing the catalytic function. Specifically, the scaffold surrounding the active site plays a critical role in many aspects of catalysis, from positioning reactants optimally to positioning functional groups for reaction to creating the ideal environment for catalysis. Each of these can be controlled with both static positioning as well as small and large dynamics that can activate or control a specific part of the reaction. In this review, we will discuss the effect of organic/peptidic scaffolds, along with medium as an extension of the scaffold, and their varying impacts on catalytic reactivity.

Laureanti, Joseph A.↗
DOE OSTI2018

Pion production in a transport model based on mean fields from chiral effective field theory

We develop a Boltzmann-Uehling-Uhlenbeck (BUU) transport model based on the Sk χm* energy density functional, which is constructed from fitting the nuclear equation of state and nucleon effective masses in asymmetric nuclear matter predicted by the two- and three-body chiral interactions as well as the binding energies of finite nuclei. This new χBUU transport model is then used to study how baryon mean-field potentials affect the kinematics of a scattering or decay process and the equilibrium properties of a hot N–Δ–π system in a box with periodic boundary conditions. We find that the inclusion of mean-field potentials in the energy conservation condition for scattering and decay processes is necessary to maintain the equilibrium numbers of N,Δ, and π. Although the baryon mean-field potentials have significant effects on the total Δ and π numbers, they only slightly affect the ratio of effective negatively to positively charged pions. We also study pion production in central 197 Au + 197 Au collisions at the incident energy of E/A = 400 MeV and compare the results with the experimental data from the Four Pi (FOPI) Collaboration at the Gesellschaft für Schwerionenforschung mbH (GSI) in Germany. We find that our model can well describe the experimental results and the threshold effect due to baryon mean-field potentials does not affect much the charged pion ratio in this model. Here, we further make predictions on pion production for the ongoing experiments of 132 Sn + 124 Sn and 108 Sn + 112 Sn at the incident energy of E/A = 270 MeV by the SAMURAI Pion-Reconstruction and Ion-Tracker (SπRIT) Collaboration at the Institute of Physical and Chemical Research (RIKEN) in Japan.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2025

Random Phase Approximation Correlation Energy Using Real-Space Density Functional Perturbation Theory

We present a real-space method for computing the random phase approximation (RPA) correlation energy within Kohn–Sham density functional theory, leveraging the low-rank nature of the frequency-dependent density response operator. In particular, we employ a cubic-scaling formalism based on density functional perturbation theory that circumvents the calculation of the response function matrix, instead relying on the ability to compute its product with a vector through the solution of the associated Sternheimer linear systems. We develop a large-scale parallel implementation of this formalism using the subspace iteration method in conjunction with the spectral quadrature method while employing the Kronecker product-based method for the application of the Coulomb operator and the conjugate orthogonal conjugate gradient method for the solution of the linear systems. We demonstrate convergence with respect to key parameters and verify the method’s accuracy by comparing with plane-wave results. We show that the framework achieves good strong scaling to many thousands of processors, reducing the time to solution for a lithium hydride system with 128 electrons to around 150 s on 4608 processors.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1998

Power Management and Distribution System Developed for Thermionic Power Converters

A spacecraft solar, bimodal system combines propulsion and power generation into a single integrated system. An Integrated Solar Upper Stage (ISUS) provides orbital transfer capabilities, power generation for payloads, and onboard propulsion to the spacecraft. A key benefit of a bimodal system is a greater payload-to-spacecraft mass ratio resulting in lower launch vehicle requirements. Scaling down to smaller launch vehicles increases space access by reducing overall mission cost. NASA has joined efforts with the Air Force Phillips Laboratory to develop enabling technologies for such a system. The NASA/Air Force bimodal concept uses solar concentrators to focus energy into an integrated power plant. This power plant consists of a graphite core that stores thermal energy within a cavity. An array of thermionic converters encircles the graphite cavity and provides electrical energy conversion functions. During the power generation phase of the bimodal system, the thermionic converters are exposed to the heated cavity and convert the thermal energy to electricity. Near-term efforts of the ISUS bimodal program are focused on a ground demonstration of key technologies in order to proceed to a full space flight test. Thermionic power generation is one key technology of the bimodal concept. Thermionic power converters impose unique operating requirements upon a power management and distribution (PMAD) system design. Single thermionic converters supply large currents at very low voltages. Operating voltages can vary over a range of up to 3 to 1 as a function of operating temperature. Most spacecraft loads require regulated 28-volts direct-current (Vdc) power. A combination of series-connected converters and powerprocessing boosters is required to deliver power to the spacecraft's payloads at this level.

Baez, Anastacio N.↗
DOE OSTI2024

N-Doped Graphene (N-G)/MOF(ZIF-8)-Based/Derived Materials for Electrochemical Energy Applications: Synthesis, Characteristics, and Functionality

In recent years, graphene-type materials originating from metal–organic frameworks (MOFs) or integrated with MOFs have exhibited notable performances across various applications. However, a comprehensive understanding of these complex materials and their functionalities remains obscure. While some studies have reviewed graphene/MOF composites from different perspectives, due to their structural–functional intricacies, it is crucial to conduct more in-depth reviews focusing on specific sets of graphene/MOF composites designed for particular applications. In this review, we thoroughly investigate the syntheses, characteristics, and performances of N-G/MOF(ZIF-8)-based/derived materials employed in electrochemical energy conversion and storage systems. Special attention is given to realizing their fundamental functionalities. The discussions are divided into three segments based on the application of N-G/ZIF-8-based/derived materials as electrode materials for batteries, electrodes for electrochemical capacitors, and electrocatalysts. As electrodes for batteries, N-G/MOF(ZIF-8) materials can mitigate issues like an electrode volume expansion for Li-ion batteries and the ‘shuttle effect’ for Li-S batteries. As electrodes for electrochemical capacitors, these materials can considerably improve the ion transfer rate and electronic conductivity, thereby enhancing the specific capacitance while maintaining the structural stability. Also, it was observed that these materials could occasionally outperform standard platinum-based catalysts for the electrochemical oxygen reduction reaction (ORR). The reported electrochemical performances and structural parameters of these materials were carefully tabulated in uniform units and scales. Through a critical analysis of the present synthesis trends, characteristics, and functionalities of these materials, specific aspects were identified that required further exploration to fully utilize their inherent capabilities.

Electrochemistry↗
DOE OSTI2017

Final technical report: SciDAC partnership "Predictive Computing for Condensed Matter"

Fundamental progress in energy technology depends critically on our ability to design, fabricate, characterize, and optimize advanced materials that can convert, transport, and store energies as well as display useful functions at minimum energy consumptions. To achieve this, we must first understand mechanisms underlying the functions and then be able to design materials with predicted properties. Unlike conventional structural materials, optoelectronic or magnetic materials for energy technology operate by quantum mechanical principles, which are hard to extract from experiments alone. Some representative unsolved problems of condensed-phase electronic structures in general include (1) the detailed mechanism of high-temperature superconductors such as cuprates and iron-arsenide materials; (2) the structures of solids in the presence of polymorphism; (3) excited states in solids and systematically accurate calculations of quasiparticle energy bands; (4) the structure of strongly correlated wave functions of solids. In this project, we aim at establishing general and predictive mathematical theories for solids and computational methods that implement them. We will then apply these methods to outstanding solid-state problems recognized by experimentalists including the above, with a view to solving them computationally. Hence, the project has the following three research objectives, all of which have been met: Predictive Electronic Structure Theories for Solids, Scalable Algorithms and Software, and Applications to Outstanding Condensed Matter Problems.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2013

Plasma channel produced by femtosecond laser pulses as a medium for amplifying electromagnetic radiation of the subterahertz frequency range

The electron energy distribution function in the plasma channel produced by a femtosecond laser pulse with a wavelength of 248 nm in atmospheric-pressure gases was considered. Conditions were determined whereby this channel may be employed for amplifying electromagnetic waves up to the terahertz frequency range over the energy spectrum relaxation time ∼10{sup -7} s. Gains were calculated as functions of time and radiation frequency. The effect of electron – electron collisions on the rate of relaxation processes in the plasma and on its ability to amplify the electromagnetic radiation was investigated. (interaction of laser radiation with matter)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

The carboxylation status of osteocalcin has important consequences for its structure and dynamics

The carboxylation status of Osteocalcin (Ocn) not only influences formation and structure in bones but also has important endocrine functions affecting energy metabolism and expenditure. In this study, the role of γ-carboxylation of the glutamate residues in the structure-dynamics-function relationship in Ocn is investigated. Three forms of Ocn, differentially carboxylated at the Glu-17, 21 and 24 residues, along with a mutated form of Ocn carrying Glu/Ala mutations, are modeled and simulated using molecular dynamics (MD) simulation in the presence of calcium ions. Characterization of the global conformational dynamics of Ocn, described in terms of the orientational variations within its 3-helical domain, highlights large structural variations in the non-carboxylated osteocalcin (nOcn). The bi-carboxylated Ocn (bOcn) and tri-carboxylated (tOcn) species, in contrast, display relatively rigid tertiary structures, with the dynamics of most regions strongly correlated. Radial distribution functions calculated for both bOcn and tOcn show long-range ordering of the calcium ion distribution around the carboxylated glutamate (γGlu) residues, likely playing an important role in promoting stability of these Ocns. Additionally, the same calcium ions are observed to coordinate with neighboring γGlu, better shielding their negative charges and in turn stabilizing these systems more than do the singly coordinating calcium ions observed in the case of nOcn. bOcn is also found to exhibit a more helical C-terminal structure, that has been shown to activate its cellular receptor GPRC6A, highlighting the allosteric role of Ocn carboxylation in modulating the stability and binding potential of the active C-terminal. Furthermore, the carboxylation status of Ocn as well and its calcium coordination appear to have a direct influence on Ocn structure and dynamics, possibly leading to the known differences in Ocn biological function.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Octahedral tilt transitions in the relaxor ferroelectric Na{sub 1/2}Bi{sub 1/2}TiO{sub 3}

The kinetics of octahedral tilt transitions in the lead-free relaxor material sodium bismuth titanate Na{sub 1/2}Bi{sub 1/2}TiO{sub 3} (NBT) is investigated by electronic structure calculations within density functional theory. Energy barriers for transitions between tetragonal, rhombohedral and orthorhombic tilts in cation configurations with [001]- and [111]-order on the A-sites are determined by nudged elastic band calculations. By tilting entire layers of octahedra simultaneously we find that the activation energy is lower for structures with 001-order compared to such with 111-order. The energetic coupling between differently tilted layers is, however, negligibly small. By introducing a single octahedral defect we create local tilt disorder and find that the deformation energy of the neighboring octahedra is less in a rhombohedral than in a tetragonal structure. By successively increasing the size of clusters of orthorhombic defects in a rhombohedral matrix with 001-order, we determine a critical cluster size of about 40 Å . Thus groups of about ten octahedra can be considered as nuclei for polar nanoregions, which are the cause of the experimentally observed relaxor behavior of NBT. - Graphical abstract: Nine orthorhombic oxygen octahedral tilt defects in a rhombohedral tilt configuration. - Highlights: • Chemical order influences energy barriers of octahedral tilt transitions. • The octahedral deformation energy is lower in rhombohedral phases. • Tilt defect clusters are more likely in rhombohedral structures. • Tilt defect clusters can act as nuclei for polar nanoregions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Mass separation of deuterium and helium with conventional quadrupole mass spectrometer by using varied ionization energy

Deuterium pressure in deuterium-helium mixture gas is successfully measured by a common quadrupole mass spectrometer (model: RGA200) with a resolution of ∼0.5 atomic mass unit (AMU), by using varied ionization energy together with new developed software and dedicated calibration for RGA200. The new software is developed by using MATLAB with the new functions: electron energy (EE) scanning, deuterium partial pressure measurement, and automatic data saving. RGA200 with new software is calibrated in pure deuterium and pure helium 1.0 × 10{sup −6}–5.0 × 10{sup −2} Pa, and the relation between pressure and ion current of AMU4 under EE = 25 eV and EE = 70 eV is obtained. From the calibration result and RGA200 scanning with varied ionization energy in deuterium and helium mixture gas, both deuterium partial pressures (P{sub D{sub 2}}) and helium partial pressure (P{sub He}) could be obtained. The result shows that deuterium partial pressure could be measured if P{sub D{sub 2}} > 10{sup −6} Pa (limited by ultimate pressure of calibration vessel), and helium pressure could be measured only if P{sub He}/P{sub D{sub 2}} > 0.45, and the measurement error is evaluated as 15%. This method is successfully employed in EAST 2015 summer campaign to monitor deuterium outgassing/desorption during helium discharge cleaning.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

Measurement of the $\textit{B}(\textit{E}2 ↑)$ strengths of 36 Ca and 38 Ca

In this work, the $B(E2, 0^+_1 → 2^+_1)$ strengths of 36 Ca and 38 Ca are measured to be 131(20) $e^2\text{fm}^4$ and 101(11) $e^2\text{fm}^4$, respectively. The $\textit{B}(\textit{E}2)$ value for 36 Ca required a measurement of the p/γ branching ratio because the 2 + state is proton unbound. This branching ratio is $B_p$=0.087(8). These $\textit{B}(\textit{E}2)$ and branching-ratio values can be reproduced in the shell-model with the ZMB2 interaction, an interaction that predicts the $\textit{Z} = 20 \textit{sd}$-shell closure is incomplete with large proton pf-shell occupancies in the ground state. These occupancies are at odds with other shell-model and energy-density-functional calculations of 36 Ca. New data are used to provide an update on constraints of the density dependence of the symmetry energy through mirror charge-radii differences as well as to help reduce uncertainties of the astrophysical important 35 K(p,γ) reaction.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2012

New solutions to the Dirac equation for particles in a magnetic field and a medium

We briefly review the application of the method of exact solutions of quantum equations for the description of charged particle motion in external fields. We develop a quantization technique by using the lowering and raising operators to describe the states of fermions moving in a magnetic field and a dense medium. For the first time we have posed and solved the problem of a charged fermion moving in a medium and an external magnetic field by taking into account the anomalous magnetic moment of the particle: we have obtained exact solutions for the wave functions and energy spectrum of the corresponding modified Dirac equation. We discuss a quasi-classic interpretation of the solutions obtained and, in particular, find a correction for the synchrotron radiation intensity dependent on medium density.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗