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NASA NTRS1981

Synergistic relationships among remote-sensing and geophysical media: Geological and hydrological applications

Skylab photographs, side-looking radar imagery, published soil maps, topographic maps, conventional aerial photography as well as LANDSAT imagery under wet and dry changes for several years were analyzed over selected areas in Minnesota to test their usefulness in detecting near-surface ground water. Results show that optical density read from LANDSAT data is not a reliable discriminator of depth to shallow ground water when one band of one scene is used alone, and is little improved when several bands of several scenes are used synergistically. The method is enhanced if information from soil maps is included in the analysis, especially for discriminating boggy ground from better drained areas. It appears, however, that in areas where soil maps and good topographic maps already exist, the depth to ground water can be predicted from those media as well as (if not better than) it can be predicted from remote imagery. The LANDSAT method used demonstrated no capability for recognizing deeper categories of ground water.

Southwick, D. L.↗

NASA NTRS2000

Geology of the V28 Quadrangle: Hecate Chasma, Venus

The Hecate Chasma Quadrangle (V28), mapped at 1:5,000,000 scale, extends from 0-25 N and 240-270 Longitude. The quadrangle has thirteen impact craters, several large volcanoes, many coronae, three chasmata, and northern Hinemoa Planitia.

Stofan, E. R.↗

NASA NTRS2021

Pluto’s Sputnik Planitia: Composition of geological units from infrared spectroscopy

We have compared spectroscopic data of Sputnik Planitia on Pluto, as acquired by New Horizons’ Linear Etalon Imaging Spectral Array (LEISA) instrument, to the geomorphology as mapped by White et al. (2017) using visible and panchromatic imaging acquired by the LOng-Range Reconnaissance Imager (LORRI) and the Multi-spectral Visible Imaging Camera (MVIC). We have focused on 13 of the geologic units identified by White et al. (2017), which include the plains and mountain units contained within the Sputnik basin. We divided the map of Sputnik Planitia into 15 provinces, each containing one or more geologic units, and we use LEISA to calculate the average spectra of the units inside the 15 provinces. Hapke-based modeling was then applied to the average spectra of the units to infer their surface composition, and to determine if the composition resulting from the modeling of LEISA spectra reflects the geomorphologic analyses of LORRI data, and if areas classified as being the same geologically, but which are geographically separated, share a similar composition. We investigated the spatial distribution of the most abundant ices on Pluto’s surface - CH4, N2, CO, H2O, and a non-ice component presumed to be a macromolecular carbon-rich material, termed a tholin, that imparts a positive spectral slope in the visible spectral region and a negative spectral slope longward of ~1.1 μm. Because the exact nature of the non-ice component is still debated and because the negative spectral slope of the available tholins in the near infrared does not perfectly match the Pluto data, for spectral modeling purposes we reference it generically as the negative spectral slope endmember (NSS endmember). We created maps of variations in the integrated band depth (from LEISA data) and areal mass fraction (from the modeling) of the components. The analysis of correlations between the occurrences of the endmembers in the geologic units led to the observation of an anomalous suppression of the strong CH4 absorption bands in units with compositions that are dominated by H2O ice and the NSS endmember. Exploring the mutual variation of the CH4 and N2 integrated band depths with the abundance of crystalline H2O and NSS endmember revealed that the NSS endmember is primarily responsible for the suppression of CH4 absorptions in mountainous units located along the western edge of Sputnik Planitia. Our spectroscopic analyses have provided additional insight into the geological processes that have shaped Sputnik Planitia. A general increase in volatile abundance from the north to the south of Sputnik Planitia is observed. Such an increase first observed and interpreted by Protopapa et al., 2017 and later confirmed by climate modeling (Bertrand et al., 2018) is expressed geomorphologically in the form of preferential deposition of N2 ice in the upland and mountainous regions bordering the plains of southern Sputnik Planitia. Relatively high amounts of pure CH4 are seen at the southern Tenzing Montes, which are a natural site for CH4 deposition owing to their great elevation and the lower insolation they are presently receiving. The NSS endmember correlates the existence of tholins within certain units, mostly those coating the low-latitude mountain ranges that are co-latitudinal with the tholin-covered Cthulhu Macula. The spectral analysis has also revealed compositional differences between the handful of occurrences of northern non-cellular plains and the surrounding cellular plains, all of which are located within the portion of Sputnik Planitia that is presently experiencing net sublimation of volatiles, and which do not therefore exhibit a surface layer of bright, freshly-deposited N2 ice. The compositional differences between the cellular and non-cellular plains here hint at the effectiveness of convection in entraining and trapping tholins within the body of the cellular plains, while preventing the spread of such tholins to abutting non-cellular plains.

Pluto's Sputnik Planitia↗

DOE OSTI2015

Update on site selection for Canada's national repository for used nuclear fuel - 15481

In 2007, the Government of Canada selected Adaptive Phased Management as Canada's plan that provides for long-term management of Canada's used nuclear fuel in a deep geological repository, located in an informed and willing host. The Nuclear Waste Management Organization is tasked through federal legislation to select the site and develop and manage all aspects of Canada's plan. In May 2010 the Nuclear Waste Management Organization published and initiated the site selection process that serves as a road map for decision-making on the location for the deep geological repository. The Nuclear Waste Management Organization continues to lead the site selection process for a deep geological repository for the long term management of Canada's used nuclear fuel and centre of expertise. The screening down process is advancing and, from an initial starting point of 22 communities expressing interest in learning about the project, as of November 2014 14 communities are now the focus of more detailed studies. Preliminary assessments are underway with these communities, which is the third step in the 9 step site selection process. Preliminary assessments involve preliminary technical and social desktop and field assessments, engagement activities within and beyond the interested community and seeking involvement of Indigenous peoples and nearby municipalities in the planning and conduct of the work. The paper provides an update on the advancement of the site selection process. It describes the nature of the technical and social studies being conducted at this phase of work, including the progressively more detailed field studies which are the focus of technical work at this stage, approach to engagement and collaboration with communities to direct these studies, and the work underway to ensure the framework used for this assessment and engagement includes the range of priorities and perspectives of First Nations and Metis peoples and communities in the broader area. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

NASA NTRS2018

The Geology of the Pluto System

NASA's New Horizons mission acquired a large set of images and other data making possible thorough geological analysis of landscapes in the Pluto System. Pluto and Charon exhibit strikingly different surface appearances, despite their similar densities and presumed bulk compositions. Systematic investigation, modelling and mapping revealed that much of Pluto's surface is attributed to surface-atmosphere interactions and the mobilization of volatile ices by insolation. Many mapped valley systems appear to be the consequence of glaciation involving nitrogen ice. Other geological activity requires or required long periods of internal heating, such as Pluto's extensive tectonic fabric. The convection and advection of volatile ices in Sputnik Planitia are thought to be powered by present-day radiogenic heat loss. The prominent mountains at the western margin of Sputnik Planitia, and the strange, multi-km-high mound features to the south, probably composed of H2O, are young geologically as inferred by light cratering and superposition relationships. These multi-km-high mound features might be cryo-volcanoes. Their origin, and what drove their formation so late in Solar System history, is under investigation. East of Sputnik Planitia are large fields of aligned ranks of sharp-crested ridges found only at high altitude that are apparently composed of massive deposits of CH4 ice, referred to as Bladed Terrain. New Horizons found evidence that Bladed Terrain may cover much of Pluto's low latitudes and may have originally formed there as a consequence of Pluto's very high obliquity. Currently Bladed Terrain is undergoing net erosion. This observation, along with evidence for formally more extensive nitrogen glaciation implies that Pluto undergoes significant climate evolution. The dynamic remolding of landscapes by volatile transport seen on Pluto is not unambiguously evident in the mapping of Charon. Charon does, however, display a large resurfaced plain and globally engirdling extensional tectonic network attesting to its early endogenic vigor.

Moore, J. M.↗

DOE OSTI2018

Final Report: Optimal Model Complexity in Geological Carbon Sequestration: A Response Surface Uncertainty Analysis

The critical component of a risk assessment study in evaluating GCS is an analysis of uncertainty in CO2 modeling. In such analyses, direct numerical simulation of CO2 flow and leakage requires many time-consuming model runs. Alternatively, analytical methods have been developed which allow fast and efficient estimation of CO2 storage and leakage, although restrictive assumptions on formation rock and fluid properties are employed. In this study, an intermediate approach is proposed based on the Design of Experiment and Response Surface methodology, which consists of using a limited number of numerical simulations to estimate a prediction outcome as a combination of the most influential uncertain site properties. The methodology can be implemented within a Monte Carlo framework to efficiently assess parameter and prediction uncertainty while honoring the accuracy of numerical simulations. The choice of the uncertain properties is flexible and can include geologic parameters that influence reservoir heterogeneity, engineering parameters that influence gas trapping and migration, and reactive parameters that influence the extent of fluid/rock reactions. The method was tested and verified on modeling long-term CO2 flow, non-isothermal heat transport, and CO2 dissolution storage by coupling two-phase flow with explicit miscibility calculation using an accurate equation of state that gives rise to convective mixing of formation brine variably saturated with CO2. All simulations were performed using three-dimensional high-resolution models including a target deep saline aquifer, overlying caprock, and a shallow aquifer. To evaluate the uncertainty in representing reservoir permeability, sediment hierarchy of a heterogeneous digital stratigraphy was mapped to create multiple irregularly shape stratigraphic models of decreasing geologic resolutions: heterogeneous (reference), lithofacies, depositional environment, and a (homogeneous) geologic formation. To ensure model equivalency, all the stratigraphic models were successfully upscaled from the reference heterogeneous model for bulk flow and transport predictions (Zhang & Zhang, 2015). GCS simulation was then simulated with all models, yielding insights into the level of parameterization complexity that is needed for the accurate simulation of reservoir pore pressure, CO2 storage, leakage, footprint, and dissolution over both short (i.e., injection) and longer (monitoring) time scales. Important uncertainty parameters that impact these key performance metrics were identified for the stratigraphic models as well as for the heterogeneous model, leading to the development of reduced/simplified models at lower characterization cost that can be used for the reservoir uncertainty analysis. All the CO2 modeling was conducted using PFLOTRAN – a massively parallel, multiphase, multi-component, and reactive transport simulator developed by a multi-laboratory DOE/SciDAC (Scientific Discovery through Advanced Computing) project (Zhang et al., 2017, in review). Within the uncertainty analysis framework, increasing reservoir depth were investigated to explore its effect on the uncertainty outcomes and the potential for developing gravity-stable injection with increased storage security (Dai et al., 20126; Dai et al., 2017, in review). Finally, to accurately model CO2 fluid-rock reactions and resulting long-term storage as secondary carbonate minerals, a modified kinetic rate law for general mineral dissolution and precipitation was proposed and verified that is invariant to a scale transformation of the mineral formula weight. This new formulation will lead to more accurate assessment of mineral storage over geologic time scales (Lichtner, 2016).

58 GEOSCIENCES↗

NASA NTRSDate not supplied

The Kinematic Navigation and Cartography Knapsack (KNaCK): Demonstrating SLAM (Simultaneous Localization and Mapping) LiDAR as a Tool for Exploration and Mapping of Lunar Pits and Caves.

Renewed interest in deep space exploration has made establishing a persistent human presence on the Moon and eventually Mars a priority. Sustained habitation of the Moon will require in-situ resource utilization (ISRU) and protection from radiation at the lunar surface. Lunar caves are of interest to the space community because they could provide shelter from radiation, access to water deposits, and a space for habitation, as well as hold information about the geology, volcanology, and evolution of the Moon. Developing the tools to explore, map, and characterize these voids is key to understanding the Moon as a planetary body and to establishing a permanent human presence there. Our team is currently developing tools that enable ultra-high resolution terrain mapping and navigation using mobile light detection and ranging (LIDAR) technology and simultaneous localization and mapping (SLAM) algorithms in fully GPS-denied and no-light environments. 3D mapping with LiDAR and SLAM is relatively under-used, particularly in the context of planetary exploration and planetary analog environments. The backpack mounted LiDAR instrument currently under development by the KNaCK (Kinematic Navigation and Cartography Knapsack) team has demonstrated the potential of mobile SLAM LiDAR for lunar, planetary, and terrestrial cave exploration, study, and utilization. A description of the instrument and associated SLAM algorithms used for mapping in GPS-denied environments are referenced here.

LiDAR↗

NASA NTRS2004

Mineral Mapping with AVIRIS and EO-1 Hyperion

Imaging Spectrometry data or Hyperspectral Imagery (HSI) acquired using airborne systems have been used in the geologic community since the early 1980 s and represent a mature technology (Goetz et al., 1985; Kruse et al., 1999). The solar spectral range, 0.4 to 2.5 m, provides abundant information about many important Earth-surface minerals (Clark et al., 1990). In particular, the 2.0 to 2.5 m (SWIR) spectral range covers spectral features of hydroxyl-bearing minerals, sulfates, and carbonates common to many geologic units and hydrothermal alteration assemblages. Previous research has proven the ability of airborne and spaceborne hyperspectral systems to uniquely identify and map these and other minerals, even in sub-pixel abundances (Kruse and Lefkoff, 1993; Boardman and Kruse, 1994; Boardman et al., 1995; Kruse, et al., 1999). This paper describes a case history for a site in northern Death Valley, California and Nevada along with selected SNR calculations/results for other sites around the world. Various hyperspectral mineral mapping results for this site have previously been presented and published (Kruse, 1988; Kruse et al., 1993, 1999, 2001, 2002, 2003), however, this paper presents a condensed summary of key details for hyperspectral data from 2000 and 2001 and the results of accuracy assessment for satellite hyperspectral data compared to airborne hyperspectral data used as ground truth.

Kruse, Fred A.↗

DOE OSTI2025

Optimizing Alabama’s CO 2 Storage in Shelby County (Project OASIS): Task 4.0 Deliverable – Geologic Analysis Report

Project OASIS (Optimizing Alabama’s CO 2 Storage in Shelby County) is a geologic and reservoir characterization study designed to evaluate deep saline formations for potential long-term carbon dioxide (CO 2 ) storage in central Alabama near the National Carbon Capture Center (NCCC) and Alabama Power’s Plant Gaston. The project centers on the Cambro-Ordovician Knox Group and underlying strata such as the Conasauga and Rome Formations, which were investigated through the drilling of two stratigraphic test wells to obtain electronic well logs, core, and sidewall core plugs. These data provide direct measurements of porosity, permeability, and lithologic variability critical for reservoir characterization. Complementing the well program, a limited 2D seismic survey was acquired to help select the site for Westover #2, and a more regional Seismic Exchange (SEI) seismic survey was licensed and interpreted to define structural and stratigraphic frameworks in a new Static Earth Model (SEM), map reservoir continuity, and identify potential sealing intervals. Integrated with geologic and reservoir modeling, these datasets form the basis for evaluating storage capacity, injectivity, and containment.

20 FOSSIL-FUELED POWER PLANTS↗

DOE OSTI2018

Discovery of a Blind Geothermal System in Southern Gabbs Valley, Western Nevada, through Application of the Play Fairway Analysis at Multiple Scales

The Great Basin region is capable of generating much greater amounts of geothermal energy than currently produced. Most geothermal resources in this region are blind, and thus favorable characteristics for geothermal activity must be synthesized and methodologies developed to discover new commercial-grade systems. The geothermal play fairway concept involves integration of multiple parameters indicative of geothermal activity to identify promising areas for new development. In the Nevada play fairway project, geologic, geochemical, and geophysical parameters were initially synthesized to produce a new geothermal potential map of 96,000 km2. Southern Gabbs Valley in western Nevada is a particularly promising site selected for detailed study. It contains favorable structural settings, including Quaternary fault intersections and a displacement transfer zone. Geologic, geophysical, and geochemical techniques were employed to define the most likely sites for high permeability and select targets for temperature-gradient holes. Permeability models were revised to reflect results of detailed analyses and generate new detailed play fairway maps. The most promising site lies in an area of multiple fault intersections in a broader displacement transfer zone directly north of the Petrified Springs dextral fault, as revealed by gravity, magnetic, and MT data. A 2-m temperature anomaly and warm temperature gradient wells (~120oC at ~150 m depth) confirm the presence of a geothermal system and provide initial validation of the play fairway methodology. The system is blind, with no surface hot springs, fumaroles, or paleo-geothermal deposits. Lessons learned in the detailed studies include: 1) initially identified sites commonly include multiple favorable settings at a finer scale; 2) promising sites in Cenozoic basins cannot be recognized without detailed geophysical surveys; and 3) play fairway analysis is critical at multiple scales.

15 GEOTHERMAL ENERGY↗

NASA NTRSDate not supplied

VALENTInE: A Concept for a New Frontiers Class Long Duration In-Situ Balloon Mission to Venus

Venus and Earth are similar in bulk composition, size, density, and approximate distance from the Sun, yet Venus’s modern-day climate and surface geology is distinctly different [1]. Previous missions to Venus revealed unusual volcanic features, possible continental crust, widespread volcanic plains, a weak magnetic field [2], and insights into the Venusian atmosphere [3,4]. Unfortunately, data from these missions were limited in spatial and temporal resolution and global extent. A future mission to Venus is critical to address fundamental questions surrounding the chemical composition and dynamics of the Venusian atmosphere [5], its geologic history [6,7], its internal structure [8,9], and its habitability throughout time [10,11]. We present the Venus Air and Land Expedition: a Novel Trailblazer for In situ Exploration (VALENTInE) mission to meet this need. VALENTInE is a variable altitude balloon that will passively float in Venus’s atmosphere between 45 and 55 km altitude. VALENTInE will acquire atmospheric data at varying latitudes and longitudes in addition to mapping the surface geomorphology and mineralogy across multiple terrains. Mission Objectives: The VALENTInE mission concept is driven by four main science objectives: 1. Determine whether the driving force of the superrotation of Venus’s atmosphere is caused by horizontal or vertical momentum transport. 2. Determine whether the atmospheric composition and noble gas inventory of the Venusian atmosphere is a product of outgassing from the initial protoplanetary source or if there are significant contributions from exogenic sources. 3. Determine whether the tesserae regions (particularly Aphrodite Terra) are felsic and relatively older than surrounding regions. 4. Determine if there is any evidence of a recent dynamo preserved in the rock record of Venus. Mission Overview: A balloon architecture provides a robust system that can survive long-term in the Venusian environment while taking accurate measurements of the lower cloud deck and surface. Two prior balloon missions to Venus, VEGA 1 and VEGA 2 in 1984, have demonstrated the potential for such planetary exploration; however, these missions were short-lived (46 hr), with limited range (54 km). Our spacecraft concept consists of a battery powered balloon with a gondola and flyby carrier stage (Fig. 1). Our novel design allows for at least 15 days of atmospheric exploration, including multiple ascents and descents in the Venus atmosphere. VALENTInE is baselined to launch in 2032, cruise on solar power for 128 days, enter, descend, and inflate (EDI) into Venus’s atmosphere above Aphrodite Terra, and float in Venus’s atmosphere for a total nominal mission duration of 15 days. The balloon, able to control its altitude by changing its buoyancy, will make one full circumnavigation every 4–8 days and move poleward ~1 o latitude per day; it will be passively directed by the horizontal air currents on Venus. The balloon can only be controlled in the z direction, and the expected latitude range is ±10° from EDI. The balloon itself will be a tracer for atmospheric structures such as zonal winds [5, 12]. During the 15-day operational period, there will be five dips to 45 km for a compositional study of the lower atmosphere and geological and magnetic mapping of the surface. Dips are used to take images and measurements closer to the surface and to obtain in situ vertical atmospheric profiles between 45 and 55 km. Instruments: The VALENTInE instrument payload will allow for extensive study of the geology, atmosphere, and interior of Venus. The instrument suite consists of six instruments. The mission profile for each instrument is shown in Fig. 2. Lower Atmosphere Meteorology Analyzer (LAMA) is an atmospheric structure instrument consisting of a thermometer, barometer, and accelerometer to continuously measure temperature and pressure as a function of altitude, longitude, and latitude. TracE and Noble Gas Investigator (TENGI) is aneutral mass spectrometer used to sample the dense atmosphere. TENGI will operate continuously at 45 km and 55 km and will measure D/H ratios, as well as Ne, Ar, and O isotopic ratios. Kilometer Scale Spectral Imager (KSSI) is amultispectral imager (850-1150 nm) used to resolve surface features on the order of km. Near InfraRed Multispectral Photometer (NIRMP) is an Infrared (IR) photometer used to image the surface through the clouds to characterize mineral assemblages at five different areas of the surface. NIRMP will be operated during dwell. ELevation REConnaissance (ELREC) is a light detection and ranging (LIDAR) instrument used for measuring topography at five different areas of the surface. The ELREC data will be combined with those of NIRMP to determine mineral assemblages and how they correlate to topography. Magnetic Exploration and Interior Detective (MEID) is a magnetometer used to detect any near-surface magnetic anomalies. The magnetometer will continuously operate at all altitudes. Mission Design: The spacecraft’s propulsion system will have a wet mass of 930 kg and will be launched on an Atlas V rocket. The spacecraft will jettison the payload upon arrival in Venus’s atmosphere before decelerating to orbital velocity. Figure 2. Notional power-dip profile while the balloon is on the dayside. Risks and Challenges: Raising and lowering the spacecraft to dip beneath the haze layer require a large amount of energy. This issue was partly compensated by limiting the number of dips over the 15 day prime mission. Power needs for pumping helium are reduced by slowing the descent speed, which consequently increases spatial resolution of in situ measurements between 45 and 55 km. The main limitation for the duration of the mission is the need to carry 15 days’ worth of batteries. The bus experiences external Venusian temperatures ranging from ~27°C at 55 km altitude to ~110°C at 45 km altitude. These high atmospheric temperatures require thermal protection for the bus (instruments, electronics, and flight systems) during its descent, dwell at 45 km, and ascent. The bus is maintained at a mechanically safe temperature range of -10°C to 50°C using white external paint, multi-layer insulation (MLI), mechanical/thermal isolation (e.g. Ti, composites), and ~57 kg of Phase Change Materials (PCM). Images and spectra taken below the haze dominate the available data transmission regardless of the time spent at 45 km. Therefore, less time at the lower altitude mainly reduces the coverage of in situ measurements there. Further, we assumed an unrealistically low-density material for the helium storage tanks on the gondola. However, this issue is partially resolved if we were to jettison 75% of the spent helium storage tanks. After the entry process, the balloon volume remains mostly inflated and storage tanks are required only for reducing balloon volume in dipping to 45 km. This mission was planned against an expected New Frontiers 5 (NF5) cost cap of $1B, as the NF5 call had not yet been released. The mission we describe fits within the predicted cost cap if the flyby carrier stage, responsible for powering the spacecraft during cruise and for relaying in situ measurements back to Earth, can be contributed by another space agency. Acknowledgments: We thank the JPL Planetary Science Summer School, especially A. Nash, J. Scully, K. Mitchell, L. Lowes, and J. Armijo, and our mentors from JPL Team X. Thank you to our review panel for their insightful review. References: [1] Kane, S. et al. (2019) JGR:Ps, 124 , 2015–2028. [2] Phillips, J. L., & Russell, C. T. (1987). JGR: Space Physics , 92 (A3), 2253-2263. [3] Nakamura, M. et al. (2018) Earth Planets Space, 70 (1), 144. [4] Svedhem, H. et al. (2009) JGR:P 114 (E5). [5] Limaye et al. (2009) Decadal Survey White Paper . [6] Ivanov, M. and Head, J. (2011) PSS, 59 (13) , 1559-1600. [7] Smrekar, S. et al. (2018) Space Sci Rev, 214 (5), 88. [8] O’Rourke, J. et al. (2018) EPSL, 502 , 46-56. [9] O’Rourke J. et al. (2019) GRL , (46), 5768–5777 [10] Way, M. et al. (2016) GRL, 43 (16), 8376-8383. [11] Way, M. et al. (2020) JGR:P, 125 (5), e2019JE006276. [12] Preston, R. A. et al. (1986) Science, 231 (4744), 1414-1416.

Mission Concept↗

DOE OSTI2020

Structural Characterization of Potential Carbon Dioxide Reservoirs and Adjacent Strata within the Llandovery Silurian to Middle Devonian Strata of Ohio

The Midwest Regional Carbon Sequestration Partnership (MRCSP) has incorporated the work of geologic research teams (Geoteams) in its regional characterization, project planning and carbon dioxide (CO 2 ) injection implementation work since the partnership was established by the U.S. Department of Energy (DOE) in 2003. Over this 16-year period, the cohort of Geoteams has grown from five to ten states and has contributed to the characterization of geologic sequestration opportunities, refinement of reservoir and seal data, and supported injection efforts through both predictive and post-injection assessments. This report details the work led by the Ohio Department of Natural Resources, Division of Geological Survey to evaluate the structure of nine formations in the Appalachian Basin of Ohio to assess seal integrity and whether carbon dioxide (CO 2 ) migration pathways could pose a potential risk. As part of Phase II MRCSP work, the Pennsylvania Geological Survey led the characterization of the Llandovery Silurian (“middle Silurian”) to Middle Devonian regional geologic characterization CO 2 utilization and storage. This preliminary assessment included generalized, regional-scale mapping, as well as the development of relatively coarse structure and isochore maps of stratigraphic intervals of interest for the Appalachian Basin. Because this stratigraphic interval offers several enhanced oil recovery targets and secondary targets for CO 2 storage, the Ohio Geological Survey undertook efforts in Phase III to characterize the Ohio’s portion of the Appalachian Basin more precisely and to resolve inconsistencies within Ohio’s formation tops. This study refined the subsurface correlations of the Silurian-through-Devonian stratigraphic section in Ohio. Higher-resolution isochore mapping of the CO 2 storage reservoirs and seals provides greater detail of potential high-porosity zones and potential structural influence on the interval.

01 COAL, LIGNITE, AND PEAT↗

NASA NTRS2007

NanoSIMS opens a New Window for Deciphering Organic Matter in Terrestrial and Extraterrestrial Samples

Recognition of the earliest morphological or chemical evidence of terrestrial life has proved to be challenging, as organic matter in ancient rocks is commonly fragmentary and difficult to distinguish from abiotically-produced materials (Schopf, 1993; Van Zuilen et al., 2002; Altermann & Kazmierczak, 2003; Cady et al., 2003; Brasier et al., 2002, 2004, 2005; Hofmann, 2004; Skrzypczak et al., 2004, 2005). Yet, the ability to identify remnants of earliest life is critical to our understanding of the timing of life's origin on earth, the nature of earliest terrestrial life, and recognition of potential remnants of microbial life that might occur in extraterrestrial materials. The search for earliest life on Earth now extends to early Archean organic remains; these tend to be very poorly preserved and considerably more difficult to interpret than the delicately permineralized microfossils known from many Proterozoic deposits. Thus, recent efforts have been directed toward finding biosignatures that can help distinguish fragmentary remnants of ancient microbes from either pseudofossils or abiotic organic materials that may have formed hydrothermally or in extraterrestrial processes (House et al., 2000; Boyce et al., 2001; Kudryavtsev et al., 2001; Schopf, 2002; Schopf et al., 2002, 2005a,b; Cady et al., 2003; Garc a-Ruiz et al., 2003; Hofmann, 2004; Brasier et al., 2005; Rushdi and Simoneit, 2005; Skrzypczak et al., 2005). An exciting area of biosignature research involves the developing technology of NanoSIMS. NanoSIMS is secondary ion mass spectrometry (SIMS) for ultrafine feature, elemental and isotopic analysis. Its resolution approaches 0.05 micrometers for element mapping, which is 10-50 times finer than that attainable with conventional SIMS or electron microprobes. Consequently, NanoSIMS has the potential to reveal previously unknown, chemical and structural characteristics of organic matter preserved in geologic materials. Robert et al. (2005) were the first to combine NanoSIMS element maps with optical microscopic imagery in an effort to develop a new method for assessing biogenicity. They showed that the ability to simultaneously map the distribution of organic elements [such as carbon (C), nitrogen (N), and sulfur (S)] and compare those element distributions with optically recognizable, cellularly preserved fossils could provide significant new insights into the origin of organic materials in ancient sediments. This chapter details a recent NanoSIMS study which was designed to acquire new data relevant to establishing critical biosignatures (Oehler et al., 2006a-c). In this study, NanoSIMS was used to characterize element distributions of spheroidal and filamentous microfossils and associated organic laminae in chert from the approx. 0.85 billion year old (Ga) Bitter Springs Formation of Australia. Previous work established preservation of a diverse microbiota in the Bitter Springs Formation (Schopf, 1968; Schopf and Blacic, 1971), and there is no dispute within the scientific community regarding the biogenicity of any of the Bitter Springs structures evaluated in this new study. Thus, the NanoSIMS results described below provide new insight into - and can be used as a guide for assessing - the origin of less well understood organic materials that may occur in early Archean samples and in meteorites or other extraterrestrial samples.

Oehler, Dorothy ZS.↗

DOE OSTI2024

Exploring Geothermal Potential of Great Basin Sub-Regions: Preprint

The INnovative Geothermal Exploration through Novel Investigations Of Undiscovered Systems (INGENIOUS) project aims to discover new, economically viable hidden geothermal systems in the Great Basin region by building on previous work in play fairway analysis and machine learning. A key objective of this project is to develop an exploration workflow to reduce geothermal exploration risks for hidden geothermal systems. A single preliminary play fairway workflow was developed from the assessment of the regional INGENIOUS geological, geophysical, and geochemical datasets. This workflow provided new preliminary predictive geothermal fairway maps for the INGENIOUS study area, which encompasses most of Nevada, western Utah, southern Idaho, southeastern Oregon, and easternmost California. However, a recent study (incorporating machine learning techniques) of a portion of Nevada identified four geologic domains and determined that the relative importance of individual datasets or features as indicators of geothermal potential may differ across these domains. The INGENIOUS study area includes a much larger and more geologically diverse region; therefore, additional geologic domains or sub-regions are expected. To assess the sub-regions in the INGENIOUS study area, principal component analysis and k-means clustering were applied. Preliminary results indicate that the INGENIOUS regional data cluster into groups that relate to different geologic domains in the Great Basin region. These include domains such as the Walker Lane, extensional western Great Basin region, broad lower strain region in the eastern Great Basin of western Utah and eastern Nevada, Quaternary volcanic fields, and the area adjacent to the Snake River Plain. These clusters are assessed to determine the key geologic drivers of the identified clusters. Understanding this variability can provide key insights for the exploration and characterization of hidden geothermal systems in the Great Basin region and could indicate the need to develop multiple geothermal conceptual models and play fairway workflows for the INGENIOUS study area.

GEOTHERMAL ENERGY↗

DOE OSTI2025

Exploring Geothermal Potential of Great Basin Sub-Regions

exploration↗

DOE OSTI2019

Vectoring into Potential Blind Geothermal Systems in the Granite Springs Valley Area, Western Nevada: Application of the Play Fairway Analysis at Multiple Scales

The Great Basin region of the western USA is capable of generating much greater amounts of geothermal energy than currently produced. Most geothermal resources in this region are blind, and thus the favorable characteristics for geothermal activity must be synthesized and methodologies developed to discover new commercial-grade systems. The geothermal play fairway concept involves integration of multiple parameters indicative of geothermal activity as a means of identifying promising areas for new development. In the Nevada play fairway project, nine geologic, geochemical, and geophysical parameters were initially synthesized to produce a new geothermal potential map of 96,000 km2. Granite Springs Valley in western Nevada is a particularly promising site selected for detailed study. It contains several favorable structural settings, including terminations of major Quaternary normal faults and fault intersections. Geologic, geophysical, and geochemical techniques were employed to define the most likely sites for high permeability and select drilling targets for temperature-gradient holes. Local and intermediate permeability models were revised to reflect results of detailed analyses and generate new detailed play fairway maps of the area. The most promising site lies in the northeastern part of the basin directly east of Adobe Flat, where the horse-tailing termination of a major normal fault (as revealed by new gravity data), opaline sinter deposits, warm shallow wells, and a low-resistivity anomaly are collocated. Geothermometry suggests a blind system with temperatures as high as ~130°C in this area. Four new temperature-gradient holes document temperatures of ~80°C at ~150 m depth. Lessons learned in the detailed studies of this project include: 1) initially identified sites commonly include multiple favorable settings at a finer scale; 2) promising sites in Cenozoic basins cannot be well defined without detailed geophysical surveys; and 3) play fairway analysis is critical at multiple scales, providing a means to select regional prospects as well as vectoring into drilling targets at individual sites.

15 GEOTHERMAL ENERGY↗

DOE OSTI2020

Analysis of Geothermal Resources in Three Texas Counties

This project updates the geothermal resources beneath our oil and gas fields, as part of the research for the Texas GEO project. This report "Analysis of Geothermal Resources in Three Texas Counties" (October 2020) improves on previous mapping of the Texas resources for the counties of Crockett (West Texas), Jackson (central Gulf Coast) and Webb (South Texas). Through additional bottom-hole temperatures (BHT), the number of well sites increased from 532 to 5,410 in total for these counties. The improved methodology to calculate formation temperatures from 3.5 km (11,500 ft) to 10 km (32,800 ft) includes thermal conductivity values more closely related to the actual county geological formations, incorporated radiogenic heat production of formations, and the related mapped depth to basement. The results show deep temperatures as hotter than previously calculated, with temperatures of 150 degrees Celcius possible for Webb County between depths of 2.6 - 5.1 km, Jackson County between depths 3.0 - 5.4 km, and Crockett County between depths of 2.7 - 8.0 km.

10 km↗

NASA NTRS1975

Present and potential land use mapping in Mexico

The Mexican Water Plan (MWP) conducted studies of present and potential land use in Mexico using LANDSAT-1 satellite imagery. Present land use studies were carried out all over the country (197 million hectares); nine soil uses were mapped according to the first classification level recommended by the U.S. Geological Survey. Also 6.3 million hectares of land with advanced erosion were detected. Work was executed at a rate of 8 million hectares per month; reliability was 90% and the cost of only 0.1 cents/hectare. The potential land use study was performed in 45 million hectares at a rate of 4 million hectares per month and at a cost of 0.33 cents/hectare. Soil units according to FAO classification were delineated scale 1:1 million; interpretative maps were also prepared dealing with potential agricultural productivity carrying capacity for cattle, water, erosion risk, and slope ranges.

Garduno, H.↗