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At least 1,189 records · Page 66

Determination of the spectral absorption of solar radiation by marine stratocumulus clouds from airborne measurements within clouds

Results of the first experimental application of the diffusion domain method to the determination of the spectral similarity parameter, and hence the single scattering albedo, of clouds are presented. The angular distribution of scattered radiation deep within a cloud layer at discrete wavelengths between 0.5 and 2.3 microns was measured by a multiwavelength scanning radiometer. The relative angular distribution of the intensity field at each wavelength was used to determine the similarity parameter of the cloud at that wavelength utilizing the diffusion domain method. Results of the analysis are presented for a 50 km section of clean marine stratocumulus clouds over the coast of California on July 10, 1987. It is concluded that the measured absorption is close to, but persistently larger than, theoretical predictions.

King, Michael D.↗

Solar Wind Charge Exchange and Local Hot Bubble X-Ray Emission with the DXL Sounding Rocket Experiment

The Diffuse X-ray emission from the Local Galaxy (DXL) sounding rocket is a NASA approved mission with a scheduled first launch in December 2012. Its goal is to identify and separate the X-ray emission of the SWCX from that of the Local Hot Bubble (LHB) to improve our understanding of both. To separate the SWCX contribution from the LHB. DXL will use the SWCX signature due to the helium focusing cone at 1=185 deg, b=-18 deg, DXL uses large area propostionai counters, with an area of 1.000 sq cm and grasp of about 10 sq cm sr both in the 1/4 and 3/4 keY bands. Thanks to the large grasp, DXL will achieve in a 5 minule flight what cannot be achieved by current and future X-ray satellites.

Galeazzi, M.↗

Solar Wind Implantation into Lunar Regolith: Hydrogen Retention in a Surface with Defects

Solar wind protons are implanted directly into the top 100 nm of the lunar near-surface region, but can either quickly diffuse out of the surface or be retained, depending upon surface temperature and the activation energy, U, associated with the implantation site. In this work, we explore the distribution of activation energies upon implantation and the associated hydrogen-retention times; this for comparison with recent observation of OH on the lunar surface. We apply a Monte Carlo approach: for simulated solar wind protons at a given local time, we assume a distribution of U values with a central peak, U(sub c) and width, U(sub w), and derive the fraction retained for long periods in the near-surface. We find that surfaces characterized by a distribution with predominantly large values of U (greater than 1 eV) like that expected at defect sites will retain implanted H (to likely form OH). Surfaces with the distribution predominantly at small values of U (less than 0.2 eV) will quickly diffuse away implanted H. However, surfaces with a large portion of activation energies between 0.3 eV less than U less than 0.9 eV will tend to be H-retentive in cool conditions but transform into H-emissive surfaces when warmed (as when the surface rotates into local noon). These mid-range activation energies give rise to a diurnal effect with diffusive loss of H at noontime.

regolith↗

Effects of particle drift on cosmic ray transport. II - Analytical solution to the modulation problem with no latitudinal diffusion

An analytical solution to a model of the modulation of galactic cosmic rays in the presence of particle drifts is presented and discussed. The solution assumes an energy-independent radial diffusion coefficient proportional to distance and no latitudinal diffusion, and includes energy-independent particle drift velocities similar to those expected in a Parker spiral magnetic field with an equatorial current sheet. The solutions clearly demonstrate the large effects of drifts on the modulated cosmic-ray intensity. For values of the radial diffusion coefficient and particle drift velocity which are plausible for 1-GV-rigidity protons, the logarithmic radial gradient in the inner solar system is reduced by more than a factor of 5 over the value calculated in the absence of drifts. It is found that even for much smaller values of particle drift velocity and radial diffusion coefficient, such as might be expected for protons with energies of the order of 10 MeV, the effects of the drifts can be substantial.

Isenberg, P. A.↗

Transformation of TiN to TiNO Films via In-Situ Temperature-Dependent Oxygen Diffusion Process and Their Electrochemical Behavior

Titanium oxynitride (TiNO) thin films represent a multifaceted material system applicable in diverse fields, including energy storage, solar cells, sensors, protective coatings, and electrocatalysis. This study reports the synthesis of TiNO thin films grown at different substrate temperatures using pulsed laser deposition. A comprehensive structural investigation was conducted by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Non-Rutherford backscattering spectrometry (N-RBS), and X-ray absorption spectroscopy (XAS), which facilitated a detailed analysis that determined the phase, composition, and crystallinity of the films. Structural control was achieved via temperature-dependent oxygen in-diffusion, nitrogen out-diffusion, and the nucleation growth process related to adatom mobility. The XPS analysis indicates that the TiNO films consist of heterogeneous mixtures of TiN, TiNO, and TiO2 phases with temperature-dependent relative abundances. The correlation between the structure and electrochemical behavior of the thin films was examined. The TiNO films with relatively higher N/O ratio, meaning less oxidized, were more electrochemically active than the films with lower N/O ratio, i.e., more oxidized films. Films with higher oxidation levels demonstrated enhanced crystallinity and greater stability under electrochemical polarization. These findings demonstrate the importance of substrate temperature control in tailoring the properties of TiNO film, which is a fundamental part of designing and optimizing an efficient electrode material.

Cherono, Sheilah↗

The modulation of low energy galactic cosmic rays

It has been clearly established by several different experiments that following the last solar maximum (about 1969), there was a significant phase lag or hysteresis effect between changes in the low rigidity galactic cosmic rays and the high rigidity components. It was possible to explain this in terms of the diffusion-convection-modulation theory by varying either the diffusion coefficient or the size of the modulation region as a function of time. During the ensuing recovery phase of the solar modulated spectra, at the mid point toward the minimum of the solar activity, new striking features have been observed, and these new observations are discussed.

Van Hollebeke, M. A. I.↗

Turbulent diffusivity

A method for determining the turbulent diffusivity tensor is proposed which has application to problems such as the mixing in the interior of the sun for the solar neutrino problem, the chemical evolution of the galaxy, and grain sedimentation on the primitive solar nebula. A model for determining the turbulent energy spectral function, the eddy decorrelation rate, and the growth rate of the underlying instability is discussed. Good agreement is obtained between the present values for the coefficient of turbulent diffusivity and those obtained from both numerical simulation studies and laboratory data on shear turbulence.

Canuto, V. M.↗

The role of magnetic helicity in cosmic ray transport theory

The pitch angle scattering of cosmic ray is modified greatly if the medium through which they propagate contains significant amounts of magnetic helicity. When helicity is present in the medium, the often used expression for the pitch angle diffusion coefficient derived from quasilinear theory must be modified. These modifications are illustrated for slab and isotropic symmetries. Using measurements of helicity in the solar wind determined from single point measurements of the correlation tensor of magnetic fluctuations obtained from Voyager 2, the effects of the observed helicity on both the pitch angle and spatial diffusion coefficients are estimated.

Goldstein, M. L.↗

Tidal influences on vertical diffusion and diurnal variability of ozone in the mesosphere

Possible dynamical influences on the diurnal behavior of ozone are investigated. A time dependent one-dimensional photochemical model is developed for this purpose; all model calculations are made at 70 deg N during summer. It is shown that the vertical diffusion can vary as much as 1 order of magnitude within a day as a result of large changes in the zonal wind induced by atmospheric thermal tides. It is found that by introducing a dissipation time scale for turbulence produced by breaking gravity waves, the agreement with Poker Flat echo data is improved. Comparisons of results from photochemical model calculations, where the vertical diffusion is a function of height only, with those in which the vertical diffusion coefficient is changing in time show large differences in the diurnal behavior of ozone between 70 and 90 km. By including the dynamical effect, much better agreement with the Solar Mesosphere Explorers data is obtained. The results are, however, sensitive to the background zonally averaged wind. The influence of including time-varying vertical diffusion coefficient on the OH densities is also large, especially between 80 and 90 km. This suggests that dynamical effects are important in determining the diurnal behavior of the airglow emission from the Meinel bands.

Bjarnason, Gudmundur G.↗

Process for utilizing low-cost graphite substrates for polycrystalline solar cells

Low cost polycrystalline silicon solar cells supported on substrates were prepared by depositing successive layers of polycrystalline silicon containing appropriate dopants over supporting substrates of a member selected from the group consisting of metallurgical grade polycrystalline silicon, graphite and steel coated with a diffusion barrier of silica, borosilicate, phosphosilicate, or mixtures thereof such that p-n junction devices were formed which effectively convert solar energy to electrical energy. To improve the conversion efficiency of the polycrystalline silicon solar cells, the crystallite size in the silicon was substantially increased by melting and solidifying a base layer of polycrystalline silicon before depositing the layers which form the p-n junction.

Chu, T. L.↗

Studies of the release of radiogenic Xe-129 from Bjurboele: Evidence against simple diffusion models

The I-Xe system, based on the decay of 15.7 Ma I-129, is a potentially precise chronometer of early solar system events. However, it is not known how the system responded to thermal events during the post-formation histories of ordinary chondrites, severely limiting the usefulness of this system. Isothermal experiments on Bjurbole for different heating durations suggest that at least three domains are responsible for the thermal release of radiogenic Xe-129 (Xe*-129) and that the system may be less susceptible to thermal resetting than some calculations indicated. Two scenarios for the release of Xe*-129 were proposed. In one, the mobility of Xe*-129 is governed by diffusion in mineral grains. This leads to predicted closure temperatures comparable to, or less than, metamorphic temperatures. In the second, mineral grains that solidified at specific temperatures trapped I-129 within them, and the resulting Xe*-129 is only released when those minerals melt, such that isotopic closure occurs at the temperature of solidification.

Burkland, M. K.↗

Improved solar models constructed with a formulation of convection for stellar structure and evolution calculations without the mixing-length theory approximations

We have updated a previous attempt to incorporate within a solar model a treatment of convection based upon numerical simulations of convection rather than mixing-length theory (MLT). We have modified our formulation of convection for a better treatment of the kinetic energy flux. Our solar model has been updated to include a complete range of OPAL opacities, the Debye-Hueckel correction to the equation of state, helium diffusion due to gravitational settling, and atmospheres by Kurucz. We construct a series of models using both MLT and our revised formulation of convection and the compared results to measurements of the solar radius, the solar luminosity, and the depth of the solar convection zone as inferred from helioseismology. We find X(solar) = 0.702 +/- 0.005, Y(solar) = 0.278 +/- 0.005, and Z(solar) = 0.0193 +/- 0.0005.

Lydon, Thomas J.↗

The local characteristic function of interplanetary particle propagation

An easily measurable intensity function which characterizes the interplanetary propagation of charged solar flare particles is presented. This function is nearly time invariant during a solar event despite the large variations of intensity and anisotropy, but varies from event to event. It characterizes the systematic and stochastic forces of the interplanetary magnetic field which focus and scatter the particles in pitch angle. The model of focused transport shows that this function is essentially determined by the local shape and amplitude of the pitch angle diffusion coefficient kappa (mu) and by the local value of the focusing length. The time profile of the solar particle injection is typically of negligible influence. The local characteristic function may be used as a powerful new tool for a systematic analysis of flare particle angular distributions, Examples are given.

Green, G.↗

What Is a Polyolefin? A Critical Overview of Ethylene Copolymers Used as Solar Photovoltaic Module Encapsulants

In recent years, photovoltaic (PV) encapsulant films marketed as polyolefins (POs), more specifically as PO elastomers (POEs) and thermoplastic POs (TPOs), have gained significant market share and are projected to become the dominant encapsulation films by 2030. Relative to other industries, there are significant misconceptions about the term PO in the PV industry. Both in the scientific literature as well as in sales and advertising, the terms PO, POE, and TPO are often misused to describe the same type of material with comparable properties, while in reality these may each consist of separate material classes. This paper provides a comprehensive literature and market review, to showcase a broad range of PO and other ethylene copolymer encapsulants from recent studies, and discusses the materials' properties to clarify what constitutes a “polyolefin.” In addition, to promote a clearer comparison of encapsulant properties, we propose a two‐dimensional taxonomy to categorize polymers used in module manufacturing, including POs. In terms of improving the reliability of solar PV modules, PO‐based encapsulants have several advantages (including lower water uptake and ion diffusion), but might come with disadvantages too, such as a more complex processing and a higher sensitivity to the storage conditions and shelf life. All this might prospectively impact adhesion properties of the encapsulant to other materials' interfaces (glass, cells etc.) and end‐product quality. Because the track record of field‐deployed PV modules containing PO encapsulants is also limited, we hope to contribute to better material understanding and precision in communication in PV to secure quality.

14 SOLAR ENERGY↗

A study of equatorial inner belt protons from 2 to 200 MeV

The diffusion theory of inner belt protons is extended to lower energies for comparison with the data of Hovestadt et al. The effects of Coulomb energy loss, nuclear inelastic scattering, and the secular decrease of the earth's magnetic field are included. The Farley and Walt solar cycle averaged atmosphere and a neutron source based on the most recent measurements are used. It is found that diffusion theory can account for the observed flux of low-energy protons provided that the diffusion coefficient increases at smaller values of the first invariant. This result is interpreted as additional evidence for the importance of electrostatic field fluctuations in causing radial diffusion.

Claflin, E. S.↗

Scatter-free collimated convection and cosmic-ray transport at 1 AU

Observations of solar cosmic rays between 0.1 MeV and 1 GeV are more consistent with scatter-free than diffusive propagation near 1 AU. Since these particles also are constrained to interplanetary magnetic field lines, the parallel and transverse flow are decoupled by collimated convection. Local propagation is therefore more appropriately described by Liouville's equation, and transport properties can be examined from the exact zeroeth and first moments of the equation averaged over all directions in momentum space. Observational results which may be explained directly without invoking local scattering include the decay of solar flare events as well as the radial gradient, diurnal and semidiurnal variation of galactic cosmic rays.

Roelof, E. C.↗

Interfacial stabilization for inverted perovskite solar cells with long-term stability

Perovskite solar cells (PSCs) commonly exhibit significant performance degradation due to ion migration through the top charge transport layer and ultimately metal electrode corrosion. Here, we demonstrate an interfacial management strategy using a boron chloride subphthalocyanine (Cl 6 SubPc)/fullerene electron-transport layer, which not only passivates the interfacial defects in the perovskite, but also suppresses halide diffusion as evidenced by multiple techniques, including visual element mapping by electron energy loss spectroscopy. As a result, we obtain inverted PSCs with an efficiency of 22.0% (21.3% certified), shelf life of 7000 h, Τ 80 of 816 h under damp heat stress (compared to less than 20 h without Cl 6 SubPc), and initial performance retention of 98% after 2000 h at 80 °C in inert environment, 90% after 2034 h of illumination and maximum power point tracking in ambient for encapsulated devices and 95% after 1272 h outdoor testing ISOS-O-1. Our strategy and results pave a new way to move PSCs forward to their potential commercialization solidly.

14 SOLAR ENERGY↗

Solar Wind Strahl Broadening by Self-Generated Plasma Waves

This Letter reports on the results of numerical simulations which may provide a possible explanation for the strahl broadening during quiet solar conditions. The relevant processes involved in the broadening are due to kinetic quasi-linear wave-particle interaction. Making use of static analytical electron distribution in an inhomogeneous field, it is found that self-generated electrostatic waves at the plasma frequency, i.e., Langmuir waves, are capable of scattering the strahl component, resulting in energy and pitch-angle diffusion that broadens its velocity distribution significantly. The present theoretical results provide an alternative or complementary explanation to the usual whistler diffusion scenario, suggesting that self-induced electrostatic waves at the plasma frequency might play a key role in broadening the solar wind strahl during quiet solar conditions.

strahl↗