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System design and analysis of thermal power dispatch systems for boiling water reactors

Nuclear power plants are crucial to meeting net zero emission goals and achieving energy sustainability. Integrating these plants with clean energy technologies such as high-temperature steam electrolysis (HTSE) may improve the efficiency and economic competitiveness of these plants. Here, the current study investigates the design and operation of a thermal power dispatch (TPD) system for coupling boiling water reactors (BWRs) to HTSE plants. The TPD system extracts a portion of the steam from the reactor’s main steam line and transfers its thermal energy to an HTSE plant through a power transport loop. A TPD system for 5 % steam extraction has been designed and the system performance during steady and transient operations has been analyzed. The TPD system dispatched a total of 197 MW thermal energy to the HTSE plant under nominal design conditions. Saturated steam at 7.17 MPa from the BWR plant was condensed and subcooled to a temperature of 168 °C, while a mass flow rate of 91.1 kg/s of superheated steam was dispatched to the HTSE plant. Furthermore, the system performance during transient operation showed a continuous transition from the initial hot standby mode to the nominal power dispatch level. The transient simulation results emphasized the importance of investigating component level performance for the TPD system design. The current results will guide future works on the development of integrated energy systems for hydrogen production or process heat applications.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Experimental Determination of PV Inverter Response to Grid Phase Shift Events: Preprint

With the continued growth of renewable energy resources which interface to the electric grid via inverters, the understanding of such devices becomes ever more important to the safe and reliable operation of the bulk power system. This work investigates the specific response of a utility-scale PV inverter to grid voltage phase shift-type disturbances which sometimes occur during grid fault events. The role of the PV inverter's phase-locked-loop (PLL) is identified as important to modeling the response. Switching-level simulations of a utility-scale PV inverter with a modeled PLL show a characteristic response when phase shift disturbances require the PLL to track what appear as fast frequency changes. Additionally, in this work a full-scale laboratory testing was carried out using the Opal real time (RT) OP5142 real time simulator and a large grid simulator to create phase shift disturbances with a high degree of repeatability. A photovoltaic (PV) inverter was connected to a grid simulator, and phase shifts were instantaneously implemented on the simulated grid, the results of the currents were then obtained. The experimental results obtained were validated with simulation results obtained from MATLAB/Simulink.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Design of a Structure for Assembly and Cooling the Magnet of the Next-Generation 45 GHz ECR Ion Source MARS-D

Here, the current Electron Cyclotron Resonance Ion Sources (ECRISs), constructed with Nb-Ti wires and the conventional racetrack-and-solenoid structure, have achieved operating frequencies up to 28 GHz and utilized about 90% of the critical current of the Nb-Ti wire. A Mixed Axial and Radial field System Demonstrator (MARS-D) is being developed at Lawrence Berkeley National Laboratory (LBNL). This system, which consists of an innovative hexagonal Closed-Loop Coil (CLC) and a set of solenoids, can generate higher magnetic fields (up to 150% ) while requiring only about 50% of the superconducting wire, enabling Nb-Ti wires to be used in the next-generation 45 GHz ECRIS. However, the assembly and cooling of such an efficient and compact magnet are particularly challenging due to the small radial gap between the CLC and solenoids, as well as the tight operating temperature margin. To address these challenges, a structure was developed that combines a three-section radially split solenoid mandrel with a series of shrink-fit reinforcement rings and cooling channels. This paper presents the detailed structure, manufacturing method, assembly procedure, impregnation method, mechanical Finite Element Analysis (FEA) comparison, and thermal FEA comparison.

ECR ion sources↗

Using Lag Compensator in Orbit Feedback

Growing demand on the beam orbit stability requires higher loop gain inside the operational bandwidth. However, increasing the gain leads to the increase of the unity gain frequency and problems with systems stability due to the additional phase shifts caused by the trims (power supplies, eddy currents in vacuum chambers, etc.) and filtering of beam position data. Conventionally employed systems have 20 dB/decade slope near the unity gain providing 90 degrees phase shift which is sufficient for stability. Increase of the slope to 40 dB/decade by adding additional pole into the signal chain increases the phase shift to 180 degrees and makes system unstable. Utilizing one or more lag compensators allows to increase the gain while keeping phase margin acceptable. The paper provides more details on the proposed solution as well as simulations of how the transients will be modified.

43 PARTICLE ACCELERATORS↗

Thermal management system options for high power space platforms

Thermal Management System (TMS) design options for a high power (75kWe), low earth orbit, multimodule space platform were investigated. The approach taken was to establish a baseline TMS representative of current technology, and to make incremental improvements through successive subsystem trades that lead to a candidate TMS. The TMS trades included centralized and decentralized transport, single-phase and two-phase transport, alternate working fluids, liquid loop and heat pipe radiators, deployed fixed, body mounted and steerable radiators, and thermal storage. The subsystem options were evaluated against criteria such as weight, TMS power requirement, reliability, system isothermality penalty, and growth potential.

Sadunas, J. A.↗

Load positioning system with gravity compensation

A load positioning system with gravity compensation has a servomotor, position sensing feedback potentiometer and velocity sensing tachometer in a conventional closed loop servo arrangement to cause a lead screw and a ball nut to vertically position a load. Gravity compensating components comprise the DC motor, gears, which couple torque from the motor to the lead screw, and constant current power supply. The constant weight of the load applied to the lead screw via the ball nut tend to cause the lead screw to rotate, the constant torque of which is opposed by the constant torque produced by the motor when fed from the constant current source. The constant current is preset as required by the potentiometer to effect equilibration of the load which thereby enables the positioning servomotor to see the load as weightless under both static and dynamic conditions. Positioning acceleration and velocity performance are therefore symmetrical.

Hollow, R. H.↗

Application of technology developed for flight simulation at NASA. Langley Research Center

In order to meet the stringent time-critical requirements for real-time man-in-the-loop flight simulation, computer processing operations including mathematical model computation and data input/output to the simulators must be deterministic and be completed in as short a time as possible. Personnel at NASA's Langley Research Center are currently developing the use of supercomputers for simulation mathematical model computation for real-time simulation. This, coupled with the use of an open systems software architecture, will advance the state-of-the-art in real-time flight simulation.

Cleveland, Jeff I., II↗

Development and Implementation of a Load-Controlled Friction Stir Welder

Lockheed Martin Michoud Space Systems, under contract to NASA/MSFC, has developed and implemented a friction stir weld tool that uses the magnitude of the spindle axial load to control the weld process. This tool was used during the process development phase and the assembly of a full-scale External Tank barrel section. Both position and load transducers are incorporated into the welder. The control algorithm allows either the position or load transducer to provide the command variable in a closed loop system. Initially, the position transducer was used to actively control the weld process and the axial load on the spindle was monitored and collected via data acquisition hardware. As part of the process development, the axial load was implemented as the command variable in the closed loop. The spindle position is monitored and used to set limits on spindle travel. A zero set point algorithm has also been developed for establishing the spindle position at the start of the weld process. In its current state, the welder operates in a dual mode in which the position control is used to plunge the pin tool to a specified depth at the initiation of the weld. The load control is then used to control the weld process. This control algorithm has been used to assemble a 27.5-ft diameter, 2195-T8 barrel using hardware designed for NASA's Space Transportation System External Tank.

Loftus, Z.↗

Environmental Control and Life Support System (ECLSS) System Engineering Workshop

This slide presentation begins with a recap on a previous lecture on the ECLSS subsystems, and the various types (i.e., Non-regenerative vs Regenerative, open loop vs closed loop, and physical-chemical vs bioregenerative) It also recaps the Equivalent system mass (ESM) metric. The presentation continues with a review of the ECLSS of the various NASA manned space exploration programs from Mercury, to the current planned Altair lunar landing, and Lunar base operations. There is also a team project to establish the ESM of two conceptualized missions.

Peterson, Laurie J.↗

X-56A MUTT: Aeroservoelastic Modeling

For the NASA X-56a Program, Armstrong Flight Research Center has been developing a set of linear states space models that integrate the flight dynamics and structural dynamics. These high order models are needed for the control design, control evaluation, and test input design. The current focus has been on developing stiff wing models to validate the current modeling approach. The extension of the modeling approach to the flexible wings requires only a change in the structural model. Individual subsystems models (actuators, inertial properties, etc.) have been validated by component level ground tests. Closed loop simulation of maneuvers designed to validate the flight dynamics of these models correlates very well flight test data. The open loop structural dynamics are also shown to correlate well to the flight test data.

Modeling↗

Predictable Patterns in Planetary Transit Timing Variations and Transit Duration Variations Due to Exomoons

We present new ways to identify single and multiple moons around extrasolar planets using planetary transit timing variations (TTVs) and transit duration variations (TDVs). For planets with one moon, measurements from successive transits exhibit a hitherto undescribed pattern in the TTV-TDV diagram, originating from the stroboscopic sampling of the planet's orbit around the planet-moon barycenter. This pattern is fully determined and analytically predictable after three consecutive transits. The more measurements become available, the more the TTV-TDV diagram approaches an ellipse. For planets with multiple moons in orbital mean motion resonance (MMR), like the Galilean moon system, the pattern is much more complex and addressed numerically in this report. Exomoons in MMR can also form closed, predictable TTV-TDV figures, as long as the drift of the moons' pericenters is suciently slow.We find that MMR exomoons produce loops in the TTV-TDV diagram and that the number of these loops is equal to the order of the MMR, or the largest integer in the MMR ratio.We use a Bayesian model and Monte Carlo simulations to test the discoverability of exomoons using TTV-TDV diagrams with current and near-future technology. In a blind test, two of us (BP, DA) successfully retrieved a large moon from simulated TTV-TDV by co-authors MH and RH, which resembled data from a known Kepler planet candidate. Single exomoons with a 10 percent moon-to-planet mass ratio, like to Pluto-Charon binary, can be detectable in the archival data of the Kepler primary mission. Multi-exomoon systems, however, require either larger telescopes or brighter target stars. Complementary detection methods invoking a moon's own photometric transit or its orbital sampling effect can be used for validation or falsification. A combination of TESS, CHEOPS, and PLATO data would offer a compelling opportunity for an exomoon discovery around a bright star.

stroboscopic sampling↗

Lunar Rover Localization Using Craters as Landmarks

Onboard localization capabilities for planetary rovers to date have used relative navigation, by integrating combinations of wheel odometry, visual odometry, and inertial measurements during each drive to track position relative to the start of each drive. At the end of each drive, a “ground-in-the-loop” (GITL) interaction is used to get a position update from human operators in a more global reference frame, such as a map frame defined by orbital reconnaissance imaging of a large region around the rover’s current position. For Mars rovers, this typically has involved downlinking imagery from the rover mast cameras and using interactive visualization tools on Earth to register such images to the orbital reconnaissance images. For safety purposes, rover mission operations typically specify “keep out zones”, which human operators recognize as being unsafe in the orbital images. Autonomous rover drives are limited in distance so that accumulated relative navigation error does not risk the possibility of the rover driving into a keep out zone. The allowable autonomous drive distance in this mode of operation depends on the distribution of keep out zones and the accuracy of relative navigation; in practice, drive limits of a few hundred meters between GITL cycles are to be expected. Several rover mission concepts have recently been studied that require much longer drives between GITL cycles, particularly for the Moon. This includes lunar rover mission concepts that involve (1) driving mostly in sunlight at low latitudes, (2) driving in permanently shadowed regions near the south pole, and (3) a mixture of day and night driving in mid-latitudes. These concepts include total traverse distance requirements of up to 1,800 km in 4 Earth years, with individual drives of several kilometers between stops for downlink. These concepts require greater autonomy to minimize GITL cycles to enable such large range; onboard global localization is a key element of such autonomy. Multiple techniques have been studied in the past for onboard rover global localization, including radio navigation aiding from an orbiter, recognizing horizon landmarks that are known in a regional elevation map, and correlating a local elevation map created onboard the rover with a regional elevation map. These techniques all have drawbacks, including requiring an expensive extra mission element (navigation orbiter), unavailability of sufficient regional elevation map data, or limited accuracy in resulting position estimates (e.g. a few hundred meters with horizon landmarks). For the Moon, the ubiquitous craters offer another possibility, which involves mapping craters from orbit, then recognizing crater landmarks with cameras and/or a lidar onboard the rover. This approach is applicable everywhere on the Moon, does not require high resolution stereo imaging from orbit as some other approaches do, and has potential to enable position knowledge with order of 10 m accuracy at all times. This paper will provide more detail on our technical approach to crater-based lunar rover localization and will present initial results on crater detection using 3-D point cloud data from onboard lidar or stereo cameras and using shading cues in monocular onboard imagery.

Ono, M.↗

Local Power Impact Experiment Design for a New Fuel Type for use in the Advanced Test Reactor

The Advanced Test Reactor (ATR), and complimentary zero-power ATR Critical (ATRC) reactor, located at Idaho National Labs (INL), are undergoing conversion from Highly Enriched Uranium (HEU) to Low Enriched Uranium (LEU). Both have a variety of testing locations that can receive large variations in flux due to its unique serpentine design, consisting of five lobes (see Figure 1). Initial criticality and power distribution throughout the core are controlled by core-external outer shim control cylinders (OSCCs). Distinct test loops allow for testing at specific temperatures, pressures, and irradiation conditions. The ATR is one of the key nuclear engineering research and testing facilities within the DOE National Laboratory Complex, and the ATRC supports its operation [1]. Currently, the Office of Material Management and Minimization (M3) within the National Nuclear Security Administration of the DOE is working to convert the remaining research reactors, including the ATR, from 93% HEU fuel to 19.75% LEU fuel (LEU) to support non-proliferation [2]. Extensive materials testing at INL and internationally has demonstrated that a high-density uranium molybdenum (U 10Mo) alloy can meet the performance requirements of the remaining high powered research reactors. However, there are many technical challenges to address before the conversion to LEU can be successful, including the accurate characterization of the reactor core physics with LEU fuel. Reactor physics safety evaluations currently use Monte Carlo for the 21st Century (MC21), a continuous-energy Monte Carlo radiation transport code [3]. Existing MC21 models of the ATR and ATRC cores have a validation basis for use in neutronics analyses with HEU fuel. The models are used to support safety analyses that include comparisons to the safety requirements for the reactors. However, the use of the LOWE element in the ATR and ATRC is not currently covered by the current model validation basis. To deploy the new fuel type, extensive computational reactor physics support is necessary to support the use of LOWE in the ATR and ATRC. Therefore, LOWE requires a rigorous validation basis, aligned with that of HEU fuel, that takes advantage of the existing software tools and processes currently used for the ATR and ATRC. The experiment to validate of the MC21 models for determining power, the Power Impact Validation Experiment, will consist of two flux runs in the ATRC, one with fully HEU loading and one with a single LOWE element. Both flux runs will be instrumented with 20 sets of azimuthal fission wires and 3 sets of axial fission wires, as shown in Figure 4. Standard flux run methodology will be used [4]. Power Impact Validation Experiment data will be compared against MC21 calculated data, both for absolute fission rate accuracy and to determine the relative change in fission rates between the two runs. The results of the Power Impact Validation Experiment and subsequent evaluations will provide the validation basis for MC21 for use with LOWE elements. Key features of the Power Impact Validation Experiment include: (1) Two flux runs to allow for LOWE perturbed measurements to be compared to already validated measurements taken from a full core of HEU fuel, (2) Optimization of instrumentation to balance analytical needs with practical considerations (e.g., limited time window to count beta particles from fission products), and (3) Standard ATRC core loading, including both driver positions and flux traps, to minimize cost while remaining representative of typical ATR core loading.

42 ENGINEERING↗

Integrated Approach to Fluoride High Temperature Reactor Technology and Licensing Challenges (FHR-IRP)

This document constitutes progress made on this project by the Georgia Tech led Integrated Approach to Fluoride High Temperature Reactor Technology and Licensing Challenges (FHR-IRP). This is the first draft of the project final report. Chapter 3 is focused on Tritium management. Tritium management in Fluoride-salt High-temperature Reactors (FHRs) presents a major operational concern and a significant challenge. Tritium is generated via multiple pathways including various interactions in fuel and structural materials, as well as coolant (primarily interaction with lithium and beryllium), leading to a complex evolution and spatial distribution of tritium generation rate. FHR generates orders of magnitude more tritium than in LWRs, and has potential for a significant release, via permeation through structural materials (due to high temperature), and through heat exchanger(s). Therefore, accurate estimate is necessary. For that purpose relevant tritium production pathways were identified. A methodology to obtain space-time dependent tritium generation rate was developed and implemented, employing SCALE and MCNP codes. Detailed models of the reference Advanced High Temperature Reactor (AHTR) design were developed. A multi-parametric metrics was introduced to capture relevant tritium production indicators, including the instantaneous tritium production rate, total tritium production (neglecting subsequent decay), and accumulated tritium production (accounting for the decay). The obtained results will inform tritium management, including the sizing of the components, and to gain insight on the impact of the core design parameters on tritium generation rates. Research effort on Liquid Salt Impurity Removal, Redox and Corrosion Control is discussed in Chapter 4. Section 4.1 is an introduction chapter. Based on the current available knowledge and operation experience on previous MSRs and other types of nuclear reactors, the report identifies the major impurities that are related to either material compatibility, salt properties or radioactive source terms, and the potential contamination sources of these impurities, their transport in the primary coolant loop and available cleanup methodologies for a particular group of impurity. In section 4.2, the available purification methods were discussed, including the liquid/liquid extraction using liquid Bi-Li which has been applied in MSBR and electrochemical purification which is developed based on Pyroprocessing. In this section, the new multi-stage and multi-salt-component was developed and discussed. Section 4.3 discussed the redox potential control for salt chemistry and corrosion mitigation, including the control theory and the soluble/soluble buffer control method. The section also developed method on how to analyze soluble/soluble redox reaction in a molten salt system and designed an electrochemical sensor for redox potential control. Corrosion models were also reported in this section. Section 4.4 focused on how to measure the fundamental properties in a molten salt. As an example, the section focused on La fluoride in the molten salt. The section developed methods on how analyze electrochemical measurement data to obtain the fundamental properties including the redox potential, diffusion coefficient and exchange current density. All these fundamental information is important for salt purification system development. Section 4.5 focused on measurements of corrosion products in the salts. Because of the different behaviors between Cr and La in the salt, new analysis method for Cr fluorides in the salt was developed. Some results for Fe fluoride in the salt and corrosion measurements were also reported. Section 4.6 demonstrated the separation of oxide from the salt. This section also measured the solubility of La 2 O 3 in the salt as function of temperature. Section 4.7 focused on the separation of La and Ce from the molten salt. These two elements were selected because La was found to be separated by using inert electrode, while for separation of Ce, reactive electrode must be selected. Section 4.8 demonstrated the separation iodine ions from the molten salt. Two kinds of working electrode materials (metal W and graphite) were investigated. Section 4.9 focused on the fundamental data of fission products and actinides in liquid Bi. The chapter reviewed the available data, then based a CALPHAD model, the available data were broadened to the concentration-dependent cases.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Using AI to Reproduce Neutrino Cross Section Analysis - Prototyping the Neutrino Discovery Platform

The Neutrino Discovery Platform (NDP) aims to accelerate DUNE-era science by making the neutrino program's existing datasets analyzable through fast, reproducible, and auditable workflows. We report a working version of two of its layers, data curation and agentic orchestration, built and tested end to end on MINERvA open data. The guiding lesson throughout is that a cross section is a measurement, and not just a plotted shape, only if it carries a defensible systematic-uncertainty budget, a trustworthy unfolding, and a reproducible record. Using a single medium-energy playlist pair from the MINERvA open-data release (about $2.05\times10^{17}$ protons on target of data), we first reproduced the shapes of two published charged-current inclusive $\nu_\mu$ measurements through a complete extraction ladder: selection, background subtraction, D'Agostini unfolding, efficiency correction, and flux normalization. These shape-level reproductions ran and tracked the published results, but they lacked the systematic-uncertainty machinery that defines a MINERvA cross section. To supply it, we vendored and built the MINERvA Analysis Toolkit and developed a many-universe systematic-uncertainty tool that produces a portable covariance artifact, a parallel event-loop runner, and a per-run auditability harness. Validated against a published covariance release, the toolchain reproduces the released statistical, flux, and muon-energy-scale terms and shows that they account for roughly 63\% of the total variance, with the remainder unreleased. Using this same infrastructure, we then performed a measurement of our own design, the hadronic recoil-energy distribution of low-energy ($E_\nu<2.5$~GeV) charged-current inclusive events, and found data/simulation shape agreement of $\chi^2/\mathrm{ndf}=1.26$. Together these results show that the platform supports original physics and not only reproductions.

Breaux, Auto [Tulane U. (main)]↗

Toward the Neutrino Discovery Platform: An Auditable, Uncertainty-Bearing Toolchain for MINERvA Open-Data Cross-Section Analysis

The Neutrino Discovery Platform (NDP) aims to accelerate DUNE-era science by making the neutrino program's existing datasets analyzable through fast, reproducible, and auditable workflows. We report a working version of two of its layers, data curation and agentic orchestration, built and tested end to end on MINERvA open data. The guiding lesson throughout is that a cross section is a measurement, and not just a plotted shape, only if it carries a defensible systematic-uncertainty budget, a trustworthy unfolding, and a reproducible record. Using a single medium-energy playlist pair from the MINERvA open-data release (about $2.05\times10^{17}$ protons on target of data), we first reproduced the shapes of two published charged-current inclusive $\nu_\mu$ measurements through a complete extraction ladder: selection, background subtraction, D'Agostini unfolding, efficiency correction, and flux normalization. These shape-level reproductions ran and tracked the published results, but they lacked the systematic-uncertainty machinery that defines a MINERvA cross section. To supply it, we vendored and built the MINERvA Analysis Toolkit and developed a many-universe systematic-uncertainty tool that produces a portable covariance artifact, a parallel event-loop runner, and a per-run auditability harness. Validated against a published covariance release, the toolchain reproduces the released statistical, flux, and muon-energy-scale terms and shows that they account for roughly 63\% of the total variance, with the remainder unreleased. Using this same infrastructure, we then performed a measurement of our own design, the hadronic recoil-energy distribution of low-energy ($E_\nu<2.5$~GeV) charged-current inclusive events, and found data/simulation shape agreement of $\chi^2/\mathrm{ndf}=1.26$. Together these results show that the platform supports original physics and not only reproductions.

Breaux, Auto [Tulane U. (main)]↗

Scalar and tensor neutrino interactions

We constrain general Dirac neutrino interactions based on the Standard Model Effective Field Theory framework extended with right-handed neutrinos N (SMNEFT) using deep inelastic and coherent elastic neutrino scattering, nuclear beta decay, and meson decay data, and high energy electron-proton and proton-proton collider data. We compute the one-loop anomalous dimensions of the low-energy effective field theory (LEFT) below the electroweak scale and of SMNEFT above the electroweak scale. The tree-level matching between LEFT and SMNEFT is performed at the electroweak scale. Currently, the most stringent limits on scalar and tensor interactions arise from pseudoscalar meson decays and the LHC measurements at the per mille level. In the future, the upcoming High-Luminosity LHC (HL-LHC) has the potential to reach the 10 -4 level and LHeC can play an important role under certain theoretical assumptions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Effect of Zn Concentration on the Structure, Morphology, and Magnetic Behavior of Ni{sub 1 − x}Zn{sub x}Fe{sub 2}O{sub 4} Ferrofluid

In this work, we investigated the effect of doping zinc ions onto nickel ferrite upon the structure, morphology, and magnetic properties of Ni{sub 1 − x}Zn{sub x}Fe{sub 2}O{sub 4} ferrite nanoparticles (x = 0, 0.25, and 0.75) prepared via co-precipitation method. X-ray diffraction analysis showed the presence of the most intense peak corresponding to the (311) crystallographic orientation of NiFe{sub 2}O{sub 4} cubic spinel phase, and the crystallite size obtained from Scherrer formula increased from 6.8 to 11.2 nm when the Zn concentration increases from x = 0 to x = 0.75. Fourier transform infrared spectroscopy analysis confirmed the presence of a prominent band associated to the vibrations of metal ions, as a feature of spinel ferrite phase formation, observing that their band positions were very sensitive to Zn doping concentration. Transmission electron microscopy studies allowed to determinate that for all Zn concentrations, the particle sizes are around 15 nm. The magnetic properties were studied by using the vibrating sample magnetometer at room temperature. The results reveal superparamagnetic behavior determined by the shape of the hysteresis loop, presenting decreased coercive magnetic field and increased saturation magnetization, with increased zinc concentration. Additionally, from field cooling and zero field cooling curves, we can observe the typical behavior of the blocking process assembly of superparamagnetic nanoparticles. Alternate current susceptibility measurements show that the blocking temperature is frequency dependent and shifts toward higher temperatures by increasing the frequency, a characteristic of superparamagnetic, and glassy systems. Furthermore, τ{sub 0}, related to the jump attempt frequency of the magnetic moment of the nanoparticle between the opposite directions of the magnetization easy axis, is in the range of 2 × 10{sup −10} and 7 × 10{sup −13} s for the three different Zn concentrations, which agrees with characteristic of non-interacting superparamagnetic systems.

36 MATERIALS SCIENCE↗