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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2015

A Comparative Analysis of the Magnetic Field Signals over Impact Structures on the Earth, Mars and the Moon

An improved description of magnetic fields of terrestrial bodies has been obtained from recent space missions, leading to a better characterization of the internal fields including those of crustal origin. One of the striking differences in their crustal magnetic field is the signature of large impact craters. A comparative analysis of the magnetic characteristics of these structures can shed light on the history of their respective planetary-scale magnetic dynamos. This has motivated us to identify impact craters and basins, first by their quasi-circular features from the most recent and detailed topographic maps and then from available global magnetic field maps. We have examined the magnetic field observed above 27 complex craters on the Earth, 34 impact basins on Mars and 37 impact basins on the Moon. For the first time, systematic trends in the amplitude and frequency of the magnetic patterns, inside and outside of these structures are observed for all three bodies. The demagnetization effects due to the impact shock wave and excavation processes have been evaluated applying the Equivalent Source Dipole forward modeling approach. The main characteristics of the selected impact craters are shown. The trends in their magnetic signatures are indicated, which are related to the presence or absence of a planetary-scale dynamo at the time of their formation and to impact processes. The low magnetic field intensity at center can be accepted as the prime characteristic of a hypervelocity impact and strongly associated with the mechanics of impact crater formation. In the presence of an active internal field, the process of demagnetization due to the shock impact is associated with post-impact remagnetization processes, generating a more complex magnetic signature.

Earth↗
DOE OSTI2017

Hanford's Double-Shell Tank AY-102 Recovery Project - 17416

Since at least August 2012, Hanford Tank 241-AY-102 (AY-102) has been leaking from its primary tank into its secondary containment. A pumping plan was developed in 2013 to provide a path forward for recommended remediation actions to be implemented as part of the AY-102 Recovery Project. On March 21, 2014, the Washington State Department of Ecology issued Administrative Order No. 10618 requiring Washington River Protection Solutions and the United States Department of Energy to conduct actions related to and including the removal of waste from AY-102. The three parties agreed to resolve the appeal of the Administrative Order through a Settlement Agreement which addresses the remaining requirements and implements enforceable milestone dates, including initiation of waste retrieval by March 4, 2016 and completion of waste retrieval operations by March 4, 2017. The AY-102 Recovery Project was developed to address the Settlement Agreement requirements. While retrieval of waste from Single-Shell Tanks has been performed at Hanford for decades, retrieval from Double-Shell Tank AY-102 required adaptation of the existing technologies to a new environment on a larger scale than previously encountered. A significant number of obstructions and in-tank equipment limit accessibility to the high source term AY-102 waste and the location of the selected receiver tank required installation of an extensive, heavily-shielded above-ground transfer line. Despite countless challenges and obstacles encountered throughout, the project successfully completed system design, fabrication, installation, testing, and the first phase of operations within a highly compressed, aggressive schedule. Waste retrieval operations in AY-102 commenced on March 3, 2016 and the initial operating phase concluded on April 30. Additional sluicing capability was required to complete the mission and four Extended Reach Sluicers were installed to support the second operating phase, which began on December 8, 2016. As of December 31, 2016, approximately 97% of the original waste volume had been removed, resulting in an estimated remaining waste volume of about 75,000 liters. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2014

VARIABILITY OF OPTICAL COUNTERPARTS IN THE CHANDRA GALACTIC BULGE SURVEY

We present optical light curves of variable stars consistent with the positions of X-ray sources identified with the Chandra X-ray Observatory for the Chandra Galactic Bulge Survey (GBS). Using data from the Mosaic-II instrument on the Blanco 4 m Telescope at CTIO, we gathered time-resolved photometric data on timescales from ∼2 hr to 8 days over the 3/4 of the X-ray survey containing sources from the initial GBS catalog. Among the light curve morphologies we identify are flickering in interacting binaries, eclipsing sources, dwarf nova outbursts, ellipsoidal variations, long period variables, spotted stars, and flare stars. Eighty-seven percent of X-ray sources have at least one potential optical counterpart. Twenty-seven percent of these candidate counterparts are detectably variable; a much greater fraction than expected for randomly selected field stars, which suggests that most of these variables are real counterparts. We discuss individual sources of interest, provide variability information on candidate counterparts, and discuss the characteristics of the variable population.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

MOTION VERIFIED RED STARS (MoVeRS): A CATALOG OF PROPER MOTION SELECTED LOW-MASS STARS FROM WISE, SDSS, AND 2MASS

We present a photometric catalog of 8,735,004 proper motion selected low-mass stars (KML-spectral types) within the Sloan Digital Sky Survey (SDSS) footprint, from the combined SDSS Data Release 10 (DR10), Two Micron All-Sky Survey (2MASS) point-source catalog (PSC), and Wide-field Infrared Survey Explorer (WISE) AllWISE catalog. Stars were selected using r − i, i − z, r − z, z − J, and z − W1 colors, and SDSS, WISE, and 2MASS astrometry was combined to compute proper motions. The resulting 3,518,150 stars were augmented with proper motions for 5,216,854 earlier type stars from the combined SDSS and United States Naval Observatory B1.0 catalog (USNO-B). We used SDSS+USNO-B proper motions to determine the best criteria for selecting a clean sample of stars. Only stars whose proper motions were greater than their 2σ uncertainty were included. Our Motion Verified Red Stars catalog is available through SDSS CasJobs and VizieR.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

Detecting new γ-ray sources based on multi-frequency data the case of 1WHSPJ031423.9+061956

We use the Fermi Science Tools in an attempt to unveil faint γ-ray blazars that may be above the threshold for detectability with Fermi-LAT and are not identified by automated methods. Our search for new sources in the 100MeV-300GeV band is mainly driven by the 1/2WHSP catalogs, which list high synchrotron peaked blazars expected to be emitters of VHE photons. Here we present the γ-ray detection of 1WHSP J031423.9+061956, modelling its high energy spectrum as a power law. We describe an example where multi-frequency selection, performed at much lower energies (from radio to X-ray), helps to pin-point a high energy source. The 1/2WHSP catalogs are built with the aim of providing a list of TeV targets for the VHE arrays of Cherenkov telescopes. Moreover, these catalogs provide useful seeds for identifying new high energy sources within the raw-data from Fermi. With the aid of multi-frequency data, we can explore the very high energy domain in greater details, improving the description of the γ-ray sky.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

Powerful Radio Sources in the Southern Sky. I. Optical Identifications

Since the early sixties, our view of radio galaxies and quasars has been drastically shaped by discoveries made thanks to observations of radio sources listed in the Third Cambridge Catalog and its revised version (3CR). However, the largest fraction of data collected to date on 3CR sources was performed with relatively old instruments, rarely repeated and/or updated. Importantly, the 3CR contains only objects located in the Northern Hemisphere, thus having limited access to new and innovative astronomical facilities. To mitigate these limitations, we present a new catalog of powerful radio sources visible from the Southern Hemisphere, extracted from the GLEAM 4 Jy (G4Jy) catalog and based on equivalent selection criteria as the 3CR. This new catalog, named G4Jy-3CRE, where the E stands for “equivalent,” lists a total of 264 sources at decl. below -5° and with 9 Jy limiting sensitivity at ~178 MHz. We explored archival radio maps obtained with different surveys and compared them with optical images available in the Pan-STARRS, DES, and DSS databases to search for optical counterparts of their radio cores. We compared mid-infrared counterparts, originally associated in the G4Jy, with the optical ones identified here, and we present results of a vast literature search carried out to collect redshift estimates for all G4Jy-3CRE sources resulting in a total of 145 reliable z measurements.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

X-ray science using the ESRF—extremely brilliant source

The Extremely Brilliant Source (EBS), the first high-energy 4th-generation synchrotron radiation source, constructed at the ESRF and based upon the novel concept of a Hybrid Multi-Bend Achromat (HMBA), has started user operation on August 25th, 2020. We report here on selected recent scientific results exploiting the greatly improved performances of this novel X-ray source.

43 PARTICLE ACCELERATORS↗
NASA NTRS2003

The Burst and Transient Source Experiment(BATSE)Earth Occultation Catalog of Low-Energy Gamma-Ray Sources. Short title: BATSE Earth Occultation Catalog v2.0

The Burst and Transient Source Experiment (BATSE), aboard the Compton Gamma Ray Observatory (CGRO), provided a record of the low-energy gamma-ray sky (approx. 20-1000 keV) between 1991 April and 2000 May (9.1y). BATSE monitored the high energy sky using the Earth occultation technique (EOT) for point sources whose emission extended for times on the order of the CGRO orbital period (approx. 92m) or greater. Using the EOT to extract flux - 2 - information, a catalog of sources using data from the BATSE large area detectors has been prepared. The first part of the catalog consists of results from the all-sky monitoring of 58 sources, mostly Galactic, with intrinsic variability on timescales of hours to years. For these sources, we have included tables of flux and spectral data, and outburst times for transients. Light curves (or flux histories) covering the entire nine mission are being placed on the world wide web. We then performed a deep-sampling of these 58 objects, plus a selection of 121 more objects, combining data from the entire 9.ly BATSE dataset. Source types considered were primarily accreting binaries, but a small number of representative active galaxies, X-ray-emitting stars, and supernova remnants were also included. The sample represents a compilation of sources monitored and/or discovered with BATSE and other high energy instruments between 1991 and 2000, known sources taken from the HEAO 1 A-4 (Levine et al. 1984) and Macomb and Gehrels (1999) catalogs. The deep sample results include definite detections of 82 objects and possible detections of 36 additional objects. The definite detections spanned three classes of sources: accreting black hole and neutron star binaries, active galaxies and supernova remnants. The average fluxes measured for the fourth class, the X-ray emitting stars, were below the confidence limit for definite detection. Flux data for the deep sample are presented in four energy bands: 20-40, 40-70, 70-160, and 160-430 keV. The limiting average flux level (9.1 y) for the sample varies from 3.5 to 20 mCrab (5delta) between 20 and 430 keV, depending on systematic error, which in turn is primarily dependent on the sky location. To strengthen the credibility of detection of weaker sources (approx.5-25 mCrab), we generated Earth occultation images, searched for periodic behavior using FFT and epoch folding methods, and critically evaluated the energy-dependent emission in the four flux bands. The deep sample results are intended for guidance in performing future all-sky surveys or pointed observations in the hard X-ray and low-energy gamma-ray band, as well as more detailed studies with the BATSE EOT.

Harmon, B. A.↗
NASA NTRS1994

On the development of an expert system for wheelchair selection

The presentation of wheelchairs for the Multiple Sclerosis (MS) patients involves the examination of a number of complicated factors including ambulation status, length of diagnosis, and funding sources, to name a few. Consequently, only a few experts exist in this area. To aid medical therapists with the wheelchair selection decision, a prototype medical expert system (ES) was developed. This paper describes and discusses the steps of designing and developing the system, the experiences of the authors, and the lessons learned from working on this project. Wheelchair Advisor, programmed in CLIPS, serves as diagnosis, classification, prescription, and training tool in the MS field. Interviews, insurance letters, forms, and prototyping were used to gain knowledge regarding the wheelchair selection problem. Among the lessons learned are that evolutionary prototyping is superior to the conventional system development life-cycle (SDLC), the wheelchair selection is a good candidate for ES applications, and that ES can be applied to other similar medical subdomains.

Madey, Gregory R.↗
DOE OSTI2023

Sustainable Materials Selection in Manufactured Products: A Framework for Design-Integrated Life Cycle Thinking with Case Studies

Materials selection can provide a major opportunity to improve the environmental performance of manufactured products. Substitution of conventional materials with eco-friendly options can lower a product's environmental impact while still meeting key application requirements. A prerequisite for sustainability-informed decision-making is that relevant data and information are available for all materials being considered. Here we outline examples of the types and sources of data needed; and we explore key considerations for sustainable materials selection through a series of practical, cross-sectoral case studies.

36 MATERIALS SCIENCE↗
DOE OSTI2015

THE YOUNG STELLAR OBJECT POPULATION IN THE VELA-D MOLECULAR CLOUD

We investigate the young stellar population in the Vela Molecular Ridge, Cloud-D, a star-forming region observed by both the Spitzer/NASA and Herschel/ESA space telescopes. The point-source, band-merged, Spitzer-IRAC catalog complemented with MIPS photometry previously obtained is used to search for candidate young stellar objects (YSOs), also including sources detected in less than four IRAC bands. Bona fide YSOs are selected by using appropriate color-color and color-magnitude criteria aimed at excluding both Galactic and extragalactic contaminants. The derived star formation rate and efficiency are compared with the same quantities characterizing other star-forming clouds. Additional photometric data, spanning from the near-IR to the submillimeter, are used to evaluate both bolometric luminosity and temperature for 33 YSOs located in a region of the cloud observed by both Spitzer and Herschel. The luminosity-temperature diagram suggests that some of these sources are representative of Class 0 objects with bolometric temperatures below 70 K and luminosities of the order of the solar luminosity. Far-IR observations from the Herschel/Hi-GAL key project for a survey of the Galactic plane are also used to obtain a band-merged photometric catalog of Herschel sources intended to independently search for protostars. We find 122 Herschel cores located on the molecular cloud, 30 of which are protostellar and 92 of which are starless. The global protostellar luminosity function is obtained by merging the Spitzer and Herschel protostars. Considering that 10 protostars are found in both the Spitzer and Herschel lists, it follows that in the investigated region we find 53 protostars and that the Spitzer-selected protostars account for approximately two-thirds of the total.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

The ALMA spectroscopic survey in the Hubble Ultra Deep Field: continuum number counts, resolved 1.2 mm extragalactic background, and properties of the faintest dusty star-forming galaxies

We present an analysis of a deep (1σ = 13 μJy) cosmological 1.2 mm continuum map based on ASPECS, the ALMA Spectroscopic Survey in the Hubble Ultra Deep Field. In the 1 arcmin{sup 2} covered by ASPECS we detect nine sources at >3.5σ significance at 1.2 mm. Our ALMA-selected sample has a median redshift of z=1.6±0.4, with only one galaxy detected at z > 2 within the survey area. This value is significantly lower than that found in millimeter samples selected at a higher flux density cutoff and similar frequencies. Most galaxies have specific star formation rates (SFRs) similar to that of main-sequence galaxies at the same epoch, and we find median values of stellar mass and SFRs of 4.0×10{sup 10} M{sub ⊙} and ∼40 M{sub ⊙} yr{sup −1}, respectively. Using the dust emission as a tracer for the interstellar medium (ISM) mass, we derive depletion times that are typically longer than 300 Myr, and we find molecular gas fractions ranging from ∼0.1 to 1.0. As noted by previous studies, these values are lower than those using CO-based ISM estimates by a factor of ∼2. The 1 mm number counts (corrected for fidelity and completeness) are in agreement with previous studies that were typically restricted to brighter sources. With our individual detections only, we recover 55% ± 4% of the extragalactic background light (EBL) at 1.2 mm measured by the Planck satellite, and we recover 80% ± 7% of this EBL if we include the bright end of the number counts and additional detections from stacking. The stacked contribution is dominated by galaxies at z∼1--2, with stellar masses of (1–3) × 10{sup 10} M {sub ⊙}. For the first time, we are able to characterize the population of galaxies that dominate the EBL at 1.2 mm.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Wastewater Disposal Has Not Significantly Altered the Regional Stress State in Southern Kansas

Wastewater disposal is primarily responsible for the increased seismicity rate since ~2013 in southern Kansas. Previous work that used shear-wave splitting (SWS) in southern Kansas interpreted an ~90° temporal rotation in the fast polarization direction and attributed it to increased pore pressures resulting from fluid injection. However, this interpreted rotation coincided with a change in the stations used to make the SWS measurements. We investigate the temporal variability of fast azimuths in southern Kansas by making SWS measurements on earthquake families with similar source–receiver paths recorded on a stable local seismic network. We select high-quality SWS measurements by investigating the stability of results across 65 different frequency bands between 0.5 and 15 Hz. We find that the fast polarization direction in southern Kansas is relatively constant with an average east-northeast (~N79°E) orientation between 2014 and 2017. Our fast polarization measurements are primarily a reflection of the maximum principal horizontal stress direction (SHmax). We observe a slight spatial change in SHmax to the northeast (~N55°E) near the Nemaha ridge in Oklahoma. However, we do not observe any significant temporal rotation of SHmax or variation in delay time (i.e., crack density) in southern Kansas, contrary to the earlier study. The previously interpreted ~90° rotation may either be a reflection of a very local stress change or a misinterpretation of SWS results potentially due to the use of inconsistent source–receiver paths. Our SWS measurements cover the period of peak wastewater disposal and seismicity rates and suggest an absence of significant temporal rotations in the local anisotropy and stress orientations associated with wastewater disposal.

Geochemistry & Geophysics↗
NASA NTRS2010

Integrity Monitoring of Mercury Discharge Lamps

Mercury discharge lamps are critical in many trapped ion frequency standard applications. An integrity monitoring system can be implemented using end-of-life signatures observed in operational mercury discharge lamps, making it possible to forecast imminent failure and to take action to mitigate the consequences (such as switching to a redundant system). Mercury lamps are used as a source of 194-nm ultraviolet radiation for optical pumping and state selection of mercury trapped ion frequency standards. Lamps are typically fabricated using 202Hg distilled into high-purity quartz, or other 194-nm transmitting material (e.g., sapphire). A buffer gas is also placed into the bulb, typically a noble gas such as argon, neon, or krypton. The bulbs are driven by strong RF fields oscillating at .200 MHz. The lamp output may age over time by two internal mechanisms: (1) the darkening of the bulb that attenuates light transmission and (2) the loss of mercury due to migration or chemical interactions with the bulb surface. During fabrication, excess mercury is placed into a bulb, so that the loss rate is compensated with new mercury emanating from a cool tip or adjacent reservoir. The light output is nearly constant or varies slightly at a constant rate for many months/years until the mercury source is depleted. At this point, the vapor pressure abruptly falls and the total light output and atomic clock SNR (signal-to-noise ratio) decrease. After several days to weeks, the light levels decrease to a point where the atomic clock SNR is no longer sufficient to stay in lock, or the lamp self-extinguishes. This signature has been observed in four separate end-of-life lamp failures while operating in the Deep Space Network (DSN). A simple integrator circuit can observe and document steady-state lamp behavior. When the light levels drop over a predetermined time interval by a specified amount (e.g., 20 percent), an alarm is set. For critical operational applications, such as the DSN or in space flight, this warning provides notice that a failure may be imminent, and for operators or control algorithm to take action.

Tjoelker, Robert L.↗
NASA NTRS2018

Linking Improvements in Sulfur Dioxide Emissions to Decreasing Sulfate Wet Deposition by Combining Satellite and Surface Observations with Trajectory Analysis

Sulfur dioxide (SO2), a criteria pollutant, and sulfate (SO42) deposition are major environmental concerns in the eastern U.S. and both have been on the decline for two decades. In this study, we use satellite column SO2 data from the Ozone Monitoring Instrument (OMI), and SO42 wet deposition data from the NADP (National Atmospheric Deposition Program) to investigate the temporal and spatial relationship between trends in SO2 emissions and the downward sulfate wet deposition over the eastern U.S. from 2005 to 2015. To establish the relationship between SO2 emission sources and receptor sites, we conducted a Potential Source Contribution Function (PSCF) analysis using HYSPLIT back trajectories for five selected Air Quality System (AQS) sites - (Hackney, OH, Akron, OH, South Fayette, PA, Wilmington, DE, and Beltsville, MD) - in close proximity to NADP sites with large downward SO42 trends since 2005. Back trajectories were run for three summers (JJA) and three winters (DJF) and used to generate seasonal climatology PSCFs for each site. The OMI SO2 and interpolated NADP sulfate deposition trends were normalized and overlapped with the PSCF, to identify the areas that had the highest contribution to the observed drop. The results suggest that emission reductions along the Ohio River Valley have led to decreases in sulfate deposition in eastern OH and western PA (Hackney, Akron and South Fayette). Farther to the east, emission reductions in southeast PA resulted in improvements in sulfate deposition at Wilmington, DE, while for Beltsville, reductions in both the Ohio River Valley and nearby favorably impacted sulfate deposition. For Beltsville, sources closer than 300km from the site contribute roughly 56% observed deposition trends in winter, and 82% in summer, reflecting seasonal changes in transport pattern as well as faster oxidation and washout of sulfur in summer. This suggests that emissions and wet deposition are linked through not only the location of sources relative to the observing sites, but also to photochemistry and the weather patterns characteristic to the region, as evidenced by a west to east shift in the contribution between winter and summer. The method developed here is applicable to other regions with significant trends such as China and India, and can be used to estimate the potential benefits of emission reduction in those areas.

Acid depostion↗
NASA NTRS2018

Linking Improvements in Sulfur Dioxide Emissions to Decreasing Sulfate Wet Deposition By Combining Satellite and Surface Observations With Trajectory Analysis

Sulfur dioxide (SO2), a criteria pollutant, and sulfate (SO42−) deposition are major environmental concerns in the eastern U.S. and both have been on the decline for two decades. In this study, we use satellite column SO2 data from the Ozone Monitoring Instrument (OMI), and SO42− wet deposition data from the NADP (National Atmospheric Deposition Program) to investigate the temporal and spatial relationship between trends in SO2 emissions and the downward sulfate wet deposition over the eastern U.S. from 2005 to 2015. To establish the relationship between SO2 emission sources and receptor sites, we conducted a Potential Source Contribution Function (PSCF) analysis using HYSPLIT back trajectories for five selected Air Quality System (AQS) sites - (Hackney, OH, Akron, OH, South Fayette, PA, Wilmington, DE, and Beltsville, MD) - in close proximity to NADP sites with large downward SO42− trends since 2005. Back trajectories were run for three summers (JJA) and three winters (DJF) and used to generate seasonal climatology PSCFs for each site. The OMI SO2 and interpolated NADP sulfate deposition trends were normalized and overlapped with the PSCF, to identify the areas that had the highest contribution to the observed drop. The results suggest that emission reductions along the Ohio River Valley have led to decreases in sulfate deposition in eastern OH and western PA (Hackney, Akron and South Fayette). Farther to the east, emission reductions in southeast PA resulted in improvements in sulfate deposition at Wilmington, DE, while for Beltsville, reductions in both the Ohio River Valley and nearby favorably impacted sulfate deposition. For Beltsville, sources closer than 300 km from the site contribute roughly 56% observed deposition trends in winter, and 82% in summer, reflecting seasonal changes in transport pattern as well as faster oxidation and washout of sulfur in summer. This suggests that emissions and wet deposition are linked through not only the location of sources relative to the observing sites, but also to photochemistry and the weather patterns characteristic to the region, as evidenced by a west to east shift in the contribution between winter and summer. The method developed here is applicable to other regions with significant trends such as China and India, and can be used to estimate the potential benefits of emission reduction in those areas.

sulfur dioxide emissions↗
DOE OSTI2023

High-Order Mesh Morphing for Boundary and Interface Fitting to Implicit Geometries

Here, we propose a method that morphs high-order meshes such that their boundaries and interfaces coincide/align with implicitly defined geometries. Our focus is particularly on the case when the target surface is prescribed as the zero isocontour of a smooth discrete function. Common examples of this scenario include using level set functions to represent material interfaces in multimaterial configurations, and evolving geometries in shape and topology optimization. The proposed method formulates the mesh optimization problem as a variational minimization of the sum of a chosen mesh-quality metric using the Target-Matrix Optimization Paradigm (TMOP) and a penalty term that weakly forces the selected faces of the mesh to align with the target surface. The distinct features of the method are use of a source mesh to represent the level set function with sufficient accuracy, and adaptive strategies for setting the penalization weight and selecting the faces of the mesh to be fit to the target isocontour of the level set field. We demonstrate that the proposed method is robust for generating boundary- and interface-fitted meshes for curvilinear domains using different element types in 2D and 3D.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2025

Scalable, biologically sourced depolymerizable polydienes with intrinsically weakened carbon–carbon bonds

Currently, there are few examples of circularly recyclable polymers with all-carbon backbones, probably owing to the challenge of using selective C–C bond cleavage to efficiently produce monomers in recycling processes. Furthermore, here we demonstrate a series of biologically sourced polymuconate polymers synthesized via simple free-radical polymerization that exhibit intrinsically weakened C–C bonds and controlled chemical recycling to monomers. Modifying the side chains and copolymerization ratios allows a wide range of mechanical property tuning, achieving performances comparable to those of commercial plastics such as polystyrene, polymethyl methacrylate and polybutadiene. Techno-economic analysis and life cycle assessment for production at a scale of 100 kilotons per year show that the materials are currently slightly more expensive and environmentally intensive compared with conventional rubbers. However, use of recycled materials via depolymerization can greatly decrease the cost and environmental impacts of polymuconate production (for example, down to US$1.59 per kilogram) to outperform its commercial counterparts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗