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All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Diffusive shock re-acceleration

Here, we have performed two-dimensional hybrid simulations of non-relativistic collisionless shocks in the presence of pre-existing energetic particles (‘seeds’); such a study applies, for instance, to the re-acceleration of galactic cosmic rays (CRs) in supernova remnant (SNR) shocks and solar wind energetic particles in heliospheric shocks. Energetic particles can be effectively reflected and accelerated regardless of shock inclination via a process that we call diffusive shock re-acceleration. We determine that re-accelerated seeds can drive the streaming instability in the shock upstream and produce effective magnetic field amplification. This can later trigger the injection of thermal protons even at oblique shocks that ordinarily cannot inject thermal particles. We characterize the current in reflected seeds, finding that it tends to a universal value $J\simeq en_{\text{CR}}v_{\text{sh}}$ , where $en_{\text{CR}}$ is the seed charge density and $v_{\text{sh}}$ is the shock velocity. When applying our results to SNRs, we find that the re-acceleration of galactic CRs can excite the Bell instability to nonlinear levels in less than ${\sim}10~\text{yr}$ , thereby providing a minimum level of magnetic field amplification for any SNR shock. Finally, we discuss the relevance of diffusive shock re-acceleration also for other environments, such as heliospheric shocks, galactic superbubbles and clusters of galaxies.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Application of the Uranium–Helium Chronometer to the Analysis of Nuclear Forensic Materials

Radiochronometers are used to constrain the manufacturing and processing history of actinide materials for nuclear forensic investigations. This paper describes here U–He ages and He diffusion kinetics obtained from a metallic, highly enriched uranium sample. The average U–He age is 8% older than the known casting date, which indicates that excess He is present and is likely due to incomplete degassing of pre-existing He during the casting process. Although the U–He age is older than expected, the accuracy is comparable to other chronometers that have been applied to this material. Diffusion kinetics obtained from the uranium metal indicate that He is quantitatively retained under plausible storage conditions.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

Colloidal Stability of PFSA-Ionomer Dispersions. Part I. Single-Ion Electrostatic Interaction Potential Energies

Charged colloidal particles neutralized by a single counterion are increasingly important for many emerging technologies. Attention here is paid specifically to hydrogen fuel cells and water electrolyzers whose catalyst layers are manufactured from a perfluorinated sulfonic acid polymer (PFSA) suspended in aqueous/alcohol solutions. Partially dissolved PFSA aggregates, known collectively as ionomers, are stabilized by the electrostatic repulsion of overlapping diffuse double layers consisting of only protons dissociated from the suspended polymer. We denote such double layers containing no added electrolyte as "single ion". Size-distribution predictions build upon interparticle interaction potential energies from the Derjaguin-Landau-Verwey-Overbeek (DLVO) formalism. However, when only a single counterion is present in solution, classical DLVO electrostatic potential energies no longer apply. Accordingly, here a new formulation is proposed to describe how single-counterion diffuse double layers interact in colloidal suspensions. Part II (Srivastav, H.; Weber, A. Z.; Radke, C. J. Langmuir 2024 DOI: 10.1021/acs.langmuir.3c03904) of this contribution uses the new single-ion interaction energies to predict aggregated size distributions and the resulting solution pH of PFSA in mixtures of n-propanol and water. A single-counterion diffuse layer cannot reach an electrically neutral concentration far from a charged particle. Consequently, nowhere in the dispersion is the solvent neutral, and the diffuse layer emanating from one particle always experiences the presence of other particles (or walls). Thus, in addition to an intervening interparticle repulsive force, a backside osmotic force is always present. With this new construction, we establish that single-ion repulsive pair interaction energies are much larger than those of classical DLVO electrostatic potentials. The proposed single-ion electrostatic pair potential governs dramatic new dispersion behavior, including dispersions that are stable at a low volume fraction but unstable at a high volume fraction and finite volume-fraction dispersions that are unstable with fine particles but stable with coarse particles. Finally, the proposed single-counterion electrostatic pair potential provides a general expression for predicting colloidal behavior for any charged particle dispersion in ionizing solvents with no added electrolyte.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Doping- and Strain-Dependent Electrolyte-Gate-Induced Perovskite to Brownmillerite Transformation in Epitaxial La 1– x Sr x CoO 3–δ Films

Much recent attention has focused on the voltage-driven reversible topotactic transformation between the ferromagnetic metallic perovskite (P) SrCoO 3-δ and oxygen-vacancy-ordered antiferromagnetic insulating brownmillerite (BM) SrCoO 2.5 . This is emerging as a paradigmatic example of the power of electrochemical gating (using, e.g., ionic liquids/gels), the wide modulation of electronic, magnetic, and optical properties generating clear application potential. SrCoO 3 films are challenging with respect to stability, however, and there has been little exploration of alternate compositions. Here, we present the first study of ion-gel-gating-induced P. BM transformations across almost the entire La 1-x SrxCoO 3 phase diagram (0 ≤ x ≤ 0.70), under both tensile and compressive epitaxial strain. Electronic transport, magnetometry, and operando synchrotron X-ray diffraction establish that voltage-induced P → BM transformations are possible at essentially all x, including x ≤ 0.50, where both P and BM phases are highly stable. Under small compressive strain, the transformation threshold voltage decreases from approximately +2.7 V at x = 0 to negligible at x = 0.70. Both larger compressive strain and tensile strain induce further threshold voltage lowering, particularly at low x. The P → BM threshold voltage is thus tunable, via both composition and strain. At x = 0.50, voltage-controlled ferromagnetism, transport, and optical transmittance are then demonstrated, achieving Curie temperature and resistivity modulations of similar to 220 K and at least 5 orders of magnitude, respectively, and enabling estimation of the voltage-dependent Co valence. The results are analyzed in the context of doping- and strain-dependent oxygen vacancy formation energies and diffusion coefficients, establishing that it is thermodynamic factors, not kinetics, that underpin the decrease in the threshold voltage with x, that is, with increasing formal Co valence. These findings substantially advance the practical and mechanistic understanding of this voltage-driven transformation, with fundamental and technological implications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Insights into oxygen diffusion in rare earth disilicate environmental barrier coatings

Environmental barrier coatings (EBC) are crucial for the use of SiC-based ceramic matrix composites in high-temperature combustion environments, yet knowledge of oxygen diffusion in these coatings is limited. This study investigates oxygen diffusion dynamics in the β-RE 2 Si 2 O 7 system to minimize oxygen penetration in rare earth disilicates. We analyze defect formation energy under varying oxygen conditions, identifying key diffusion mechanisms. In oxygen-rich environments, the most favorable neutral interstitial oxygen diffuses along the [110] direction. In oxygen-poor conditions, neutral oxygen vacancies rotate around Y and Si atoms, exhibiting a diffusivity of 6.59×10 −22 m 2 /s at 1500 K for β-Yb 2 Si 2 O 7 . Under intermediate oxygen levels, charged interstitial oxygen diffuses via concerted interstitialcy along the [001] direction with a diffusivity of 6.21×10 −17 m 2 /s. Additionally, alloying rare earth Y with Er and Yb increases diffusion barriers, contributing to improved EBC performance in extreme environments. The insights gained provides valuable guidance for designing robust coatings tailored to withstand extreme operational environments.

36 MATERIALS SCIENCE↗
DOE OSTI2012

Spark discharge formation in an inhomogeneous electric field under conditions of runaway electron generation

In this article we report on work where the formation of a spark in nanosecond high-voltage discharges was studied in nitrogen, nitrogen-methane mixtures, and air at increased pressures under the conditions of runaway electron generation. Voltage pulses of amplitude {approx}90 and {approx}250 kV were applied to a point-to-plane gap with a planar anode and a cathode of small curvature radius. Cathode spots appeared early in the discharge, within {approx}200 ps of a corona discharge at high rate of rise of the voltage ({approx}5 x 10{sup 14} V/s) across centimeter point-to-plane gap spacing. The spark leader that bridged the point-to-plane gap propagated from the planar anode with cathode spots and a voltage pulse rise time of less than 1 ns. The discharge from diffuse clouds took the form of diffuse jets with increasing pulse repetition rate, thus achieving the accumulation effect in a repetitively pulsed discharge. Characteristic emission spectra are presented for spark diffuse and corona discharges.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2012

10 ps resolution, 160 ns full scale range and less than 1.5% differential non-linearity time-to-digital converter module for high performance timing measurements

We present a compact high performance time-to-digital converter (TDC) module that provides 10 ps timing resolution, 160 ns dynamic range and a differential non-linearity better than 1.5% LSB{sub rms}. The TDC can be operated either as a general-purpose time-interval measurement device, when receiving external START and STOP pulses, or in photon-timing mode, when employing the on-chip SPAD (single photon avalanche diode) detector for detecting photons and time-tagging them. The instrument precision is 15 ps{sub rms} (i.e., 36 ps{sub FWHM}) and in photon timing mode it is still better than 70 ps{sub FWHM}. The USB link to the remote PC allows the easy setting of measurement parameters, the fast download of acquired data, and their visualization and storing via an user-friendly software interface. The module proves to be the best candidate for a wide variety of applications such as: fluorescence lifetime imaging, time-of-flight ranging measurements, time-resolved positron emission tomography, single-molecule spectroscopy, fluorescence correlation spectroscopy, diffuse optical tomography, optical time-domain reflectometry, quantum optics, etc.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2013

Control of contamination of radon-daughters in the DEAP-3600 acrylic vessel

DEAP-3600 is a 3600kg single-phase liquid-argon dark matter detector under construction at SNOLAB with a sensitivity of 10{sup −46}cm{sup 2} for a 100 GeV WIMP. The argon is held an an acrylic vessel coated with wavelength-shifting 1,1,4,4-tetraphenyl-1,3-butadiene (TPB). Acrylic was chosen because it is optically transparent at the shifted wavelength of 420 nm; an effective neutron shield; and physically strong. With perfect cleaning of the acrylic surface before data taking the irreducible background is that from bulk {sup 210}Pb activity that is near the surface. To achieve a background rate of 0.01 events in the 1000-kg fiducial volume per year of exposure, the allowed limit of Pb-210 in the bulk acrylic is 31 mBq/tonne (= 1.2 × 10{sup −20}g/g). We discuss how pure acrylic was procured and manufactured into a complete vessel paying particular attention to exposure to radon during all processes. In particular field work at the acrylic panel manufacturer, RPT Asia, and acrylic monomer supplier, Thai MMA Co. Ltd, in Thailand is described. The increased diffusion of radon during annealing the acrylic at 90C as well as techniques to mitigate against this are described.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2014

Hard X-ray spatial array diagnostics on Joint Texas Experimental Tokamak

A spatially distributed hard X-ray detection array has been developed to diagnose the loss of runaway electron with toroidal and poloidal resolution. The hard X-ray radiation in the energy ranges of 0.3–1 MeV resulted from runaway electrons can be measured. The detection array consists of 12 CdTe detectors which are arranged surrounding the tokamak. It is found that most runaway electrons which transport to plasma boundary tend to loss on limiters. The application of electrode biasing probe resulted in enhancement of local runaway loss. Resonant magnetic perturbations enhanced the runaway electrons diffusion and showed an asymmetric poloidal loss rate.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2018

The ecology of flows and drift wave turbulence in CSDX: A model

This paper describes the ecology of drift wave turbulence and mean flows in the coupled drift-ion acoustic wave plasma of a CSDX linear device. A 1D reduced model that studies the spatiotemporal evolution of plasma mean density $\bar{n}$, and mean flows $\bar{v}$y and $\bar{v}$z, in addition to fluctuation intensity ε, is presented. Here, ε = 〈 n ~ 2 + ( ∇ ⊥ Φ ~ ) 2 + v ~ z 2 〉 is the conserved energy field. The model uses a mixing length l mix inversely proportional to both axial and azimuthal flow shear. This form of l mix closes the loop on total energy. The model self-consistently describes variations in plasma profiles, including mean flows and turbulent stresses. It investigates the energy exchange between the fluctuation intensity and mean profiles via particle flux &#9001 n ~ v ~ x 〉 and Reynolds stresses 〈 v ~ x v ~ y 〉 and 〈 v ~ x v ~ z 〉 Acoustic coupling breaks parallel symmetry and generates a parallel residual stress Π res xz . The model uses a set of equations to explain the acceleration of $\bar{v}_y$ and $\bar{v}_z$ via Π x y r e s ∝ ∇ n - and Π x y r e s ∝ ∇ n - . Flow dynamics in the parallel direction are related to those in the perpendicular direction through an empirical coupling constant σVT. This constant measures the degree of symmetry breaking in the 〈$k_mk_z$〉 correlator and determines the efficiency of ∇$\bar{n}$ in driving $\bar{v}_z$. The model also establishes a relation between ∇$\bar{v}_y$ and ∇$\bar{v}_z$, via the ratio of the stresses Π res xy and Π res xz . When parallel to perpendicular flow coupling is weak, axial Reynolds power P x z R e = - 〈 v ~ x v ~ z &#9002 ∇ v - z is less than the azimuthal Reynolds power P x y R e = - 〈 v ~ x v ~ y 〉 ∇ v - y ∇$\bar{v}_y$. The model is then reduced to a 2-field predator/prey model where $\bar{v}_z$ is parasitic to the system and fluctuations evolve self-consistently. Finally, turbulent diffusion in CSDX follows the scaling: D CSDX = D B ρ * 0.6 , where D B is the Bohm diffusion coefficient and ρ * is the ion gyroradius normalized to the density gradient | ∇ n - / n - | - 1

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2024

Production of warm ions in electron beam generated E × B plasma

Several recent experiments have demonstrated low-damage processing of 2D materials, such as graphene and single crystal diamond, using electron beam (e-beam) generated plasmas with applied crossed electric and magnetic (E × B) fields. Here, the low damage of these sensitive materials is commonly attributed to the low energy of ions incident to the substrate surface and the ion confinement in E x B fields. In this work, measurements of atom and ion velocity distribution functions in an e-beam E × B plasma at sub-mTorr argon pressures using a laser-induced fluorescence diagnostic revealed the presence of a warm population of ions with temperatures of ~ 1 eV that are sufficient to destroy the ion confinement in E × B fields and drive the ion flux by cross field diffusion in the direction opposite to the applied electric field, toward the plasma-bounded walls or substrate. Thus, it is this nearly ambipolar diffusion process that is responsible for the flux of charged particles impinging on the wall/substrate surface.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

A new ductile, tougher resin for impregnation of superconducting magnets

A major remaining challenge for Nb 3 Sn high field magnets is their training due to random temperature variations in the coils. The main objective of our research is to reduce or eliminate it by finding novel impregnation materials in replacement of the epoxies currently used. An organic olefin-based thermosetting dicyclopentadiene resin, C 10 H 12 , commercially available in Japan as TELENE® by RIMTEC, was used to impregnate a short Nb 3 Sn undulator coil developed by ANL and FNAL. This magnet reached short sample limit after only two quenches, compared with ∼100 when CTD-101K® was used. Ductility, i.e. the ability to accept large strains, and toughness were identified as key properties to achieve these results. In addition, we have been investigating whether mixing TELENE with high heat capacity ceramic powders such as Gd 2 O 3 , Gd 2 O 2 S, and HoCu 2 , increases the specific heat (C p ) of impregnated Nb3Sn superconducting magnets. The viscosity, heat capacity, thermal conductivity, and other physical properties of TELENE with high-C p powder fillers were measured in this study as a function of temperature and magnetic field. The TELENE-87 wt%Gd 2 O 2 S had a peak in C p between 4.3 K and 5.3 K at fields between 0 and 8 T. We have also investigated the effect on the mechanical properties of pure and mixed TELENE under 10 MGy of gamma ray irradiation at the Takasaki Advanced Radiation Research Institute in Takasaki, Japan. TELENE-87 wt%Gd 2 O 2 S exhibited exceptional radiation resistance. Impregnating an undulator coil with TELENE mixed with Gd 2 O 2 S powder will verify whether the coils' thermal stability further improves, or whether its low diffusivity will require engineering the material with high-thermal conductivity components. Short magnet training will lead to better magnet reliability, lower magnet margins, lower risk and substantial saving in accelerators' commissioning costs. Part of this study is supported by the U.S.-Japan Science and Technology Cooperation Program in high energy physics operated by MEXT in Japan and DOE in the U.S.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2015

Scaling of Magnetic Reconnection in Relativistic Collisionless Pair Plasmas

Using fully kinetic simulations, we study the scaling of the inflow speed of collisionless magnetic reconnection from the non-relativistic to ultra-relativistic limit. In the anti-parallel configuration, the inflow speed increases with the upstream magnetization parameter σ and approaches the light speed when σ>O(100), leading to an enhanced reconnection rate. In all regimes, the divergence of pressure tensor is the dominant term responsible for breaking the frozen-in condition at the x-line. The observed scaling agrees well with a simple model that accounts for the Lorentz contraction of the plasma passing through the diffusion region. The results demonstrate that the aspect ratio of the diffusion region remains ~0.1 in both the non-relativistic and relativistic limits.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Characteristics of a DC discharge with a water cathode in argon

The characteristics of a dc discharge excited between a metal anode and a water cathode in argon were studied experimentally. The dimensions of the positive column and the electric field in it were measured, and the vibrational temperature in the positive column was determined from the N{sub 2}C{sup 3}Π{sub u} → B{sup 3}Π{sub g} (0–2) emission band. It is shown that the power deposited in the positive column is almost entirely spent on gas heating. The obtained dependence of the reduced electric field on the gas pressure and the ionization frequencies calculated by solving the Boltzmann equation indicate that electrons are lost diffusively, whereas ionization proceeds in a stepwise manner via the lower metastable states of argon atoms.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Building and experimenting with an agent-based model to study the population-level impact of CommunityRx, a clinic-based community resource referral intervention

CommunityRx (CRx), an information technology intervention, provides patients with a personalized list of healthful community resources (HealtheRx). In repeated clinical studies, nearly half of those who received clinical “doses” of the HealtheRx shared their information with others (“social doses”). Clinical trial design cannot fully capture the impact of information diffusion, which can act as a force multiplier for the intervention. Furthermore, experimentation is needed to understand how intervention delivery can optimize social spread under varying circumstances. To study information diffusion from CRx under varying conditions, we built an agent-based model (ABM). This study describes the model building process and illustrates how an ABM provides insight about information diffusion through in silico experimentation. To build the ABM, we constructed a synthetic population (“agents”) using publicly-available data sources. Using clinical trial data, we developed empirically-informed processes simulating agent activities, resource knowledge evolution and information sharing. Using RepastHPC and chiSIM software, we replicated the intervention in silico, simulated information diffusion processes, and generated emergent information diffusion networks. The CRx ABM was calibrated using empirical data to replicate the CRx intervention in silico. We used the ABM to quantify information spread via social versus clinical dosing then conducted information diffusion experiments, comparing the social dosing effect of the intervention when delivered by physicians, nurses or clinical clerks. The synthetic population (N = 802,191) exhibited diverse behavioral characteristics, including activity and knowledge evolution patterns. In silico delivery of the intervention was replicated with high fidelity. Large-scale information diffusion networks emerged among agents exchanging resource information. Varying the propensity for information exchange resulted in networks with different topological characteristics. Community resource information spread via social dosing was nearly 4 fold that from clinical dosing alone and did not vary by delivery mode. This study, using CRx as an example, demonstrates the process of building and experimenting with an ABM to study information diffusion from, and the population-level impact of, a clinical information-based intervention. While the focus of the CRx ABM is to recreate the CRx intervention in silico, the general process of model building, and computational experimentation presented is generalizable to other large-scale ABMs of information diffusion.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2017

Geomechanics-Based Stochastic Analysis of Injection- Induced Seismicity

The production of geothermal energy from dry and low permeability reservoirs is achieved by water circulation in natural and/or man-made fractures, and is referred to as enhanced or engineered geothermal systems (EGS). Often, the permeable zones have to be created by stimulation, a process which involves fracture initiation and/or activation of discontinuities such as faults and joints due to pore pressure and the in-situ stress perturbations. The stimulation of a rock mass is often accompanied by multiple microseismic events. Micro-seismic events associated with rock failure in shear, and shear slip on new or pre-existing fracture planes and possibly their propagations. The microseismic signals contain information about the sources of energy that can be used for understanding the hydraulic fracturing process and the created reservoir properties. Detection and interpretation of microseismic events is useful for estimating the stimulated zone, created reservoir permeability and fracture growth, and geometry of the geological structures and the in-situ stress state. The process commonly is referred to as seismicity-based reservoir characterization (SBRC). Although, progress has been made by scientific & geothermal communities for quantitative and qualitative analysis of reservoir stimulation using SBRC several key questions remain unresolved in the analysis of micro-seismicity namely, variation of seismic activity with injection rate, delayed micro-seismicity, and the relation of stimulated zone to the injected volume and its rate, and the resulting reservoir permeability. In addition, the current approach to SBRC does not consider the full range of relevant poroelastic and thermoelastic phenomena and neglects the uncertainty in rock properties and in-situ stress in the data inversion process. The objective of this research and technology developments was to develop a 3D SBRC model that addresses these shortcomings by taking into account hydro-thermo-poro-mechanical mechanisms associated with injection and utilizing a state-of-the-art stochastic inversion procedure. The approach proposed herein is innovative and significantly improves the existing SBCR technology (e.g., Shapiro et al. 2003) for geothermal reservoirs in several ways. First, the current scope of the SBRC is limited with respect to the physical processes considered and the rock properties used. Usually, the geomechanics analyses within SBRC is limited to the pore pressure diffusion in the rock mass, which is modeled using a time-dependent parabolic equation and solved using a finite element algorithm with either a line or a point source. However, water injection induces both poroelastic and thermoelastic stresses in the rock mass which affect the stress state. In fact, it has been suggested that thermoelastic stresses can play a dominant role in reservoir seismicity (Ghassemi et al., 2007). We include these important effects by using a fully-coupled poro-thermoelastic constitutive equations for the rock mass which will be solved using a 3D finite element model with more realistic injection geometries such as multiple injection/extraction sources (and in fractures), uncertainty in the material parameters and the in-situ stress distribution to better reflect the pore pressure and stress distributions. In addition, we developed a 3D stochastic fracture network model to study MEQ generation in fracture rocks. The model was verified using laboratory experiments, and calibrated and applied to Newberry EGS stimulation. In previous SBRC approaches, the triggering of micro-seismicity is modeled base on the assumption that the prior stochastic criticality model of the rock mass is a valid and adequate description. However, this assumption often does not hold in the field. Thus, we improved upon the current SBRC approach by using the micro-seismic responses to estimate the hydraulic diffusivity as well as the criticality distribution itself within the field. In this way, instead of relying on our a priori knowledge of criticality distribution, we combine an initial probabilistic description of criticality with the information contained in microseismic measurements to arrive at criticality solutions that are conditioned on both field data and our prior knowledge. Previous SBRC have relied upon a deterministic inversion approach to estimate the permeability, and the extent of the stimulated zone, whereas a stochastic inversion algorithm that recognizes and quantifies the uncertainties in the prior model, the time evolution of pore pressure distributions (modeling errors), and the observed seismic events is developed and used herein to realistically assess the quality of the solution. Finally, we developed a technique for processing discrete MEQ data to estimate fracture network properties such as dip and dip directions. The approach was successfully applied to the Fenton Hill HRD experiment and the Newberry EGS with results in good agreement with field observations.

15 GEOTHERMAL ENERGY↗
DOE OSTI2024

Investigations on the multiple-sector hard-copper X-band accelerating structures

The development of advanced, high gradient accelerating structures is one of the leading activity of the particle accelerator community. In the technological research of new construction methods for these devices, high-power testing is a critical step for the verification of their viability. Recent experiments showed that accelerating cavities made out of hard copper, fabricated without high-temperature processes, can achieve better performance as compared with soft copper ones. Recently, we have built cavities using Tungsten Inert Gas welding and the high-power experiments confirmed that this joining process is a robust and low-cost alternative to brazing or diffusion bonding. This is a good solution for high-gradient operation, with a gradient of about 150 MV/m in X-band, at a breakdown rate of 10 -3 /pulse/meter using a shaped RF pulse with a 150 ns flat part. We continue the design, construction and high power tests of three-cells standing-wave X-band accelerating cavities fabricated with a split-open geometry, made of hard copper and vacuum-sealed by welding. Our aim is the fabrication of accelerating structures made out of hard copper alloys by using innovative cost-effective technologies. Moreover, our method of multiple-sector structures opens the way to new technological approaches and design methods, for example providing the possibility of placing dampers of the parasitic higher-order modes. Such structures with dampers allow for acceleration of multi-bunch beams, both in standing and in travelling-wave accelerating modality. Here, this paper describes the design of two cavities made of multiple sectors that were fabricated at the Italian Institute for Nuclear Physics in Frascati, Italy (INFN-LNF), assembled by means of clamping and then joined with the Tungsten Inert Gas welding in order to preserve the hardness of the metal. These are three-cell standing-wave X-band accelerating cavities, to be operated in the π-mode. We report the low-power RF tests of the first one, made of two halves, and the RF design of the second one, made of four quadrants. Both structures were built for high-gradient tests at SLAC National Accelerator Laboratory.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2012

Proton Conduction in Exchange Membranes across Multiple Length Scales

Concerns over global climate change associated with fossil-fuel consumption continue to drive the development of electrochemical alternatives for energy technology. Proton exchange fuel cells are a particularly promising technology for stationary power generation, mobile electronics, and hybrid engines in automobiles. For these devices to work efficiently, direct electrical contacts between the anode and cathode must be avoided; hence, the separator material must be electronically insulating but highly proton conductive. As a result, researchers have examined a variety of polymer electrolyte materials for use as membranes in these systems. In the optimization of the membrane, researchers are seeking high proton conductivity, low electronic conduction, and mechanical stability with the inclusion of water in the polymer matrix. A considerable number of potential polymer backbone and side chain combinations have been synthesized to meet these requirements, and computational studies can assist in the challenge of designing the next generation of technologically relevant membranes. Such studies can also be integrated in a feedback loop with experiment to improve fuel cell performance. However, to accurately simulate the currently favored class of membranes, perfluorosulfonic acid containing moieties, several difficulties must be addressed including a proper treatment of the proton-hopping mechanism through the membrane and the formation of nanophase-separated water networks. We discuss our recent efforts to address these difficulties using methods that push the limits of computer simulation and expand on previous theoretical developments. We describe recent advances in the multistate empirical valence bond (MS-EVB) method that can probe proton diffusion at the nanometer-length scale and accurately model the so-called Grotthuss shuttling mechanism for proton diffusion in water. Using both classical molecular dynamics and coarse-grained descriptions that replace atomistic representations with collective coordinates, we investigated the proton conductivity of polymer membrane structure as a function of hydration level. Nanometer-sized water channels form torturous pathways that are traversed by the charges during fuel cell operation. Using a combination of coarse-grained membrane structure and novel multiscale methods, we demonstrate emerging approaches to treat proton motion at the mesoscale in these complex materials.

Jorn, Ryan↗