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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,225 records · Page 68
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

Carrier accumulation near electrodes in ferroelectric films due to polarization boundary conditions

We study the effect of surface polarization on the distribution of free carriers in a wide bandgap semiconductor ferroelectric (FE) film using a thermodynamic approach. We show that free carriers, namely, holes and electrons from ionizable impurities or atomic vacancies can accumulate near the film-electrode interface, if FE polarization profile has a very steep change near the surface that is specified by the extrapolation length. Such an outcome is just the opposite of what happens in a Schottky junction in a partially or fully depleted film. This is also an entirely different effect than what has been often studied in similar structures, where the work function and screening length of the electrode metal determines the electronic character of the interface. Even for low-to-moderate densities of ionizable defects with states within the bandgap close to the band edges, high densities of carriers can localize close to the electrodes in a single domain state FE film when above a critical thickness. For very low densities of such ionizable defects, short extrapolation lengths cause electrical domain formation with minimal carrier accumulation because of the already weak depolarizing fields. This is also true for films below a critical thickness with low-to-moderate densities of ionizable impurities, i.e., electrical domains get stabilized regardless of defect density. The implications of our findings for polarization controlled Schottky to Ohmic-like transition of an interface and experimental results are discussed. It is also found that interfaces of an n-type FE heterostructure can behave like a p-type depending on the barrier heights and impurity density. We conclude that, for low-to-moderate ionizable impurity densities, it is the rate of change of polarization at the interface with position rather than solely its presence that leads to carrier accumulation and that both interfaces can become Ohmic-like with opposite signs of carriers.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2024

Data-driven nonlocal model for fragmentation in the crushing of solids

A technique is proposed for reproducing particle size distributions in three-dimensional simulations of the crushing and comminution of solid materials. The method is designed to produce realistic distributions over a wide range of loading conditions, especially for small fragments. In contrast to most existing methods, the new model does not explicitly treat the small-scale process of fracture. Instead, it uses measured fragment distributions from laboratory tests as the basic material property that is incorporated into the algorithm, providing a data-driven approach. The algorithm is implemented within a nonlocal peridynamic solver, which simulates the underlying continuum mechanics and contact interactions between fragments after they are formed. Finally, the technique is illustrated in reproducing fragmentation data from drop weight testing on sandstone samples.

58 GEOSCIENCES↗
NASA NTRS1979

A passive microwave technique for profiling of atmospheric water vapor

There is considerable interest in remote measurements of the vertical distribution of water vapor, particularly under cloud conditions. The net integrated amount of water vapor has been measured using the 22.235-GHz water vapor line (Staelin et al., 1975). Attempts to use this line for obtaining vertical distribution information have not been fruitful because of the weakness of absorption even at line center. The 183.310-GHz line is much stronger and thus provides a possibility of profiling water vapor. The paper presents a preliminary analysis of this possibility. A technique is described for retrieval of water vapor profiles from microwave radiometric measurements near the 183-GHz water vapor line, and weighting functions useful in the retrievals are developed. The results suggest that microwave radiometry near the 183-GHz water vapor line could yield interesting water vapor profiles, at least over oceans.

Schaerer, G.↗
DOE OSTI2016

VOLTTRON™: Tech-to-Market Best-Practices Guide for Small- and Medium-Sized Commercial Buildings

VOLTTRON™ is an open-source distributed control and sensing platform developed by Pacific Northwest National Laboratory for the U.S. Department of Energy. It was developed to be used by the Office of Energy Efficiency and Renewable Energy to support transactive controls research and deployment activities. VOLTTRON is designed to be an overarching integration platform that could be used to bring together vendors, users, and developers and enable rapid application development and testing. The platform is designed to support modern control strategies, including the use of agent- and transaction-based controls. It also is designed to support the management of a wide range of applications, including heating, ventilation, and air-conditioning systems; electric vehicles; and distributed-energy and whole-building loads. This report was completed as part of the Building Technologies Office’s Technology-to-Market Initiative for VOLTTRON’s Market Validation and Business Case Development efforts. The report provides technology-to-market guidance and best practices related to VOLTTRON platform deployments and commercialization activities for use by entities serving small- and medium-sized commercial buildings. The report characterizes the platform ecosystem within the small- and medium-sized commercial building market and articulates the value proposition of VOLTTRON for three core participants in this ecosystem: 1) platform owners/adopters, 2) app developers, and 3) end-users. The report also identifies key market drivers and opportunities for open platform deployments in the small- and medium-sized commercial building market. Possible pathways to the market are described—laboratory testing to market adoption to commercialization. We also identify and address various technical and market barriers that could hinder deployment of VOLTTRON. Finally, we provide “best practice” tech-to-market guidance for building energy-related deployment efforts serving small- and medium-sized commercial buildings.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS2015

System and Method for Monitoring Distributed Asset Data

A computer-based monitoring system and monitoring method implemented in computer software for detecting, estimating, and reporting the condition states, their changes, and anomalies for many assets. The assets are of same type, are operated over a period of time, and outfitted with data collection systems. The proposed monitoring method accounts for variability of working conditions for each asset by using regression model that characterizes asset performance. The assets are of the same type but not identical. The proposed monitoring method accounts for asset-to-asset variability; it also accounts for drifts and trends in the asset condition and data. The proposed monitoring system can perform distributed processing of massive amounts of historical data without discarding any useful information where moving all the asset data into one central computing system might be infeasible. The overall processing is includes distributed preprocessing data records from each asset to produce compressed data.

Gorinevsky, Dimitry↗
NASA NTRS1993

Dynamic of Langmuir and Ion-Sound Waves in Type 3 Solar Radio Sources

The evolution of Langmuir and ion-sound waves in type 3 sources is investigated, incorporating linear growth, linear damping, and nonlinear electrostatic decay. Improved estimates are obtained for the wavenumber range of growing waves and the nonlinear coupling coefficient for the decay process. The resulting prediction for the electrostatic decay threshold is consistent with the observed high-field cutoff in the Langmuir field distribution. It is shown that the conditions in the solar wind do not allow a steady state to be attained; rather, bursty linear and nonlinear interactions take place, consistent with the highly inhomogeneous and impulsive waves actually observed. Nonlinear growth is found to be fast enough to saturate the growth of the parent Langmuir waves in the available interaction time. The resulting levels of product Langmuir and ion-sound waves are estimated theoretically and shown to be consistent with in situ ISEE 3 observations of type 3 events at 1 AU. Nonlinear interactions slave the growth and decay of product sound waves to that of the product Langmuir waves. The resulting probability distribution of ion-sound field strengths is predicted to have a flat tail extending to a high-field cutoff. This prediction is consistent with statistics derived here from ISEE 3 observations. Agreement is also found between the frequencies of the observed waves and predictions for the product S waves. The competing processes of nonlinear wave collapse and quasilinear relaxation are discussed, and it is concluded that neither is responsible for the saturation of Langmuir growth. When wave and beam inhomogeneities are accounted for, arguments from quasi-linear relaxation yield an upper bound on the Langmuir fields that is too high to be relevant. Nor are the criteria for direct wave collapse of the beam-driven waves met, consistent with earlier simulation results that imply that this process is not responsible for saturation of the beam instability. Indeed, even if the highest observed Langmuir fields are assumed to he part of a long-wavelength 'condensate' produced via electrostatic decay, they still fall short of the relevant requirements for wave collapse. The most stringent requirement for collapse is that collapsing wave packets not be disrupted by ambient density fluctuations in the solar wind. Fields of several mV m(exp -1) extending over several hundred km would be needed to satisfy this requirement; at 1 AU such fields are rare at best.

Robinson, P. A.↗
DOE OSTI2017

High-speed, two-dimensional synchrotron white-beam x-ray radiography of spray breakup and atomization

High-speed, two-dimensional synchrotron x-ray radiography and phase-contrast imaging are demonstrated in propulsion sprays. Measurements are performed at the 7-BM beamline at the Advanced Photon Source user facility at Argonne National Laboratory using a recently developed broadband x-ray white beam. This novel enhancement allows for high speed, high fidelity x-ray imaging for the community at large. Quantitative path-integrated liquid distributions and spatio-temporal dynamics of the sprays were imaged with a LuAG:Ce scintillator optically coupled to a high-speed CMOS camera. Images are collected with a microscope objective at frame rates of 20 kHz and with a macro lens at 120 kHz, achieving spatial resolutions of 12 μm and 65 μm, respectively. Imaging with and without potassium iodide (KI) as a contrast-enhancing agent is compared, and the effects of broadband attenuation and spatial beam characteristics are determined through modeling and experimental calibration. In addition, phase contrast is used to differentiate liquid streams with varying concentrations of KI. The experimental approach is applied to different spray conditions, including quantitative measurements of mass distribution during primary atomization and qualitative visualization of turbulent binary fluid mixing. High-speed, two-dimensional synchrotron white-beam x-ray radiography of spray breakup and atomization. Available from: https://www.researchgate.net/publication/312567827_High-speed_two-dimensional_synchrotron_white-beam_x-ray_radiography_of_spray_breakup_and_atomization [accessed Aug 31, 2017].

Halls, Benjamin R.↗
DOE OSTI2020

Three-dimensional microstructure-explicit and void-explicit mesoscale simulations of detonation of HMX at millimeter sample size scale

Fully three-dimensional (3D) microstructure-explicit and void-explicit mesoscale simulations of the shock-to-detonation (SDT) process of pressed granular HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) are performed. The overall size scale of the models is up to 3 × 3 × 15 mm3, with ∼30 000 grains and 206 265 voids. The models account for the heterogeneous material microstructure, constituent distribution, constituent morphology, and voids. Loading conditions considered involve piston velocities in the range of 600–1200 m/s or pressures in the range of 4–8 GPa. The focus is on analyzing the SDT process and the effects of microstructure and voids on the run-to-detonation distance (RDD). Companion two-dimensional (2D) simulations are also carried out to assess the differences between 2D and 3D. Statistically equivalent microstructure sample sets (SEMSSs) are generated and used for both 2D and 3D, allowing the prediction of the statistical and probabilistic Pop plots (PPs). The predictions are in general agreement with trends in available experimental data in the literature. It is found that both the microstructure (heterogeneous grain size, morphology, and size distribution) and voids significantly affect the RDD and the PPs. These effects are systematically delineated and quantified via the use of SEMSSs with different combinations of attributes. A recently developed probabilistic formulation for the PPs is used to characterize the results, allowing uncertainties in the relations between the shock pressure and RDD arising from material heterogeneities to be quantified. The probabilistic formulation is further used to quantify the confidence levels in the ranked order of influences of different combinations of microstructure and voids on the PPs.

Miller, Christopher (ORCID:0000000206844381)↗
DOE OSTI2021

Cost Analysis Framework for Comparing AC and DC Design Alternatives for Building Electrical Distribution Systems

In recent years, in response to the changing nature of building load, direct current (DC) distribution systems for buildings have been proposed as alternatives to traditional alternating current (AC) systems. DC distribution offers a closer match to the types of loads and generation sources found in modern buildings, the majority of which use DC electricity internally either natively or as a power conditioning stage. The proposed benefits of DC distribution compared to AC distribution within buildings include higher efficiency, lower installation cost, lower operating cost, higher reliability, improved communication and control, and simplicity. Most recent DC distribution research has focused on quantifying the efficiency advantage of DC distribution over AC distribution. However, energy savings alone do not guarantee cost savings; a more complete cost accounting is required to establish financial benefit. This report provides a framework for cost analysis and comparison of building electrical distribution systems, including common variants for both AC and DC distribution systems. The framework includes all major cost categories, including up-front costs (capital, installation labor, soft costs) and long-term costs (energy, operations and maintenance).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2021

Local structure and Ca/Si ratio in C-S-H gels from hydration of blends of tricalcium silicate and silica fume

At the microscale, C-S-H gels from alite, or neat Portland cements, has a Ca/Si ratio close to 1.80. At the nanoscale, C-S-H is described by a defective tobermorite structure which allows a maximum Ca/Si ratio close to 1.40. There is no agreement in the location of the extra 0.40 mol of Ca(OH){sub 2} at the nanoscale. Atomistic modelling studies reported Ca(OH){sub 2} species within the tobermorite interlayer space. Other works point toward a fine intermixing of defective tobermorite and nanoportlandite. Here, we have prepared a series of alite blended with silica fume and studied the pastes by several techniques including synchrotron pair distribution function (PDF). In the employed conditions, the C-S-H gel formed by the pozzolanic reaction has nearly the same local structure than the primary C-S-H gel. Furthermore, differential PDF points toward Ca(OH){sub 2} excess having a local structure compatible with few-layer thick nanoparticles stretched along the c-axis.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Propagation, proppant transport and the evolution of transport properties of hydraulic fractures

Hydraulic fracturing is a widely used method for well stimulation to enhance hydrocarbon recovery. Permeability, or fluid conductivity, of the hydraulic fracture is a key parameter to determine the fluid production rate, and is principally conditioned by fracture geometry and the distribution of the encased proppant. A numerical model is developed to describe proppant transport within a propagating blade-shaped fracture towards defining the fracture conductivity and reservoir production after fracture closure. Fracture propagation is formulated based on the PKN-formalism coupled with advective transport of an equivalent slurry representing a proppant-laden fluid. Empirical constitutive relations are incorporated to define rheology of the slurry, proppant transport with bulk slurry flow, proppant gravitational settling, and finally the transition from Poiseuille (fracture) flow to Darcy (proppant pack) flow. At the maximum extent of the fluid-driven fracture, as driving pressure is released, a fracture closure model is employed to follow the evolution of fracture conductivity with the decreasing fluid pressure. This model is capable of accommodating the mechanical response of the proppant pack, fracture closure of potentially contacting rough surfaces, proppant embedment into fracture walls, and most importantly flexural displacement of the unsupported spans of the fracture. Results show that reduced fluid viscosity increases the length of the resulting fracture, while rapid leak-off decreases it, with both characteristics minimizing fracture width over converse conditions. Proppant density and size do not significantly influence fracture propagation. Proppant settling ensues throughout fracture advance, and is accelerated by a lower viscosity fluid or greater proppant density or size, resulting in accumulation of a proppant bed at the fracture base. ‘Screen-out’ of proppant at the fracture tip can occur where the fracture aperture is only several times the diameter of the individual proppant particles. After fracture closure, proppant packs comprising larger particles exhibit higher conductivity. More importantly, high-conductivity flow channels are necessarily formed around proppant banks due to the flexural displacement of the fracture walls, which offer preferential flow pathways and significantly influence the distribution of fluid transport. Higher compacting stresses are observed around the edge of proppant banks, resulting in greater depths of proppant embedment into the fracture walls and/or an increased potential for proppant crushing.

Mechanics↗
NASA NTRS1978

Characterization of a swept-strut hydrogen fuel-injector for scramjet applications

Results of an experimental investigation of a swept-strut hydrogen fuel-injector simulating the center strut of a three strut scramjet module at Mach 6 flight conditions are presented. Detailed wall pressure distributions from over 100 separate tests with overall fuel flow from 0.1 to 1.3 times stoichiometric and test gas stagnation temperature from 1100 to 2400 K were recorded. The distance for pressure rise from the point of injection was found to increase with increasing test stagnation temperature. This trend indicates that chemical kinetics in the immediate region of perpendicular injection are not likely to be the mechanism controlling the onset of pressure rise. A fluid dynamic mechanism is suggested involving separation of the boundary layer downstream of injection which is forced upstream from the trailing edge by pressure rise due to combustion occurring in the base region of the strut. The results obtained indicate that the swept-strut fuel-injector concept can be adapted to a wide range of flight conditions by varying the amount of perpendicular fuel injection.

Northam, G. B.↗
DOE OSTI2023

Scaling hyporheic nitrogen cycling in large river alluvial aquifers

Research Element 1: Denitrification is a difficult flux to measure when fluxes are low and when the ecosystem is difficult to sample. These attributes describe Nyack floodplain, a large gravel-bedded aquifer adjacent to the Middle Fork Flathead River. Given that denitrification is simply respiration with nitrate as a terminal electron acceptor, we reasoned that N 2 production should negatively covary with oxygen respiration so long that oxygen is available. We sampled 16 wells 8 times throughout a year and analyzed these water samples on a membrane-inlet mass spectrometer for N 2 :Ar and O 2 . We fit multilevel models to N 2 :Ar as a function of dissolved oxygen. Within wells, there was no relationship between O 2 and N 2 :Ar. Among wells N 2 :Ar increased as O 2 declined. Based on the slope of this relationship, ~ -0.07, and estimated oxygen respiration in Nyack derived from prior studies, a possible range for denitrification is 0-8 mmol m -2 d -1 corresponding to a turnover rate for nitrate of 0-0.2/d. This estimated turnover rate is in the lower 20% of rates measured in the LINX 2 study, yet shows that even in a low nitrate (0.005 mmol/L) aquifer denitrification can be a substantial sink for dissolved N. Research Element 3 and 4: We developed a new theoretical approach to describe the relationship between water inflow, water outflow, and water age in porous media control volumes under dynamic flow conditions. Our approach had three distinct steps. First we described the application of well-established equations borrowed from Chemical Engineering to describe water age distributions in the hyporheic zone under steady state conditions. We published the associated results in the scientific journal PLOS ONE. Second, we developed a new theory ("flow spans") to describe how predicted steady-state water age distributions will respond to time varying imbalances in hyporheic discharge and recharge. Finally, we developed a proof-of-concept simulation model based on the new theory and used the model to examine the effects of flow regulation on a simulated river with characteristics representative of western U.S. montane rivers with expansive hyporheic zones.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Excitation and evolution of finite-amplitude plasma wave

The evolution of a small spatially periodic perturbation in the electron velocity distribution function in collisionless plasma is reconsidered by numerically solving the Vlasov and Poisson equations. The short as well as long time behaviors of the excited oscillations and damping/modulation are followed. In the small but finite-amplitude excited plasma wave, resonant electrons become trapped in the wave potential wells and their motion affects the low-velocity electrons participating in the plasma oscillations, leading to modulation of the latter at an effective trapping frequency. It is found that the phase space of the resonant and low-velocity electrons becomes chaotic, but then self-organization takes place but remains fine-scale chaotic. It is also found that as long as particles are trapped, there is only modulation and no monotonic damping of the excited plasma wave. The modulation period/amplitude increases/decreases as the magnitude of the initial disturbance is reduced. For the initial and boundary conditions used here, linear Landau damping corresponds to the asymptotic limit of the modulation period becoming infinite, or no trapping of the resonant electrons.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1989

Laboratory measurements of the 7.5-9.38-mm absorption of gaseous ammonia (NH3) under simulated Jovian conditions

An attempt is made to infer the abundance and distribution of ammonia from RF emission measurements more accurately than heretofore, on the basis of the results of laboratory measurements for the mm-wave opacity of gaseous ammonia under simulated Jovian atmosphere conditions. The measurements were conducted at various frequencies in the 32-40 GHz range at 2 atm and 203 K; the atmospheric mixture was 88.34 percent H2, 9.81 percent He, and 1.85 percent NH3. Experimental results are found to be readily modeled by the Gross (1955) line-shape factor, rather than that of Van Vleck and Weisskopf (1945).

Joiner, Joanna↗
DOE OSTI2017

Development of Classification Systems for Wave Energy Resources and WEC Technologies

The submission includes wave resource classification reports, summary of classification statistics and regional trends, and data files with classification statistics for selected sites for extreme significant wave height. Two conference papers were uploaded that include classification metrics and geographic distributions for US coastal waters. These conference papers are: Neary, V.S., Coe, R.G., Cruz, J., Haas, K., Bacelli, G., Debruyne, Y., Ahn, S., Nevarez, V. (2017) Classification systems for wave energy resources and WEC technologies. Proceedings of 12th European Wave and Tidal Energy Conference Series (EWTEC 2017), Cork, Ireland, August 27-September 1, 2017 Haas, K., Ahn, S., Neary, V.S., and S. Bredin (2017) Development of a wave energy classification system. Proceedings of the 5th Marine Energy Technology Symposium (METS2017), Washington, D.C., May 1-3, 2017

16 TIDAL AND WAVE POWER↗
NASA NTRS1979

Improvements in surface singularity analysis and design methods

The coupling of the combined source vortex distribution of Green's potential flow function with contemporary numerical techniques is shown to provide accurate, efficient, and stable solutions to subsonic inviscid analysis and design problems for multi-element airfoils. The analysis problem is solved by direct calculation of the surface singularity distribution required to satisfy the flow tangency boundary condition. The design or inverse problem is solved by an iteration process. In this process, the geometry and the associated pressure distribution are iterated until the pressure distribution most nearly corresponding to the prescribed design distribution is obtained. Typically, five iteration cycles are required for convergence. A description of the analysis and design method is presented, along with supporting examples.

Bristow, D. R.↗
DOE OSTI2015

Kinetic model of force-free current sheets with non-uniform temperature

The kinetic model of a one-dimensional force-free current sheet (CS) developed recently by Harrison and Neukirch [Phys. Rev. Lett. 102(13), 135003 (2009)] predicts uniform distributions of the plasma temperature and density across the CS. However, in realistic physical systems, inhomogeneities of these plasma parameters may arise quite naturally due to the boundary conditions or local plasma heating. Moreover, as the CS spatial scale becomes larger than the characteristic kinetic scales (the regime often referred to as the MHD limit), it should be possible to set arbitrary density and temperature profiles. Thus, an advanced model has to allow for inhomogeneities of the macroscopic plasma parameters across the CS, to be consistent with the MHD limit. In this paper, we generalise the kinetic model of a force-free current sheet, taking into account the inhomogeneity of the density and temperature across the CS. In the developed model, the density may either be enhanced or depleted in the CS central region. The temperature profile is prescribed by the density profile, keeping the plasma pressure uniform across the CS. All macroscopic parameters, as well as the distribution functions for the protons and electrons, are determined analytically. Applications of the developed model to current sheets observed in space plasmas are discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗