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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,225 records · Page 68

Impacts of the Minamata Conventionon on Mercury Emissions and Global Deposition from Coal-Fired Power Generation in Asia

We explore implications of the United Nations Minamata Convention on Mercury for emissions from Asian coal-fired power generation, and resulting changes to deposition worldwide by 2050. We use engineering analysis, document analysis, and interviews to construct plausible technology scenarios consistent with the Convention. We translate these scenarios into emissions projections for 2050, and use the GEOS-Chem model to calculate global mercury deposition. Where technology requirements in the Convention are flexibly defined, under a global energy and development scenario that relies heavily on coal, we project similar to 90 and 150 Mg.y(-1) of avoided power sector emissions for China and India, respectively, in 2050, compared to a scenario in which only current technologies are used. Benefits of this avoided emissions growth are primarily captured regionally, with projected changes in annual average gross deposition over China and India similar to 2 and 13 mu g.m(-2) lower, respectively, than the current technology case. Stricter, but technologically feasible, mercury control requirements in both countries could lead to a combined additional 170 Mg.y(-1) avoided emissions. Assuming only current technologies but a global transition away from coal avoids 6% and 36% more emissions than this strict technology scenario under heavy coal use for China and India, respectively.

ANTHROPOGENIC SOURCES↗

Turbulence and Control of Wind Farms

The dynamics of the turbulent atmospheric boundary layer play a fundamental role in wind farm energy production, governing the velocity field that enters the farm as well as the turbulent mixing that regenerates energy for extraction at downstream rows. Understanding the dynamic interactions among turbines, wind farms, and the atmospheric boundary layer can therefore be beneficial in improving the efficiency of wind farm control approaches. Anticipated increases in the sizes of new wind farms to meet renewable energy targets will increase the importance of exploiting this understanding to advance wind farm control capabilities. This review discusses approaches for modeling and estimation of the wind farm flow field that have exploited such knowledge in closed-loop control, to varying degrees. We focus on power tracking as an example application that will be of critical importance as wind farms transition into their anticipated role as major suppliers of electricity. The discussion highlights the benefits of including the dynamics of the flow field in control and points to critical shortcomings of the current approaches.

Automation & Control Systems↗

The Impact of Transformer Winding Connections of A Grid-Connected PV on Voltage Quality Improvement

In this paper, the high-power PV plant is connected to the weak grid by means of a three-phase power transformer. The selection of transformer winding connection is critical especially when the PV inverter has a reactive power controller. In general, transformer winding connection can be arranged in star-star (with neutral earthed) or star-delta. The reactive power controller supports voltage regulation of the power system particularly under transient faults. Its control strategy is based on utilizing the grid currents to make a three-phase reactive unbalanced current with a small gain. The gain is determined by the system impedance. Simulation results exhibit that the control strategy works very well particularly under disturbance conditions when the transformer winding connection is star-star with both neutrals grounded. The power quality in terms of the voltage quality is improved.

14 SOLAR ENERGY↗

Prostaglandin potentiates 5-HT responses in stomach and ileum innervating visceral afferent sensory neurons

Highlights: • Prostaglandin E2 (PGE{sub 2}) effect was tested on visceral afferent neurons. • PGE{sub 2} did not evoke response but potentiated serotonin (5-HT) currents up to 167%. • PGE{sub 2}-induced potentiation was blocked by E-prostanoid type 4 receptors antagonist. • PGE{sub 2} effect on 5-HT response was also blocked by protein kinase A inhibitor KT5720. • Thus, PGE{sub 2} modulate visceral afferent neurons via synergistic signaling with 5-HT. - Abstract: Gastrointestinal disorder is a common symptom induced by diverse pathophysiological conditions that include food tolerance, chemotherapy, and irradiation for therapy. Prostaglandin E{sub 2} (PGE{sub 2}) level increase was often reported during gastrointestinal disorder and prostaglandin synthetase inhibitors has been used for ameliorate the symptoms. Exogenous administration of PGE{sub 2} induces gastrointestinal disorder, however, the mechanism of action is not known. Therefore, we tested PGE{sub 2} effect on visceral afferent sensory neurons of the rat. Interestingly, PGE{sub 2} itself did not evoked any response but enhanced serotonin (5-HT)-evoked currents up to 167% of the control level. The augmented 5-HT responses were completely inhibited by a 5-HT type 3 receptor antagonist, ondansetron. The PGE{sub 2}-induced potentiation were blocked by a selective E-prostanoid type4 (EP{sub 4}) receptors antagonist, L-161,982, but type1 and 2 receptor antagonist AH6809 has no effect. A membrane permeable protein kinase A (PKA) inhibitor, KT5720 also inhibited PGE{sub 2} effects. PGE{sub 2} induced 5-HT current augmentation was observed on 15% and 21% of the stomach and ileum projecting neurons, respectively. Current results suggest a synergistic signaling in visceral afferent neurons underlying gastrointestinal disorder involving PGE{sub 2} potentiation of 5-HT currents. Our findings may open a possibility for screen a new type drugs with lower side effects than currently using steroidal prostaglandin synthetase inhibitors by selectively targeting EP{sub 4} receptor/PKA pathway without interrupt prostaglandin synthesis.

60 APPLIED LIFE SCIENCES↗

A Conceptual Architecture for National Biosurveillance: Moving Beyond Situational Awareness to Enable Digital Detection of Emerging Threats

Despite numerous calls for improvement, the U.S. biosurveillance enterprise remains a patchwork of uncoordinated systems that fail to take advantage of the rapid progress in information processing, communication, and analytics made in the past decade. By synthesizing components from the extensive biosurveillance literature, we propose a conceptual framework for a national biosurveillance architecture and provide suggestions for implementation. The framework differs from the current federal biosurveillance development pathway in that it is not focused on systems useful for “situational awareness,” but is instead focused on the long-term goal of having true warning capabilities. Therefore, a guiding design objective is the ability to digitally detect emerging threats that span jurisdictional boundaries, because attempting to solve the most challenging biosurveillance problem first provides the strongest foundation to meet simpler surveillance objectives. Core components of the vision are: (1) a whole-of-government approach to support currently disparate federal surveillance efforts that have a common data need, including those for food safety, vaccine and medical product safety, and infectious disease surveillance; (2) an information architecture that enables secure, national access to electronic health records, yet does not require that data be sent to a centralized location for surveillance analysis; (3) an inference architecture that leverages advances in ‘big data’ analytics and learning inference engines—a significant departure from the statistical process control paradigm that underpins nearly all current syndromic surveillance systems; and, (4) an organizational architecture with a governance model aimed at establishing national biosurveillance as a critical part of the U.S. national infrastructure. Although it will take many years to implement, and a national campaign of education and debate to acquire public buy-in for such a comprehensive system, the potential benefits warrant increased consideration within the U.S. government.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Imaging-based optical caliper for objects in hot manufacturing processes

OG Technologies, Inc. (OGT), in conjunction with its industrial and academic partners, proposes to develop an Imaging-Based Optical Caliper (hereafter referred to as OC) for Objects in Hot Manufacturing Processes. The goal is to develop and demonstrate the OC with the synergy of OGT's current technological pool and other innovations to provide a light weight, robust, safe and accurate portable dimensional measurement device for hot objects with integrated wireless communication capacity to enable real time process control. The technical areas of interest in this project are the combination of advanced imaging, Sensor Fusion, and process control. OGT believes that the synergistic interactions between its current set of technologies and other innovations could deliver products that are viable and have high impact in the hot manufacture processes, such as steel making, steel rolling, open die forging, and glass industries, resulting in a new energy efficient control paradigm in the operations through improved yield, prolonged tool life and improved quality. In-line dimension measurement and control is of interest to the steel makers, yet current industry focus is on the final product dimension only instead of whole process due to the limit of man power, system cost and operator safety concerns. As sensor technologies advances, the industry started to see the need to enforce better dimensional control throughout the process, but lack the proper tools to do so. OGT along with its industrial partners represent the indigenous effort of technological development to serve the US steel industry. The immediate market that can use and get benefited from the proposed OC is the Steel Industry. The deployment of the OC has the potential to provide benefits in reduction of energy waste, CO2 emission, waste water amount, toxic waste, and so forth. The potential market after further expended function includes Hot Forging and Freight Industries. The OC prototypes were fabricated, and were progressively tested on-site in several steel mill and hot forging facilities for evaluation. Software refinements and new calibration procedures were also carried out to overcome the discovered glitches. Progress was presented to the hot manufacture facilities worldwide. Evidence showed a great interest and practical need for this product. OGT is in the pilot commercialization mode for this new development. The R&D team also successfully developed a 3D measurement function with no additional investment of hardware or equipment to measure low or room temperature object dimensions. Several tests were conducted in the reality environment to evaluate the measurement results. This new application will require additional development in product design.

47 OTHER INSTRUMENTATION↗

Mechanism of phase control in a klystron-like relativistic backward wave oscillator by an input signal

Theoretical analyses and particle-in-cell (PIC) simulations are carried out to understand the mechanism of microwave phase control realized by the external RF signal in a klystron-like relativistic backward wave oscillator (RBWO). Theoretical calculations show that a modulated electron beam can lead the microwave field with an arbitrary initial phase to the same equilibrium phase, which is determined by the phase factor of the modulated current, and the difference between them is fixed. Furthermore, PIC simulations demonstrate that the phase of input signal has a close relation to that of modulated current, which initiates the phase of the irregularly microwave during the build-up of oscillation. Since the microwave field is weak during the early time of starting oscillation, it is easy to be induced, and a small input signal is sufficient to control the phase of output microwave. For the klystron-like RBWO with two pre-modulation cavities and a reentrant input cavity, an input signal with 100 kW power and 4.21 GHz frequency can control the phase of 5 GW output microwave with relative phase difference less than 6% when the diode voltage is 760 kV, and beam current is 9.8 kA, corresponding to a power ratio of output microwave to input signal of 47 dB.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Reactive CO 2 capture via controlled amine speciation in non-aqueous electrolytes

Current efforts to integrate CO 2 capture and electrochemical conversion (reactive capture) are often performed under aqueous conditions, resulting in undesired hydrogen evolution and reliance on precious metal catalysts and pure CO 2 streams. Here, in this study, we explore reactive capture in aprotic media. By shifting the amine–CO 2 adduct speciation to carbamic acid (instead of carbamate) in dimethyl sulfoxide, we increased CO 2 uptake threefold compared with an aqueous medium, suppressing hydrogen evolution and supporting a 78% Faradaic efficiency towards CO over an earth-abundant zinc catalyst. Under simulated high-oxygen-content flue gas (17% CO 2 , 17% O 2 , 66% N 2 ), we also obtained up to 43% CO Faradaic efficiency over multiple capture–conversion cycles. Our findings showcase the confluence of reactant speciation, electrolyte composition and electrocatalyst design in enabling selective and active electrochemical transformations.

Gomes, Reginaldo J. [Univ. of Chicago, IL (United ↗

Low Cost High Efficiency Magnetrons for Accelerator Applications

High efficiency, low cost RF sources are required for proton, ion, and muon accelerators. These sources must be compact and provide precise control of the output power and phase. Currently only large, expensive klystrons can provide this performance. Calabazas Creek Research Inc. proposes to develop a phase locked magnetron-based system that has phase and amplitude control via a low power amplifier. The system uses phase modulation to control the RF power. The efficiency can exceed 80% and the cost is expected to be less than $3/Watt, significantly lower than other high power amplifiers. CCR originally proposed to develop a magnetron with a grid for control of phase and amplitude. Detailed simulations showed that this was not a promising approach. The grid was found to be viable only in magnetrons with low duty cycle, and amplitude control was demonstrated; but the grid was found to be not effective for phase locking. Attention was turned to a concept from Fermilab, which is very promising for both amplitude and phase control and does not require a grid. CCR will develop an RF system providing phase and amplitude control of a 100 kW peak, 10 kW average 1.3 GHz magnetron. Procedures and techniques will be applicable to design of systems at other frequencies and power levels. The program will include development of the magnetron and locking electronics. The system will be tested at Fermilab. Commercial Applications and Other Benefits Magnetrons can provide high levels of RF power at very high efficiency at low cost. As oscillators, however, their applications are limited. Magnetrons with more precise control of the output power and control of the phase could find wide application in accelerators and colliders. They would also provide improved performance for high resolution radar.

43 PARTICLE ACCELERATORS↗

Enabling Extreme Fast Charging through Control of Li Deposition Overpotential on Graphite Electrodes

Currently produced electric vehicles (EVs) rely on the use of lithium ion battery technology due to its high energy and power density. However, a major barrier facing the adoption of electric vehicles is that currently utilized Li-ion batteries take significantly longer to recharge (~ 30 minutes) compared to the time necessary to refuel vehicles powered by internal combustion engines (< 10 minutes). Thus, the need to develop Li-ion batteries which can be charged in approximately 10 minutes (6 C rate) without sacrificing range, cost, or cycle life is critical for the widespread implementation of EVs.

25 ENERGY STORAGE↗

Ultrafast THz emission spectroscopy of spin currents in the metamagnet FeRh

Heterostructures of ferromagnetic (FM) and noble metal (NM) thin films have recently attracted considerable interest as viable platforms for the ultrafast generation, control, and transduction of light-induced spin currents. In such systems, an ultrafast laser can generate a transient spin current in the FM layer, which is then converted to a charge current at the FM/NM interface due to strong spin–orbit coupling in the NM layer. Whether such conversion can happen in a single material and how the resulting spin current can be quantified are open questions under active study. Here, we report ultrafast THz emission from spin–charge conversion in a bare FeRh thin film without any NM layer. Our results highlight that the magnetic material by itself can enable spin–charge conversion in the same order as that in a FM/NM heterostructure. We further propose a simple model to estimate the light-induced spin current in FeRh across its metamagnetic phase transition temperature. Our findings have implications for the study of the ultrafast dynamics of magnetic order in quantum materials using THz emission spectroscopy.

36 MATERIALS SCIENCE↗

Fault Ride-Through Control Strategy for Single-Phase Virtual Synchronous Generator

This paper presents a fault ride-through control strategy for grid-tied virtual synchronous generator (VSG) under two main grid fault conditions, grid voltage sag fault and unintentional grid outage fault. Considering the overcurrent issue of VSG during the grid voltage sag fault, mechanism on overcurrent issue and the relationship among power angle, voltage amplitude, active power and reactive power are analyzed. Based on the analysis, a control strategy based on direct power angle and voltage amplitude control is proposed. Compared to the common control strategy based on additional inner current loop, the proposed VSG requires no add extra voltage or current sensors. For the grid outage fault, detailed analysis on the relationship among power angle, active power and frequency has been conducted, and it is found that the power angle is related to the output active power when the converter operates on grid-tied condition; under unintentional islanding conditions, the power angle is related to the voltage frequency. Based on the found, a detection method based on small frequency disturbance is proposed. Simulation studies on a prototype VSG system are presented to demonstrate the validity of the proposed control strategy.

Zeng, Rong↗

Controlling electron beam-induced structure modifications and cation exchange in cadmium sulfide–copper sulfide heterostructured nanorods

The atomic structure and interfaces of CdS/Cu 2 S heterostructured nanorods are explored with the aberration-corrected TEAM 0.5 electron microscope operated at 80 kV and 300 kV applying in-line holography and complementary techniques. Cu 2 S exhibits a low-chalcocite structure in pristine CdS/Cu 2 S nanorods. Under electron beam irradiation the Cu 2 S phase transforms into a high-chalcocite phase while the CdS phase maintains its wurtzite structure. Time-resolved experiments reveal that Cu + -Cd 2+ cation exchange at the CdS/Cu 2 S interfaces is stimulated by the electron beam and proceeds within an undisturbed and coherent sulfur sub-lattice. A variation of the electron beam current provides an efficient way to control and exploit such irreversible solid-state chemical processes that provide unique information about system dynamics at the atomic scale. Particularly, we show that the electron beam-induced copper-cadmium exchange is site specific and anisotropic. A resulting displacement of the CdS/Cu 2 S interfaces caused by beam-induced cation interdiffusion equals within a factor of 3-10 previously reported Cu diffusion length measurements in heterostructured CdS/Cu 2 S thin film solar cells with an activation energy of 0.96 eV.

36 MATERIALS SCIENCE↗

PEDOT:PSS-based Multilayer Bacterial-Composite Films for Bioelectronics

Abstract Microbial electrochemical systems provide an environmentally-friendly means of energy conversion between chemical and electrical forms, with applications in wastewater treatment, bioelectronics, and biosensing. However, a major challenge to further development, miniaturization, and deployment of bioelectronics and biosensors is the limited thickness of biofilms, necessitating large anodes to achieve sufficient signal-to-noise ratios. Here we demonstrate a method for embedding an electroactive bacterium, Shewanella oneidensis MR-1, inside a conductive three-dimensional poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) matrix electropolymerized on a carbon felt substrate, which we call a multilayer conductive bacterial-composite film (MCBF). By mixing the bacteria with the PEDOT:PSS precursor in a flow-through method, we maintain over 90% viability of S. oneidensis during encapsulation. Microscopic analysis of the MCBFs reveal a tightly interleaved structure of bacteria and conductive PEDOT:PSS up to 80 µm thick. Electrochemical experiments indicate S. oneidensis in MCBFs can perform both direct and riboflavin-mediated electron transfer to PEDOT:PSS. When used in bioelectrochemical reactors, the MCBFs produce 20 times more steady-state current than native biofilms grown on unmodified carbon felt. This versatile approach to control the thickness of bacterial composite films and increase their current output has immediate applications in microbial electrochemical systems, including field-deployable environmental sensing and direct integration of microorganisms into miniaturized organic electronics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Grid Forming Inverter With Increased Short-Circuit Contribution to Address Inverter-Based Microgrid Protection Challenges

Substantial differences in fault levels between grid-tied and islanded modes is one of the primary challenges of microgrid protection. During grid-tied mode, the bulk grid provides significant short-circuit, while during islanded operation the short-circuit magnitude is small due to inverter-based resources limiting their current output close to nominal ratings. Consequently, conventional distribution protection strategies based on overcurrent cannot reliably protect microgrids when operating in islanded mode. Fuses and circuit breakers are particularly affected because of their inverse characteristics. Presently, the absence of affordable solutions for protecting microgrids in islanded mode leads to microgrids shutting down during electrical faults. The contribution of this article is two-fold. The first innovation proposes specific hardware modifications to grid-forming inverters to increase their short-circuit current during electrical faults. The second innovation introduces a novel control strategy designed to preserve control stability margins even when the grid-filter saturates, ensuring sinusoidal output currents under normal and fault conditions. Through experimental results, the inverter with the proposed modifications can provide more than three-times its nominal current during electrical faults. For the prototype testbed, this was sufficient to enable the use of traditional legacy overcurrent protection, achieving the fuse-to-relay and relay-to-relay minimum coordination time for the line-to-ground, line-to-line to ground, and three-phase electrical faults.

42 ENGINEERING↗

Reaction‐induced morphology control in block copolymers

Abstract Controlling the self‐assembly behaviors of block copolymers (BCPs) is a focal point of many research thrusts due to their broad use in various applications. While BCP molecular weight, volume fraction, and chemical identities are key thermodynamic parameters to determine their morphology, an emergent method in this area is through reaction‐induced changes to the characteristics of a BCP in situ , which provides access to multiple morphologies and domain sizes from a single parent polymer, as well as enabling the formation of metastable morphologies which may be difficult to attain otherwise. This work provides a focused review about the current state of reaction‐induced morphology control in BCPs in both solution and solid states. Furthermore, we provide a forward‐looking perspective on the future opportunities of understanding and employing reaction engineering to manipulate and advance BCP self‐assembly. © 2023 Society of Industrial Chemistry.

Robertson, Mark↗

Assessment and Commissioning of Electrical Substation Grid Testbed with a Real-Time Simulator and Protective Relays/Power Meters in the Loop

Electrical utility substations are wired with intelligent electronic devices (IEDs), such as protective relays, power meters, and communication switches. Substation engineers commission these IEDs to assess the appropriate measurements for monitoring, control, power system protection, and communication applications. Like real electrical utility substations, complex electrical substation grid testbeds (ESGTs) need to be assessed for measuring current and voltage signals in monitoring, power system protection, control (synchro check), and communication applications that are limited by small measurement percentage errors. In the process of setting an ESGT with real-time simulators and IEDs in the loop, protective relays, power meters, and communication devices must be commissioned before running experiments. In this study, an ESGT with IEDs and distributed ledger technology was developed. The ESGT with a real-time simulator and IEDs in the loop was satisfactorily assessed and commissioned. The commissioning and problem-solving tasks of the testbed are described to define a method with flowcharts to assess possible trouble-shooting in ESGTs. This method was based on comparing the simulations versus IED measurements for the phase current and voltage magnitudes, three-phase phasor diagrams, breaker states, protective relay times with selectivity coordination at electrical faults, communication data points, and time-stamp sources.

Piesciorovsky, Emilio↗

Field emission device driven by self-powered contact-electrification: Simulation and experimental analysis

A self-powered field emission device (FED) driven by a single-electrode tribo-electric nanogenerator (TENG) is demonstrated. The mechanical motion works as both a power supply to drive the FED and a control unit to regulate the amount of emitted electrons. By using the Fowler-Nordheim equation and Kirchhoff laws, a theoretical model of this self-powered FED is proposed, and accordingly the real-time output characteristics of the device are systematically investigated. It is found that the motion distance of the TENG controls switch-on of the FED and determines the charge amount for emission, while the motion velocity regulates the amplitude of emission current. The minimum contact area for the TENG to generate field emission is about 9 cm{sup 2}, which can be improved by optimizing FED structure and the tribo-materials of TENG. The demonstrated concept of this self-powered FED as well as the proposed physical analysis can serve as guidance for further applications of FED in such fields of self-powered electronics and soft electronics.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗