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At least 1,225 records · Page 68

Two Cycling Centers in One Molecule: Communication by Through-Bond Interactions and Entanglement of the Unpaired Electrons

Many applications in quantum information science (QIS) rely on the ability to laser- cool molecules. The scope of applications can be expanded if laser-coolable molecules possess two or more cycling centers, i.e., moieties capable of scattering photons via multiple absorption-emission events. Here in this paper we employ equation-of-motion coupled-cluster method for double electron attachment (EOM-DEA-CCSD) to study the electronic structure of hypermetallic molecules with two alkaline earth metals connected by an acetylene linker. The electronic structure of the molecules is similar to that of two separated alkali metals; however, the interaction between the two electrons is weak and largely dominated by through-bond interactions. The communication between the two cycling centers is quantified by the extent of the entanglement of the two unpaired electrons associated with each center. This contribution highlights the rich electronic structure of hypermetallic molecules that may advance various applications in QIS and beyond.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Cost effective nanostructured copper substrates prepared with ultrafast laser pulses for explosives detection using surface enhanced Raman scattering

Ultrafast laser pulses induced surface nanostructures were fabricated on a copper (Cu) target through ablation in acetone, dichloromethane, acetonitrile, and chloroform. Surface morphological information accomplished from the field emission scanning electron microscopic data demonstrated the diversities of ablation mechanism in each case. Fabricated Cu substrates were utilized exultantly to investigate the surface plasmon (localized and propagating) mediated enhancements of different analytes using surface enhance Raman scattering (SERS) studies. Multiple utility of these substrates were efficiently demonstrated by collecting the SERS data of Rhodamine 6G molecule and two different secondary explosive molecules such as 5-amino-3-nitro-l,2,4-triazole and trinitrotoluene on different days which were weeks apart. We achieved significant enhancement factors of >10{sup 5} through an easily adoptable cleaning procedure.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

MC generator HARDPING: Nuclear effects in hard interactions of leptons and hadrons with nuclei

Hadron and lepton production in hard interaction of high-energy particles with nuclei are considered in context of developing of Monte Carlo generator HARDPING (Hard Probe Interaction Generator). Such effects as energy losses and multiple re-scattering initial and produced hadrons and their constituents are taken into account. These effects are implemented in current version of generator HARDPING. Data of experiments HERMES on hadron production in lepton-nuclei collisions and E866 on muon pair production in proton-nuclei collisions were described with current version of generator HARDPING. Predictions from recent version HARPING 3.0 for lepton pairs production at proton beam energy I20 GeV are presented.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Enhancing Thomson scattering polychromator performance with multi-pass spectral filters

In photon-deficient, noncollective Thomson scattering diagnostics, filter polychromators are typically employed in the spectral analysis of Thomson-scattered signals to achieve acceptable signal-to-noise performance. Currently, the most common polychromator filter configuration employs a set of single-passband optical filters that define individual spectral channels. Here, we introduce a new spectral analysis method for Thomson scattering based on spectral filters with multiple passbands, referred to as Thomson scattering spectral multiplexing. Implementing multi-bandpass spectral filters on polychromators increases the achievable range of electron temperature measurement for a given number of filters employed. In addition, Thomson scattering spectral multiplexing reduces systematic measurement uncertainty, with fewer required spectral channels, thereby decreasing light loss from reduced optical element interactions. A multi-bandpass filter set, optimized by a genetic algorithm, has been successfully installed and tested on the Helically Symmetric eXperiment (HSX), demonstrating the benefits of the Thomson scattering spectral multiplexing method.

Instruments & Instrumentation↗

Multibeam Stimulated Raman Scattering in Inertial Confinement Fusion Conditions

Stimulated Raman scattering (SRS) from multiple laser beams arranged in a cone sharing a common daughter wave is investigated for inertial confinement fusion (ICF) conditions in a inhomogeneous plasma. It is found that the shared-electron plasma wave (EPW) process, where the lasers collectively drive the same EPW, can lead to an absolute instability when the electron density reaches a matching condition dependent on the cone angle of the laser beams. This mechanism could explain recent experimental observations of hot electrons at early times in ICF experiments, at densities well below quarter-critical when two plasmon decay is not expected to occur.

42 ENGINEERING↗

ADARA

The ADARA software is a collection of programs which gather neutron scattering data from multiple detector banks, multiplex the data into a single stream and distribute that stream to analysis, reduction and translation utilities in real-time.

Miller, Ross↗

Recent results from the MINERvA experiment

MINERvA is a dedicated neutrino-nucleus scattering experiment with multiple nuclear targets in the Neutrinos from the Main Injector (NuMI) beam line at Fermilab. MINERvA can provide high precision measurements of neutrino interaction cross sections in the 1 to 20 GeV energy range in support to current and future oscillation experiments. MINERvA can also provide information about the structure of protons and neutrons and about the dynamics affecting neutrino-nucleus interactions. The heart of the MINERvA detector is a fine-grained scintillating tracking cham-ber, surrounded by electromagnetic and hadronic calorimeters. Carbon, iron and lead targets are used to study the effect of the nuclear medium on neutrino-induced interactions. In conclusion, this document summarizes the most recent MINERvA results

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

A simple code for use in shielding and radiation dosage analyses

A simple code for use in analyses of gamma radiation effects in laminated materials is described. Simple and good geometry is assumed so that all multiple collision and scattering events are excluded from consideration. The code is capable of handling laminates up to six layers. However, for laminates of more than six layers, the same code may be used to incorporate two additional layers at a time, making use of punch-tape outputs from previous computation on all preceding layers. Spectrum of attenuated radiation are obtained as both printed output and punch tape output as desired.

Wan, C. C.↗

On the interpretation of the 'inverse phase effect' for CO2 equivalent widths on Venus

Computations of the equivalent widths of absorption lines as a function of planetary phase angle are made for a homogeneous cloud with particles having the properties (shape, refractive index, and size distribution) deduced from polarimetry of Venus. The computed equivalent widths show an 'inverse phase effect' comparable to that which is observed for CO2 lines on Venus. This result verifies a recent suggestion of Regas et al. that the existence of an inverse phase effect does not by itself imply the presence of multiple layers of scattering particles in the atmosphere of Venus.

Whitehill, L. P.↗

Spatially and spectrally resolved multipoint coherent anti-Stokes Raman scattering from N2 and O2 flows

Single-shot spectrally resolved broadband rotational coherent anti-Stokes Raman scattering (CARS) from multiple points along a line intersecting a flow has been observed for N2 and O2. A large-angle phase-matching configuration was used to achieve spatial resolution of 0.1 mm x 0.1 mm x 0.1 mm for each of 20 points in the interaction volume. Single-shot multipoint CARS of N2 at different temperatures and of several species in a coflowing jet was observed.

Snow, J. B.↗

On ion acceleration in interplanetary quasi-perpendicular shock waves

The kinematic and pitch angle scattering constraints for multiple shock encounters to occur are investigated. The results suggest that (1) large particle anisotropies and a large number of shock encounters are not mutually exclusive and (2) solar wind ions are not directly injected into the nearly perpendicular interplanetary shock acceleration process. Also, the average number of shock encounters required to accelerate an ion between two energies is calculated. The results are consistent with the shock geometry dependence observed in interplanetary shock spike and corotating interaction region associated energetic ion events.

Pesses, M. E.↗

Absorption Filter Based Optical Diagnostics in High Speed Flows

Two major regimes where laser light scattered by molecules or particles in a flow contains significant information about the flow are Mie scattering and Rayleigh scattering. Mie scattering is used to obtain only velocity information, while Rayleigh scattering can be used to measure both the velocity and the thermodynamic properties of the flow. Now, recently introduced (1990, 1991) absorption filter based diagnostic techniques have started a new era in flow visualization, simultaneous velocity and thermodynamic measurements, and planar velocity measurements. Using a filtered planar velocimetry (FPV) technique, we have modified the optically thick iodine filter profile of Miles, et al., and used it in the pressure-broaden regime which accommodates measurements in a wide range of velocity applications. Measuring velocity and thermodynamic properties simultaneously, using absorption filtered based Rayleigh scattering, involves not only the measurement of the Doppler shift, but also the spectral profile of the Rayleigh scattering signal. Using multiple observation angles, simultaneous measurement of one component velocity and thermodynamic properties in a supersonic jet were measured. Presently, the technique is being extended for simultaneous measurements of all three components of velocity and thermodynamic properties.

Samimy, Mo↗

A Microfabricated 8-40 GHz Dual-Polarized Reflector Feed

Planar antennas based on tightly coupled dipole arrays (also known as a current sheet antenna or CSA) are amenable for use as electronically scanned phased arrays. They are capable of performance nearing a decade of bandwidth. These antennas have been demonstrated in many implementations at frequencies below 18 GHz. This paper describes the implementation using a relatively new multi-layer microfabrication process resulting in a small, 6x6 element, dual-linear polarized array with beamformer that operates from 8 to 40 GHz. The beamformer includes baluns that feed the dual-polarized differential antenna elements and reactive splitter networks that also cover the full frequency range of operation. This antenna array serves as a reflector feed for a multi-band instrument designed to measure snow water equivalent (SWE) from airborne platforms. The instrument has both radar and radiome try capability at multiple frequencies. Scattering-parameter and time-domain measurements have been used to characterize the array feed. Radiation patterns of the antenna have been measured and are compared to simulation. To the best of the authors' knowledge, this work represents the most integrated multi-octave millimeter-wave antenna feed fabricated to date.

current sheet antenna↗

Empirical Hydrometeor Type Identification from GMI Brightness Temperature Measurements

Brightness temperatures (TB) from GMI and related sensors contain information about the types and amounts of precipitation particles in a column. Approaches like GPROF or machine learning are good for providing precipitation estimates and other quantified information, but it can be difficult to understand why / how a given set of TBs traces to a given retrieval solution. Outlier TBs that are not well-represented in a training sample can lead to dubious solutions. Our goal is to use the scattering signatures at multiple frequencies to determine whether hail is present, or otherwise graupel, or otherwise snow, or otherwise liquid rain without a substantial precipitation ice component. (A hierarchical approach is employed, so a prediction of hail can include the presence of all other categories, but a prediction of snow implies a lack of graupel or hail, and a prediction of liquid rain implies a lack of any detectable precipitation ice.)

Daniel J. Cecil↗

Hydrometeor Identification from GMI Radiometer, Trained Using Polarimetric Radar

Brightness temperatures (TB) from GMI and related sensors contain information about the types and amounts of precipitation particles in a column. Approaches like GPROF or machine learning are good for providing precipitation estimates and other quantified information, but it can be difficult to understand why / how a given set of TBs traces to a given retrieval solution. Outlier TBs that are not well-represented in a training sample can lead to dubious solutions. Our goal is to use the scattering signatures at multiple frequencies to determine whether hail is present, or otherwise graupel, or otherwise snow, or otherwise liquid rain without a substantial precipitation ice component. (A hierarchical approach is employed, so a prediction of hail can include the presence of all other categories, but a prediction of snow implies a lack of graupel or hail, and a prediction of liquid rain implies a lack of any detectable precipitation ice.)

Daniel J. Cecil↗

ADARA

The ADARA software is a collection of programs which gather neutron scattering data from multiple detector banks, multiplex the data into a single stream and distribute that stream to analysis, reduction and translation utilities in real-time.

Miller, Ross↗

Analog neutron transport for nuclear instrumentation applications with the Monte-Carlo code TRIPOLI-4 - Paper 3

Monte-Carlo codes simulating particle transport usually make use of well-known variance reduction techniques, leading to more efficient simulations. Even in configurations which do not deal with deep-penetration, some of these techniques, such as the implicit capture, are actually often used by default. The statistical weight of the simulated particles is then modified in order to take into account the modification of the sampling without introducing any bias in the estimation process. For instance, the implicit capture decreases the statistical weight of the particles at each collision, whereas the sampling of a single outgoing particle increases this statistical weight in case of scattering reactions producing multiple neutrons. In addition, Russian roulette and splitting operations, which are usually also played at each collision, lead to other modifications of the statistical weights. As a result, Monte-Carlo codes provide particle histories that are valid on average, but collect statistical weights which differ from 1, when tallying the estimation of the quantities of interest. Yet, some nuclear instrumentation calculations inherently need to work with statistical weights equal to 1, since either individual events have to be collected (such as the arrival of a particle at a detector, the measurement of a time of flight, etc), or the coincidence of events or also correlations between individual events have to be taken into account. To address these specific applications with Monte-Carlo simulation codes, users need a full analog simulation mode. The continuous-energy Monte-Carlo code TRIPOLI4{sup R} is mainly dedicated to shielding, reactor physics and criticality safety calculations. Its capabilities have recently been extended to widen its use to nuclear instrumentation with the possibility of γ-spectrometry calculations and the simulation of photonuclear reactions for instance. Other features needed by nuclear instrumentation applications have been available in TRIPOLI-4 for a long time, such as the sampling of the time variable and the possibility of tallying in a time grid for most of the available tallies (fluxes, reaction rates, dose equivalent rates, energy depositions, etc). In TRIPOLI-4, the transport between two consecutive collisions is analog if no variance reduction technique is requested by the user to handle deep-penetration configurations. However, up to the version 9 of the code, the collision itself is sampled in a non-analog way. This paper presents a first implementation of a full analog neutron transport mode in TRIPOLI-4, preliminary verification results and an application of this functionality to the simulation of the Nucifer detector located in Saclay, France. It should be noted that only neutron transport is dealt with in this work and that all nuclear data come from JEFF-3.1.1 or ENDF/B-VII.0 evaluations, including fission data when needed. (authors)

61 RADIATION PROTECTION AND DOSIMETRY↗