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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,225 records · Page 68

Chemometrics and Experimental Design for the Quantification of Nitrate Salts in Nitric Acid: Near-Infrared Spectroscopy Absorption Analysis

Implementing remote, real-time spectroscopic monitoring of radiochemical processing streams in hot cell environments requires efficiency and simplicity. The success of optical spectroscopy for the quantification of species in chemical systems highly depends on representative training sets and suitable validation sets. Selecting a training set (i.e., calibration standards) to build multivariate regression models is both time- and resource-consuming using standard one-factor-at-a-time approaches. This study describes the use of experimental design to generate spectral training sets and a validation set for the quantification of sodium nitrate (0–1 M) and nitric acid (0.1–10 M) using the near-infrared water band centered at 1440 nm. Partial least squares regression models were built from training sets generated by both D- and I-optimal experimental designs and a one-factor-at-a-time approach. The prediction performance of each model was evaluated by comparing the bias and standard error of prediction for statistical significance. D- and I-optimal designs reduced the number of samples required to build regression models compared with one-factor-at-a-time while also improving performance. Models must be confirmed against a validation sample set when minimizing the number of samples in the training set. The D-optimal design performed the best when considering both performance and efficiency by improving predictive capability and reducing number of samples in the training set by 64% compared with the one-factor-at-a-time approach. The experimental design approach objectively selects calibration and validation spectral data sets based on statistical criterion to optimize performance and minimize resources.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Final Results for 99 Mo, 111 Ag, 147 Nd, 140 Ba

Seven depleted uranium targets were irradiated at the ACRR reactor in three different irradiations occurring on June 4th, 5th, and 6th, 2019. The targets were received at LANL on July 10, 2019, unpackaged, and analyzed by autoradiography and gamma-ray spectrometry. Table 1 shows a chart of the Target ID, target mass, time the irradiation occurred, and the corresponding LANL sample ID. Six of the targets were dissolved and chemically separated radiochemical analyses were performed for a suite of radionuclides on four of the targets. The final results of the radiochemical separation and analysis of 99 Mo, 111 Ag, 147 Nd and 140 Ba for depleted U samples 4416-01, 4417-01, 4418-01 and 4418-03 are presented in Table 2. Associated errors represent 1σ uncertainty.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

An Evaluation of a Neutron Time Correlated Interrogation Method for Measurement of Fissile Content in Research Reactor Spent Fuel Assemblies

There are many research reactors worldwide that have been, or are being converted from the use of high enrichment uranium (HEU) to low enrichment uranium (LEU, < 20% enriched). The verification of fissile content and initial enrichment of the spent fuel is needed for the effective safeguards of the fuel. The advanced experimental fuel counter (AEFC) was developed for the measurement of spent fuel rods and assemblies from research reactors for safeguards verification. This measurement system contains components for active neutron interrogation, passive neutron totals counting, neutron coincidence counting, and gross gamma-ray counting. This report presents the first application of the time correlated interrogation technique for the measurement of the 235 U content in research reactor spent fuel assemblies. The technique, called time correlated induced fission (TCIF), uses a 252 Cf neutron source to irradiate the fuel assembly, and the subsequent induced fission events in the fissile material are measured by coincidence counting. The doubles rates are enhanced by having the neutron trigger events from both the 252 Cf source and the induced fission neutrons in the same time gate in the coincidence analysis. The average neutrons per fission of the 252 Cf source is 3.76 and the induced fission neutrons for 235 U is 2.44, so the number of neutrons that are produced is higher than for random neutron interrogation. This high effective neutron number increases the multiplicity counting rates and reduces the statistical error. The background coincidence counts from the 252 Cf are reduced by the water in the sample cavity and the polyethylene surrounding the 3 He detector tubes. This method of active neutron interrogation has been applied to the measurement of spent research reactor (IRT) fuel assemblies. The advanced experimental fuel counter (AEFC) was used to compare the TCIF method with the typically used AmLi neutron interrogation source that emits neutrons that are random in time. The statistical uncertainty for the use of the random neutron source (AmLi) and the time correlated source ( 252 Cf) for spent fuel interrogations was evaluated.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Graph Neural Networks for Parameterized Quantum Circuits Expressibility Estimation (Rev.1)

Parameterized quantum circuits (PQCs) are fundamental to quantum machine learning (QML), quantum optimization, and variational quantum algorithms (VQAs). The expressibility of PQCs is a measure that determines their capability to harness the full potential of the quantum state space. It is thus a crucial guidepost to know when selecting a particular PQC ansatz. However, the existing technique for expressibility computation through statistical estimation requires a large number of samples, which poses significant challenges due to time and computational resource constraints. This paper introduces a novel approach for expressibility estimation of PQCs using Graph Neural Networks (GNNs). We demonstrate the predictive power of our GNN model with a dataset consisting of 25,000 samples from the noiseless IBM QASM Simulator and 12,000 samples from three distinct noisy quantum backends. The model accurately estimates expressibility, with root mean square errors (RMSE) of 0.05 and 0.06 for the noiseless and noisy backends, respectively. We compare our model’s predictions with reference circuits from Sim et al. and IBM Qiskit’s hardwareefficient ansatz sets to further evaluate our model’s performance. Our experimental evaluation in noiseless and noisy scenarios reveals a close alignment with ground truth expressibility values, highlighting the model’s efficacy. Moreover, our model exhibits promising extrapolation capabilities, predicting expressibility values with low RMSE for out-of-range qubit circuits trained solely on only up to 5-qubit circuit sets. This work thus provides a reliable means of efficiently evaluating the expressibility of diverse PQCs on noiseless simulators and hardware.

97 MATHEMATICS AND COMPUTING↗

Results of scatterometer systems analysis for NASA/MSC Earth observation sensor evaluation program

A systems evaluation of the 13.3 GHz scatterometer system is presented. The effects of phase error between the scatterometer channels, antenna pattern deviations, aircraft attitude deviations, environmental changes, and other related factors such as processing errors, system repeatability, and propeller modulation, are established. Furthermore, the reduction in system errors and calibration improvement is investigated by taking into account these parameter deviations. Typical scatterometer data samples are presented.

Krishen, K.↗

Results of scatterometer systems analysis for NASA/MSC Earth Observation Sensor Evaluation Program.

Radar scatterometers have applications in the NASA/MSC Earth Observation Aircraft Program. Over a period of several years, several missions have been flown over both land and ocean. In this paper a system evaluation of the NASA/MSC 13.3-GHz Scatterometer System is presented. The effects of phase error between the Scatterometer channels, antenna pattern deviations, aircraft attitude deviations, environmental changes, and other related factors such as processing errors, system repeatability, and propeller modulation, were established. Furthermore, the reduction in system errors and calibration improvement was investigated by taking into account these parameter deviations. Typical scatterometer data samples are presented.

Krishen, K.↗

Study of application of ERTS-A imagery to fracture-related mine safety hazards in the coal mining industry

The author has identified the following significant results. Mined land reclamation analysis procedures developed within the Indiana portion of the Illinois Coal Basin were independently tested in Ohio utilizing 1:80,000 scale enlargements of ERTS-1 image 1029-15361-7 (dated August 21, 1972). An area in Belmont County was selected for analysis due to the extensive surface mining and the different degrees of reclamation occurring in this area. Contour mining in this area provided the opportunity to extend techniques developed for analysis of relatively flat mining areas in Indiana to areas of rolling topography in Ohio. The analysts had no previous experience in the area. Field investigations largely confirmed office analysis results although in a few areas estimates of vegetation percentages were found to be too high. In one area this error approximated 25%. These results suggest that systematic ERTS-1 analysis in combination with selective field sampling can provide reliable vegetation percentage estimates in excess of 25% accuracy with minimum equipment investment and training. The utility of ERTS-1 for practical and reasonably reliable update of mined lands information for groups with budget limitations is suggested. Many states can benefit from low cost updates using ERTS-1 imagery from public sources.

Wier, C. E.↗

Photospheric faculae and the solar oblateness - A reply to 'Faculae and the solar oblateness' by R. H. Dicke.

Dicke has recently contested our statement in an earlier paper that faculae could account for a large part, if not all, of the solar oblateness signal measured by Dicke and Goldenberg in 1966. Using the facular oblateness signal published in our earlier paper and some hitherto unpublished data from his 1966 observations, he concludes that faculae account for only a small part (11%) of the observed excess oblateness. His analysis considers data only from a restricted 48-day sample and is based on the assumption that only the observed oblateness signal is subject to error. Our analysis considers data from all 64 days on which observations were made, and is based on the assumption that both the observed oblateness signal and the facular signal are subject to error. We find that faculae account for at least one-third to one-half of the observed excess oblateness, depending on whether 48 days or 64 days are used in the analysis.

Chapman, G. A.↗

Multi-calculation rate simulations

It is common in real time simulations of large aerospace systems to separate the high and low frequency subsystems within the simulation and perform the integrations of the subsystems at different calculation rates. This is done to strike a balance between accuracy of calculation and capacity of the digital computer. Questions arising as to the accuracy of this structure compared to single calculation rates were studied using a linear aircraft model. Also investigated were interactions arising to cause errors worse than those expected. Problems are specifically identified and guidelines are given for selection of sample rates for multiple rate simulations.

Powell, J. D.↗

Effects of data asymmetry on Shuttle Ku-band communications link performance

This paper systematically analyzes the signal-to-noise ratio degradations which can potentially occur due to data asymmetry in digital transmission systems. Suitable asymmetry models are developed and error probability performance for various types of data detectors (integrate-and-dump filter, filter-sample detector, and gated-integrate-and-dump filter) is derived. Although this work was done to resolve problems being encountered in the Shuttle Ku-band return link design, specifically for the 50 Mbit/s convolutionally encoded channel (NRZ format), generalizations are made which provide results for other cases of interest (other Ku-band return link channels, or other systems entirely). This paper therefore considers Manchester data formats (in addition to NRZ) and uncoded transmission (in addition to convolutionally coded transmission). The effects of bandlimiting are also considered.

Simon, M. K.↗

Cloud cover sampling capability of various satellite combinations for ISCCP

One of the most important objectives of the International Satellite Cloud Climatology Project (ISCCP) is the quantification of cloud cover and associated radiation parameters for climate research. The time-varying nature of cloud cover requires a measurement system that obtains cloud radiance at sufficient time intervals for determining accurate values of cloudiness for the appropriate averaging period. Current plans for the ISCCP call for such day to be acquired every 3 hours during both data and night to ensure that the diurnal cycle of cloud cover is adequately sampled. The satellite system proposed is an array of geostationary and polar-orbiting satellites. The error in mean cloud cover estimates for observation systems which do not include geostationary satellites are quantified. Candidates for such a system include two NOAA Sun-synchronous satellites with daylight equatorial-crossing times of 0730 and 1430, and a USSR satellite in an 81 deg. inclination, 900-km altitude orbit.

Harrison, E. F.↗

X-ray sources in regions of star formation. III - Naked T Tauri stars associated with the Taurus-Auriga complex

Ground-based and IRAS optical and IR spectroscopic and photometric observations are reported for 90 stars in or near 59 Einstein Observatory X-ray error circles in the Tau-Aur region. The data are presented in extensive tables and sample spectra and characterized in detail, with particular attention to 28 newly discovered 'naked' T Tau stars, which are shown to be normal stars with no significant IR or UV excess and ages of 1-40 Myr. These stars are found to outnumber normal T Tau stars by a factor of 10 in an area near the Tau-Aur dark clouds, and it is argued that their evolution toward the ZAMS is typical for low-mass stars. The implications of this finding for the time scales of circumstellar-disk dissipation and planet formation are discussed.

Walter, Frederick M.↗

A Photometric Technique for Determining Fluid Concentration using Consumer-Grade Hardware

In support of a separate study to produce an exponential concentration gradient in a magnetic fluid, a noninvasive technique for determining, species concentration from off-the-shelf hardware has been developed. The approach uses a backlighted fluid test cell photographed with a commercial digital camcorder. Because the light extinction coefficient is wavelength dependent, tests were conducted to determine the best filter color to use, although some guidance was also provided using an absorption spectrophotometer. With the appropriate filter in place, the provide attenuation of the light passing, through the test cell was captured by the camcorder. The digital image was analyzed for intensity using, software from Scion Image Corp. downloaded from the Internet. The analysis provides a two-dimensional array of concentration with an average error of 0.0095 ml/ml. This technique is superior to invasive techniques, which require extraction of a sample that disturbs the concentration distribution in the test cell. Refinements of this technique using a true monochromatic laser light Source are also discussed.

Leslie, F.↗

Galaxy Cluster Gas Mass Fractions From Sunyaev-Zel'dovich Effect Measurement: Constraints on Omega_M

Using sensitive centimeter-wave receivers mounted on the Owens Valley Radio Observatory and Berkeley-Illinois-Maryland-Association millimeter arrays, we have obtained interferometric measurements of the Sunyaev-Zei'dovich (SZ) effect toward massive galaxy clusters. We use the SZ data to determine the pressure distribution of the cluster gas and, in combination with published X-ray temperatures, to infer the gas mass and total gravitational mass of 18 clusters. The gas mass fraction, f~g, is calculated for each cluster, and is extrapolated to the fiducial radius r_{500} using the results of numerical simulations. The mean f_g within r_{500} is 0.081 + 0.009 - 0.011/(h_{100} (statistical uncertainty at 68% confidence level, assuming OmegaM=0.3, OmegaL=0.7). We discuss possible sources of systematic errors in the mean f 9 measurement. We derive an upper limit for OmegaM from this sample under the assumption that the mass composition of clusters within r_{500} reflects the universal mass composition: Omega_M h <Omega_B/f_g.The gas mass f on cosmology through the angular diameter distance and the r_{500} correction factors. For a flat universe (Omegal, = 1 - OmegaM) and h=0.7, we find the measured gas mass fractions are consistent with OmegaM less than 0.40, at 68% confidence. Including estimates of the baryons contained in galaxies and the baryons which failed to become bound during the cluster formation process, we find OmegaM\approximately 0.25.

Grego, Laura↗

Atmospheric Pressure Corrections in Geodesy and Oceanography: a Strategy for Handling Air Tides

Global pressure data are often needed for processing or interpreting modern geodetic and oceanographic measurements. The most common source of these data is the analysis or reanalysis products of various meteorological centers. Tidal signals in these products can be problematic for several reasons, including potentially aliased sampling of the semidiurnal solar tide as well as the presence of various modeling or timing errors. Building on the work of Van den Dool and colleagues, we lay out a strategy for handling atmospheric tides in (re)analysis data. The procedure also offers a method to account for ocean loading corrections in satellite altimeter data that are consistent with standard ocean-tide corrections. The proposed strategy has immediate application to the on-going Jason-1 and GRACE satellite missions.

Ponte, Rui M.↗

NASA Tech Briefs, August 2008

Customizable Digital Receivers for Radar Two-Camera Acquisition and Tracking of a Flying Target Visual Data Analysis for Satellites A Data Type for Efficient Representation of Other Data Types Hand-Held Ultrasonic Instrument for Reading Matrix Symbols Broadband Microstrip-to-Coplanar Strip Double-Y Balun A Topographical Lidar System for Terrain-Relative Navigation Programmable Low-Voltage Circuit Breaker and Tester Electronic Switch Arrays for Managing Microbattery Arrays Topics covered include: Lower-Dark-Current, Higher-Blue-Response CMOS Imagers; Fabricating Large-Area Sheets of Single-Layer Graphene by CVD; Support for Diagnosis of Custom Computer Hardware; Providing Goal-Based Autonomy for Commanding a Spacecraft; Dynamic Method for Identifying Collected Sample Mass; Optimal Planning and Problem-Solving; Attitude-Control Algorithm for Minimizing Maneuver Execution Errors; Grants Document-Generation System; Heat-Storage Modules Containing LiNO3 3H2O and Graphite Foam; Precipitation-Strengthened, High-Temperature, High-Force Shape Memory Alloys; Improved Relief Valve Would Be Less Susceptible to Failure; Safety Modification of Cam-and-Groove Hose Coupling; Using Composite Materials in a Cryogenic Pump; Using Electronic Noses to Detect Tumors During Neurosurgery; Producing Newborn Synchronous Mammalian Cells; Smaller, Lower-Power Fast-Neutron Scintillation Detectors; Rotationally Vibrating Electric-Field Mill; Estimating Hardness from the USDC Tool-Bit Temperature Rise; Particle-Charge Spectrometer; Automated Production of Movies on a Cluster of Computers; FIDO-Class Development Rover; and Tone-Based Command of Deep Space Probes Using Ground Antennas.

Source record↗

Spatio-Temporal Variability of Groundwater Storage in India

Groundwater level measurements from 3907 monitoring wells, distributed within 22 major river basins of India, are assessed to characterize their spatial and temporal variability. Ground water storage (GWS) anomalies (relative to the long-term mean) exhibit strong seasonality, with annual maxima observed during the monsoon season and minima during pre-monsoon season. Spatial variability of GWS anomalies increases with the extent of measurements, following the power law relationship, i.e., log-(spatial variability) is linearly dependent on log-(spatial extent).In addition, the impact of well spacing on spatial variability and the power law relationship is investigated. We found that the mean GWS anomaly sampled at a 0.25 degree grid scale closes to unweighted average over all wells. The absolute error corresponding to each basin grows with increasing scale, i.e., from 0.25 degree to 1 degree. It was observed that small changes in extent could create very large changes in spatial variability at large grid scales. Spatial variability of GWS anomaly has been found to vary with climatic conditions. To our knowledge, this is the first study of the effects of well spacing on groundwater spatial variability. The results may be useful for interpreting large scale groundwater variations from unevenly spaced or sparse groundwater well observations or for siting and prioritizing wells in a network for groundwater management. The output of this study could be used to maintain a cost effective groundwater monitoring network in the study region and the approach can also be used in other parts of the globe.

Groundwater monitoring↗

Numerical Investigation and Optimization of a Flushwall Injector for Scramjet Applications at Hypervelocity Flow Conditions

An investigation utilizing Reynolds-averaged simulations (RAS) was performed in order to demonstrate the use of design and analysis of computer experiments (DACE) methods in Sandia’s DAKOTA software package for surrogate modeling and optimization. These methods were applied to a flow- path fueled with an interdigitated flushwall injector suitable for scramjet applications at hyper- velocity conditions and ascending along a constant dynamic pressure flight trajectory. The flight Mach number, duct height, spanwise width, and injection angle were the design variables selected to maximize two objective functions: the thrust potential and combustion efficiency. Because the RAS of this case are computationally expensive, surrogate models are used for optimization. To build a surrogate model a RAS database is created. The sequence of the design variables comprising the database were generated using a Latin hypercube sampling (LHS) method. A methodology was also developed to automatically build geometries and generate structured grids for each design point. The ensuing RAS analysis generated the simulation database from which the two objective functions were computed using a one-dimensionalization (1D) of the three-dimensional simulation data. The data were fitted using four surrogate models: an artificial neural network (ANN), a cubic polynomial, a quadratic polynomial, and a Kriging model. Variance-based decomposition showed that both objective functions were primarily driven by changes in the duct height. Multiobjective design optimization was performed for all four surrogate models via a genetic algorithm method. Optimal solutions were obtained at the upper and lower bounds of the flight Mach number range. The Kriging model predicted an optimal solution set that exhibited high values for both objective functions. Additionally, three challenge points were selected to assess the designs on the Pareto fronts. Further sampling among the designs of the Pareto fronts may be required to lower the surrogate model errors and perform more accurate surrogate-model-based optimization.

Shenoy, Rajiv R.↗