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At least 1,225 records · Page 68

Methanol Steam Reforming on Ru/m-ZrO 2 : Sodium Promotion of the CO 2 -Forming Pathway

Sodium (Na) promotion of Ru/m-ZrO 2 was investigated to elucidate how an alkali modification tunes selectivity in methanol steam reforming (MSR). H 2 -TPR/XANES/EXAFS show that Na increases surface basicity and strengthens Ru–O interactions, shifting RuO x reduction and H 2 spillover to a higher temperature. DRIFTS reveals Na-induced red shifts of the formate ν(CH) band and changes in OCO vibrational splitting, consistent with weakening of the formate C–H bond and an altered binding geometry. CO 2 -TPD confirms a monotonic shift toward stronger basic sites with increasing Na concentrations. Under MSR conditions, Na selectively increases CO2 concentration at the expense of CO. At ~80% conversion and 325 °C, CO 2 selectivity increases from 12.0% (unpromoted) to 16.2, 21.0, and 26.5% for 0.5, 1.0, and 1.8% Na, respectively; at ~300 °C and ~66–69% conversion, CO 2 selectivity increases from 8.6% to 23.7% at 1.8% Na. Transient MSR experiments further show earlier and larger H 2 evolution upon Na addition, corroborating the promotion of the dehydrogenation/decarbonylation route to CO 2 + H 2 . We propose that Na increases basicity and modifies the Ru–support interface to favor formate dehydrogenation/decarboxylation, thereby increasing the H 2 yield and lowering CO formation. Ru’s higher-energy, less occupied d-band stabilizes CO and oxygenated intermediates more strongly in the reforming environment, making the CO-forming pathway more resistant to suppression than on Pt.

CO2 selectivity↗

Influence of debris dent on EHD lubrication

Film thickness measurements associated with a debris dent have been made with interferometry under static and dynamic conditions. The presence of a debris dent alters the shape of the inlet region so that the local film thickness at the leading edge of the dent can become substantially lower than the trailing edge. The pressure modifications associated with these local EHD effects are in line with the frequent occurrence of surface initiated fatigue spalls originating at the trailing edge of debris dents. The effectiveness of the EHD mechanism in reducing the stress concentrations at the shoulders of the dent is related to inlet dimensions and dent size.

Wedeven, L. D.↗

Nighttime observations of thunderstorm electrical activity from a high altitude airplane

Photographs from a NASA U-2 airplane flying over nocturnal thunderstorms show frequent lightning activity in the upper part of the cloud. In some cases, unobscured segments of lightning channels 1 km or longer are visible in clear air around and above the cloud. Multiple images of lightning channels indicate multiple discharges in the same channel. Photographs taken through a diffraction grating show that the lightning has a spectrum similar to that observed in the lower troposphere. Lightning spectra obtained with a slitless line-scan spectrometer show strong singly ionized nitrogen emissions at 463.0 and 500.5 nm. Field changes measured with an electric field-change meter correlate with pulses measured with a photocell optical system. Optical signals corresponding to dart leader, return stroke, and continuing current events are readily distinguished in the scattered light emerging from the cloud surface. The variation of light intensity with time in lightning events is consistent with predicted modification of optical lightning signals by clouds. It appears that satellite based optical sensor measurements cannot provide reliable information on current rise times in return strokes. On the other hand, discrimination between cloud-to-ground and intracloud flashes and the counting of ground strokes is possible using the optical pulse pairs which have been identified with leader, return-stroke events in the cloud-to-ground flashes studied.

Brook, M.↗

Reduction of Vane Noise in Wind-Tunnel Nozzles

Vane-induced noise reduced by adhering thin layer of porous material such as foam to downwind surface of vanes, particularly near sharp trailing edges, to prevent occurrence of edge tones. Other modifications made to aerodynamically streamline vane structure were rounding leading edges and smoothly fairing trailing edges. Boundary layer trip applied to leading edge to prevent laminar tone shedding from trailing edge.

Martin, R. M.↗

Pressure-Assisted Seal for Castings

Modification of widely used pressure-assisted gasket ensures tight seal even when one sealed surface somewhat rough or porous. Modified U-cross-section gasket has thin lips increasing sealing area and conform to slightly rough surface. Lips provide wider sealing area and extend highly loaded region at tip. Coating of polytetrafluoroethylene on tip and lip augments conformance.

Stuck, Donald E.↗

Adaptation of the ISCCP cloud detection algorithm to combined AVHRR and SMMR arctic data

The International Satellite Cloud Climatology Project (ISCCP) cloud detection algorithm is applied to artic data, and modifications are suggested. Both Advanced Very High Resolution Radiometer (AVHRR) and Scanning Multichannel Microwave Radiometer (SMMR) data are examined. Synthetic AVHRR and SMMR data are also generated. Modifications suggested include the use of snow and ice data sets for the estimation of surface parameters, additional AVHRR channels, and surface class characteristic values when clear sky values cannot be obtained. Greatest improvement in computed cloud fraction is realized over snow and ice surfaces; over other surfaces all versions perform similarly. Since the use of SMMR for surface analysis increases the computational burden, its use may be justified only over snow and ice-covered regions.

Key, J.↗

MAMS - A high spatial resolution multispectral scanner

The Multispectral Atmospheric Mapping Sensor (MAMS) is an airborne scanner which collects imagery in eight visible and three IR bands, with ground resolution of 100 m at a nominal aircraft altitude of 20 km. The visible channels provide continuous spectral coverage from 0.42 to 1.05 microns, and the IR channels measure upwelling and reflected radiation at combinations of 3.7, 6.5, 11.1, and 12.5 microns. These include channels nearly identical to the Landsat TM channels 1-4, and similar to those on the VISSR Atmospheric Sounder (VAS) and AVHRR instruments. The high spatial resolution permits investigation of surface thermal and atmospheric water vapor structure at scales not available from current stabilities. Significant modifications have been made since engineering flights in 1985 to improve the radiometric performance. The increased data quality and recent multidisciplinary applications of this data are presented.

Atkinson, Robert J.↗

A Mars base

This study was initiated to provide an approach to the development of a permanently manned Mars base. The objectives for a permanently manned Mars base are numerous. Primarily, human presence on Mars will allow utilization of new resources for the improvement of the quality of life on Earth, allowing for new discoveries in technologies, the solar system, and human physiology. Such a mission would also encourage interaction between different countries, increasing international cooperation and leading to a stronger unification of mankind. Surface studies of Mars, scientific experiments in the multiple fields, the research for new minerals, and natural resource production are more immediate goals of the Mars mission. Finally, in the future, colonization of Mars will ensure man's perpetual presence in the universe. Specific objectives of this study were: (1) to design a Mars habitat that minimizes the mass delivered to the Mars surface, provides long-stay capability for the base crew, and accommodates future expansion and modification; (2) to develop a scenario of the construction of a permanently manned Mars base; and (3) to incorporate new and envisioned technologies.

Soule, Veronique↗

Critical issues in connection with human missions to Mars: protection of and from the Martian environment

Human missions to Mars are planned to happen within this century. Activities associated therewith will interact with the environment of Mars in two reciprocal ways: (i) the mission needs to be protected from the natural environmental elements that can be harmful to human health, the equipment or to their operations; (ii) the specific natural environment of Mars should be protected so that it retains its value for scientific and other purposes. The following environmental elements need to be considered in order to protect humans and the equipment on the planetary surface: (i) cosmic ionizing radiation, (ii) solar particle events; (iii) solar ultraviolet radiation; (iv) reduced gravity; (v) thin atmosphere; (vi) extremes in temperatures and their fluctuations; and (vii) surface dust. In order to protect the planetary environment, the requirements for planetary protection as adopted by COSPAR for lander missions need to be revised in view of human presence on the planet. Landers carrying equipment for exobiological investigations require special consideration to reduce contamination by terrestrial microorganisms and organic matter to the greatest feasible extent. Records of human activities on the planet's surface should be maintained in sufficient detail that future scientific experimenters can determine whether environmental modifications have resulted from explorations. c2002 COSPAR. Published by Elsevier Science Ltd. All rights reserved.

Extraterrestrial Environment↗

Modeling of Laser Vaporization and Plume Chemistry in a Boron Nitride Nanotube Production Rig

Flow in a pressurized, vapor condensation (PVC) boron nitride nanotube (BNNT) production rig is modeled. A laser provides a thermal energy source to the tip of a boron ber bundle in a high pressure nitrogen chamber causing a plume of boron-rich gas to rise. The buoyancy driven flow is modeled as a mixture of thermally perfect gases (B, B2, N, N2, BN) in either thermochemical equilibrium or chemical nonequilibrium assuming steady-state melt and vaporization from a 1 mm radius spot at the axis of an axisymmetric chamber. The simulation is intended to define the macroscopic thermochemical environment from which boron-rich species, including nanotubes, condense out of the plume. Simulations indicate a high temperature environment (T > 4400K) for elevated pressures within 1 mm of the surface sufficient to dissociate molecular nitrogen and form BN at the base of the plume. Modifications to Program LAURA, a finite-volume based solver for hypersonic flows including coupled radiation and ablation, are described to enable this simulation. Simulations indicate that high pressure synthesis conditions enable formation of BN vapor in the plume that may serve to enhance formation of exceptionally long nanotubes in the PVC process.

Gnoffo, Peter A.↗

Assessment of Potential Mars Relay Network Enhancements

In anticipation of increased demands on Mars relay services, including planned arrivals of NASA’s InSight Lander in November 2018, and of NASA’s Mars 2020 rover and ESA’s ExoMars Rover & Surface Platform mission in Feb-Mar.2021, we have assessed a number of potential modifications and upgrades to Mars relay orbiters and quantified their impacts in terms of key relay support metrics, to support NASA and ESA programmatic decisions. Specific areas of investigation include: 1) implementation of “split-pass” relay capability for support to collocated landers, 2) modifications of the extended mission orbit for the Mars Atmosphere and Volatile EvolutioN Mission (MAVEN), and 3) introduction of Low-Density Parity Check (LDPC) coding. We report here on each of these potential upgrades, quantify the performance implications each would have on future Mars relay services in the context of future mission support scenarios, and provide a status on implementation.

Wenkert, Daniel↗

Hydrodynamic Instability and Thermal Coupling in a Dynamic Model of Liquid-Propellant Combustion

For liquid-propellant combustion, the Landau/Levich hydrodynamic models have been combined and extended to account for a dynamic dependence of the burning rate on the local pressure and temperature fields. Analysis of these extended models is greatly facilitated by exploiting the realistic smallness of the gas-to-liquid density ratio rho. Neglecting thermal coupling effects, an asymptotic expression was then derived for the cellular stability boundary A(sub p)(k) where A(sub p) is the pressure sensitivity of the burning rate and k is the disturbance wavenumber. The results explicitly indicate the stabilizing effects of gravity on long-wave disturbances, and those of viscosity and surface tension on short-wave perturbations, and the instability associated with intermediate wavenumbers for critical negative values of A(sub p). In the limit of weak gravity, hydrodynamic instability in liquid-propellant combustion becomes a long-wave, instability phenomenon, whereas at normal gravity, this instability is first manifested through O(1) wavenumbers. In addition, surface tension and viscosity (both liquid and gas) each produce comparable effects in the large-wavenumber regime, thereby providing important modifications to the previous analyses in which one or more of these effects was neglected. For A(sub p)= O, the Landau/Levich results are recovered in appropriate limiting cases, although this typically corresponds to a hydrodynamically unstable parameter regime for p << 1. In addition to the classical cellular form of hydrodynamic stability, there exists a pulsating form corresponding to the loss of stability of steady, planar burning to time-dependent perturbations. This occurs for negative values of the parameter A(sub p), and is thus absent from the original Landau/Levich models. In the extended model, however, there exists a stable band of negative pressure sensitivities bounded above by the Landau type of instability, and below by this pulsating form of hydrodynamic instability. Indeed, nonsteady modes of combustion have been observed at low pressures in hydroxylammonium nitrate (HAN)-based liquid propellants, which often exhibit negative pressure sensitivities. While nonsteady combustion may correspond to secondary and higher-order bifurcations above the cellular boundary, it may also be a manifestation of this pulsating type of hydrodynamic instability. In the present work, a nonzero temperature sensitivity is incorporated into our previous asymptotic analyses. This entails a coupling of the energy equation to the previous purely hydrodynamic problem, and leads to a significant modification of the pulsating boundary such that, for sufficiently large values of the temperature-sensitivity parameter, liquid-propellant combustion can become intrinsically unstable to this alternative form of hydrodynamic instability. For simplicity, further attention is confined here to the inviscid version of the problem since, despite the fact that viscous and surface-tension effects are comparable, the qualitative nature of the cellular boundary remains preserved in the zero-viscosity limit, as does the existence of the pulsating boundary. The mathematical model adopts the classical assumption that there is no distributed reaction in either the liquid or gas phases, but now the reaction sheet, representing either a pyrolysis reaction or an exothermic decomposition at the liquid/gas interface, is assumed to depend on local conditions there.

Margolis, S. B.↗

Modification of a Limbed Robot to Favor Climbing

The figure shows the LEMUR IIb, which is a modified version of the LEMUR II the second generation of the Limbed Excursion Mechanical Utility Robot (LEMUR). Except as described below, the LEMUR IIb hardware is mostly the same as that of the LEMUR II. The IIb and II versions differ in their kinematic configurations and characteristics associated with their kinematic configurations. The differences are such that relative to the LEMUR II, the LEMUR IIb is simpler and is better suited to climbing on inclined surfaces. The first-generation LEMUR, now denoted the LEMUR I, was described in Six-Legged Experimental Robot (NPO-20897), NASA Tech Briefs, Vol. 25, No. 12 (December 2001), page 58. The LEMUR II was described in Second-Generation Six-Limbed Experimental Robot (NPO-35140) NASA Tech Briefs, Vol. 28, No. 11 (November 2004), page 55. To recapitulate: the LEMUR I and LEMUR II were six-legged or sixlimbed robots for demonstrating robotic capabilities for assembly, maintenance, and inspection. They were designed to be capable of walking autonomously along a truss structure toward a mechanical assembly at a prescribed location. They were equipped with stereoscopic video cameras and image-data-processing circuitry for navigation and mechanical operations. They were also equipped with wireless modems, through which they could be commanded remotely. Upon arrival at a mechanical assembly, the LEMUR I would perform simple mechanical operations by use of one or both of its front legs (or in the case of the LEMUR II, any of its limbs could be used to perform mechanical operations). Either LEMUR could also transmit images to a host computer. The differences between the LEMUR IIb and the LEMUR II are the following: Whereas the LEMUR II had six limbs, the LEMUR IIb has four limbs. This change has reduced both the complexity and mass of the legs and of the overall robot. Whereas each limb of the LEMUR II had four degrees of freedom (DOFs), each limb of the LEMUR IIb has three DOFs. This change has also reduced both complexity and mass. Notwithstanding the decrease in the number of DOFs, the three remaining DOFs are configured to provide greater dexterity for motion along a surface. To extend reach, the limbs of the LEMUR IIb are 25 percent longer than those of the LEMUR II. Additional benefits stemming from the modifications are that the robot body supported by the limbs is now less massive and its center of gravity is now closer to the surface along which the robot is to move. These benefits have been obtained without sacrificing load-carrying capacity. Hence, overall, the LEMUR IIb is a more adept climber.

Okon, Avi↗

Influence of defects on the femtosecond laser damage resistance of multilayer dielectric gratings

Multilayer dielectric (MLD) gratings with high diffraction efficiency and a high laser-induced damage (LID) threshold for pulse compressors are key to scaling the peak and average power of chirped pulse amplification lasers. However, surface defects introduced by manufacturing, storage, and handling processes can reduce the LID resistance of MLD gratings and impact the laser output. The underlying mechanisms of such defect-initiated LID remain unclear, especially in the femtosecond regime. In this Letter, we model dynamic processes in interactions of a 20-fs near-infrared (NIR) laser pulse and a MLD grating design in the presence of cylindrically symmetrical nodules and particle contaminants and cracks at the surface. Utilizing a dynamic model based on a 2D finite difference in time domain (FDTD) field solver coupled with photoionization, electron collision, and refractive index modification, we study the simulation results for the damage site distribution initiated by defects of various types and sizes and its impact on the LID threshold of the grating design.

Zhang, Simin (ORCID:0000000174948230)↗

Surface brightness, standard candles and q/0/

The most direct way to determine the deceleration parameter, q(0), of the universe is through the study of the redshift-magnitude relation of extragalactic sources. Progress has been slow because the necessary sources for this study must be standard candles, which have identical absolute total luminosity (balometric or monochromatic). The present paper shows, first of all, that, although necessary, this is not a sufficient condition for nonpoint-like (or resolved) sources. A modification of the redshift-magnitude relation is then described for a certain class of nonstandard candles using measurements of isophotal surface brightness. It is noted that such measurements can be used to standardize the central surface brightness of galaxies, but the standardization of the scale parameter remains beyond observations.

Petrosian, V.↗

High-Temperature Smart Structures for Engine Noise Reduction and Performance Enhancement

One of key NASA goals is to develop and integrate noise reduction technology to enable unrestricted air transportation service to all communities. One of the technical priorities of this activity has been to account for and reduce noise via propulsion/airframe interactions, identifying advanced concepts to be integrated with the airframe to mitigate these noise-producing mechanisms. An adaptive geometry chevron using embedded smart structures technology offers the possibility of maximizing engine performance while retaining and possibly enhancing the favorable noise characteristics of current designs. New high-temperature shape memory alloy (HTSMA) materials technology enables the devices to operate in both low-temperature (fan) and high-temperature (core) exhaust flows. Chevron-equipped engines have demonstrated reduced noise in testing and operational use. It is desirable to have the noise benefits of chevrons in takeoff/landing conditions, but have them deployed into a minimum drag position for cruise flight. The central feature of the innovation was building on rapidly maturing HTSMA technology to implement a next-generation aircraft noise mitigation system centered on adaptive chevron flow control surfaces. In general, SMA-actuated devices have the potential to enhance the demonstrated noise reduction effectiveness of chevron systems while eliminating the associated performance penalty. The use of structurally integrated smart devices will minimize the mechanical and subsystem complexity of this implementation. The central innovations of the effort entail the modification of prior chevron designs to include a small cut that relaxes structural stiffness without compromising the desired flow characteristics over the surface; the reorientation of SMA actuation devices to apply forces to deflect the chevron tip, exploiting this relaxed stiffness; and the use of high-temperature SMA (HTSMA) materials to enable operation in the demanding core chevron environment. The overall conclusion of these design studies was that the cut chevron concept is a critical enabling step in bringing the variable geometry core chevron within reach. The presence of the cut may be aerodynamically undesirable in some respects, but it is present only when the chevron is not immersed in the core jet exhaust. When deployed, the gap closes as the chevron tip enters the high-speed, high-temperature core stream. Aeroacoustic testing and flow visualization support the contention that this cut is inconsequential to chevron performance.

Quackenbush, Todd R.↗

Optimization of Picosecond Laser Parameters for Surface Treatment of Composites Using a Design of Experiments (DOE) Approach

Based on guidelines from the Federal Aviation Administration, research supported by the NASA Advanced Composites Project is investigating methods to improve process control for surface preparation and pre-bond surface characterization on aerospace composite structures. The overall goal is to identify high fidelity, rapid, and reproducible surface treatments and surface characterization methods to reduce the uncertainty associated with the bonding process. The desired outcome is a more reliable bonded airframe structure, and to reduce time to achieve certification. In this work, a design of experiments (DoE) approach was conducted to determine optimum laser ablation conditions using a pulsed laser source with a nominal pulse width of 10 picoseconds. The laser power, frequency, scan speed, and number of passes (1 or 2) were varied within the laser system operating boundaries. Aerospace structural carbon fiber reinforced composites (Torayca® 3900-2/T800H) were laser treated, then characterized for contamination, and finally bonded for mechanical testing. Pre-bond characterization included water contact angle (WCA) using a handheld device, ablation depth measurement using scanning electron microscopy (SEM), and silicone contamination measurement using laser induced breakdown spectroscopy (LIBS). In order to accommodate the large number of specimens in the DoE, a rapid-screening, double cantilever beam (DCB) test specimen configuration was devised based on modifications to ASTM D5528. Specimens were tested to assess the failure modes observed under the various laser surface treatment parameters. The models obtained from this DoE indicated that results were most sensitive to variation in the average laser power. Excellent bond performance was observed with nearly 100% cohesive failure for a wide range of laser parameters. Below about 200 mW, adhesive failure was observed because contamination was left on the surface. For laser powers greater than about 600 mW, large amounts of fiber were exposed, and the failure mode was predominately fiber tear.

Palmieri, Frank L.↗

Significant results from Apollo 14 lunar orbital photography.

Apollo 14 obtained 950 photographs from lunar orbit using the Hasselblad and Hycon cameras. The photographs reveal a number of new geologic features as well as previously unrecognized details of the morphology, structure, and stratigraphy of lunar surface units. The primary result is the verification of the extensive role of volcanism in the formation and modification of the lunar highlands, especially on the far side. Terra volcanism appears to be manifest in the formation of (1) constructional units of hilly and furrowed materials of regional extent as in the Kant Plateau in the central near-side highlands and northwest of the crater Pasteur near the eastern limb of the moon; (2) somewhat viscous lava flows and pools associated with fracture systems and/or what appear to be volcanic craters; (3) craters, crater chains, and irregular depressions, particularly on the lunar far side. The first photographs of a flow channel, a leveed sinuous rille that apparently originated by lava flowage on the surface, were obtained by Apollo 14. Another first is a high-resolution photograph of the interior of what appears to be the youngest lunar crater yet photographed in the 20- 40-km size range.

El-Baz, F.↗