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At least 1,225 records · Page 68

Angular and Seasonal Variation of Spectral Surface Reflectance Ratios: Implications for the Remote Sensing of Aerosol over Land

We obtain valuable information on the angular and seasonal variability of surface reflectance using a hand-held spectrometer from a light aircraft. The data is used to test a procedure that allows us to estimate visible surface reflectance from the longer wavelength 2.1 micrometer channel (mid-IR). Estimating or avoiding surface reflectance in the visible is a vital first step in most algorithms that retrieve aerosol optical thickness over land targets. The data indicate that specular reflection found when viewing targets from the forward direction can severely corrupt the relationships between the visible and 2.1 micrometer reflectance that were derived from nadir data. There is a month by month variation in the ratios between the visible and the mid-IR, weakly correlated to the Normalized Difference Vegetation Index (NDVI). If specular reflection is not avoided, the errors resulting from estimating surface reflectance from the mid-IR exceed the acceptable limit of DELTA-rho approximately 0.01 in roughly 40% of the cases, using the current algorithm. This is reduced to 25% of the cases if specular reflection is avoided. An alternative method that uses path radiance rather than explicitly estimating visible surface reflectance results in similar errors. The two methods have different strengths and weaknesses that require further study.

Remer, L. A.↗

Methods of editing cloud and atmospheric layer affected pixels from satellite data

The location and migration of cloud, land and water features were examined in spectral space (reflective VIS vs. emissive IR). Daytime HCMM data showed two distinct types of cloud affected pixels in the south Texas test area. High altitude cirrus and/or cirrostratus and "subvisible cirrus" (SCi) reflected the same or only slightly more than land features. In the emissive band, the digital counts ranged from 1 to over 75 and overlapped land features. Pixels consisting of cumulus clouds, or of mixed cumulus and landscape, clustered in a different area of spectral space than the high altitude cloud pixels. Cumulus affected pixels were more reflective than land and water pixels. In August the high altitude clouds and SCi were more emissive than similar clouds were in July. Four-channel TIROS-N data were examined with the objective of developing a multispectral screening technique for removing SCi contaminated data.

Nixon, P. R.↗

Seasonal Characteristics of Non-Meteorological Radar Reflectivity Returns in Central Florida and Their Impact on TRMM Ground Validation

Radar data quality control is a major component to the Tropical Rainfall Measuring Mission (TRMM) Ground Validation (GV) effort. The quality control algorithm utilizes several adjustable height and reflectivity threshold parameters to remove non-precipitation echoes from ground-based radar data. Spurious radar reflectivity returns not removed during the quality control process may create biases in ground validation rainfall products used to evaluate rainfall measurements retrieved from aboard the TRMM satellite. To better evaluate the performance of the quality control algorithm, WSR-88D radar data from one primary GV site, Melbourne, Florida, are used to determine the seasonal characteristics of non-meteorological radar echoes in cast central Florida during the first year of the TRMM mission. It is demonstrated that unique spurious echo regimes develop throughout the year, leading to different levels of successful non-meteorological echo removal by the quality control algorithm. In addition to the type of non- precipitation echoes present, the success of the algorithm is also greatly dependent upon the amount of precipitation present. Less aggressive attempts to remove non-meteorological echoes must be employed when rain is observed so as not to remove these echoes as well. Therefore, precipitation statistics from ground validation monthly rainfall products will be utilized to further document the quality control algorithm performance. Moreover, these precipitation statistics will be used to demonstrate the relationship between dominant spurious echo regimes and rainfall amount. Finally, monthly statistics of contaminated ground validation radar data will be calculated and the effect on rainfall accumulation products will be discussed.

Robinson, Michael↗

Disorderly Conduct of Benzamide IV: Crystallographic and Computational Analysis of High Entropy Polymorphs of Small Molecules

Benzamide, a simple derivative of benzoic acid and a common intermediate of pharmaceutical compounds, was reported to form two polymorphs in 1832, but the single crystal structure of the more stable form was not solved until 1959. Nearly 50 years later, the second form was characterized by powder diffraction, followed shortly thereafter by characterization of a third form, a polytype of the most thermodynamically stable Form I. These two new forms, Forms II and III, are metastable. Herein, we describe a fourth polymorph, Form IV, discovered by melt crystallization concurrently with its crystallization under confinement at small length scales (<10 nm), where it is stable indefinitely. Form III exists under confinement in larger pores, and melting point data for different pore sizes corroborate the existence of Form IV below 10 nm. Form IV is highly disordered, precluding indexing of powder diffraction data other than hk0 reflections. Nonetheless, a combination of powder X-ray diffraction and computational crystal structure prediction reveals that Form IV contains a 2D motif resembling that of Form II, but with longrange order in the third dimension masked by ubiquitous stacking faults. This approach relies on distilling a large number of candidate structures to a few possible disorder models based on benzamide tetrads that organize in 2D parquet-like tiles, with organization along the third dimension, that can be modeled with various stacking fault configurations having distinct intermolecular interactions and translations in the dimension orthogonal to the tiling planes. These observations reveal a bewildering crystallographic complexity for such a simple molecule. Nonetheless, the approach described herein demonstrates that challenging structures that may be abandoned prematurely because of poor crystallinity, twinning, or disorder can be solved.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Regional Moment Tensor Inversion Using Rotational Observations

There are benefits from the addition of rotational motions to translational displacements for moment tensor (MT) inversions. The rotational radiation pattern is orthogonal to the shear radiation pattern, thus incorporating rotations is equivalent to gaining another observation point on the focal sphere. We demonstrated this by simulating curl and displacement wavefields for a regional distance station. Thus, one 6-C station (3-Component translational + 3-Component rotational) gathers the same information on radiation pattern as two 3-C stations at 90° azimuth from one another along the focal plane axis, which is sometimes difficult to obtain when restricted to surface sensors. We added rotational Green's functions to a regional MT inversion scheme (long-period, time-domain, and linear inversion) by computing spatial gradients from f-κ reflectivity synthetics. For rotational data, we used Array Derived Rotations (ADR) from Piñon Flats Observatory Array and Golay array deployed during IRIS Community Wavefield Demonstration Experiment. The hope is to ultimately use compact and field deployable broadband rotational seismometers instead of ADRs. Rotational motions were predicted from well-constrained deviatoric MT solutions of nine earthquakes recorded by the arrays and other seismic networks. Additionally, we formed three station sparse datasets with (3-C and 6-C) and without rotational ground motions (3-C only) for eight earthquakes testing the benefits of including rotational waveforms in MT inversions when they are equally weighted with translational waveforms. Adding rotational motions improved the double-couple components and reduced compensated-linear-vector-dipole and isotropic components in full-MT solutions using sparse datasets with poor coverage.

58 GEOSCIENCES↗

Ex situ metrology and data analysis for optimization of beamline performance of aspherical pre-shaped x-ray mirrors at the advanced light source

Super high quality aspherical x-ray mirrors with a residual slope error of ~100 nrad (root-mean-square) and a height error of ~1-2 nm (peak-to-valley), and even lower, are now available from a number of the most advanced vendors utilizing deterministic polishing techniques. The mirror specification for the fabrication is based on the simulations of the desired performance of the mirror in the beamline optical system and is normally given with the acceptable level of deviation of the mirror figure and finish from the desired ideal shape. For example, in the case of aspherical x-ray mirrors designed for the Advanced Light Source (ALS) QERLIN beamline, the ideal shape is defined with the beamline application (conjugate) parameters and their tolerances. Here, we first introduce an original procedure and dedicated software developed at the ALS X-Ray Optics Laboratory (XROL) for optimization of beamline performance of pre-shaped hyperbolic and elliptical mirrors. The optimization is based on results of ex situ surface slope metrology and consists in minimization of the mirror shape error by determining the conjugate parameters of the best-fit ideal shape within the specified tolerances. We describe novel optical metrology instrumentation, measuring techniques, and analytical methods used at the XROL for acquisition of surface slope data and optimization of the optic’s beamline performance. The high efficacy of the developed experimental methods and data analysis procedures is reflected in results of measurements with and performance optimization of hyperbolic and elliptical cylinder mirrors designed and fabricated for the ALS QERLIN beamline.

47 OTHER INSTRUMENTATION↗

Refinements for Bragg coherent X-ray diffraction imaging: electron backscatter diffraction alignment and strain field computation

Bragg coherent X-ray diffraction imaging (BCDI) allows the 3D measurement of lattice strain along the scattering vector for specific microcrystals. If at least three linearly independent reflections are measured, the 3D variation of the full lattice strain tensor within the microcrystal can be recovered. However, this requires knowledge of the crystal orientation, which is typically attained via estimates based on crystal geometry or synchrotron microbeam Laue diffraction measurements. Presented here is an alternative method to determine the crystal orientation for BCDI measurements using electron backscatter diffraction (EBSD) to align Fe–Ni and Co–Fe alloy microcrystals on three different substrates. The orientation matrix is calculated from EBSD Euler angles and compared with the orientation determined using microbeam Laue diffraction. The average angular mismatch between the orientation matrices is less than ∼6°, which is reasonable for the search for Bragg reflections. The use of an orientation matrix derived from EBSD is demonstrated to align and measure five reflections for a single Fe–Ni microcrystal via multi-reflection BCDI. Using this data set, a refined strain field computation based on the gradient of the complex exponential of the phase is developed. This approach is shown to increase accuracy, especially in the presence of dislocations. The results demonstrate the feasibility of using EBSD to pre-align BCDI samples and the application of more efficient approaches to determine the full lattice strain tensor with greater accuracy.

42 ENGINEERING↗

FTLADS: Object-Logging Based Fault-Tolerant Big Data Transfer System Using Layout Aware Data Scheduling

The layout-aware data scheduling (LADS) data movement framework optimizes congestion for end-to-end data transfers. During data transfer, LADS can avoid congested storage elements by exploiting the underlying storage layout at each endpoint. This improves the I/O bandwidth and hence the data transfer rate across high-speed networks. However, the absence of fault tolerance (FT) in LADS results in data retransmission overhead and may lead to possible data integrity issues upon faults. In this paper, we propose object-logging FT mechanisms to avoid transmitting the objects that are successfully written into the parallel file system (PFS) at the sink end. Depending on the number of log files created for the whole dataset, we have classified our FT mechanisms into three different categories: file logger, transaction logger, and universal logger. Also, to address the space overhead, we have proposed different methods of populating the log files with the information of the successfully transferred objects. We have evaluated the data transfer performance and recovery time overhead of the proposed object-logging-based FT mechanisms on the LADS data transfer framework. Our experimental results reflect that FT mechanisms exhibit negligible overhead (<; 1%) with respect to the data transfer time. Yet, the fault recovery time is 10% higher than the total data transfer time at any fault point.

97 MATHEMATICS AND COMPUTING↗

Measurement and Reporting Guidelines for Solar Mirror Aging Tests Using Xenon Arc Lamp Exposure (XALE)

This technical report provides a guideline for accelerated aging tests on solar reflectors. Solar reflectors must have a high durability, with goal lifespans reaching 30 years. To test and develop state-of-the-art solar reflectors, relevant durability tests must be conducted. Existing guidelines for materials testing include isothermal testing, humidity testing, corrosion, etc., but many tests do not specify to include solar irradiance or address its relevance to solar reflector durability. The guideline focuses on test design and reporting guidelines for using Xenon Arc Lamp Exposure (XALE). The XALE environmental chambers can subject samples to a combination of relevant environmental factors including concentrated solar irradiance, heat, humidity, and weathering cycles. The guideline is meant to provide information on developing relevant test conditions, exposure times, reflectance characterization procedures, and data reporting.

14 SOLAR ENERGY↗

2023 Standard Scenarios Report: A U.S. Electricity Sector Outlook

This report, originally published in December 2023, has been revised in January 2024. There were three changes in the revision. First, Anthony Lopez was added as a contributing author, as he had been erroneously omitted in the original publication. Second, in appendix section A.1 the cost of upgrading a hydrogen combustion turbine from a natural gas turbine was erroneously reported as 20% when it should have been 33%. Lastly, appendix Figure A-8 was erroneously a duplication of the same figure from the Standard Scenarios 2022, it has now been updated to reflect this year’s data.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Earth resources data systems design: S192 instrument measurements and characteristics

The design, development, and characteristics of the S192 instrument for use with the earth resources data systems are discussed. Subjects presented are: (1) multispectral scanner measurements, (2) measurement characteristics, (3) calibration and aligment, (4) operating modes, and (5) time tagging and references. The S192 will obtain high spatial resolution, quantitative line scan imagery data of the radiation reflected and emitted by selected test sites in up to 13 spectral bands of visible, near infrared, and thermal infrared regions of the electromagnetic spectrum.

Goldstein, A. S.↗

Composition of the upper clouds of Venus.

Recent developments have shed new light on the composition of the upper Venus clouds. An analysis of the Mariner 5 occultation data has led to improved temperature and pressure profiles. When these are combined with transit data, it is concluded that there is an optically thin cloud layer with a top at 81-km altitude where the temperature and pressure are, respectively, 175 K and 3 mb. The inclusion of temperatures derived from the near-infrared CO2 bands leads to the postulate of a second cloud deck with a top at 61-km altitude, where temperature and pressure are 260 K and 240 mb. Additional important constraints on cloud models are imposed by the measured abundances of HCl and H2O, by the polarization data, and by the reflection and emission spectra. It is concluded that the leading candidate for the uppermost clouds is liquid drops of HCl-H2O, that there is no recommended candidate for the second cloud deck, and that H2O ice is at most a minor component of these cloud systems.

Rea, D. G.↗

Investigation of techniques for correcting ERTS data for solar and atmospheric effects

The author has identified the following significant results. The design and fabrication of five radiant power measuring instruments (RPMI) for ERTS ground truth have been completed. These instruments will be deployed in concert with ERTS overflights to obtain radiometric measurements needed to determine solar and atmospheric parameters that effect ERTS radiance measurements. With these parameters, the accuracy and capability of various procedures for transforming ERTS data into absolute target reflectance signatures will be evaluated. The RPMI is a rugged, hand-carried instrument accurately calibrated to measure both downwelling and reflected radiance within each ERTS multispectral scanner band. A foldover handle permits a quick change from wide angle global or sky irradiance measurements to narrow angle radiance measurements from sky and ground targets. These measurements yield ground truth site reflectance and permit calculation of additional parameters such as beam transmittance between spacecraft and ground, and path radiance (path reflectance).

Rogers, R. H.↗

Investigation of techniques for correction ERTS data for solar and atmospheric effects

Significant findings during this report period are: (1) The feasibility of using techniques for obtaining and using atmospheric parameter to transform ERTS data into absolute target reflectance was demonstrated. (2) Ground-truth instrumentation must have a dynamic range of 100,000 for obtaining the full set of atmospheric parameters encountered in the field. (3) Atmospheric transmittance for January through May 1973 varied from 13 to 18 percent in the ERTS bands. (4) Energy scattered to the spacecraft from the atmosphere for the March overflight was equivalent to that produced by a target having a reflectance of 11% in band 4, 5% in band 5, 3% in band 6, and 1% in band 7. (5) This atmospheric radiance varies as a function of sun zenith angle (scatter angle) and is predicted to change by 30% for sun angles at the latitude of the Michigan test site. (6) If not removed from spacecraft measurements before computing reflectance of surface targets, this radiance is a major source of error.

Rogers, R. H.↗

Acoustical characteristics of the NASA Langley full scale wind tunnel test section

The full-scale wind tunnel at NASA-Langley Research Center was designed for low-speed aerodynamic testing of aircraft. Sound absorbing treatment has been added to the ceiling and walls of the tunnel test section to create a more anechoic condition for taking acoustical measurements during aerodynamic tests. The results of an experimental investigation of the present acoustical characteristics of the tunnel test section are presented. The experimental program included measurements of ambient nosie levels existing during various tunnel operating conditions, investigation of the sound field produced by an omnidirectional source, and determination of sound field decay rates for impulsive noise excitation. A comparison of the current results with previous measurements shows that the added sound treatment has improved the acoustical condition of the tunnel test section. An analysis of the data indicate that sound reflections from the tunnel ground-board platform could create difficulties in the interpretation of actual test results.

Abrahamson, A. L.↗

Irrigation scheduling, freeze warning and soil salinity detecting

The author has identified the following significant results. Correlations of multispectral scanner (MSS) digital data differences between vegetated and bare soil areas with salinity levels from the eight saline areas using MSS bands seven and ten in the infrared region were significant. Correlations were derived for Cameron County, Texas. Detection of saline soils may be possible, using either film density readings or multispectral scanner data, when the lower reflectance of vegetation on highly saline soil and the higher reflectance of vegetation on lower saline soil are considered by using film on MSS contrasts between vegetation and bare soil.

Wiegand, C. L.↗