Evaluation of a Material Balance Only and Material Balance with Real-Time In-line Monitoring Approaches for DFLAW Processing
The Assistant Manager, WTP chartered an Integrated Technical Team (ITT), which includes personnel from the Savannah River National Laboratory (SRNL), Pacific Northwest National Laboratory (PNNL), from the Savannah River National Laboratory (SRNL), Pacific Northwest National Laboratory (PNNL), Bechtel National, Inc., and DOE-ORP, to evaluate the capability and potential benefits of replacing sample collection/analyses requirements with real-time, in-line monitoring. The initial focus of the ITT is the Direct Feed Low Activity Waste (DFLAW) Program. This work scope is being performed in multiple phases. The Phase 2 work scope contains tasks to evaluate a materials balance only approach as well as continuing scoping evaluations for instruments that could be used for Real-Time In-Line Monitoring (RTIM). The Phase 2 work scope for evaluation of a materials balance approach was completed by both SRNL and PNNL and is documented in this report. The material balance evaluation included a review of the WTP Low Activity Waste (LAW) vitrification process as well as the WTP Effluent Management Facility (EMF) process. Sampling requirements and unit operations were reviewed to determine which sample requirements could be met with a material balance without significantly increasing processing or reporting uncertainties.