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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,243 records · Page 69

Explosive Ice Multiplication Induced by Multiplicative-Noise Fluctuation of Mechanical Breakup in Ice–Ice Collisions

The number of ice fragments generated by breakup of large graupel in collisions with small graupel fluctuates randomly owing to fluctuations in relative sizes and densities of colliding graupel particles and the stochastic nature of fracture propagation. This paper investigates the impact of the stochasticity of breakup on ice multiplication. When both the rate of generation of primary ice and the initial number concentration of ice crystals are low, the system most likely loses all the initial ice and graupel owing to a lack of sustaining sources. Even randomness does not change this mean evolution of the system in its phase space. However, a fluctuation of ice breakup number gives a small but finite chance that substantial ice crystal fragments are generated by breakup of large graupel. That, in turn, generates more large graupel. This multiplicative process due to fluctuations potentially leads to a small but finite chance of explosive growth of ice number.A rigorous stochastic analysis demonstrates this point quantitatively. The randomness considered here belongs to a particular category called ‘‘multiplicative’’ noise, because the noise amplitude is proportional to a given physical state. To contrast the multiplicative-noise nature of ice breakup with a standard ‘‘additive’’ noise process, fluctuation of the primary ice generation rate is also considered as an example of the latter. These processes are examined by taking the Fokker–Planck equation that explicitly describes the evolution of the probability distribution with time. As an important conclusion, stability in the phase space of the cloud microphysical system of breakup in ice–ice collisions is substantially altered by the multiplicative noise.

54 ENVIRONMENTAL SCIENCES↗

Growing Pacific Linkage with Western North Atlantic Explosive Cyclogenesis

Abstract Explosive cyclones (ECs), defined as extratropical cyclones that experience normalized pressure drops of at least 24 hPa in 24 h, are impactful weather events in the North Atlantic sector, but year-to-year changes in the frequency and impacts of these storms are sizeable. To analyze the sources of this interannual variability, we track cases of ECs and dissect them into two spatial groups: those that formed near the east coast of North America (coastal) and those in the north central Atlantic (high latitude). The frequency of high-latitude ECs is strongly correlated with the North Atlantic Oscillation, a well-known feature, whereas coastal EC frequency is statistically linked with an atmospheric wave train emanating from the North Pacific in the last 30 years. This wave train pattern of alternating high and low pressure is associated with heightened upper-level divergence and Eady growth rates along the east coast of North America, likely resulting in a stronger correspondence between the atmospheric wave train and coastal EC frequency. Using coupled model experiments, we show that the tropical and North Pacific oceans are an important factor for this atmospheric wave train and the subsequent enhancement of seasonal baroclinicity in the North Atlantic.

58 GEOSCIENCES↗

Polymorphic Phase Control of RDX-Based Explosives

The polymorphic phase of 1,3,5-trinitro-1,3,5-triazine (RDX) was examined as a function of mass loading, solvent, and sample deposition technique. When RDX was deposited at a high mass loading, the vibrational modes in the obtained Raman spectra were indicative of concomitant polymorphism as both the α-RDX and β-RDX phases were present. At low mass loadings, only β-RDX was observed regardless of solvent when using the drop cast crystallization method. However, α-RDX (the thermodynamically stable polymorphic phase observed with visible quantities of the explosive) was observed when RDX deposits were dry transferred. Observation of α-RDX was independent of the initial mass loading or the initial deposition solvent when using the dry transfer methodology. These data indicate that the use of the dry transfer preparation method can be used to successfully prepare RDX-based test articles with the α-RDX phase regardless of the solvent used to initially dissolve the RDX, the initial deposition technique, or the mass loading.

Brady, John J.↗

Exascale models of stellar explosions: Quintessential multi-physics simulation

The ExaStar project aims to deliver an efficient, versatile, and portable software ecosystem for multi-physics astrophysics simulations run on exascale machines. The code suite is a component-based multi-physics toolkit, built on the capabilities of current simulation codes (in particular Flash-X and Castro), and based on the massively parallel adaptive mesh refinement framework AMReX. It includes modules for hydrodynamics, advanced radiation transport, thermonuclear kinetics, and nuclear microphysics. The code will reach exascale efficiency by building upon current multi- and many-core packages integrated into an orchestration system that uses a combination of configuration tools, code translators, and a domain-specific asynchronous runtime to manage performance across a range of platform architectures. The target science includes multi-physics simulations of astrophysical explosions (such as supernovae and neutron star mergers) to understand the cosmic origin of the elements and the fundamental physics of matter and neutrinos under extreme conditions.

79 ASTRONOMY AND ASTROPHYSICS↗

Infrared near-field spectroscopy of trace explosives using an external cavity quantum cascade laser

Utilizing a broadly-tunable external cavity quantum cascade laser for scattering-type scanning near-field optical microscopy (s-SNOM), we measure infrared spectra of explosives particles by probing characteristic nitro-group resonances in the 7.1-7.9 µm wavelength range. Measurements are presented with spectral resolution of 0.25 cm-1, spatial resolution of 25 nm, <100 attomolar sensitivity, and at a rapid acquisition time of 90 s per spectrum. We demonstrate high reproducibility of the acquired s-SNOM spectra with very high signal-to-noise ratios and relative noise of <0.02 in self-homodyne detection.

(140.5965) Semiconductor lasers, quantum cascade↗

PoroTomo: Horizontal Distributed Acoustic Sensing (DAS) Measurements During an M 2.3 Explosion

Included here are Distributed Acoustic Sensing (DAS) data collected by the horizontal DAS array at Brady's Hot Springs Geothermal Field. The system recorded this data during an M 2.3 explosion at the Nevada Test Site (NTS), which is located approximately 400km southeast of the field. On December 19, 2018, a Silixa iDAS interrogator continuously acquired data on single-mode fibers, starting approximately two hours prior to the detonation and extending until 15 minutes after the event. This dataset comprises separate SEG-Y files that span the entire recording interval. The measurement fiber was part of the PoroTomo experiment and is horizontally emplaced in alluvial fan gravels at a depth of approximately one meter for a distance of more than 2.5 km in a zig-zag pattern. Exact coordinates of this DAS surface array are provided in the attached GDR dataset below. The iDAS interrogator channel spacing is 1.021 m and gauge length is 10 m. Concurrent Distributed Temperature Sensing (DTS) measurements made with a Silixa XT on the multi-mode fibers aided in calibrating the DAS measurements.

15 GEOTHERMAL ENERGY↗

Nonlinearities in Magnetic Confinement, Ionospheric Physics, and Population Explosion Leading to Profile Resilience Нелінійності в магнетному утриманні, фізиці іоносфери та процесі демографічного вибуху, які приводять до стійкості профілю

Nonlinearities play an important role in many fields. In the field of thermonuclear fusion, they are involved in questions such as profile resilience and fluid closure. A nonlinear phenomenon common to both fusion and astrophysical planets is the generation of zonal flows. These flows play a significant role in determining the level of turbulence and fluid closure in fusion. The effects of resonance broadening and nonlinearities are investigated, specifically focusing on the case of nonlinear instability that has appeared in drift waves. Similarities and differences between our systems are discussed, with population explosion and the dynamics of nonlinear systems for drift waves by different states in profile resilience described with great precision. The aim of our study is to put our fluid model for drift waves in tokamaks within the wider framework of statistical physics principles. This reinforces our belief in the broad application of our drift wave model, which encompasses current tokamaks, ITER, and the fusion pilot plant.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Explosion Discrimination Using Seismic Gradiometry and Spectral Filtering of Data

Here, we present a new method to discriminate between earthquakes and buried explosions using observed seismic data. The method is different from previous seismic discrimination algorithms in two main ways. First, we use seismic spatial gradients, as well as the wave attributes estimated from them (referred to as gradiometric attributes), rather than the conventional three-component seismograms recorded on a distributed array. The primary advantage of this is that a gradiometer is only a fraction of a wavelength in aperture compared with a conventional seismic array or network. Second, we use the gradiometric attributes as input data into a machine learning algorithm. The resulting discrimination algorithm uses the norms of truncated principal components obtained from the gradiometric data to distinguish the two classes of seismic events. Using high-fidelity synthetic data, we show that the data and gradiometric attributes recorded by a single seismic gradiometer performs as well as a conventional distributed array at the event type discrimination task.

58 GEOSCIENCES↗

Joint Inversion of Regional Waveform, First-Motion Polarity, and Synthetic Aperture Radar Surface Displacement for the Fourth and Sixth North Korean Declared Nuclear Explosions

Here, this study analyzed the Democratic People’s Republic of Korea’s (DPRK) fourth (DPRK4, 6 January 2016 M w 4.49) and sixth (DPRK6, 7 September 2017 M w 5.2) declared nuclear tests, employing a joint seismic and Interferometric Synthetic Aperture Radar (InSAR) inversion to improve understanding of these events and enhance moment tensor (MT) inversion capabilities. The recent efforts have focused on employing seismic waveform and InSAR geodetic deformation data separately to analyze these and the previous nuclear tests (e.g., Chiang et al., 2018; Myers et al., 2018; Wang et al., 2018). Building upon our previous work (Chi-Durán et al., 2021), we performed a joint regional waveform, first-motion (FM) polarity, and surface displacement inversion, which demonstrated improved source-type discrimination, a revised MT solution with reduced scalar moment uncertainty, and an independently constrained location. In this article, we build on the previous results for DPRK6 by including an analysis using a four-layered velocity model with free-surface topography to compute the near-source static deformation Green’s functions. The model consists of a 50 m basalt layer (⁠V P = 2.07 km/s, V S = 1.2 km/s⁠), a 250 m stratified volcanic deposit layer (⁠V P = 1.73 km/s, V S = 1.0 km/s⁠), a 700 m weathered granodiorite layer (⁠V P = 2.5 km/s, V S = 1.3 km/s⁠⁠), and a granodiorite half-space (⁠V P = 5.35 km/s, V S = 3.09 km/s⁠⁠). The half-space shares the velocity of the regional MDJ2 velocity model (Ford et al., 2010), which has proven effective for waveform inversion in the region. This model considers the range of reported values for various lithologies and weathering effects. Our findings show that using the layered velocity model enhances the recovery of source location and depth for both the explosions by improving fits and reducing uncertainties. The joint inversion also improves source-type discrimination and better constrains the scalar seismic moment necessary for downstream yield estimation.

58 GEOSCIENCES↗

Moment Tensor Source-Type Analysis for the Democratic People's Republic of Korea-Declared Nuclear Explosions (2006-2017) and 3 September 2017 Collapse Event

The Democratic People's Republic of Korea (DPRK) conducted its sixth announced nuclear test on 3 September 2017 03:30 UTC (mb 6.1). There was an aftershock 8.5 min later (mb 4.1). Such aftershocks were noteworthy and often associated with post–nuclear explosion collapses. We performed moment tensor (MT) and network sensitivity solution (NSS) analysis using regional long-period surface-wave and first-motion (FM) polarities. We also extended this analysis to the previous five DPRK nuclear tests. The NSS results, which include MT solution uncertainties, show large isotropic components for the events and are within the population of other U.S. nuclear and collapse events on the fundamental lune. The FM data improved the NNS source-type resolution. The agreement between MT seismic moments and independent coda-envelope amplitudes indicated no biases with the Earth model error or poorly constrained seismic moment for shallow seismic sources. The MT for the collapse is not a pure implosion and consistent with an equivalent tensional closing crack mechanism and two-sided vertical point force.

58 GEOSCIENCES↗

Data supporting the article titled "Heterogeneous Multiphase Flow Properties of Volcanic Rocks and Implications for Noble Gas Transport from Underground Nuclear Explosions"

The submission is a Reproducible Research (RR) data archive that contains the supporting multiphase fluid flow and curve fitting results of the Vadose Zone Journal article titled: "Heterogeneous Multiphase Flow Properties of Volcanic Rocks and Implications for Noble Gas Transport from Underground Nuclear Explosions." The article's DOI number is the following: https://doi.org/10.1002/vzj2.20123. Please see the "Methods and Materials" section of the journal article and the ReadMe.txt in the RR_ARCHIVE folder for further details. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525. SAND Number: SAND2021-3407 O.

mercury injection capillary pressure↗

Ionization potential and electron affinity for six common explosive compounds by DFT, MP2, and CBS-QB3

The vertical and adiabatic ionization potential (IP V and IP A ) and vertical electron affinity (EA V ) for six explosives (RDX, HMX, TNT, PETN, HMTD, and TATP) have been studied by ab initio computational methods. The IPV was calculated using MP2 and CBS-QB3 while the IP A was calculated with B3LYP, CAM-B3LYP, ω B97XD, B2PLYP, and MP2. RDX and TNT IP A ’s were also reported using CBS -QB3. Excluding results by CBS-QB3, B3LYP and B2PLYPD provided superior and more consistent results for calculating the IP. The EA V were calculated using the same methods however B3LYP performed the worst in this case with MP2 and B2PLYPD predicting values closest to those made by CBS-QB3, which was used a reference due to lacking experimental data. Basis set effects were evaluated using 6- 31+G(d,p), 6-311+G(d,p), and 6-311+(3df,2p) for both IP and EA. 6-31+G(d,p) gave satisfactory results for calculating both IP however 6-311+G(3df,2p) had improved results in calculating the EA. The four nitro containing compounds had exothermic reduction potentials while the peroxides were unfavorable. Additionally, it was seen that RDX, HMX, TATP and HMTD were unstable in their reduced forms. Results are aimed to assist detection and screening methods.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Rock Valley Direct Earthquake-Explosion Comparison Experiment (RV-DC): Initial Feasibility Study

The RV-­DC is designed to be the capstone of the ongoing Source Physics Experiments. This report describes the motivation behind the RV-­DC and the tremendous potential scientific payoff for both nuclear explosion monitoring and earthquake source physics expected from the RV-­DC experiment. The report describes the issues, work to date and plans for FY13 in the areas of defining the shot location, depth and size, as well as addressing potential concerns about induced seismicity. We believe the RV-­DC is feasible. There do not appear to be any significant technical or scientific issues that would prevent the RV-DC from being carried out in the approximately FY14‐16 timeframe. This timeframe allows sufficient time for work to continue in FY13 to better define the experimental plan. It is our recommendation, based on the work to date and the potential payoff of the RV-­DC experiment, that the currently defined work for FY13 to better define the experimental plan, proceed.

58 GEOSCIENCES↗

Field Testing of the COTS DESI/DART-MS/MS System Against High Explosives Residues

This testing was performed to evaluate the performance of the FLIR systems® portable DESI/DART MS/MS (Direct ElectroSpray Ionization)/Direct Analysis in Real Time-Mass Spectrometer/ Mass Spectrometer) system against high explosives residues under field conditions. The samples collected for analysis do not require sample preparation and are analyzed in less than 20 seconds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Modeling the thermal deformation of TATB-based explosives. Part 1: Thermal expansion of “neat-pressed” polycrystalline TATB

We detail a modeling approach to simulate the anisotropic thermal expansion of polycrystalline (1,3,5-triamino-2,4,6-trinitrobenzene) TATB-based explosives that utilizes microstructural information including porosity, crystal aspect ratio, and processing-induced texture. This report, the first in a series, focuses on nonlinear thermal expansion of “neat-pressed” polycrystalline TATB specimens which do not contain any binder; additional complexities related to polymeric binder and irreversible ratcheting behavior are briefly discussed, however detailed investigation of these aspects are deferred to subsequent reports. In this work we have, for the first time, developed a mesoscale continuum model relating the thermal expansion of polycrystal TATB specimens to their microstructural characteristics. A self-consistent homogenization procedure is used to relate macroscopic thermoelastic response to the constitutive behavior of single-crystal TATB. The model includes a representation of grain aspect ratio, porosity, and crystallographic texture attributed to the consolidation process. A quantitative model is proposed to describe the evolution of preferred orientation of graphitic planes in TATB during consolidation and an algorithm constructed to develop a discrete representation of the associated orientation distribution function. Analytical and numerical solutions using this model are shown to produce textures consistent with previous measurements and characterization for isostatic and uniaxial “die-pressed” specimens. Predicted thermal strain versus temperature for textured specimens are shown to be in agreement with corresponding experimental measurements. Using the developed modeling approach, several simulations have been run to investigate the influence of microstructure on macroscopic thermal expansion behavior. Results from these simulations are used to identify qualitative trends. Implications of the identified trends are discussed in the context of thermal deformation of engineered components whose consolidation process is generally more complex than isostatic or die-pressed specimens. Finally, an envisioned application of the modeling approach to simulating thermal expansion of weapon systems and components is outlined along with necessary future work to introduce the effects of binder and ratcheting behavior. Key conclusions from this work include the following. Both porosity and grain aspect ratio have an influence on the thermal expansion of polycrystal TATB considering realistic material variability. Thepreferred orientation of the single crystal TATB [001] poles within a polycrystal gives rise to pronounced anisotropy of the macroscopic thermal expansion. The extent of this preferred orientation depends on the magnitude of deformation, and consequently, is expected to vary spatially throughout manufactured components much like porosity. The modeling approach presented here has utility toward bringing spatially variable microstructural features into macroscale system engineering modelsAbstract Not Provided

36 MATERIALS SCIENCE↗

Advanced explosives research and education [Slides]

LANL Advanced Homemade Explosives Course: • Joint Course offered for all DOD EOD Technicians. – First course June 2013, 12 courses to date , ~ 220 EOD technicians trained. • Focus is on the safety and recognition of HMEs, formulation/ synthesis, improvised detonators and detection. • LANL instructors numerous divisions.

33 ADVANCED PROPULSION SYSTEMS↗

Investigation of the fragmentation of an explosively driven cylinder

Explosively driven fragmentation is highly complex. To better understand the field detonation, different methodologies (Lagrangian (with a failure threshold in VisIt and element erosion), ALE and embedded grid) were simulated to provide a comparison to the experimental data through the utilization of fragment distributions and gross deformation metrics. Provided with the geometrical parameters and the results from the experimental data, the computer simulations were conducted after the successful writing of each input file. Mesh refinement – a scalar multiplier applied to the mesh to refine the results – was then studied. The objective was to find a value that parallels the experimental results as the mesh can be refine indefinitely, theoretically. Various mesh resolution scales were simulated and the results graphically compared, using the damage and failure variables from a statistical Johnson Cook failure model, the number of fragments over time as well as time required for each simulation to run and number of processors utilized. The desired result is a calculated method to quantify the comparison being performed.

36 MATERIALS SCIENCE↗