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NASA NTRS2015

Research from the NASA Twins Study and Omics in Support of Mars Missions

The NASA Twins Study, NASA's first foray into integrated omic studies in humans, illustrates how an integrated omics approach can be brought to bear on the challenges to human health and performance on a Mars mission. The NASA Twins Study involves US Astronaut Scott Kelly and his identical twin brother, Mark Kelly, a retired US Astronaut. No other opportunity to study a twin pair for a prolonged period with one subject in space and one on the ground is available for the foreseeable future. A team of 10 principal investigators are conducting the Twins Study, examining a very broad range of biological functions including the genome, epigenome, transcriptome, proteome, metabolome, gut microbiome, immunological response to vaccinations, indicators of atherosclerosis, physiological fluid shifts, and cognition. A novel aspect of the study is the integrated study of molecular, physiological, cognitive, and microbiological properties. Major sample and data collection from both subjects for this study began approximately six months before Scott Kelly's one year mission on the ISS, continue while Scott Kelly is in flight and will conclude approximately six months after his return to Earth. Mark Kelly will remain on Earth during this study, in a lifestyle unconstrained by this study, thereby providing a measure of normal variation in the properties being studied. An overview of initial results and the future plans will be described as well as the technological and ethical issues raised for spaceflight studies involving omics.

Kundrot, C.↗
NASA NTRS2015

Sample Acquisition and Analytical Chemistry Challenges to Verifying Compliance to Aviators Breathing Oxygen (ABO) Purity Specification

NASA has been developing and testing two different types of oxygen separation systems. One type of oxygen separation system uses pressure swing technology, the other type uses a solid electrolyte electrochemical oxygen separation cell. Both development systems have been subjected to long term testing, and performance testing under a variety of environmental and operational conditions. Testing these two systems revealed that measuring the product purity of oxygen, and determining if an oxygen separation device meets Aviator's Breathing Oxygen (ABO) specifications is a subtle and sometimes difficult analytical chemistry job. Verifying product purity of cryogenically produced oxygen presents a different set of analytical chemistry challenges. This presentation will describe some of the sample acquisition and analytical chemistry challenges presented by verifying oxygen produced by an oxygen separator - and verifying oxygen produced by cryogenic separation processes. The primary contaminant that causes gas samples to fail to meet ABO requirements is water. The maximum amount of water vapor allowed is 7 ppmv. The principal challenge of verifying oxygen produced by an oxygen separator is that it is produced relatively slowly, and at comparatively low temperatures. A short term failure that occurs for just a few minutes in the course of a 1 week run could cause an entire tank to be rejected. Continuous monitoring of oxygen purity and water vapor could identify problems as soon as they occur. Long term oxygen separator tests were instrumented with an oxygen analyzer and with an hygrometer: a GE Moisture Monitor Series 35. This hygrometer uses an aluminum oxide sensor. The user's manual does not report this, but long term exposure to pure oxygen causes the aluminum oxide sensor head to bias dry. Oxygen product that exceeded the 7 ppm specification was improperly accepted, because the sensor had biased. The bias is permanent - exposure to air does not cause the sensor to return to its original response - but the bias can be accounted for by recalibrating the sensor. After this issue was found, continuous measurements of water vapor in the oxygen product were made using an FTIR. The FTIR cell is relatively large, so response time is slow - but moisture measurements were repeatable and accurate. Verifying ABO compliance for oxygen produced by commercial cryogenic processes has a different set of sample acquisition and analytical chemistry challenges. Customers want analytical chemists to conserve as much as possible. Hygrometers are not exposed to hours of continuous flow of oxygen, so they don't bias, but small amounts of contamination in valves can cause a "fail". K bottles are periodically cleaned and recertified - after cleaning residual moisture can cause a "fail". Operators let bottle pressure drop to room pressure, introduce outside air into the bottle, and the subsequent fill will "fail". Outside storage of K‐bottles has allowed enough in‐leakage, so contents will "fail".

Graf, John↗
DOE OSTI2018

Evaluating the Implications of Climate Projections on Heat Hardiness Zones for Green Infrastructure Planning

Background: Green Infrastructure (GI) is widely being promoted as an adaptation strategy for urban flooding. Like urban flooding, tree species could be impacted by future climatic conditions. However, there have been limited studies on the implications of future climate on GI planning, mostly due to the lack of climate data at higher spatial resolutions. Objective: Here in this paper, we analyze the implications of climate projections on heat hardiness zones since this could impact the GI landscape in the coming years. This is an extension of our earlier work on evaluating impacts of climate projections on plant hardiness zones. Method: Using downscaled daily temperature data from ten Coupled Model Intercomparison Project Phase 5 (CMIP5) climate models for the historical (1980-2005) and projected (2025-2050) periods, we analyzed future heat hardiness zones in the watershed bounding Knox County, TN. We analyzed the implications of these outputs for the current list of suggested native and non-native tree species selected for GI in the study area. Results: All the models suggest that a considerable part of the study area will move into the next warmer heat zone. While most trees remain suitable for GI, several are at the limit of their ideal heat zones. Conclusion: The insights from this study will help to guide the selection and placement of GI across the study area. Specifically, it should help green infrastructure planners design better mitigation and adaptation strategies to achieve higher returns on investments as more cities are now investing in GI projects.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2004

Satellite IR Thermal Measurements Prior to the September 2004 Earthquakes in Central California

We present and discuss observed variations in thermal transients and radiation fields prior to the earthquakes of September 18 near Bodie (M5.5) and September 28,2004 near Parkfield(M6.0) in California. Previous analysis of earthquake events have indicated the presence of a thermal anomaly, where temperatures increased or did not return to its usual nighttime value. The procedures used in our work is to analyze weather satellite data taken at night and to record the general condition where the ground cools after sunset. Two days before the Bodie earthquake lower temperature radiation was observed by the NOAA/AVHRR satellite. This occurred when the entire region was relatively cloud-free. IR land surface nighttime temperature from the MODIS instrument rose to +4 C in a 100 km radius around the Bodie epicenter. The thermal transient field recorded by MODIS in the vicinity of Parkfield, also with a cloud free environment, was around +l C and it is significantly smaller than the Parkfield epicenter, however, for that period showed a steady increase 4 days prior to the earthquake and a significant drop of the night before the quake. Geosynchronous weather satellite thermal IR measurements taken every half hour from sunset to dawn, were also recorded for 10 days prior to the Parkfield event and 5 days after as well as the day of the quake. To establish a baseline we also obtained GOES data for the same Julian sets were then used to systematically observe and record any thermal anomaly prior to the events that deviated from the baseline. Our recent results support the hypothesis of a possible relationship between an thermodynamic processes produced by increasing tectonic stress in the Earth's crust and a subsequent electro-chemical interaction between this crust and the atmosphere/ionosphere.

Ouzounov, D.↗
DOE OSTI2024

Dynamic data-driven multiscale modeling for predicting the degradation of a 316L stainless steel nuclear cladding material

Here, we have developed a long short-term memory stacked ensemble (LSTM-SE) surrogate modeling approach that can provide rapid predictions of microstructural evolution and the resultant mechanical properties of American Iron and Steel Institute (AISI) 316L series stainless steel (316LSS) fuel cladding under conditions of varying temperature and radiation dose rate. To acquire training data, we developed and implemented a kinetic Monte Carlo (KMC) model to simulate precipitation kinetics of M 23 C 6 , γ', and G phases within SS316L cladding. Experimentally reported precipitation kinetics of SS316L in literature were linked to the kinetic parameters of the simulated precipitation in our KMC model. The model was then used to simulate microstructure evolution under synthetically generated treatments of varying temperature and radiation dose rate, for periods of up to 3000 hours. Changes in volume fraction, number density, and particle size of precipitates were recorded, and particle area fractions were correlated using statistical methods to develop the surrogate model. Simultaneously, the mechanical properties of the simulated microstructures were evaluated using microstructure-based finite element method (FEM) analysis to determine the elastic modulus, yield stress, ultimate tensile strength, and elongation to failure of the aged microstructures. Using this approach, our surrogate model can predict precipitation behavior within 0.25% volume fraction and mechanical properties within 6% relative error from the values predicted by the KMC and FEM models using 50 training simulations as input. The trained recurrent neural network-based model can return estimations of precipitation kinetics and mechanical properties ~1000 times faster than the physics-based codes. This work demonstrates, as a proof of concept, that reactor material service lifetimes under variable service conditions can be predicted for a statistics-based model from a practicably obtainable dataset.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Dynamic Data-Driven Multiscale Modeling for Predicting Microstructure and Mechanical Properties of 316L Stainless Steel

We have developed a long short-term memory stacked ensemble (LSTM-SE) surrogate modeling approach that can provide rapid predictions of microstructural evolution and the resultant mechanical properties of American Iron and Steel Institute (AISI) 316L series stainless steel (316LSS) fuel cladding under conditions of varying temperature and radiation dose rate. To acquire training data, we developed and implemented a kinetic Monte Carlo (KMC) model to simulate precipitation kinetics of M 23 C 6 , γ', and G phases within SS316L cladding. Experimentally reported precipitation kinetics of SS316L in literature were linked to the kinetic parameters of the simulated precipitation in our KMC model. The model was then used to simulate microstructure evolution under synthetically generated treatments of varying temperature and radiation dose rate, for periods of up to 3000 hours. Changes in volume fraction, number density, and particle size of precipitates were recorded, and particle area fractions were correlated using statistical methods to develop the surrogate model. Simultaneously, the mechanical properties of the simulated microstructures were evaluated using microstructure-based finite element method (FEM) analysis to determine the elastic modulus, yield stress, ultimate tensile strength, and elongation to failure of the aged microstructures. Using this approach, our surrogate model can predict precipitation behavior within 0.25% volume fraction and mechanical properties within 6% relative error from the values predicted by the KMC and FEM models using 50 training simulations as input. The trained recurrent neural network-based model can return estimations of precipitation kinetics and mechanical properties ~1000 times faster than the physics-based codes. This work demonstrates, as a proof of concept, that reactor material service lifetimes under variable service conditions can be predicted for a statistics-based model from a practicably obtainable dataset.

36 MATERIALS SCIENCE↗
NASA NTRS2018

Sustaining PICA TPS for Future NASA Robotic Science Missions

Phenolic Impregnated Carbon Ablator (PICA), invented in the mid 1990's, is a low-density ablative thermal protection material proven capable of meeting sample return mission needs from the moon, asteroids, comets and other "unrestricted class V destinations" as well as for Mars. Its low density and efficient performance characteristics have proven effective for use from Discovery to Flagship class missions. It is important that NASA maintain this TPS material capability and ensure its availability for future NASA use. The rayon based carbon precursor raw material used in PICA preform manufacturing required replacement and requalification at least twice in the past 25 years and a third substitution is now needed. The carbon precursor replacement challenge is twofold – the first involves finding a long-term replacement for the current rayon and the second is to assess its future availability periodically to ensure it is sustainable and be alerted if additional replacement efforts need to be initiated. Rayon is no longer a viable process in the US and Europe due to environmental concerns. In the early 80's rayon producers began investigating a new method of producing a cellulosic fiber through a more environmentally responsible process. This cellulosic fiber, lyocell, is a viable replacement precursor for PICA fiberform. This presentation reviews current SMD-PSD funded PICA sustainability activities in ensuring a rayon replacement for the long term is identified and in establishing that the capability of the new PICA derived from an alternative precursor is in family with previous versions of the so called "heritage" PICA.State of the Art Low Density Carbon Phenolic AblatorsStardust SRC post flight withPICA forebody heat shield(0.8m max. diameter)PICA Processing StepsRole of Rayon/Lyocellin PICA.

Stackpoole, Mairead↗
DOE OSTI2013

THE IMPACT OF BOUND STELLAR ORBITS AND GENERAL RELATIVITY ON THE TEMPORAL BEHAVIOR OF TIDAL DISRUPTION FLARES

We have carried out general relativistic particle simulations of stars tidally disrupted by massive black holes. When a star is disrupted in a bound orbit with moderate eccentricity instead of a parabolic orbit, the temporal behavior of the resulting stellar debris changes qualitatively. The debris is initially all bound, returning to pericenter in a short time about the original stellar orbital timescale. The resulting fallback rate can thus be much higher than the Eddington rate. Furthermore, if the star is disrupted close to the hole, in a regime where general relativity is important, the stellar and debris orbits display general relativistic precession. Apsidal precession can make the debris stream cross itself after several orbits, likely leading to fast debris energy dissipation. If the star is disrupted in an inclined orbit around a spinning hole, nodal precession reduces the probability of self-intersection, and circularization may take many dynamical timescales, delaying the onset of flare activity. An examination of the particle dynamics suggests that quasi-periodic flares with short durations, produced when the center of the tidal stream passes pericenter, may occur in the early-time light curve. The late-time light curve may still show power-law behavior which is generic to disk accretion processes. The detection triggers for future surveys should be extended to capture such 'non-standard' short-term flaring activity before the event enters the asymptotic decay phase, as this activity is likely to be more sensitive to physical parameters such as the black hole spin.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2026

Gear Test Assembly - Experimental Testing and Analysis of Gears and Bearings - FY2026

The Gear Test Assembly (GTA) is an experimental test apparatus built and installed in the Mechanisms and Engineering Test Loop (METL) at Argonne National Laboratory (ANL). While designed to accommodate a variety of components intended for use in advanced compact in-vessel transfer machine, the focus of GTA been the testing of large radial spur gears. The performance of the components used in GTA motivates the choices made in the design, components, and material choices for the forthcoming METL test articles; the Gripper Test Assembly (GrTA), and the Bearing Test Assembly (BTA). To date, GTA has completed nine experimental testing campaigns and achieved over 21 million revolutions under prototypic sodium fast reactor loads and operating conditions. This report provides an overview and results for the two most recent experiments Campaign #8 and Campaign #9. `Campaign #8 was the first campaign to make use of a set of nickel alloy radial spur gears, made from Hastelloy C-22HS, and combined with heat-treated tapered roller bearings. The bearings and torque profile used allowed Campaign #8 to be directly compared with Campaign #1 where Inconel 718 gears were used instead. Campaign #8 attained 1,058,880 shaft revolutions within 23% of the 1,314,855 revolutions achieved in Campaign #1. These results demonstrate that the heat-treated tapered roller bearings show consistent increased lifetimes, approximately three times longer than for non heat-treated taper rollers, and that the particular material of the gear does not play a substantial role in performance. Similar to Campaign #7 where bearing failure resulted in fragmentation and transport of bearing material into the gear teeth led to tooth damage in the Inconel gears, a similar process led to the damage of the Hastelloy gears. Subsequent NDE analysis showed that the damage was only limited to the tooth surface and does not extend into the gear interiors. Based on the NDE reports, the Hastelloy gears can be reconditioned and put back into service for future campaigns as was done for the Inconel gears. Reconditioned Inconel 718 gears damaged in Campaign #7 were returned to service in Campaign #9 and paired with non heat-treated tapered roller bearings. In Campaign #9 a novel set of operating conditions were implemented whereby the gears and bearings were cycled between hot, submerged refueling conditions where fuel handling operations occurred and cold, dry, and inert conditions where the sodium was drained and the vessel was allowed to cool simulating long, ex-vessel storage of the fuel handling machine. A total of eight of these operating cycles were achieved before a bearing failure occurred after the accumulation of 475,692 shaft revolutions were achieved. During Campaign #9, one of the drive motors was damaged and over the course of a 240 day standby period, the entire GTA drive system was upgraded from a 480VAC system to a 240VAC system that provided the opportunity to consolidate wall-space in the METL facility and provide more space for additional test articles being installed in the coming year. The over 475,000 shaft revolutions achieved in Campaign #9 eclipses the previous record for lifetime of non heat-treated tapered roller bearings held by Campaign #3 of 392,000 shaft revolutions. Further analysis and future campaigns hope to shed light on the cause of this approximately 17% increase in lifetime.

42 ENGINEERING↗
NASA NTRS2011

The Space Review

Human space flight in the US and other space-faring countries is faced with a twin challenge that is likely to persist for many years: flat or declining budgets along with an expectation of continuing, significant achievements. A partial solution may involve increased participation by multiple commercial competitors with the promise - albeit yet to be fully demonstrated - of much-reduced costs. That said, most commercial goals are concentrated on low-Earth orbit (LEO) for the time being, leaving human trips beyond Earth orbit (BED) as governmental initiatives. The past decade, beginning with the 1999/2000 Decadal Planning Team (DPT)/NASA Exploration Team (NExT) human space flight studies for the White House Office of Management and Budget (http://history.nasa.gov/DPT/DPT.htm), can arguably be described as a Golden Age of engineering design, strategic planning, technology capability prioritization, and development programs on the International Space Station (ISS). However, cynics have criticized the same period as little more than PowerPoint presentations, and unfocused technology investments with only limited progress toward a goal of human space flight beyond the immediate vicinity of the Earth. We disagree with the cynics. Experience with the ISS on increasingly sophisticated capabilities have prepared international partners to deploy a major "stepping stone" for human space flight: a habitation system in free space beyond low-Earth orbit. Such an achievement would be a major milestone in human space flight and, very likely, an essential demonstration site for subsequent, very ambitious exploration missions such as to Mars. Developing critical capabilities for human voyages beyond LEO, such as Earth-Moon libration points, offers, as just one example, easy return to Earth within days (see, e.g., Farquhar 1971 (Aeronautics & Astronautics, July, p. 59ff), Thronson, Lester, and Talay 2011 (http://www.thespacereview.com/article/1756/1), and Lester 2012 (http://www.thespacereview.com/article/1650/1). Use of Earth-Moon libration points as sites for early demonstrations of capabilities necessary for human missions to Mars, for example, contrasts sharply with using missions to near-Earth asteroids (NEAs) for that purpose.

Thronson, Harley↗
DOE OSTI2025

Better Climate Challenge Working Groups Non-Energy Benefits of Energy Projects-Improving Financial Payback

Energy efficiency is a key strategy recently identified by the United States Department of Energy as a pillar of industrial decarbonization. For manufacturing companies, improving energy efficiency will reduce money spent on energy utilities such as gas, electricity, and oil. Energy improvement projects also provide valuable benefits outside of simple operating cost reductions, such as reducing the carbon footprint, improving safety metrics and even enhancing quality and productivity. Unfortunately, energy efficiency projects have typically faced an adoption gap, even when they meet criteria such as payback period for capital projects. The inclusion and quantification of non-energy benefits (NEBs), also known as co-benefits, in the decision-making process for energy efficiency projects can improve the overall financial payback periods for those projects as well as potentially improve the company's key performance metrics aligned with business strategies. There are no readily available tools that facilitate this, however, and the most used tools for energy audits address NEBs in a perfunctory way if at all. We integrated research for finding and quantifying non-energy benefits of energy efficiency projects into a commonly recognized continuous improvement practice, the Define, Measure, Analyze, Improve and Control (DMAIC) Process. This process, along with software and supplemental materials, guides energy assessments to find and to quantify NEBs associated with energy conservation opportunities. Our aim is to deliver an easy to use and effective process and software tool and to maximize return on investment for energy efficiency projects as well as contribute to companies' strategic performance goals.

DMAIC↗
DOE OSTI2015

Web tools concerning performance analysis and planning support for solar energy plants starting from remotely sensed optical images

We present innovative web tools, developed also in the frame of the FP7 ENDORSE (ENergy DOwnstReam SErvices) project, for the performance analysis and the support in planning of solar energy plants (PV, CSP, CPV). These services are based on the combination between the detailed physical model of each part of the plants and the near real-time satellite remote sensing of incident solar irradiance. Starting from the solar Global Horizontal Irradiance (GHI) data provided by the Monitoring Atmospheric Composition and Climate (GMES-MACC) Core Service and based on the elaboration of Meteosat Second Generation (MSG) satellite optical imagery, the Global Tilted Irradiance (GTI) or the Beam Normal Irradiance (BNI) incident on plant's solar PV panels (or solar receivers for CSP or CPV) is calculated. Combining these parameters with the model of the solar power plant, using also air temperature values, we can assess in near-real-time the daily evolution of the alternate current (AC) power produced by the plant. We are therefore able to compare this satellite-based AC power yield with the actually measured one and, consequently, to readily detect any possible malfunctions and to evaluate the performances of the plant (so-called “Controller” service). Besides, the same method can be applied to satellite-based averaged environmental data (solar irradiance and air temperature) in order to provide a Return on Investment analysis in support to the planning of new solar energy plants (so-called “Planner” service). This method has been successfully applied to three test solar plants (in North, Centre and South Italy respectively) and it has been validated by comparing satellite-based and in-situ measured hourly AC power data for several months in 2013 and 2014. The results show a good accuracy: the overall Normalized Bias (NB) is − 0.41%, the overall Normalized Mean Absolute Error (NMAE) is 4.90%, the Normalized Root Mean Square Error (NRMSE) is 7.66% and the overall Correlation Coefficient (CC) is 0.9538. The maximum value of the Normalized Absolute Error (NAE) is about 30% and occurs for time periods with highly variable meteorological conditions. - Highlights: • We developed an online service (Controller) dedicated to solar energy plants real-time monitoring • We developed an online service (Planner) that supports the planning of new solar energy plants • The services are based on the elaboration of satellite optical imagery in near real-time • The validation with respect to in-situ measured hourly AC power data for three test solar plants shows good accuracy • The maximum value of the Normalized Absolute Error is about 30% and occurs for highly variable meteorological conditions.

14 SOLAR ENERGY↗
DOE OSTI2021

Climate and atmospheric deposition drive the inter-annual variability and long-term trend of dissolved organic carbon flux in the conterminous United States

The lateral flux of dissolved organic carbon (DOC) from soils to inland waters and ultimately to the ocean represents a fundamental component of the global carbon cycle. To estimate the DOC flux, we developed an empirical terrestrial-aquatic DOC fluxes model (TAF-DOC). TAF-DOC incorporates various environmental factors (e.g., meteorology, sulfur, and nitrogen deposition) that to-date have not been comprehensively considered or well-represented in existing modeling frameworks. TAF-DOC was applied to estimate spatial-temporal patterns of DOC flux and potential fates across the conterminous United States during the 1985 to 2018 time period. Our results suggest that TAF-DOC successfully characterized spatial-temporal of DOC flux. As expected, the interannual pattern of DOC flux was strongly regulated by precipitation, but the long-term trend was significantly influenced by the rate of atmospheric wet sulfur deposition. From 1985 to 2018, TAF-DOC estimated DOC loading from terrestrial to aquatic ecosystems in the conterminous United States to be 33.5 ± 2.2 TgC per year, which was roughly 0.39–0.49% of total soil organic carbon stock estimates. The dominant fate of terrestrially-derived DOC was delivery to the coastal ocean in riverine export (41%), with another 21% buried in sediment and the remaining 12.8 ± 0.4 TgC per year (38%) returned to the atmosphere through outgassing from inland waters. Finally, assuming the quantities of DOC sediment burial and export to the ocean as an annual sink of terrestrially-derived carbon, budget inventories and models that do not account for DOC flux in the conterminous United States will underestimate the net annual carbon sink by as much as 5.5–6.4%.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

Solvent hold tank sample results for MCU-16-53-55. January 2016 Monthly sample

Savannah River National Laboratory (SRNL) received one set of Solvent Hold Tank (SHT) samples (MCU-16-53-54-55), pulled on 01/25/2016 for analysis. The samples were combined and analyzed for composition. Analysis of the composite sample MCU-16-53-54-55 indicated the Isopar™L, and MaxCalix are at nominal levels. The modifier and TiDG concentrations are 3% and 23 % below their nominal concentrations. This analysis confirms the addition of TiDG, MaxCalix, and modifier to the solvent on November 28, 2015. Based on the current monthly sample, the levels of TiDG, Isopar™L, MaxCalix, and modifier are sufficient for continuing operation but are expected to decrease with time. Periodic characterization and trimming additions to the solvent are recommended. No impurities above the 1000 ppm level were found in this solvent by the Semi-Volatile Organic Analysis (SVOA). No impurities were observed in the Hydrogen Nuclear Magnetic Resonance (HNMR). However, the Fourier transform infra-red spectroscopy (FTIR) method detected trace levels (a few ppm) of amides (a possible degradation product of TiDG). In addition, up to 21 ± 4 micrograms of mercury per gram of solvent (or 17.5 μg/mL) was detected in this sample. There appears to be a possible correlation between the mercury level and the TiDG concentration in the solvent. The current gamma level (9.16 E4 dpm/mL) confirmed that the gamma concentration has returned to previous level where the process operated normally and as expected. The laboratory will continue to monitor the quality of the solvent in particular for any new impurities or degradation of the solvent components.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS2009

Origin and Evolution of Organic Matter Preserved in Stardust Cometary Aerogel Tracks

The STARDUST spacecraft captured dust samples from Comet 81P/Wild 2 at a relative velocity of 6.1 km/s in a low density silica aerogel and returned them to the Earth. One of the main of the scientific goals established for the mission was to determine whether comets contained complex organic materials and, contingently, the nature and abundance of this material. [1] Although contamination concerns due to carbonaceous impurities intrinsic to the flight aerogel remain, it is generally accepted that at least a fraction of the captured dust particles contain an indigenous organic component. [2] However, understanding the nature and abundance of this material is complicated by nature of the collection process. The rapid dissipation of particle s kinetic energy during its impact and deceleration cause both the particle and surrounding aerogel to experience an intense thermal pulse of upwards of 2000K for a period up to several hundred nanoseconds [3]. During this period thermal alteration and or destruction of organic species present in the impacting particle are likely to occur. We have used the technique of ultrafast two-step laser mass spectrometry (ultra L2MS) [4] to investigate how the nature and distribution of aromatic and conjugated organic species varies between and within aerogel cometary tracks and their associated terminal particles.

McKay, D.S.↗
DOE OSTI2025

Intrabasin Comparison of the Microbiology and Geochemistry of Produced Fluid From Hydraulically Fractured Wells in the Permian Region

The Permian Basin is the highest producing oil reservoir in the United States. Hydrocarbon extraction methods in this region are often associated with frac hits, or interwell communication events where an established well is affected by the pumping of fracture fluid into a new well. Our previous work revealed a geochemical signal indicating the presence of frac hits in the Permian Basin. We returned to this area with the goal of expanding our understanding of subsurface interactions common in this region. To do so, we collected produced water from 25 unique sites across the Permian Basin, 10 of which had previously been characterized during an active frac hit. For each sample, we measured the pH, alkalinity, geochemistry, microbial load, and microbial community composition. Permian Basin produced water is characterized by higher sulfate and lower total dissolved solids (TDS) concentrations compared to other regions. Interestingly, wells impacted by frac hits have a geochemical profile that resembles that of fracture fluid, with both lowered sulfate and lowered TDS concentrations compared to unaffected wells. Due to the year-long recovery window between sample collection periods, we anticipate that all our data will be characterized by the typical high sulfate, low TDS concentrations.

geochemistry↗
NASA NTRS2001

Advanced Thin Ionization Calorimeter (ATIC) Balloon Experiment

During grant NAG5-5064, Louisiana State University (LSU) led the ATIC team in the development, construction, testing, accelerator validation, pre-deployment integration and flight operations of the Advanced Thin Ionization Calorimeter (ATIC) Balloon Experiment. This involved interfacing among the ATIC collaborators (UMD, NRL/MSFC, SU, MSU, WI, SNU) to develop a new balloon payload based upon a fully active calorimeter, a carbon target, a scintillator strip hodoscope and a pixilated silicon solid state detector for a detailed investigation of the very high energy cosmic rays to energies beyond 10(exp 14) eV/nucleus. It is in this very high energy region that theory predicts changes in composition and energy spectra related to the Supernova Remnant Acceleration model for cosmic rays below the "knee" in the all-particle spectrum. This report provides a documentation list, details the anticipated ATIC science return, describes the particle detection principles on which the experiment is based, summarizes the simulation results for the system, describes the validation work at the CERN SPS accelerator and details the balloon flight configuration. The ATIC experiment had a very successful LDB flight from McMurdo, Antarctica in 12/00 - 1/01. The instrument performed well for the entire 15 days. Preliminary data analysis shows acceptable charge resolution and an all-particle power law energy deposition distribution not inconsistent with previous measurements. Detailed analysis is underway and will result in new data on the cosmic ray charge and energy spectra in the GeV - TeV energy range. ATIC is currently being refurbished in anticipation of another LDB flight in the 2002-03 period.

Wefel, John P.↗
NASA NTRS2015

Halite as a Methane Sequestration Host: A Possible Explanation for Periodic Methane Release on Mars, and a Surface-accessible Source of Ancient Martian Carbon

We present the hypothesis that halite may play a role in methane sequestration on the martian surface. In terrestrial examples, halite deposits sequester large volumes of methane and chloromethane. Also, examples of chloromethane-bearing, approximately 4.5 Ga old halite from the Monahans meteorite show that this system is very stable unless the halite is damaged. On Mars, methane may be generated from carbonaceous material trapped in ancient halite deposits and sequestered. The methane may be released by damaging its halite host; either by aqueous alteration, aeolian abrasion, heating, or impact shock. Such a scenario may help to explain the appearance of short-lived releases of methane on the martian surface. The methane may be of either biogenic or abiogenic origin. If this scenario plays a significant role on Mars, then martian halite deposits may contain samples of organic compounds dating to the ancient desiccation of the planet, accessible at the surface for future sample return missions.

Fries, M. D.↗