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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,243 records · Page 69
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Synthesis of Actinide Materials for the Study of Basic Actinide Science and Rapid Separation of Fission Products

This dissertation covers several distinct projects relating to the fields of nuclear forensics and basic actinide science. Post-detonation nuclear forensics, in particular, the study of fission products resulting from a nuclear device to determine device attributes and information, often depends on the comparison of fission products to a library of known ratios. The expansion of this library is imperative as technology advances. Rapid separation of fission products from a target material, without the need to dissolve the target, is an important technique to develop to improve the library and provide a means to develop samples and standards for testing separations. Several materials were studied as a proof-of-concept that fission products can be extracted from a solid target, including microparticulate (< 10 μm diameter) dUO 2 , porous metal organic frameworks (MOFs) synthesized from depleted uranium (dU), and other organicbased frameworks containing dU. The targets were irradiated with fast neutrons from one of two different neutron sources, contacted with dilute acids to facilitate the separation of fission products, and analyzed via gamma spectroscopy for separation yields. The results indicate that smaller particle sizes of dUO 2 in contact with the secondary matrix KBr yield higher separation yields than particles without a secondary matrix. It was also discovered that using 0.1 M HNO 3 as a contact acid leads to the dissolution of the target material. Lower concentrations of acid were used for future experiments. In the case of the MOFs, a larger pore size in the framework leads to higher separation yields when contacted with 0.01 M HNO 3 . Different types of frameworks also yield different results.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Enabling Ultralow Volume Analysis with a High-Resolution Ion Mobility Mass Spectrometry Platform

Of all the molecules thought to exist in the universe, it is estimated that researchers only know the chemical structures of 5% of them. Identifying the chemical structures of the remaining 95% has proven extremely challenging because many molecules exhibit low abundance, are contained in small volumes (e.g., <10 nL), do not readily ionize, exhibit similar structures to other molecules, etc. No single analytical technique exists to definitively identify the structure of an unknown molecule, and thus multiple different molecular measurements are typically made (i.e., multi-modal approach). Ion mobility (IMS) and mass spectrometry (MS) are two key tools that researchers use to determine the chemical structures of unknown molecules, and recently high-resolution and ultrahigh resolution IMS-MS instruments have provided greater confidence than ever before. However, HR-IMS-MS instruments typically exhibit low ion utilization efficiency, meaning they require large amounts of sample for an analysis (e.g., >10 µL). Unfortunately, this limitation prohibits the analysis of small volume samples where many unknown molecules exist. Described herein are the efforts made to enable the analysis of ultralow volumes with an HR-IMS-MS platform. A new scanning technique, termed a ‘stuttered traveling wave scan’, was developed as a replacement for the dual-gated scanning technique and works by halting the traveling waves after allowing ions to separate and then repeatedly restarting and stopping the traveling waves to incrementally move ions from the SLIM to the Orbitrap. Ions were stored inside the SLIM while the TWs were stopped, allowing the Orbitrap to perform high-resolution mass analysis. When the Orbitrap was ready, the TWs were restarted for short periods of time (<10 ms) to move ions from the SLIM to the Orbitrap. It was discovered that lower TW amplitudes and speeds than used during IMS separation were required to produce IMS peaks with the highest signal intensities and best resolving powers. The stuttered TW scan was found to produce similar resolutions and signal intensities compared to the dual-gated scanning technique. A new IMS design possessing an intersecting ‘tee’ with a reversible traveling wave was also developed to improve ion utilization efficiency during cyclic operation, which is necessary when only a single IMS spectrum can be acquired, such as when analyzing ultralow volume samples. The new capabilities described in this report lay the groundwork for acquiring HR-IMS-MS spectra of ultralow volume biological samples, such as single cells, where HR-IMS-MS can help elucidate the structures of unknown compounds.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Preliminary Assessment of Alternate Chlorination Process

Recent advancements towards low-temperature chlorination with disulfur dichloride and thionyl chloride of Al-clad used nuclear fuel (UNF) have been summarized for work control technical expertise development at the Savannah River National Laboratory (SRNL). This technique aims to provide a more effective method for separating U from cladding or alloying elements. A preliminary assessment determined needs for unit operation developments in regard to reaction kinetics and reagent quality. Furthermore, an analysis of an Uruguay fuel plate (U-Al x fuel meat), with low-enriched uranium (LEU) and located at SRNL, was a potential candidate for future experiments with lightly irradiated (0.08% burnup) fuel to test for chlorination. Future proposed work would involve kinetic studies, reagent quality assessments, and the machining of the fuel plate down to an appropriate bench-scale size and testing the effectiveness of low-temperature chlorination on the fuel plate.

Chlorination↗
DOE OSTI2023

Optimized purification methods for metallic contaminant removal from directly recycled Li-ion battery cathodes

Metallic contaminants pose a significant challenge to the viability of directly recycling Li-ion batteries. To date, few strategies exist to selectively remove metallic impurities from mixtures of shredded end-of-life material (black mass; BM) without concurrently damaging the structure and electrochemical performance of the target active material. We herein present tailored methods to selectively ionize two major contaminants—Al and Cu—while retaining a representative cathode (LiNi 0.33 Mn 0.33 Co 0.33 O 2 ; NMC-111) intact. This BM purification process is conducted at moderate temperatures in a KOH-based solution matrix. We rationally evaluate approaches to increase both the kinetic corrosion rate and the thermodynamic solubility of Al 0 and Cu 0 , and evaluate the impact of these treatment conditions on the structure, chemistry, and electrochemical performance of NMC. Specifically, we explore the impacts of chloride-based salts, a strong chelating agent, elevated temperature, and sonication on the rate and extent of contaminant corrosion, while concurrently evaluating the effects on NMC. The reported BM purification process is then demonstrated on samples of “simulated BM” containing a practically relevant 1 wt% concentration of Al or Cu. Increasing the kinetic energy of the purifying solution matrix through elevated temperature and sonication accelerates the corrosion of metallic Al and Cu, such that ∼100% corrosion of 75 μm Al and Cu particles is achieved within 2.5 hr. Further, we determine that effective mass transport of ionized species critically impacts the efficacy of Cu corrosion, and that saturated Cl – hinders rather than accelerates Cu corrosion by increasing solution viscosity and introducing competitive pathways for Cu surface passivation. The purification conditions do not induce bulk structural damage to NMC, and electrochemical capacity is maintained in half-cell format. Testing in full cells suggests that a limited quantity of residual surface species are present after treatment, which initially disrupt electrochemical behavior at the graphite anode but are subsequently consumed. Process demonstration on simulated BM suggests that contaminated samples—which prior to treatment show catastrophic electrochemical performance—can be recovered to pristine electrochemical capacity. The reported BM purification method offers a compelling and commercially viable solution to address contamination, particularly in the “fine” fraction of BM where contaminant sizes are on the same order of magnitude as NMC and where traditional separation approaches are unfeasible. Thus, this optimized BM purification technique offers a pathway towards viable direct recycling of BM feedstocks that would otherwise be unusable.

25 ENERGY STORAGE↗
NASA NTRS1970

Classifying forest and nonforest land on space photographs

Although the research reported is in its preliminary stages, results show that: (1) infrared color film is the best single multiband sensor available; (2) there is a good possibility that forest can be separated from all nonforest land uses by microimage evaluation techniques on IR color film coupled with B/W infrared and panchromatic films; and (3) discrimination of forest and nonforest classes is possible by either of two methods: interpreters with appropriate viewing and mapping instruments, or programmable automatic scanning microdensitometers and automatic data processing.

Aldrich, R. C.↗
NASA NTRS1973

Investigation of the environmental change pattern of Japan

The author has identified the following significant results. ERTS-1 imagery clearly identifies the relationships between the status of erosion, effluent patterns affected by the coastal current, and the cultural construction activities. Simple photographic techniques can be used for detecting water mass distribution separately from cloud cover and also noise caused by reflected sunlight from wave surfaces. Polluted water does not diffuse continuously into the oceanic water, but forms masses in the water in the Kuroshio area. The polluted or turbid water in the area just north of the Tomogashima Channel, the south outlet of the Osaka Bay, shows that the northward tidal current runs in a clockwise eddy at the tidal period when the imagery was taken. Such an eddy-like pattern of tidal current had never been revealed by conventional oceanographic data. A front between an oceanic water mass and a polluted water mass runs in a NW-SE direction in the central part of the Osaka Bay. The patterns of turbid water discharged from the Kii River and Yoshino River show a northward tidal current in the North Kii Straits. The pattern of lighter turbid or polluted water located in the northwest region of the North Kii straits suggests the existence of a clockwise eddy in the straits.

Maruyasu, T.↗
NASA NTRS1977

Concatenated algebraic decoder

Technique for manipulating digital data consists of mating two separate coding/decoding methods to produce hybrid inner-code/outer-code system. Interactive digital circuitry is used to manipulate casually related digital data.

Source record↗
NASA NTRS1982

Nonlinear zero-sum differential game analysis by singular perturbation methods

A class of nonlinear, zero-sum differential games, exhibiting time-scale separation properties, can be analyzed by singular-perturbation techniques. The merits of such an analysis, leading to an approximate game solution, as well as the 'well-posedness' of the formulation, are discussed. This approach is shown to be attractive for investigating pursuit-evasion problems; the original multidimensional differential game is decomposed to a 'simple pursuit' (free-stream) game and two independent (boundary-layer) optimal-control problems. Using multiple time-scale boundary-layer models results in a pair of uniformly valid zero-order composite feedback strategies. The dependence of suboptimal strategies on relative geometry and own-state measurements is demonstrated by a three dimensional, constant-speed example. For game analysis with realistic vehicle dynamics, the technique of forced singular perturbations and a variable modeling approach is proposed. Accuracy of the analysis is evaluated by comparison with the numerical solution of a time-optimal, variable-speed 'game of two cars' in the horizontal plane.

Sinar, J.↗
NASA NTRS1982

Neutron star envelopes

It is pointed out that the separate study of neutron star envelopes is a valuable technique for gaining insights into neutron star cooling calculations. It is shown that, to an excellent approximation, the temperature at the inner boundary of the envelope, T sub b, is a function only of T sub s to the 4th power over g sub s, where T sub s is the effective temperature and g sub s is the surface gravity. This result makes it possible to investigate very simply the effects of general relativity and of opacity changes on the T sub b - T sub s relation and to compare calculations by different workers, even though they use different neutron star models. It is also shown that the most important opacity source for obtaining a reliable T sub b - T sub s relation is the conductive opacity of matter when the ions are liquid. Calculations are presented in which particular attention is given to this region and the best available opacities are used.

Gudmundsson, E. H.↗
NASA NTRS1981

Geomagnetic modeling by optimal recursive filtering

The results of a preliminary study to determine the feasibility of using Kalman filter techniques for geomagnetic field modeling are given. Specifically, five separate field models were computed using observatory annual means, satellite, survey and airborne data for the years 1950 to 1976. Each of the individual field models used approximately five years of data. These five models were combined using a recursive information filter (a Kalman filter written in terms of information matrices rather than covariance matrices.) The resulting estimate of the geomagnetic field and its secular variation was propogated four years past the data to the time of the MAGSAT data. The accuracy with which this field model matched the MAGSAT data was evaluated by comparisons with predictions from other pre-MAGSAT field models. The field estimate obtained by recursive estimation was found to be superior to all other models.

Gibbs, B. P.↗
NASA NTRS1983

Effect of hydration on nitrogen washout in human subjects

Five subjects were tested to assess the influence of drinking hypotonic water (distilled water) on whole body tissue nitrogen washout. During the test, the subjects breathed aviators' oxygen for three hours. Each subject performed two baseline nitrogen washouts in a two-week period. The third washout, in the third week, was done under a transient hydrated condition. This was accomplished by having the subjects drink 1.5 liters of hypotonic water 30 minutes before the washout. Five-minute plots of tissue nitrogen removal from the three separate washouts were analyzed to ascertain if the hydration technique had any effect. Our results clearly indicate that the hydration technique did not alter the tissue nitrogen washout characteristics to any degree over three hours. An increase in tissue nitrogen washout under a transient hydrated condition using hypotonic fluid was not demonstrated to be the mechanism responsible for the reported benefit of this technique in preventing Type I altitude decompression pain in man.

Waligora, J.↗
NASA NTRS1983

Acoustic loading in planar networks

The acoustic loading in a complex planar network of ducts is determined by a method in which Green function surface elements are used. The network consists of straight ducts, elbows and branched ducts. A transfer matrix technique is developed in which each duct is treated separately and the matrix of the influence coefficients is transformed to tri-diagonal form allowing efficient inversion.

El-Raheb, M.↗
NASA NTRS1987

Analysis of the all-specular Linlor baffle design

This paper presents the results of a full three-dimensional analysis of a new type of reflecting baffle vane cavity. The analysis is divided into two separate parts. The first employs advanced geometrical ray tracing techniques to analyze the specular reflecting properties of the cavities. The second part uses deterministic radiation transfer methods to analyze the diffuse scattering properties of the reflecting cavities relative to absorbing ones. In both cases, an operating wavelength of 10.6 microns is initially used. These results are then used to estimate the performance at 2.0 microns.

Greynolds, Alan W.↗
NASA NTRS1988

Fiber-optic displacement sensor with temporally separated signal and reference channels

A fiber-optic displacement sensor with temporally separated signal and reference channels is proposed. The sensing technique used is based on determining the relative amplitude of the signal and reference pulses that together form a double pulse. The relative amplitude of the pulses in the double pulse is a function of the displacement. A setup to generate the double pulse with individual pulses of 5-ns duration and 10-ns delay is described. A novel signal processing technique, used to determine the relative amplitude of such pulses in the double pulse by analyzing different portions of the signal spectrum, is explained. Experimental data are also provided.

Adamovsky, Grigory↗
NASA NTRS1990

Non-linear dynamic analysis of geared systems

Under driving conditions, a typical geared system may be subjected to large dynamic loads. Also, the vibration level of the geared system is directly related to the noise radiated from the gear box. The steady state dynamic behavior of the system is examined in order to design reliable and quiet transmissions. The scope is limited to a system containing a spur gear pair with backlash and periodically time varying mesh stiffness, and rolling element bearings with clearance type nonlinearities. The internal static transmission error at the gear mesh, which is of importance from high frequency noise and vibration control view point, is considered in the formulation in sinusoidal or periodic form. A dynamic finite element model of the linear time invariant (LTI) system is developed. Effects of several system parameters, such as torsional and transverse flexibilities of the shafts and prime mover/load inertias, on free and forced vibration characteristics are investigated. Several reduced order LTI models are developed and validated by comparing their eigen solutions with the finite element model results. Using the reduced order formulations, a three degree of freedom dynamic model is developed which includes nonlinearities associated with radical clearances in the radial rolling element bearings, backlash between a spur gear pair and periodically varying gear mesh stiffness. As a limiting case, a single degree of freedom model of the spur gear pair with backlash is considered and mathematical conditions for tooth separation and back collision are defined. Both digital simulation technique and analytical models such as method of harmonic balance and the method of multiple scales were used to develop the steady state frequency response characteristics for various nonlinear and/or time varying cases.

Singh, Rajendra↗
NASA NTRS1989

The University of Arizona program in solid propellants

The University of Arizona program is aimed at introducing scientific rigor to the predictability and quality assurance of composite solid propellants. Two separate approaches are followed: to use the modern analytical techniques to experimentally study carefully controlled propellant batches to discern trends in mixing, casting, and cure; and to examine a vast bank of data, that has fairly detailed information on the ingredients, processing, and rocket firing results. The experimental and analytical work is described briefly. The principle findings were that: (1) pre- (dry) blending of the coarse and fine ammonium perchlorate can significantly improve the uniformity of mixing; (2) the Fourier transformed IR spectra of the uncured and cured polymer have valuable data on the state of the fuel; (3) there are considerable non-uniformities in the propellant slurry composition near the solid surfaces (blades, walls) compared to the bulk slurry; and (4) in situ measurements of slurry viscosity continuously during mixing can give a good indication of the state of the slurry. Several important observations in the study of the data bank are discussed.

Ramohalli, Kumar↗
NASA NTRS1991

Experiments with conjugate gradient algorithms for homotopy curve tracking

There are algorithms for finding zeros or fixed points of nonlinear systems of equations that are globally convergent for almost all starting points, i.e., with probability one. The essence of all such algorithms is the construction of an appropriate homotopy map and then tracking some smooth curve in the zero set of this homotopy map. HOMPACK is a mathematical software package implementing globally convergent homotopy algorithms with three different techniques for tracking a homotopy zero curve, and has separate routines for dense and sparse Jacobian matrices. The HOMPACK algorithms for sparse Jacobian matrices use a preconditioned conjugate gradient algorithm for the computation of the kernel of the homotopy Jacobian matrix, a required linear algebra step for homotopy curve tracking. Here, variants of the conjugate gradient algorithm are implemented in the context of homotopy curve tracking and compared with Craig's preconditioned conjugate gradient method used in HOMPACK. The test problems used include actual large scale, sparse structural mechanics problems.

Irani, Kashmira M.↗
NASA NTRS1991

A computer code for multiphase all-speed transient flows in complex geometries. MAST version 1.0

The operation of the MAST code, which computes transient solutions to the multiphase flow equations applicable to all-speed flows, is described. Two-phase flows are formulated based on the Eulerian-Lagrange scheme in which the continuous phase is described by the Navier-Stokes equation (or Reynolds equations for turbulent flows). Dispersed phase is formulated by a Lagrangian tracking scheme. The numerical solution algorithms utilized for fluid flows is a newly developed pressure-implicit algorithm based on the operator-splitting technique in generalized nonorthogonal coordinates. This operator split allows separate operation on each of the variable fields to handle pressure-velocity coupling. The obtained pressure correction equation has the hyperbolic nature and is effective for Mach numbers ranging from the incompressible limit to supersonic flow regimes. The present code adopts a nonstaggered grid arrangement; thus, the velocity components and other dependent variables are collocated at the same grid. A sequence of benchmark-quality problems, including incompressible, subsonic, transonic, supersonic, gas-droplet two-phase flows, as well as spray-combustion problems, were performed to demonstrate the robustness and accuracy of the present code.

Chen, C. P.↗