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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,243 records · Page 69
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

Effect of laser surface texturing (LST) on tribochemical films dynamics and friction and wear performance

Surface texturing or topographical design is one of the primary techniques to control friction and wear performance of surfaces in tribological contact. Laser surface texturing (LST), whereby a laser beam is used to produce regular arrays of dimples on a surface, has been demonstrated to reduce friction in conformal lubricated contacts. Friction and wear behavior under boundary lubrication is also known to be dependent on the formation and durability of the tribochemical film formed from lubricant additives. In this paper, the effects of LST on the formation and durability of tribochemical films and its consequent impacts on friction and wear behavior in various lubrication regimes were evaluated. Friction and wear tests that cycled through different lubrication regimes were conducted with both polished and LST treated surfaces using a synthetic lubricant with and without model additives of ZDDP and MoDTC mixture. In the base oil without additives, LST produced noticeable reduction in friction in all lubrication regimes. However, with low-friction model additives, friction was higher in tests with LST due to significant differences in the tribochemical film formation in the polished and LST surfaces, as well as the sliding counterface. Continuous tribo-films were formed on ball conterface rubbed against polished surfaces while the films were streaky and discontinuous in ball rubbed against LST surfaces. LST produced more wear on the ball counterface in both base and additized oils. Lastly, no measurable wear was observed in both the polished and LST flat specimens.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Effect of laser surface remelting on the microstructure and properties of Al-Al2Cu-Si ternary eutectic alloy

Bimodal ultrafine eutectic composites (BUECs) exhibit a good combination of strength and plasticity owing to a dual-hierarchy in eutectic length-scales in the microstructure. The present study investigates the variation of phase, morphology, feature length-scales and modality of microstructures obtained in a Al81Cu13Si6 (at. %) ternary alloy after laser surface remelting. A novel approach of varying component bimodal eutectic volume fractions by controlling the cooling rate of the laser solidification process has been presented. The volume fraction of the fine eutectic matrix has a profound effect on the flow strength. Laser remelted microstructures with volume fractions of the fine eutectic varying from 25 to 40% exhibiting compressive flow strengths ranging from 500 to 900MPa have been obtained. The volume fraction of the fine eutectic decreased with cooling rate and completely ceased to exist at cooling rates greater than 4 × 10 °C/s 4 .

36 MATERIALS SCIENCE↗
DOE OSTI2022

Determining the hydronium pKα at platinum surfaces and the effect on pH-dependent hydrogen evolution reaction kinetics

Electrocatalytic hydrogen evolution reaction (HER) is critical for green hydrogen generation and exhibits distinct pH-dependent kinetics that have been elusive to understand. A molecular-level understanding of the electrochemical interfaces is essential for developing more efficient electrochemical processes. Here we exploit an exclusively surface-specific electrical transport spectroscopy (ETS) approach to probe the Pt-surface water protonation status and experimentally determine the surface hydronium pK a = 4.3. Quantum mechanics (QM) and reactive dynamics using a reactive force field (ReaxFF) molecular dynamics (RMD) calculations confirm the enrichment of hydroniums (H 3 O + * ) near Pt surface and predict a surface hydronium pK a of 2.5 to 4.4, corroborating the experimental results. Importantly, the observed Pt-surface hydronium pK a correlates well with the pH-dependent HER kinetics, with the protonated surface state at lower pH favoring fast Tafel kinetics with a Tafel slope of 30 mV per decade and the deprotonated surface state at higher pH following Volmer-step limited kinetics with a much higher Tafel slope of 120 mV per decade, offering a robust and precise interpretation of the pH-dependent HER kinetics. These insights may help design improved electrocatalysts for renewable energy conversion.

Zhong, Guangyan↗
NASA NTRS1965

Surface properties of metals

Effect of surface oxidation on spectral emission of stainless steel and Pt and Inconel surfaces coated with SiO and method for obtaining Al surfaces with periodic distributions of ridges

STAINLESS STEEL↗
NASA NTRS1989

Limex'87 ice surface characteristics and their effect upon C-band SAR sigantures

Ice surface characterization data were recorded during March 1987 in the Labrador Sea marginal ice zone, at the onset of spring melt. Measured data are used as input parameters in a simple scattering model to simulate the effects of temporal variations in material properties upon C-band scattering signatures. Snow moisture and surface roughness have a significant effect upon sigma(0)HH and large differences are predicted between undeformed floe surfaces and deformed or rubbled ice areas. The model reproduces a calibrated synthetic-aperture-radar (SAR)-derived signature obtained during the experiment with a reasonable degree of certainty. Predictions also simulate a trend observed in SAR images of increasing backscatter contrast between deformed and undeformed ice over period of surface warming.

Drinkwater, Mark R.↗
DOE OSTI2023

Remote effects of Tibetan Plateau spring land temperature on global subseasonal to seasonal precipitation prediction and comparison with effects of sea surface temperature: the GEWEX/LS4P Phase I experiment

The prediction skill for precipitation anomalies in late spring and summer months—a significant component of extreme climate events—has remained stubbornly low for years. This paper presents a new idea that utilizes information on boreal spring land surface temperature/subsurface temperature (LST/SUBT) anomalies over the Tibetan Plateau (TP) to improve prediction of subsequent summer droughts/floods over several regions over the world, East Asia and North America in particular. The work was performed in the framework of the GEWEX/LS4P Phase I (LS4P-I) experiment, which focused on whether the TP LST/SUBT provides an additional source for subseasonal-to-seasonal (S2S) predictability. The summer 2003, when there were severe drought/flood over the southern/northern part of the Yangtze River basin, respectively, has been selected as the focus case. With the newly developed LST/SUBT initialization method, the observed surface temperature anomaly over the TP has been partially produced by the LS4P-I model ensemble mean, and 8 hotspot regions in the world were identified where June precipitation is significantly associated with anomalies of May TP land temperature. Consideration of the TP LST/SUBT effect has produced about 25–50% of observed precipitation anomalies in most hotspot regions. The multiple models have shown more consistency in the hotspot regions along the Tibetan Plateau-Rocky Mountain Circumglobal (TRC) wave train. The mechanisms for the LST/SUBT effect on the 2003 drought over the southern part of the Yangtze River Basin are discussed. For comparison, the global SST effect has also been tested and 6 regions with significant SST effects were identified in the 2003 case, explaining about 25–50% of precipitation anomalies over most of these regions. This study suggests that the TP LST/SUBT effect is a first-order source of S2S precipitation predictability, and hence it is comparable to that of the SST effect. With the completion of the LS4P-I, the LS4P-II has been launched and the LS4P-II protocol is briefly presented.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1955

Effect of Surface-active Additives on Physical Properties of Slurries of Vapor-process Magnesium

The presence of 3 to 5 percent surface-active additive gave the lowest Brookfield apparent viscosity, plastic viscosity, and yield value that were obtained for slurry fuels containing approximately 50 percent vapor-process magnesium in JP-1 fuel. The slurries settled little and were easily remixed. A polyoxyethylene dodecyl alcohol was the most effective of 13 additives tested in reducing the Brookfield apparent viscosity and the yield value of the slurry. The seven most effective additives all had a hydroxyl group plus an ester or polyoxethylene group in the molecule. The densities of some of the slurries were measured.

Pinns, Murray L↗
NASA NTRS1983

Nonlinear damage analysis: Postulate and evaluation

The objective of this program is to assess the viability of a damage postulate which asserts that the fatigue resistance curve of a metal is history dependent due to inelastic action. The study focusses on OFE copper because this simple model material accentuates the inelastic action central to the damage postulate. Data relevant to damage evolution and crack initiation are developed via a study of surface topography. The effects of surface layer residual stresses are explored via comparative testing as were the effects in initial prestraining. The results of the study very clearly show the deformation history dependence of the fatigue resistance of OFE copper. Furthermore the concept of deformation history dependence is shown to qualitatively explain the fatigue resistance of all histories considered. Likewise quantitative predictions for block cycle histories are found to accurately track the observed results. In this respect the assertion that damage per cycle for a given level of the damage parameter is deformation history dependent appears to be physically justified.

Leis, B. N.↗
NASA NTRS1982

Different atmospheric effects in remote sensing of uniform and nonuniform surfaces

The atmospheric effect on the radiance of sunlight scattered from the earth-atmosphere system is greatly dependent on the surface reflectance pattern, the contrast between adjacent fields, and the optical properties of the atmosphere. In addition, the atmospheric effect is described by the range and magnitude of the adjacency effects, the atmospheric modulation transfer function, and the apparent spatial resolution of remotely sensed imagery. This paper discusses the atmospheric effect on classification of surface features and shows that surface nonuniformity can be used for developing procedures to remove the atmospheric effect from the satellite imagery.

Kaufman, Y. J.↗
NASA NTRS1980

Ion thruster plume effects on spacecraft surfaces

A charge-exchange plasma, generated by an ion thruster, is capable of flowing upstream from the ion thruster and therefore represents a source of contamination to a spacecraft. An analytical model of the charge-exchange plasma density around a spacecraft is used to estimate the contamination which various spacecraft materials may be exposed to. Measurements of plasma density around an ion thruster are compared to this model. Results of experimental studies regarding the effects on various spacecraft materials' properties due to exposure to expected mercury contamination levels are presented.

Carruth, M. R., Jr.↗
NASA NTRS1981

Ion thruster plume effects on spacecraft surfaces

A charge-exchange plasma, generated by an ion thruster, is capable of flowing upstream from the ion thruster and therefore represents a source of contamination to a spacecraft. An analytical model of the charge-exchange plasma density around a spacecraft was used to estimate the contamination which various spacecraft materials may be exposed to. Measurements of plasma density around an ion thruster were compared to this model. Results of experimental studied regarding the effects on various spacecraft materials' properties due to exposure to expected mercury contamination levels are presented.

Carruth, M. R., Jr.↗
DOE OSTI2017

Surface and bulk effects of K in Cu 1-x K x In 1-y Ga y Se 2 solar cells

Two strategies for enhancing photovoltaic (PV) performance in chalcopyrite solar cells were investigated: Cu 1-x K x In 1-y Ga y Se 2 absorbers with low K content (K/(K+Cu), or x ~ 0.07) distributed throughout the bulk, and CuIn 1-y Ga y Se 2 absorbers with KIn 1-y Ga y Se 2 grown on their surfaces. Distributing K throughout the bulk absorbers improved power conversion efficiency, open-circuit voltage (VOC) and fill factor (FF) for Ga/(Ga+In) of 0, 0.3 and 0.5. Surface KIn 1-y Ga y Se 2 and bulk x ~ 0.07 Cu 1-x K x In 1-y Ga y Se 2 films with Ga/(Ga+In), or y of 0.3 and 0.5 also had improved efficiency, VOC, and FF, relative to CuIn 1-y Ga y Se 2 baselines. On the other hand, y ~ 1 absorbers did not benefit from K introduction. Similar to Cu 1-x K x InSe 2 , the formation of Cu 1-x K x GaSe 2 alloys was favored at low temperatures and high Na supply by the substrate, relative to the formation of mixed-phase CuGaSe 2 + KGaSe 2 . KIn 1-y Ga y Se 2 alloys were grown for the first time, as evidenced by X-ray diffraction and ultraviolet/visible spectroscopy. For all Ga/(Ga+In) compositions, the surface KIn 1-y Ga y Se 2 absorbers had superior PV performance in buffered and buffer-free devices. However, the bulk x ~ 0.07 absorbers only outperformed the baselines in buffered devices. The data demonstrate that KIn 1-y Ga y Se 2 passivates the surface of CuIn 1-y Ga y Se 2 to increase efficiency, VOC, and FF, while bulk Cu 1-x K x In 1-y Ga y Se 2 absorbers with x ~ 0.07 enhance efficiency, VOC, and FF by some other mechanism.

(Cu,K)GaSe2↗
NASA NTRS1986

Effects of cone surface waviness and freestream noise on transition in supersonic flow

A comparison of transition on wavy-wall and smooth-wall cones in a Mach 3.5 wind tunnel is made under conditions of either low freestream noise (quiet flow) or high freestream noise (noisy flow). The noisy flow compares to that found in conventional wind tunnels while the quiet flow gives transitional Reynolds numbers on smooth sharp cones comparable to those found in flight. The waves were found to have a much smaller effect on transition than similar sized trip wires. A satisfatory correlating parameter for the effect of waves on transition was simply the wave height-to-length ratio. A given value of this ratio was found to cause the same percentage change in transition location in quiet and noisy flows.

Morrisette, E. L.↗
NASA NTRS1992

Mars: Correcting surface albedo observations for effects of atmospheric dust loading

We have developed a radiative transfer model which allows the effects of atmospheric dust loading on surface albedo to be investigated. This model incorporates atmospheric dust opacity, the single scattering albedo and particle phase function of atmospheric dust, the bidirectional reflectance of the surface, and variable lighting and viewing geometry. The most recent dust particle properties are utilized. The spatial and temporal variability of atmospheric opacity (Tan) strongly influences the radiative transfer modelling results. We are currently using the approach described to determine Tan for IRTM mapping sequences of selected regions. This approach allows Tan to be determined at the highest spatial and temporal resolution supported by the IRTM data. Applying the radiative transfer modelling and determination of Tan described, IRTM visual brightness observations can be corrected for the effects of atmospheric dust loading a variety of locations and times. This approach allows maps of 'dust-corrected surface albedo' to be constructed for selected regions. Information on the variability of surface albedo and the amount of dust deposition/erosion related to such variability results. To date, this study indicates that atmospheric dust loading has a significant effect on observations of surface albedo, amounting to albedo corrections of as much as several tens of percent. This correction is not constant or linear, but depends upon surface albedo, viewing and lighting geometry, the dust and surface phase functions, and the atmospheric opacity. It is clear that the quantitative study of surface albedo, especially where small variations in observed albedo are important (such as photometric analyses), needs to account for the effects of the atmospheric dust loading. Maps of 'dust-corrected surface albedo' will be presented for a number of regions.

Lee, S. W.↗
NASA NTRS1951

Boundary Layer Effect on the Surface Pressure of an Infinite Cone in Supersonic Flow

The theory of Taylor and Maccoll (Ref,1) gives the surface pressure on an infinite cone in supersonic flow as a function of the cone vertex angle and the free stream Mach number and static pressure for a gas of vanishing viscosity. When a slender conical probe is used together with an impact pressure probe to determine the static pressure and Mach number in a low density gas stream, it is desirable to have some theoretical estimate of the effect of viscous boundary layer on the probe readings. Theoretical and experimental results with respect to impact probes have been presented in Refs. 5 and 6. A simple approximation for a conical probe based on linearized supersonic flow and compressible boundary layer theory is presented here.

Lin, T. C.↗