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Spatial Growth Modeling and High Resolution Remote Sensing Data Coupled with Air Quality Modeling to Assess the Impact of Atlanta, Georgia on the Local and Regional Environment

The growth of cities, both in population and areal extent, appears as an inexorable process. Urbanization continues at a rapid rate, and it is estimated that by the year 2025, 60 percent of the world s population will live in cities. Urban expansion has profound impacts on a host of biophysical, environmental, and atmospheric processes within an urban ecosystems perspective. A reduction in air quality over cities is a major result of these impacts. Because of its complexity, the urban landscape is not adequately captured in air quality models such as the Community Multiscale Air Quality (CMAQ) model that is used to assess whether urban areas are in attainment of EPA air quality standards, primarily for ground level ozone. This inadequacy of the CMAQ model to sufficiently respond to the heterogeneous nature of the urban landscape can impact how well the model predicts ozone levels over metropolitan areas and ultimately, whether cities exceed EPA ozone air quality standards. We are exploring the utility of high-resolution remote sensing data and urban spatial growth modeling (SGM) projections as improved inputs to a meteorological/air quality modeling system focusing on the Atlanta, Georgia metropolitan area as a case study. These growth projections include business as usual and smart growth scenarios out to 2030. The growth projections illustrate the effects of employing urban heat island mitigation strategies, such as increasing tree canopy and albedo across the Atlanta metro area, which in turn, are used to model how air temperature can potentially be moderated as impacts on elevating ground-level ozone, as opposed to not utilizing heat island mitigation strategies. The National Land Cover Dataset at 30m resolution is being used as the land use/land cover input and aggregated to the 4km scale for the MM5 mesoscale meteorological model and the CMAQ modeling schemes. Use of these data has been found to better characterize low density/suburban development as compared with USGS lkm land use/land cover data that have traditionally been used in modeling. Air quality prediction for future scenarios to 2030 is being facilitated by land use projections using a spatial growth model. Land use projections were developed using the 2030 Regional Transportation Plan developed by the Atlanta Regional Commission, the regional planning agency for the area. This allows the Georgia Environmental Protection Division to evaluate how these transportation plans will affect future air quality. The coupled SGM and air quality modeling approach provides insight on what the impacts of Atlanta s growth will be on the local and regional environment and exists as a mechanism that can be used by policy makers to make rational decisions on urban growth and sustainability for the metropolitan area in the future.

Quattrochi, Dale A.↗

6S Return Samples: Assessment of Air Quality in the International Space Station (ISS) Based on Solid Sorbent Air Sampler (SSAS) and Formaldehyde Monitoring Kit (FMK) Analyses

The toxicological assessments of SSAS and FMK analytical results are reported. Analytical methods have not changed from earlier reports. Surrogate standard recoveries from the SSAS tubes were 66-76% for 13C-acetone, 85-96% for fluorobenzene, and 73-89% for chlorobenzene. Post-flight flows were far below pre-flight flows and an investigation of the problem revealed that the reduced flow was caused by a leak at the interface of the pump inlet tube and the pump head. This resulted in degradation of pump efficiency. Further investigation showed that the problem occurred before the SSAS was operated on orbit and that use of the post-flight flows yielded consistent and useful results. Recoveries from formaldehyde control badges were 86 to 104%. The two general criteria used to assess air quality are the total-non-methane-volatile organic hydrocarbons (NMVOCs) and the total T-value (minus the CO2 and formaldehyde contributions). The T values will not be reported for these data due to the flow anomaly. Control of atmospheric alcohols is important to the water recovery system engineers, hence total alcohols (including acetone) are also shown for each sample. Octafluoropropane (OFP) is not efficiently trapped by the sorbents used in the SSAS. Because formaldehyde is quantified from sorbent badges, its concentration is also listed separately. These five indices of air quality are summarized.

James, John T.↗

LA100 Equity Strategies. Chapter 11: Truck Electrification for Improved Air Quality and Health

The LA100 Equity Strategies project integrates community guidance with robust research, modeling, and analysis to identify strategy options that can increase equitable outcomes in Los Angeles' clean energy transition. This report focuses on truck electrification as a means to improve air quality and health in traffic and air quality disadvantaged communities. It also identifies potential strategies to more equitably distribute air quality benefits from electrification of trucks, defined here as heavy-duty vehicles over 8,500 pounds (lbs) gross vehicle weight. Specifically, NREL analyzed 1) baseline air pollutant emissions, 2) emissions reductions associated with incremental increases in electrification of three types of heavy-duty trucks in 2035, and 3) resultant changes to air pollutant concentrations for selected census tracts along major roadways in disadvantaged and non-disadvantaged communities for comparison. In addition, NREL analyzed the impact of estimated pollutant concentrations on several health effects and the distribution of those health effects by disadvantaged community status. NREL's analysis is complemented by a University of California Los Angeles (UCLA) analysis of air quality benefits from transportation electrification, which included light-duty vehicles (Chapter 15) and evaluated regional air-quality changes across Los Angeles. Research was guided by input from the community engagement process, and associated equity strategies are presented in alignment with that guidance.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Impacts of a Prescribed Fire on Air Quality in Central New Mexico

A short-duration but high-impact air quality event occurred on 28 November 2018 along the Rio Grande Valley of New Mexico. This fire occurred outside the typical wildfire season, and greatly impacted the air quality in Socorro, NM, and the surroundings. Measurements were taken during the event using an aerosol light scattering technique (integrating nephelometer) and a particulate mass concentration monitor (DustTrak PM optical monitor). The instruments sampled the ambient air during the event on the campus of the New Mexico Institute of Mining and Technology in Socorro, New Mexico. The peak values on a 5-min basis of light scattering and the PM mass concentration reached 470 Mm -1 and 270 µg/m 3 , respectively. We examined the meteorological context of the event using local meteorological data and back trajectories using the NOAA HYSPLIT model to determine atmospheric transport and possible sources. Several fires, both prescribed and wildfires, occurred in the region including a prescribed burn at Bosque del Apache National Wildlife Refuge (17 km south-southeast of the receptor site). The data suggest that the prescribed burn at Bosque del Apache was the dominant contributor due to transport evidence and the event’s narrow spatiotemporal extent. The increasing importance of restoring ecosystem function using prescribed fire in wildland fire management will likely lead to more frequent air quality impacts and sets up policy tradeoffs that require a balance between these public goals. This study examines the evidence of the effects of a prescribed fire in a protected wildland area impacting the air quality in a nearby populated area.

54 ENVIRONMENTAL SCIENCES↗

Satellite Data of Atmospheric Pollution for U.S. Air Quality Applications: Examples of Applications, Summary of Data End-user Resources, Answers to Faqs, and Common Mistakes to Avoid

Satellite data of atmospheric pollutants are becoming more widely used in the decision-making and environmental management activities of public, private sector and non-profit organizations. They are employed for estimating emissions, tracking pollutant plumes, supporting air quality forecasting activities, providing evidence for "exceptional event" declarations, monitoring regional long-term trends, and evaluating air quality model output. However, many air quality managers are not taking full advantage of the data for these applications nor has the full potential of satellite data for air quality applications been realized. A key barrier is the inherent difficulties associated with accessing, processing, and properly interpreting observational data. A degree of technical skill is required on the part of the data end-user, which is often problematic for air quality agencies with limited resources. Therefore, we 1) review the primary uses of satellite data for air quality applications, 2) provide some background information on satellite capabilities for measuring pollutants, 3) discuss the many resources available to the end-user for accessing, processing, and visualizing the data, and 4) provide answers to common questions in plain language.

remote sensing↗

Morgan State University Air Quality Monitor Field Campaign Report

This activity was to enable us to install air quality and meteorological instrumentation such as an automated Air Quality Drone, PurpleAir Sensor, and Sensit Ramp Air Quality Sensor. This installation formed part of the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) User Facility’s Coast-Urban-Rural Atmospheric Gradient Experiment (CoURAGE) at the Baltimore site. Figure 1 shows the aerial image of the CoURAGE Baltimore site with all the installed instruments.

47 OTHER INSTRUMENTATION↗

Satellite Data of Atmospheric Pollution for U.S. Air Quality Applications: Examples of Applications, Summary of Data End-User Resources, Answers to FAQs, and Common Mistakes to Avoid

Satellite data of atmospheric pollutants are becoming more widely used in the decision-making and environmental management activities of public, private sector and non-profit organizations. They are employed for estimating emissions, tracking pollutant plumes, supporting air quality forecasting activities, providing evidence for "exceptional event" declarations, monitoring regional long-term trends, and evaluating air quality model output. However, many air quality managers are not taking full advantage of the data for these applications nor has the full potential of satellite data for air quality applications been realized. A key barrier is the inherent difficulties associated with accessing, processing, and properly interpreting observational data. A degree of technical skill is required on the part of the data end-user, which is often problematic for air quality agencies with limited resources. Therefore, we 1) review the primary uses of satellite data for air quality applications, 2) provide some background information on satellite capabilities for measuring pollutants, 3) discuss the many resources available to the end-user for accessing, processing, and visualizing the data, and 4) provide answers to common questions in plain language.

Duncan, Bryan↗

Air quality impacts from the development of unconventional oil and gas well pads: Air toxics and other volatile organic compounds

Unconventional oil and natural gas development (UOGD) has expanded rapidly across the United States in recent decades and raised concerns about associated air quality impacts. While significant effort has been made to quantify methane emissions, relatively few observations have been made of Volatile Organic Compounds (VOCs), especially during drilling and completion of new wells. Extensive air monitoring during development of several large, multi-well pads in Broomfield, Colorado, in the Denver-Julesburg Basin, provides a novel opportunity to examine changes in local air toxics and other VOC concentrations during well drilling and completions and production. These operations offer an especially useful case to study as several management practices were implemented to reduce emissions (e.g., electrified, grid-powered drill rigs and closed loop fluid handling systems to reduce truck traffic and limit fluid handling on the pad). With simultaneous measurements of methane and 50 VOCs from October 2018 to December 2022 at as many as 19 sites near well pads, in adjacent neighborhoods, and at a more distant reference location, we identify impacts from each phase of well development and production. Use of weekly, time-integrated canisters, a Proton Transfer Reaction Mass Spectrometer (PTR-MS), continuous photoionization detectors (PID) to trigger canister collection upon detection of VOC-rich plumes, and an instrumented vehicle, provided a powerful suite of measurements to characterize both transient plumes and longer-term changes in air quality. Prior to the start of well development, VOC gradients were small across Broomfield. Once drilling commenced, concentrations of oil and gas (O&G) related VOCs, including alkanes and aromatics, increased around active well pads. Concentration increases were clearly apparent during certain operations, including drilling, coil tubing/millout operations, and production tubing installation. Emissions of C 8 –C 10 n-alkanes during drilling operations highlighted the importance of VOC emissions from synthetic drilling mud chosen to reduce odor impacts. More than 90 samples were collected of transient plumes. Using composition measurements, meteorological data, and information about well pad activities, these plumes were connected with specific UOGD operations including drilling, flowback, and production equipment maintenance. The chemical signatures of these plumes differed by operation type (e.g., C 8 –C 10 n-alkanes constituted a larger fraction of measured VOCs in drilling-related plumes). Concentrations of individual, oil and gas-related VOCs in these plumes were often several orders of magnitude higher than in background air, with maximum ethane and benzene concentrations of 79,600 and 819 ppbv, respectively. Because these plumes typically impact a monitoring site for just several minutes, they are easily missed by slower-responding instruments. Study measurements highlight future emission mitigation opportunities during UOGD operations, including better control of emissions from shakers that separate drill cuttings from drilling mud, production separator maintenance operations, and periodic emptying of sand cans during flowback operations.

54 ENVIRONMENTAL SCIENCES↗

The Spacecraft Mass Balance as a Diagnostic Tool for Cabin Air Quality

The spacecraft-level mass balance is a powerful tool for diagnosing and decoupling factors influencing cabin air quality, especially with respect to trace contaminant propagation. Successful implementation of this approach relies upon accurate and temporally relevant air quality measurements, which are often challenging to attain for emerging trace contaminants. In addition to the proper interpretation of air quality data trends, a thorough understanding of subsystem-level mass transfer is required to characterize process performance. For many Environmental Control and Life Support System processes, subsystem mass transfer may be predicted based on physicochemical properties and classic unit operation design approaches. Gaps in understanding of process performance should be supplemented with thorough ground testing. A high confidence in the fidelity of one of these two aspects, air quality data or process performance, may help offset uncertainties in the other. At minimum, thresholding assumptions and numerical methods can be imposed to constrain unknown parameters within the physical envelope of the situation at hand. Finally, the complexity of cabin-wide integrated mass balances may be reduced by implementing a phenomenological approach towards subsystem discretization.

Cabin Air-quality↗

Utilization of the NASA/MSFC diffusion model in support of aerospace air quality analyses

The basic types of diffusion models available for aerospace air quality analyses are reviewed in terms of meteorological input differences. The NASA/MSFC rocket exhaust effluent diffusion (REED) code is summarized and discussed as a tool for aerospace air quality analyses. The generic approach to a climatological air quality analysis using the NASA/MSFC REED code is considered.

Stephens, J. B.↗

The role of Environmental Health System air quality monitors in Space Station Contingency Operations

This paper describes the Space Station Freedom (SSF) Environmental Health System's air-quality monitoring strategy and instrumentation. A two-tier system has been developed, consisting of first-alert instruments that warn the crew of airborne contamination and a volatile organic analyzer that can identify volatile organic contaminants in near-real time. The strategy for air quality monitoring on SSF is designed to provide early detection so that the contamination can be confined to one module and so that crew health and safety can be protected throughout the contingency event. The use of air-quality monitors in fixed and portable modes will be presented as a means of following the progress of decontamination efforts and ensuring acceptable air quality in a module after an incident. The technology of each instrument will be reviewed briefly; the main focus of this paper, however, will be the use of air-quality monitors before, during, and after contingency incidents.

Limero, Thomas F.↗

Technical Note: AQMEII4 Activity 1: Evaluation of Wet and Dry Deposition Schemes as an Integral Part of Regional-scale Air Quality Models

We present in this technical note the research protocol for phase 4 of the Air Quality Model Evaluation International Initiative (AQMEII4). This research initiative is divided into two activities, collectively having three goals: (i) to define the current state of the science with respect to representations of wet and especially dry deposition in regional models, (ii) to quantify the extent to which different dry deposition parameterizations influence retrospective air pollutant concentration and flux predictions, and (iii) to identify, through the use of a common set of detailed diagnostics, sensitivity simulations, model evaluation, and reduction of input uncertainty, the specific causes for the current range of these predictions. Activity 1 is dedicated to the diagnostic evaluation of wet and dry deposition processes in regional air quality models (described in this paper), and Activity 2 to the evaluation of dry deposition point models against ozone flux measurements at multiple towers with multiyear observations (to be described in future submissions as part of the special issue on AQMEII4). The scope of this paper is to present the scientific protocols for Activity 1, as well as to summarize the technical information associated with the different dry deposition approaches used by the participating research groups of AQMEII4. In addition to describing all common aspects and data used for this multi-model evaluation activity, most importantly, we present the strategy devised to allow a common process-level comparison of dry deposition obtained from models using sometimes very different dry deposition schemes. The strategy is based on adding detailed diagnostics to the algorithms used in the dry deposition modules of existing regional air quality models, in particular archiving diagnostics specific to land use–land cover (LULC) and creating standardized LULC categories to facilitate cross-comparison of LULC-specific dry deposition parameters and processes, as well as archiving effective conductance and effective flux as means for comparing the relative influence of different pathways towards the net or total dry deposition. This new approach, along with an analysis of precipitation and wet deposition fields, will provide an unprecedented process-oriented comparison of deposition in regional air quality models. Examples of how specific dry deposition schemes used in participating models have been reduced to the common set of comparable diagnostics defined for AQMEII4 are also presented.

Air Quality Model Evaluation International Initiat↗

Air Quality Analysis and Tools For Policy

South Asia is home to some of the most significant air quality challenges in the world. More than 99% of the region’s population is exposed to unhealthy fine particulate matter (PM2.5) concentrations, as defined by the World Health Organization. Recent policy initiatives in South Asia show that air quality policy is a priority, given the health impacts of air pollution. At the same time, capacity and data to assess and address air pollution remains limited in many areas. The main objective of this report is to outline a set of publicly-available tools that can be used to inform policies to improve air quality in South Asia. The report primarily focuses on tools such as emission inventories and integrated modeling systems with country-level resolution and illustrates their air quality assessment capabilities through examples and brief technical summaries. The report focuses on: (a) the Community Emissions Data System (CEDS) that provides historical emissions of key pollutants for all countries in South Asia, and (b) profiles an analysis of Indian air pollution and policy scenarios, using several integrated modeling tools. Both of these examples draw on recent research and data that outlines the scale of the challenge as well as the policy options for reducing air pollution in the region. The report concludes with key recommendations for regional stakeholders working towards mitigating air pollution in South Asia.

54 ENVIRONMENTAL SCIENCES↗

Impact of Canadian Wildfires on Mid Atlantic’s Region Air Quality: An Analysis Using ASDC Data

Wildfires pose a growing concern in North America due to their harmful impacts on air quality and public health, with increased wildfire activity in recent years leading to widespread smoke plumes that can transcend borders. The exposure of New York City (NYC), the most populous city in North America, to Canadian wildfire smoke highlights the substantial implications for public health and urban environments. To better understand the impact of Canadian wildfires on air quality in NYC, satellite data from the NASA Atmospheric Science Data Center (ASDC) at Langley Research Center, along with ground-based measurements and atmospheric modeling results, are analyzed. We examine concentrations of atmospheric aerosols—particularly PM2.5 particulate matter originating from Canadian wildfires—their dispersion patterns, and the duration and intensity of smoke events impacting NYC. Data from multiple satellites, such as those from the Earth Polychromatic Imaging Camera (EPIC), are synergistically used to identify regions affected by wildfires and estimate aerosol loading. Ground-based measurements, including data from air quality monitoring stations, provide localized information for validation and calibration purposes. The findings of this study contribute to our understanding of the impact of Canadian wildfires on NYC's air quality and emphasize the importance of monitoring and prediction of transboundary smoke events using data synthesized from multiple sources, such as those provided by the ASDC. This information is crucial for policymakers, public health officials, and residents in affected areas to develop effective strategies for mitigating the health risks associated with wildfire smoke and improving air quality during wildfire seasons. The utilization of ASDC data in this research highlights the critical role of atmospheric remote sensing in addressing the challenges posed by wildfires and their consequences on regional scales.

Ingrid Garcia-Solera↗

Statistical summary and trend evaluation of air quality data for Cleveland, Ohio in 1967 to 1971: Total suspended particulate, nitrogen dioxide, and sulfur dioxide

Air quality data for Cleveland, Ohio, for the period of 1967 to 1971 were collated and subjected to statistical analysis. The total suspended particulate component is lognormally distributed; while sulfur dioxide and nitrogen dioxide are reasonably approximated by lognormal distributions. Only sulfur dioxide, in some residential neighborhoods, meets Ohio air quality standards. Air quality has definitely improved in the industrial valley, while in the rest of the city, only sulfur dioxide has shown consistent improvement. A pollution index is introduced which displays directly the degree to which the environmental air conforms to mandated standards.

Neustadter, H. E.↗

Air Quality Research and Applications Using AURA OMi Data

The Ozone Monitoring Instrument (OMI) on EOS Aura is a new generation of satellite remote sensing instrument designed to measure trace gas and aerosol absorption at the UV and blue wavelengths. These measurements are made globally at urban scale resolution with no inter-orbital gaps that make them potentially very useful for air quality research, such as the determination of the sources and processes that affect global and regional air quality, and to develop applications such as air quality forecast. However, the use of satellite data for such applications is not as straight forward as satellite data have been for stratospheric research. There is a need for close interaction between the satellite product developers, in-situ measurement programs, and the air quality research community to overcome some of the inherent difficulties in interpreting data from satellite-based remote sensing instruments. In this talk we will discuss the challenges and opportunities in using OMI products for air quality research and applications. A key conclusion of this work is that to realize the full potential of OMI measurements it will be necessary to combine OMI data with data from instruments such as MLS, MODIS, AIRS, and CALIPSO that are currently flying in the "A-train" satellite constellation. In addition similar data taken by satellites crossing the earth at different local times than the A-train (e.g., the recently MetOp satellite) would need to be processed in a consistent manner to study diurnal variability, and to capture the effects on air quality of rapidly changing events such as wild fires.

Bhartia, P.K.↗

NASA’s High-Resolution GEOS Forecasting and Reanalysis Products: Impact of Stratospheric Intrusions on Surface Ozone Air Quality

A new approach to the study of stratospheric intrusions (SIs)? the introduction of ozone-rich lower stratospheric air into the troposphere ? uses NASA's Goddard Earth Observing System Model (GEOS) model and assimilation products with an objective feature tracking algorithm to investigate the atmospheric dynamics in the UTLS region that generate SIs and the different mechanisms through which SIs may influence tropospheric chemistry and surface air quality. In particular, SIs have been linked with surface ozone air quality exceedances, especially at the high elevations in the western USA in springtime. However, the impact of SIs in the remaining seasons and over the rest of the USA is less clear. Improved understanding of the connections between large-scale climate variability and local-scale dynamically-driven air quality events may support improved seasonal prediction of SI events. While the spring over the western USA does exhibit the largest number of SIs affecting the lower troposphere, we demonstrate that the number of intrusions in the remaining seasons and over the eastern USA is sizable. Using a multitude of observational datasets, including lidar data, ozonesondes and air quality monitoring surface sites, in combination with GEOS forecast and reanalysis products, the transport of ozone from the stratosphere toward the surface is assessed. By focusing on recent reports of high ozone at monitoring station sites likely associated with SIs, we aim to provide the public with tools which are available in near-real time to enhance their capability to identify the impact of stratospheric air on surface ozone concentrations separate from anthropogenic sources.

Knowland, K. Emma↗