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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

Azimuth variation in microwave scatterometer and radiometer data over Antarctica

In this paper, we explore the use of NASA scatterometer (NSCAT) data, European remote sensing (ERS) advanced microwave instrument (AMI) scatterometer mode data, and special sensor microwave/imager (SSM/I) data to study surface roughness effects in Antarctica. All three sensors provide strong evidence of azimuth modulation, which is correlated with the surface slope environment and results in a katabatic wind flow regime.

azimuthal↗

Mapping Environmental Contaminants at Ray Mine, AZ

Airborne Visible and Infrared Imaging Spectrometer (AVIRIS) data was collected over Ray Mine as part of a demonstration project for the Environmental Projection Agency (EPA) through the Advanced Measurement Initiative (AMI).

AVIRIS↗

Changes in the Magnetic Field Topology and the Dayside/Nightside Reconnection Rates in Response to a Solar Wind Dynamic Pressure Front A Case Study

One of the most significant observations associated with a sharp enhancement in solar wind dynamic pressure, SWP, is the poleward expansion of the auroral oval and the closing of the polar cap. The polar cap shrinking over a wide range of magnetic local times (MLTs), in connection with an observed increase in ionospheric convection and the transpolar potential, led to the conclusion that the nightside reconnection rate is significantly enhanced after a pressure front impact. However, this enhanced tail reconnection has never been directly measured. We demonstrate the effect of a solar wind dynamic pressure front on the polar cap closure, and for the first time, measure the enhanced reconnection rate in the magnetotail, for a case occurring during southward background Interplanetary Magnetic Field (IMF) conditions. We use Polar Ultra-Violet Imager (UVI) measurements to detect the location of the open-closed field line boundary, and combine them with Assimilative Mapping of Ionospheric Electrodynamics (AMIE) potentials to calculate the ionospheric electric field along the polar cap boundary, and thus evaluate the variation of the dayside/nightside reconnection rates. We find a strong response of the polar cap boundary at all available MLTs, exhibiting a significant reduction of the open flux content. We also observe an immediate response of the dayside reconnection rate, plus a phased response, delayed by 15–20min, of the nightside reconnection rate. Finally, we provide comparison of the observations with the results of the Open Geospace General Circulation Model (OpenGGCM), elucidating significant agreements and disagreements

A Boudouridis↗

Automated Technique for the Detection of Step-Like Solar Wind Dynamic Pressure Changes: Application to the Response of the Transpolar Potential to Solar Wind Dynamic Pressure Fronts

The input from the solar wind (SW) and the accompanying Interplanetary Magnetic Field (IMF) is the defining feature of the solar wind-magnetosphere interactions. One of the most important SW drivers is the solar wind dynamic pressure, and most significantly its sharp changes known as pressure fronts. Sudden enhancements in solar wind dynamic pressure, SWP, have been shown to lead to intensification of the auroral electrojets (and Region 1 field-aligned currents), increase in auroral emissions, and significant enhancement in ionospheric convection and the transpolar potential. Case studies of the interaction between pressure fronts and the terrestrial space environment shed great light on their importance to the structure and dynamics of the system. However, thorough understanding of the interaction requires fully statistical investigations. These statistical studies require a large number of suitable pressure front events. In the past these have been obtained through laborious manual inspection of solar wind data. We present an automated procedure that identifies sudden step enhancements in SWP that satisfy a desired set of limiting step-like characteristics, such as magnitude of the change, sign of the change (positive/negative), and rate of change. The procedure yields a list of suitable events, along with their step features within minutes. The technique is tested for missed events and false positives by direct comparison to manual inspection of the data. Its utility is illustrated by application to the statistical effect of pressure fronts to the transpolar potential as measured by the Assimilative Mapping of Ionospheric Electrodynamics (AMIE) technique.

A. Boudouridis↗

Development of a Global Reference Surface Reflectance and BRDF Datasets from Geostationary Satellite Observations and AERONET Measurements

Surface reflectances and their dependency on illumination-view geometries (i.e., BRDF) are the foundation of many high-level satellite products for land and water monitoring. Yet it is difficult to evaluate the quality of satellite-based surface reflectances with ground-based measurements due to the spatial scale differences. In order to fill the gap, here we develop a reference dataset of surface reflectance and BRDF at the global AERONET sites with data streams from operational geostationary sensors including Himawari 8/9 AHI, GK-2A AMI, and GOES 16/17 ABI. Taking the top-of-atmosphere (TOA) reflectance and the site measured atmospheric aerosol optical depth (AOD) as the main inputs, we apply the GeoNEX-AC algorithm to performance accurate atmospheric correction and derive 10-minute surface reflectance and daily Ross-Thick-Li-Sparse (RTLS) BRDF parameters at AERONET sites where coincident AOD measurements and TOA observations are available from 2016 (for Himawari) or 2018 (for GOES) onwards. The algorithm ensures that the retrieved surface BRDF parameters, along with the site-measured AOD, allow the atmospheric radiative transfer model, SHARM, accurately simulate the observed TOA reflectance at diurnal and longer time scales. They are our best estimates of the surface optical properties and thus can serve as the “reference” to evaluate the performance of operational atmospheric correction algorithms (where AOD is assumed unknown and needs to be retrieved). The reference BRDF also allow us to evaluate the spectral band ratios between the SWIR (e.g., 2200 nm) and the visible (e.g., 650 nm) regions, which are commonly used in operational atmospheric correction algorithms. Finally, we demonstrate that the reference dataset can be used to develop potential data synergies between different GEO satellites as well as GEO-LEO sensors.

Weile Wang↗

Enhancing Air Quality Applications in the Hindu Kush-Himalayan Region Using Satellite, Model, and Machine Learning Techniques

Air pollution in the Hindu Kush Himalayan (HKH) region of South Asia is a severe issue, as increases in emissions over the past two decades have degraded air quality (AQ) across the region, which poses major threats to human health, the ecosystem, climate, and agriculture. A diversity of anthropogenic and natural emission sources including transportation, power plants, industries, open biomass burning of crop residue, forest fires, cooking and heating fires, and dust storms contribute to unhealthy AQ and transboundary pollution issues in the region. Further complicating matters is the importance of meteorology and terrain on AQ, especially in the Kathmandu Valley where extreme haze episodes frequently develop from the atmospherically stable weather conditions during the winter monsoon. This study uses state-of-the-art satellite observations and modeling capabilities in conjunction with machine learning techniques to develop a comprehensive toolkit for enhancing AQ monitoring and forecasting in HKH. The toolkit incorporates new generation satellite observations from the TROPOspheric Monitoring Instrument (TROPOMI), Geostationary Environment Monitoring Spectrometer (GEMS), and Advanced Meteorological Imager (AMI), which provide unprecedented resolution on aerosols and trace gases, including nitrogen dioxide (NO 2 ), formaldehyde (CH2O), sulfur dioxide (SO 2 ), carbon monoxide (CO), and ozone (O 3 ), and aerosol optical depth (AOD). Value-added products [e.g., Particulate matter with diameters less than 2.5 micrometers (PM2.5)] are developed from the suite of satellite observations to further improve AQ monitoring capabilities in the region. The satellite products are also used to assimilate a high-resolution chemical transport model tailored for the HKH region, which is providing daily, 54-hour AQ forecasts with horizontal grid spacings of 12- and 4-km. This presentation will provide an overview of the suite of satellite- and model-based products in the AQ toolkit and application and performance of the toolkit for AQ monitoring and forecasting in HKH.

Air Quality↗

Enhancing Air Quality Applications in the Hindu Kush-Himalayan Region Using Satellite, Model, and Machine Learning Techniques

Air pollution in the Hindu Kush Himalayan (HKH) region of South Asia is a severe issue, as increases in emissions over the past two decades have degraded air quality (AQ) across the region, which poses major threats to human health, the ecosystem, climate, and agriculture. A diversity of anthropogenic and natural emission sources including transportation, power plants, industries, open biomass burning of crop residue, forest fires, cooking and heating fires, and dust storms contribute to unhealthy AQ and transboundary pollution issues in the region. Further complicating matters is the importance of meteorology and terrain on AQ, especially in the Kathmandu Valley where extreme haze episodes frequently develop from the atmospherically stable weather conditions during the winter monsoon. This study uses state-of-the-art satellite observations and modeling capabilities in conjunction with machine learning techniques to develop a comprehensive toolkit for enhancing AQ monitoring and forecasting in HKH. The toolkit incorporates new generation satellite observations from the TROPOspheric Monitoring Instrument (TROPOMI), Geostationary Environment Monitoring Spectrometer (GEMS), and Advanced Meteorological Imager (AMI), which provide unprecedented resolution on aerosols and trace gases, including nitrogen dioxide, formaldehyde, sulfur dioxide, carbon monoxide, and ozone, and aerosol optical depth. Value-added products, such as level 4 PM2.5 products, are developed from the suite of satellite observations to further improve AQ monitoring capabilities in the region. The satellite products are also used to assimilate a high-resolution chemical transport model tailored for the HKH region, which is providing daily, 54-hour AQ forecasts with horizontal grid spacings of 12- and 4-km. This presentation will provide an overview of the suite of satellite- and model-based products in the AQ toolkit and application and performance of the toolkit for AQ monitoring and forecasting in HKH.

Forecasting↗

Short-Term Electric Load Forecasting for a Residential Household in Alaska

Accurate short-term load forecasting at a fine scale is essential for demand response programs, peak shaving, and load-shedding strategies [1]. While traditionally, only aggregate short-term consumption data was available, advanced metering infrastructure (AMI) now provides data at the individual consumer level [1]. There is increasing interest in utilizing this data for short-term load forecasting (from an hour to a few days) to optimize grid operations. Electricity consumption in individual households is highly influenced by residents’ personal behaviors [2]. As a result, unlike aggregate loads, electrical power usage in single households often shows significant volatility, making meter-level load forecasting for individual users particularly challenging [3], [4]. Deep learning methods, with their strong ability to model nonlinear data, have become popular for improving the accuracy of household electricity consumption forecasting [4]. Notably, the Long ShortTerm Memory (LSTM) has attracted significant attention [5], [6].

42 ENGINEERING↗

Generation and Study of Am(IV) by Temperature-Controlled Electron Pulse Radiolysis

Used nuclear fuel (UNF) separation techniques that strive to separate radiotoxic americium (Am) from trivalent lanthanide fission products through oxidation state control have increased research efforts surrounding Am(V) and Am(VI). However, equivalent knowledge of the tetravalent state, Am(IV), has remained elusive, particularly in conditions more representative of UNF reprocessing, i.e., in concentrated nitric acid (HNO3). With this in mind, we have used electron pulse radiolysis to study the radiation-induced redox reaction of Am(III) with the oxidizing nitrate radical (NO3?) in 6 M HNO3: Am(III) + NO3? ? Am(IV) + NO3? . These experiments enabled us to observe the growth and decay of Am(IV) in a concentrated acidic solution for the first time. The transient Am(IV) species was found to have a lifetime of ~16 µs?sufficiently long-lived to play a critical mechanistic role in UNF reprocessing systems. Additionally, we performed the first-ever temperature-dependent kinetics study of an actinide element, elucidating unprecedented Arrhenius and Eyring activation parameters for the reaction of Am(III) with NO3?. This new knowledge provides much-needed molecular-level insights into the radiation-induced behavior of Am.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Raccoon density estimation from camera traps for raccoon rabies management

Abstract Density estimation for unmarked animals is particularly challenging, yet density estimates are often necessary for effective wildlife management. Raccoons ( Procyon lotor ) are the primary terrestrial wildlife reservoir for Lyssavirus rabies within the United States. The raccoon rabies variant (RRVV) is actively managed at landscape scales using oral rabies vaccination (ORV) within the eastern United States. To effectively manage RRVV, it is important to know the density of raccoons to appropriately scale the density of ORV baits distributed on the landscape. We compared methods to estimate raccoon densities from camera‐trap data versus more intensive capture‐mark‐recapture (CMR) estimates across 2 land cover types (upland pine and bottomland hardwood) in the southeastern United States during 2019 and 2020. We evaluated the effect of alternative camera configurations and durations of camera trapping on density estimates and used an N‐mixture model to estimate raccoon densities, including covariates on abundance and detection. We further compared different methods of scaling camera‐based counts, with the maximum number of raccoons seen on any given image within a day best explaining density. Camera‐trap density estimates were moderately correlated with CMR estimates ( r = 0.56). However, densities from camera‐trap data were more reliable when classifying category of density as an index used to inform management (83% correct when compared to CMR estimates), although the densities in our study fell into the 2 lowest density classes only. Using more cameras reduced bias and uncertainty around density estimates; however, if ≤6 camera traps were used at a site, a line transect approach proved less biased than a grid design. Camera trapping should be conducted for at least 3 weeks for more accurate estimates of raccoon population density in our study area (<5% bias). We show that camera‐trap data can be used to assign raccoon densities to management‐relevant density index bins, but more studies are needed to ensure reliability across a greater range of environmental conditions and raccoon densities.

Davis, Amy J.↗

Annotation of DOM metabolomes with an ultrahigh resolution mass spectrometry molecular formula library

Current approaches to analyzing metabolomic data often rely on matching MS/MS fragmentation data to sparse libraries or databases. This approach results in limited identification of features, often with less than 10% of the dataset being annotated. A complementary approach is to assign molecular formula to features based on accurate mass measurements, but the platforms commonly used for metabolomics do not have the needed accuracy or resolving power to do this robustly, particularly for larger molecules. Using our newly modified analysis tool, CoreMS, we generated a library of molecular formula from pooled samples analyzed with LC-21T FT-ICR MS. This library successfully annotated approximately 53.2% of features identified from the exometabolome of marine diatom Phaeodactylum tricornutum – a nearly ten-fold increase over the 5.9% annotation rate achieved using a conventional MS/MS library matching approach. Using this FT-ICR MS library approach, we were able to differentiate differences in the exometabolome of P. tricornutum in iron replete and iron limited conditions, with 668 metabolites being differentially expressed (p < 0.05, 2 x intensity difference) under these conditions. The traditional MS/MS fragmentation-based annotation approach only annotated 61 of these metabolites, while our novel pipeline annotated 450 metabolites and revealed 12 metabolites that were significantly more abundant under low iron conditions. Our results demonstrate the utility of ultrahigh resolution mass spectrometry for generating more comprehensive and confident molecular annotations.

21T-FTICR-MS, CoreMS↗

Ultrafast population and structural dynamics of a Ni-bipyridine photoredox catalyst reveal a significant deactivation pathway

The ultrafast excited state pathways and dynamics of NiII-bipyridine complexes influence the yield of photochemical processes involved in their catalytic cross-coupling reactions. Here we present ultrafast Ni K x-ray emission spectroscopy (XES) and x-ray solution scattering (XSS) of a NiII-bipyridine aryl halide complex, [Ni(t-Bubpy)(o-tol)Br], to quantify the excited state population dynamics and structural changes of the pre-catalyst. Due to the local spin-sensitivity of XES, the population dynamics of metal-to-ligand charge transfer (MLCT) and metal-centered (MC) excited states is established. A rapid ground state recovery pathway is newly identified, representing a significant deactivation pathway during photocatalysis. Furthermore, the pseudotetrahedral structure of the long-lived MC excited state is unambiguously identified and refined by XSS. The results advance our understanding of the ultrafast relaxation mechanisms that impact the photocatalytic mechanism and yield for NiII-bipyridine aryl halide cross-coupling catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Unified and Consistent Structure Growth Measurements from Joint ACT, SPT, and Planck CMB Lensing

We present the tightest cosmic microwave background (CMB) lensing constraints to date on the growth of structure by combining CMB lensing measurements from the Atacama Cosmology Telescope (ACT), the South Pole Telescope (SPT), and Planck. Each of these surveys individually provides lensing measurements with similarly high statistical power, achieving signal-to-noise ratios of approximately 40. The combined lensing band powers represent the most precise CMB lensing power spectrum measurement to date with a signal-to-noise ratio of 61 and an amplitude of A lens recon = 1.025 ± 0.017 with respect to the theory prediction from the best-fit CMB Planck-ACT cosmology. The band powers from all three lensing datasets, analyzed jointly, yield a 1.6% measurement of the parameter combination S 8 CMBL ≡ σ 8 ( Ω m / 0.3 ) 0.25 = 0.82 5 - 0.013 + 0.015 . Including dark energy spectroscopic instrument baryon acoustic oscillation (BAO) data improves the constraint on the amplitude of matter fluctuations to σ 8 = 0.829 ± 0.009 (a 1.1% determination). When combining with uncalibrated supernovae from Pantheon+, we present a 4% sound-horizon-independent estimate of H 0 = 66.4 ± 2.5 km s - 1 Mpc - 1 . The joint lensing constraints on structure growth and present-day Hubble rate are fully consistent with a Λ CDM model fit to the primary CMB data from Planck and ACT. While the precise upper limit is sensitive to the choice of data and underlying model assumptions, when varying the neutrino mass sum within the Λ CDM cosmological model, the combination of primary CMB, BAO, and CMB lensing drives the probable upper limit for the mass sum towards lower values, comparable to the minimum mass prior required by neutrino oscillation experiments.

79 ASTRONOMY AND ASTROPHYSICS↗

High-pressure melt dynamics in shock-compressed titanium

In this work we study the high-pressure melting behavior of titanium using laser-driven shock compression with in situ femtosecond x-ray diffraction and molecular-dynamics simulations based on a machine-learned interatomic potential. The MD simulations predict the solid-liquid coexistence on the Hugoniot in the ∼111−124GPa range. Experimentally, we observe the first evidence of liquid at 86 GPa. We also observe pronounced microstructural changes with pressure, with strong grain refinement associated with the emergence of liquid, within the solid-liquid coexistence (∼110−126GPa). Above 126 GPa, we observe the persistence of residual levels of highly textured crystalline Ti to ∼180GPa, well above the expected melt completion pressure. We discuss the accuracy that current laser-shock experimental platforms have at determining the melt onset and completion pressures.

36 MATERIALS SCIENCE↗

Body-Centered-Cubic Phase Transformation in Gold at TPa Pressures

In situ x-ray diffraction at both the National Ignition Facility and Omega-EP Laser Facility has been utilized to determine the crystallographic state of ramp and shock-ramp compressed gold up to 1.2 TPa (1 T⁢Pa=10 Mbar = 10 × 10 6 atmospheres). In this Letter, we describe a series of experiments that explore a variety of pressure-temperature states in Au, accessed using tailored laser pulses. Here, we find that the ambient pressure face-centered-cubic phase is stable under ramp compression to pressures of at least 1 TPa where the body-centered-cubic phase is observed simultaneously.

High-pressure studies↗

Orthogonal chemical genomics approaches reveal genomic targets for increasing anaerobic chemical tolerance in Zymomonas mobilis

Genetically engineered microbes have the potential to increase efficiency in the bioeconomy by overcoming growth-limiting production stress. Screens of gene perturbation libraries against production stressors can identify high-value engineering targets, but follow-up experiments needed to guard against false positives are slow and resource-intensive. In principle, the use of orthogonal gene perturbation approaches could increase recovery of true positives over false positives because the strengths of one technique compensate for the weaknesses of the other, but, in practice, two parallel screens are rarely performed at the genome scale. Here, we screen genome-scale CRISPRi (CRISPR interference) knockdown and transposon insertion libraries of the bioenergy-relevant Alphaproteobacterium, Zymomonas mobilis, against growth inhibitors commonly found in deconstructed plant material. Integrating data from the two gene perturbation techniques, we established an approach for defining engineering targets with high specificity. This allowed us to identify all known genes in the cytochrome bc1 and cytochrome c synthesis pathway as potential targets for engineering resistance to phenolic acids under anaerobic conditions, a subset of which we validated using precise gene deletions. Strikingly, this finding is specific to the cytochrome bc1 and cytochrome c pathway and does not extend to other branches of the electron transport chain. We further show that exposure of Z. mobilis to ferulic acid causes substantial remodeling of the cell envelope proteome, as well as the downregulation of TonB-dependent transporters. Our work provides a generalizable strategy for identifying high-value engineering targets from gene perturbation screens that is broadly applicable.

CRISPRi↗