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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

2D photofragmentation LIF imaging of H 2 O 2 and HO 2 in the effluent of an atmospheric-pressure plasma jet: effects of solid and liquid interfaces

Two-dimensional (2D) absolute measurements of hydrogen peroxide (H 2 O 2 ) and approximations of the hydroperoxyl radical (HO 2 ) in the effluent of a COST Reference Microplasma Jet operated with a He/H 2 O feed gas are presented. Gas-phase densities are mapped using photofragmentation laser-induced fluorescence (PF-LIF) under three boundary conditions: open effluent, a solid target, and a liquid target. A novel method is presented for separating PF-LIF signals from H 2 O 2 and HO 2 using comparative measurements in oxygen-rich and oxygen-free environments to exploit the preferential formation of HO 2 in the presence of molecular oxygen. This separation strategy is supported by results from a plug-flow plasma chemistry model. Measured densities agree closely with model predictions in both magnitude and trend, while the 2D experimental distributions provide additional insight into the spatial dependencies of these species. In particular, the results show distinct differences in species transport depending on the target type: solid surfaces induce lateral deflection and reduced centerline densities, whereas liquid interfaces promote axial accumulation and higher near-axis concentrations.

atmospheric-pressure plasma jet (APPJ)↗

Differential absorption lidars for remote sensing of atmospheric pressure and temperature profiles

A near infrared differential absorption lidar technique is developed using atmospheric oxygen as a tracer for high resolution vertical profiles of pressure and temperature with high accuracy. Solid-state tunable lasers and high-resolution spectrum analyzers are developed to carry out ground-based and airborne measurement demonstrations and results of the measurements presented. Numerical error analysis of high-altitude airborne and spaceborne experiments is carried out, and system concepts developed for their implementation.

Korb, C. Laurence↗

Inelastic collision processes in ozone and their relation to atmospheric pressure broadening

The research task employs infrared double-resonance to determine rotational energy transfer rates and pathways, in both the ground and vibrationally excited states of ozone. The resulting data base will then be employed to test inelastic scattering theories and to assess intermolecular potential models, both of which are necessary for the systematization and prediction of infrared pressure-broadening coefficients, which are in turn required by atmospheric ozone monitoring techniques based on infrared remote sensing. In addition, observation of excited-state absorption transitions will permit us to improve the determination of the 2 nu(sub 3), nu(sub 1) + nu(sub 2), and 2 nu(sub 1) rotational constants and to derive band strengths for hot-band transitions involving these levels.

Steinfeld, J. I.↗

The seasonal variation of atmospheric pressure on Mars as affected by the south polar cap

The daily mean pressures at two locations on Mars, observed over 57% of a Martian year, reveal a semiannual oscillation with a peak-to-peak difference that is 26% of the mean pressure. This intrinsically Martian phenomenon is caused by exchange of CO2 between the atmosphere and the winter polar caps. Evidence is presented that the difference in pressure at the two landers varies with season and that the seasonal variation is not completely removed by hydrostatic correction for the difference in elevation. The mass CO2 sublimed from the south polar cap is estimated to be greater than or equal to 7.9 x 10 to the 12th metric tons, corresponding to a mean thickness of solid CO2 over the maximum extent of that cap of greater than or equal to 23 cm. Estimates are formed of the meridonal wind speed conveying gas out of the dissipating cap and the associated zonal geostrophic wind, both averaged over longitude. The results are approximately 2.3 m/sec and 14 m/sec, respectively.

Hess, S. L.↗

A lidar system for measuring atmospheric pressure and temperature profiles

The design and operation of a differential absorption lidar system capable of remotely measuring the vertical structure of tropospheric pressure and temperature are described. The measurements are based on the absorption by atmospheric oxygen of the spectrally narrowband output of two pulsed alexandrite lasers. Detailed laser output spectral characteristics, which are critical to successful lidar measurements, are presented. Spectral linewidths of 0.026 and 0.018 per cm for the lasers were measured with over 99.99 percent of the energy contained in three longitudinal modes.

Schwemmer, Geary K.↗

Microgravity Flame Spread in Exploration Atmospheres: Pressure, Oxygen, and Velocity Effects on Opposed and Concurrent Flame Spread

Microgravity tests of flammability and flame spread were performed in a low-speed flow tunnel to simulate spacecraft ventilation flows. Three thin fuels were tested for flammability (Ultem 1000 (General Electric Company), 10 mil film, Nomex (Dupont) HT90-40, and Mylar G (Dupont) and one fuel for flame spread testing (Kimwipes (Kimberly-Clark Worldwide, Inc.). The 1g Upward Limiting Oxygen Index (ULOI) and 1g Maximum Oxygen Concentration (MOC) are found to be greater than those in 0g, by up to 4% oxygen mole fraction, meaning that the fuels burned in 0g at lower oxygen concentrations than they did using the NASA Standard 6001 Test 1 protocol. Flame spread tests with Kimwipes were used to develop correlations that capture the effects of flow velocity, oxygen concentration, and pressure on flame spread rate. These correlations were used to determine that over virtually the entire range of spacecraft atmospheres and flow conditions, the opposed spread is faster, especially for normoxic atmospheres. The correlations were also compared with 1g MOC for various materials as a function of pressure and oxygen. The lines of constant opposed flow agreed best with the 1g MOC trends, which indicates that Test 1 limits are essentially dictated by the critical heat flux for ignition. Further evaluation of these and other materials is continuing to better understand the 0g flammability of materials and its effect on the oxygen margin of safety.

Olson, Sandra L.↗

Airborne Lidar Measurements of Atmospheric Pressure Made Using the Oxygen A-Band

Accurate measurements of greenhouse gas mixing ratios on a global scale are currently needed to gain a better understanding of climate change and its possible impact on our planet. In order to remotely measure greenhouse gas concentrations in the atmosphere with regard to dry air, the air number density in the atmosphere is also needed in deriving the greenhouse gas concentrations. Since oxygen is stable and uniformly mixed in the atmosphere at 20.95%, the measurement of an oxygen absorption in the atmosphere can be used to infer the dry air density and used to calculate the dry air mixing ratio of a greenhouse gas, such as carbon dioxide or methane. OUT technique of measuring Oxygen uses integrated path differential absorption (IPDA) with an Erbium Doped Fiber Amplifier (EDF A) laser system and single photon counting module (SPCM). It measures the absorbance of several on- and off-line wavelengths tuned to an O2 absorption line in the A-band at 764.7 nm. The choice of wavelengths allows us to maximize the pressure sensitivity using the trough between two absorptions in the Oxygen A-band. Our retrieval algorithm uses ancillary meteorological and aircraft altitude information to fit the experimentally obtained lidar O2 line shapes to a model atmosphere and derives the pressure from the profiles of the two lines. We have demonstrated O2 measurements from the ground and from an airborne platform. In this paper we will report on our airborne measurements during our 2011 campaign for the ASCENDS program.

Riris, Haris↗

Computer Code Study of Asteroid Entry into Venusian Atmosphere: Pressure and Density Fields

Analysis of the cratering records on the Moon, Mercury, and Mars have shown similar size-frequency distributions of craters produced during the late heavy bombardment of the inner solar system (Strom, 1988). Venus provides a valuable data base of information on the impacting population for more recent time. Because of resurfacing events, the Venusian cratering record has been estimated to be only about 500 million years old, and for the most part is in pristine condition, thereby producing an opportunity to discover the properties (size/velocity distribution) of the objects that recently impacted its surface. The Magellan IR mapping of the Venusian surface has produced an extremely high-quality set of crater topographies. The observed deficit of small craters is qualitatively explained by atmospheric effects on impactor breakup and the retardation effects of pressure on crater formation. Information about resurfacing history and impactor flux population can only be conjectured using arrant approximations for atmospheric effects on crater size scaling, such as assuming the absence of pressure effects or using other ad hoc approximations for this dependence. The recent work by Ivanov et al.(1986; 1992); Phillips et al.(199 1; 1992); Schaber et al. (1992) and others support the notion that atmospheric effects may have strongly influenced the Venusian cratering record. The work reported here looks at the potential synergism of aerodynamic entry and the gas dynamic flow fields that govern during the time scale and in the vicinity of crater formation.

Schmidt, Robert M.↗

Martian Atmospheric Pressure Static Charge Elimination Tool

A Martian pressure static charge elimination tool is currently in development in the Electrostatics and Surface Physics Laboratory (ESPL) at NASA's Kennedy Space Center. In standard Earth atmosphere conditions, static charge can be neutralized from an insulating surface using air ionizers. These air ionizers generate ions through corona breakdown. The Martian atmosphere is 7 Torr of mostly carbon dioxide, which makes it inherently difficult to use similar methods as those used for standard atmosphere static elimination tools. An initial prototype has been developed to show feasibility of static charge elimination at low pressure, using corona discharge. A needle point and thin wire loop are used as the corona generating electrodes. A photo of the test apparatus is shown below. Positive and negative high voltage pulses are sent to the needle point. This creates positive and negative ions that can be used for static charge neutralization. In a preliminary test, a floating metal plate was charged to approximately 600 volts under Martian atmospheric conditions. The static elimination tool was enabled and the voltage on the metal plate dropped rapidly to -100 volts. This test data is displayed below. Optimization is necessary to improve the electrostatic balance of the static elimination tool.

Johansen, Michael R.↗

Development of propulsion for high atmospheric pressure or dense environments

The development of a propulsion system that employs a detonating propellant is described, and the need for such a system and its use in certain planetary atmospheres are demonstrated. A theoretical formulation of the relevant gas-dynamic processes was developed, and a related series of experimental tests were pursued.

Varsi, G.↗

Mars atmosphere pressure periodicities from Viking observations

The first Martian year of pressure data taken by the Viking landers on Mars is subjected to power spectrum analysis. The analysis suggests that strong periodicities are present in the Martian atmosphere, especially at the high-latitude (48 deg N) site of the second lander. Most of these periodicities are probably due to the passage of baroclinic waves. Inspection of individual segments of data shows that the periodicities of the dominant waves vary significantly with time of year. This may be related to the amount of dust in the atmosphere since the dominant frequencies of the waves during times of major dust storms are quite different than at other times.

Sharman, R. D.↗

In-situ ETEM study of plasma-facing tungsten nanofuzz oxidation at atmospheric pressure: Microstructure evolution and substrate-free oxidation kinetics

To enable sustainable carbon-free fusion energy, managing reactor structural material degradation during normal operation as well as accident scenarios is vital. Tungsten (W) plasma-facing materials (PFMs) are susceptible to aggressive high-temperature oxidation during air-ingress fusion reactor accidents, yet there's a lack of oxidation kinetic data for irradiated tungsten. Here, in this study, we utilize atmospheric environmental transmission electron microscopy (ETEM) to present the first kinetic data for substrate-free W nanofuzz oxidation at 400 ºC and 500 ºC in 1 bar dry air. Comparison with pristine bulk W during the early parabolic stage suggests an irradiationdecelerated oxidation for W nanofuzz. Our time-resolved in-situ characterization reveals a durable amorphous surface oxide, likely promoted by high-flux He + irradiation-induced surface defects, serving as an effective passivating layer that impedes nanofuzz oxidation onset. This surface oxide layer also interfaces well with newly formed orthorhombic WO 3 , facilitated by stress relief through He bubble shrinkage, providing lasting passivating protection throughout the nanofuzz parabolic oxidation. This new finding challenges conventional notions of irradiation's negative impact on metal oxidation, and calls for advanced characterization to enhance our understanding of fusion energy materials degradation, informed by further accident modeling.

36 MATERIALS SCIENCE↗

Method of purifying metallurgical grade silicon employing reduced pressure atmospheric control

A method in which a quartz tube is charged with chunks of metallurgical grade silicon and/or a mixture of such chunks and high purity quartz sand, and impurities from a class including aluminum, boron, as well as certain transition metals including nickel, iron, and manganese is described. The tube is then evacuated and heated to a temperature within a range of 800 C to 1400 C. A stream of gas comprising a reactant, such as silicon tetrafluoride, is continuously delivered at low pressures through the charge for causing a metathetical reaction of impurities of the silicon and the reactant to occur for forming a volatile halide and leaving a residue of silicon of an improved purity. The reactant which included carbon monoxide gas and impurities such as iron and nickel react to form volatile carbonyls.

Ingle, W. M.↗

Atmospheric Pressure Corrections in Geodesy and Oceanography: a Strategy for Handling Air Tides

Global pressure data are often needed for processing or interpreting modern geodetic and oceanographic measurements. The most common source of these data is the analysis or reanalysis products of various meteorological centers. Tidal signals in these products can be problematic for several reasons, including potentially aliased sampling of the semidiurnal solar tide as well as the presence of various modeling or timing errors. Building on the work of Van den Dool and colleagues, we lay out a strategy for handling atmospheric tides in (re)analysis data. The procedure also offers a method to account for ocean loading corrections in satellite altimeter data that are consistent with standard ocean-tide corrections. The proposed strategy has immediate application to the on-going Jason-1 and GRACE satellite missions.

Ponte, Rui M.↗

Atmospheric-pressure ammonia synthesis on AuRu catalysts enabled by plasmon-controlled hydrogenation and nitrogen-species desorption

The Haber–Bosch process for ammonia synthesis contributes up to ~3% of global greenhouse gas emissions. Plasmonic catalysts strongly concentrate light and can alter the reaction intermediates via out-of-equilibrium processes, providing the potential for an alternative, less-energy-intensive pathway to synthesize ammonia. Here, in this study, we show that gold-ruthenium (AuRu) bimetallic nanoparticles can synthesize ammonia at room temperature and pressure using visible light. We create AuRu alloys with varying compositions and achieve ammonia production rates of ~60 μmol per gram of catalyst bed per hour. In situ infrared spectroscopy reveals that light accelerates the hydrogenation of nitrogen intermediates compared to conventional thermal catalysis. Through computational modelling, we demonstrate that photo-excited electrons enable associative hydrogenation pathways for nitrogen activation rather than direct nitrogen–nitrogen bond breaking. This light-assisted mechanism requires both hydrogen and light working together to overcome the nitrogen activation barrier, mimicking how biological enzymes produce ammonia naturally and providing fundamental insights for developing sustainable, energy-efficient chemical synthesis.

Yuan, Lin [Stanford Univ., CA (United States)] (OR↗