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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
NASA NTRS2012

An Overview of the NASA Ames Millimeter-Wave Thermal Launch System

The Millimeter-Wave Thermal Launch System (MTLS) is a beamed-energy propulsion concept being designed at NASA Ames Research Center. This effort is in response to the NASA Office of the Chief Technologist s announcement of the Ride the Light program. Our objective is to produce a design that goes beyond the feasibility analysis level of previous studies and provides a solid foundation for low cost access to space. The MTLS is designed to place a 500 lb payload into Low Earth Orbit (LEO) two times a day. This frequent launch, small payload niche is well suited for the particular advantages and constraints of beamed-energy propulsion, and has the potential to drastically increase access to space by reducing the cost per kilogram of placing payloads into LEO. This paper summarizes the findings of the MTLS study. The chemical rocket engine is in principle a simple device. It acts by releasing the chemical energy stored in propellants such as hydrogen and oxygen through combustion, then converting that thermal energy into kinetic energy by expansion through a nozzle. As such, it is fundamentally limited by the energy released in combustion reactions and the molecular weight of the products of those reactions. The highest performing conventional propellant combination, liquid oxygen and liquid hydrogen, can produce vacuum specific impulses of around 450 seconds. The design space of current launch vehicles (which tend to be large, multi-stage, and expendable) are defined by these limitations. An entirely new approach may be necessary in order to enable future launch vehicles of radically improved capabilities. Beamed-energy propulsion (BEP) is an alternative approach that bypasses the energy limitations of chemical propulsion. Instead of relying on a chemical reaction as the energy source, it is supplied externally via a beam of electromagnetic energy produced on the ground. In the concept examined in the MTLS, this energy is absorbed by a heat exchanger which then transfers the energy to the propellant. This decouples the energy source from the working fluid, vastly expanding the design space. For example, a launch vehicle could use only water as propellant, making it very safe and easy to handle. However, the most commonly proposed way to take advantage of this decoupling is to use pure hydrogen as the working fluid, which enables specific impulses of around 800 seconds1 if the heat exchanger material can operate at 2200 K. With such a significantly increased Isp, it may be possible to build single-stage to orbit vehicles, with enough mass margins left over to permit lower cost fabrication techniques.

Murakami, David↗
DOE OSTI2023

Boosting the performance of reversible solid oxide electrochemical cells with a novel hybrid oxygen electrode, Pr 1.39 Ba 0.14 Sr 0.53 Co 1.48 Fe 0.76 O 6- δ -Ba 0.66 Sr 0.34 CoO 3- δ

Solid oxide electrochemical cells (SOECs) stand out as a highly promising clean energy technology that offers several benefits, showing significant potential to play a pivotal role in the transition towards a sustainable and low-carbon energy future. SOECs can efficiently convert the chemical energy stored in fuels to electricity in fuel cell mode, and produce various chemicals from abundant feedstocks (e.g., CO 2 , H 2 O) and intermittent solar/wind-based renewable electricity. Despite extensive efforts that have been devoted to designing novel materials and optimizing SOEC manufacturing processes, aiming to achieve enhanced energy efficiency, the current SOECs still suffer from poor performance, which is mainly due to the sluggish oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) kinetics. To address this challenge, in this work, we have successfully designed an in situ formed hybrid oxygen electrode material (Pr 1.39 Ba 0.14 Sr 0.53 Co 1.48 Fe 0.76 O 6- δ -Ba 0.66 Sr 0.34 CoO 3- δ ), which significantly improves the surface oxygen exchange coefficient and bulk oxygen-ion diffusion coefficient, enhancing the OER and ORR electrocatalytic activities. Further, the SOECs equipped with this newly developed oxygen electrode achieved exceptional performance for power generation using both hydrogen and propane as the fuels. At 750 °C, a peak power density of 2.4 W cm -2 was obtained with H 2 as the fuel. Additionally, the SOECs attain unprecedented performance in steam electrolysis mode. A current density of 4.4 A cm -2 was achieved at 1.3 V and 750 °C, which represents the highest performance among all yttria-stabilized zirconia (YSZ) electrolyte-based SOECs. The SOECs also deliver remarkable stability during the accelerated stability testing, highlighting the great potential of Pr 1.39 Ba 0.14 Sr 0.53 Co 1.48 Fe 0.76 O 6- δ -Ba 0.66 Sr 0.34 CoO 3- δ as a high-performance oxygen electrode for next generation SOECs.

08 HYDROGEN↗
DOE OSTI2022

Ionomer Optimization for Hydroxide-Exchange-Membrane Water Electrolyzers Operated with Distilled Water: A Modeling Study

The hydroxide-exchange-membrane water electrolyzer (HEMWE) is a promising means to store intermittent renewable energy in the form of hydrogen chemical energy. The hydroxide-exchange ionomer (HEI) in the gas-evolving electrodes and the hydroxide-exchange membrane (HEM) are key components of HEMWE. In this work, we simulate the cell and examine explicitly the impact of HEI and HEM properties with a focus on improving HEMWE performance when operated with distilled water ( i.e ., no supporting electrolyte). The tradeoff between the ionic conductivity gain and electrochemically active surface area (ECSA) loss is studied. For a constant catalyst loading, distributing more catalyst next to the HEM or making thinner but denser catalyst layer is beneficial for HEMWE performance. The results demonstrate that a higher water diffusion coefficient is desired for HEM to supply reactant water to the cathode. In contrast, a lower water diffusion coefficient is preferred for the cathode HEI to retain the water in the regions with high reaction rates. Overall, the findings provide important insights to optimizing HEI/HEM materials for improved HEMWE performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2003

Records of our Early Biosphere Illuminate our Origins and Guide our Search for Life Beyond Earth

A scientific "mission of exploration to early Earth" will help us chart the distribution of life elsewhere. We must discriminate between attributes of biospheres that are universal versus those attributes that represent principally the outcomes of long-term survival specifically on Earth. In addition to the basic physics and chemistry of matter, the geologic evolution of rocky habitable planets and their climates might be similar elsewhere in the Universe. Certain key agents that drive long-term environmental change (e.g., stellar evolution, impacts, geothermal heat flow, tectonics, etc.) can help us to reconstruct ancient climates and to compare their evolution among populations of Earth- like planets. Early Earth was tectonically more active than today and therefore it exhaled reduced chemical species into the more oxidized surface environment at greater rates. This tectonic activity thus sustained oxidation-reduction reactions that provided the basis for the development of biochemical pathways that harvest chemical energy ("bioenergetics"). Most examples of bioenergetics today that extract energy by reacting oxidized and reduced chemicals in the environment were likely more pervasive among our microbial ancestors than are the presently known examples of photosynthesis. The geologic rock record indicates that, as early as 3.5 billion years ago (3.5 Ga), microbial biofilms were widespread within the coastal environments of small continents and tectonically unstable volcanic islands. Non oxygen-producing (non-oxygenic) photosynthesis preceded oxygenic photosynthesis, but all types of photosynthesis contributed substantially to the long-term increase in global primary biological productivity. Evidence of photosynthesis is tentative by 3.5 Ga and compelling by 2.7 Ga. Evidence of oxygenic photosynthesis is strong by 2.7 Ga and compelling by 2.3 Ga. These successive innovations transformed life from local communities that survived principally by catalyzing chemical equilibration to a globally dominant agent that created and sustained widespread chemical disequilibria in the environment and shallow crust. Major biogeochemical perturbations ca. 2.3 to 2.0 Ga, 1.3 Ga, and also 0.8 to 0.6 Ga, contributed to the irreversible oxidation of the global environment and perhaps also triggered evolutionary innovations (e.g., the development of multi-cellular biota) that became the foundations of our modern biosphere. Understanding the nature and timing of this ascent of life is crucial for discerning our o m beginnings. This understanding also empowers OUT search for the origins, evolution and distribution of life elsewhere in our solar system and beyond.

DesMarais, David J.↗
NASA NTRS1980

Application of a reversible chemical reaction system to solar thermal power plants

Three distributed dish solar thermal power systems using various applications of SO2/SO3 chemical energy storage and transport technology were comparatively assessed. Each system features various roles for the chemical system: (1) energy storage only, (2) energy transport, or (3) energy transport and storage. These three systems were also compared with the dish-Stirling, using electrical transport and battery storage, and the central receiver Rankine system, with thermal storage, to determine the relative merit of plants employing a thermochemical system. As an assessment criterion, the busbar energy costs were compared. Separate but comparable solar energy cost computer codes were used for distributed receiver and central receiver systems. Calculations were performed for capacity factors ranging from 0.4 to 0.8. The results indicate that SO2/SO3 technology has the potential to be more cost effective in transporting the collected energy than in storing the energy for the storage capacity range studied (2-15 hours)

Hanseth, E. J.↗
NASA NTRS2002

Fuel Cell Activities at the NASA Glenn Research Center

Fuel cells have a long history in space applications and may have potential application in aeronautics as well. A fuel cell is an electrochemical energy conversion device that directly transforms the chemical energy of a fuel and oxidant into electrical energy. Alkaline fuel cells have been the mainstay of the U.S. space program, providing power for the Apollo missions and the Space Shuttle. However, Proton Exchange Membrane (PEM) fuel cells offer potential benefits over alkaline systems and are currently under development for the next generation Reusable Launch Vehicle (RLV). Furthermore, primary and regenerative systems utilizing PEM technology are also being considered for future space applications such as surface power and planetary aircraft. In addition to these applications, the NASA Glenn Research Center is currently studying the feasibility of the use of both PEM and solid oxide fuel cells for low- or zero-emission electric aircraft propulsion. These types of systems have potential applications for high altitude environmental aircraft, general aviation and commercial aircraft, and high attitude airships. NASA Glenn has a unique set of capabilities and expertise essential to the successful development of advanced fuel cell power systems for space and aeronautics applications. NASA Glenn's role in past fuel cell development programs as well as current activities to meet these new challenges will be presented

Kohout, Lisa L.↗
NASA NTRSDate not supplied

Electrochemical Life Detection Methods for Ocean World Exploration

Ubiquitous across terrestrial life is cellular machinery that allows chemical energy flow by facilitating and regulating electron-transfer and chemical modification pathways. Key classes of energy transport molecules enable this movement of electrons for a variety of biological purposes. Additionally, biological enzymes function to add or remove functional groups such asphosphate moieties to redox biomolecules. Presumably, extraterrestrial life is likely to rely on similar energy transport mechanisms. With the search for life in our solar system focused on the icy satellites of Jupiter and Saturn, Europa and Enceladus, developing instrumentation capable of measuring electrochemical redox signatures representative of biomolecules or enzymatic activity in seawater appears a promising and novel means of life detection. Here, we report our adaptation of the Mars Phoenix Wet Chemistry Laboratory (WCL) electroanalytical voltammetry capabilities to assay life-critical redox molecules in synthetic seawater representative of a saline alkaline solution similar to what has been predicted from the Cassini mission data of Enceladus’ sub-surface ocean. In addition, we employ a well-established electrochemical assay that indicates phosphatase activity by comparing substrate and product redox signatures. Our study demonstrated a 10 nM limit of detection for biological redox molecules and a 3 aM limit of detection for alkaline phosphatase in seawater. Incorporation of these methods into next generation WCL payloads aimed at ocean world life detection will enable the search for biological redox-active species and enzymatic activity as indicators of life.

planetary instruments↗
DOE OSTI2022

Hydride-based thermal energy storage

Abstract The potential and research surrounding metal hydride (MH) based thermal energy storage is discussed, focusing on next generation thermo-chemical energy storage (TCES) for concentrated solar power. The site availability model to represent the reaction mechanisms of both the forward and backward MH reaction is presented, where this model is extrapolated to a small pilot scale reactor, detailing how a TCES could function/operate in a real-world setting using a conventional shell & tube reactor approach. Further, the important parameter of effective thermal conductivity is explored using an innovative multi-scale model, to providing extensive and relevant experimental data useful for reactor and system design. Promising high temperature MH material configurations may be tuned by either destabilisation, such as using additions to Ca and Sr based hydrides, or by stabilisation, such as fluorine addition to NaH, MgH 2 , or NaMgH 3 . This versatile thermodynamic tuning is discussed, including the challenges in accurately measuring the material characteristics at elevated temperatures (500 –700 °C). Attention to scale up is explored, including generic design and prototype considerations, and an example of a novel pilot-scale pillow-plate reactor currently in development; where materials used are discussed, overall tank design scope and system integration.

25 ENERGY STORAGE↗
DOE OSTI2020

Biological Electron Transfer and Catalysis EFRC

The focus of the Biological Electron Transfer and Catalysis (BETCy) EFRC research is elucidating mechanisms of conversion of electrochemical potential into chemical bond energy and is organized into two integrated Thrusts: Electron Bifurcation Catalysis and Electron Transfer Kinetics. We are developing a collective knowledge of metalloenzymes as models for redox reactions by applying physical science and computational tools to characterize biochemical reactions catalyzed by multi- subunit enzymes harboring arrays of iron-sulfur clusters and flavin cofactors. Understanding these mechanisms is central to overcoming the thermodynamic barriers that currently limit production of reduced products and fuels. Biological systems have elegant strategies for converting electrochemical potential energy into chemical bond energy (e.g., C-H, H-H, and N-H) stored in reduced compounds that can serve as advanced biofuels. One significant limitation for the production of highly reduced compounds is that their production in natural and industrial processes relies on low oxidation-reduction potential chemicals as feedstocks.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

The overlooked role of adsorption isotherms in electrocatalysis

Electrocatalysts enable the efficient interconversion of electrical and chemical energy for the sustainable production of fuels and chemicals. Here, in this Comment, we highlight the importance of developing electrochemical adsorption isotherms to demystify complex reaction mechanisms and rationalize catalytic activity.

electrocatalysis↗
DOE OSTI2024

Integrated protonic ceramic electrochemical cell for sustainable energy economy using water-energy nexus framework

Reliance on fossil fuels will continue for the next decades even though there are global pushes away from it to mitigate the overarching climate challenge, most especially by its highest consumers and availability. While there is a hastening global shift away from fossil fuel, integrating its assets into this technology helps limit the risk and future losses of stranded assets and reduce the cost of investment in the new technologies. Moreover, the generation of electricity from intermittent renewable sources like solar and wind has witnessed a significant surge in recent years, leading to a pressing demand for practical energy storage systems. Electrical energy storage is anticipated to play a pivotal role in the future global energy system, facilitating load-leveling operations to support the greater integration of renewable and distributed generation. Reversible electrochemical cells (RECs) offer a promising option for addressing the fossil fuel assets integration and energy storage challenges through the interconversion between electrical and chemical energy and concurrent utilizing carbon emission. In their electrolysis mode, the RECs convert electricity into durable, storable, and portable valuable chemical fuels such as syngas and methane. Conversely, the produced chemical fuels can be used as reactants in the fuel cell mode to generate electricity on demand with minimal (hydrocarbons) or zero when H2 or NH3 is used emissions. However, a challenging goal for this type of technology remains to achieve optimal operation and high roundtrip efficiencies, which has hindered the deployment of previous electrochemical cells. This dissertation demonstrates how reversible protonic ceramic electrochemical cells (RePCECs) can be integrated with fossil fuel power plants and renewable energy sources as a potential energy storage system. In this work, integrated RePCEC systems are designed and examined using computational modeling at scales to determine appropriate system configurations and operating conditions that achieve high roundtrip efficiencies. Cell level design of the PCEC is the first approach, several cells are assembled for the stack level model that is integrated into combined cycle powerplant and solar photovoltaic for the system level model. After critical literature review, this answered the operational and integration research questions proposed to address these challenges. The designed systems perform two functions, utilizing captured CO2 and storing renewable energy through co-electrolysis of steam and CO2. The co-electrolysis reaction involves endothermic water electrolysis and exothermic methanation reaction. To enhance high roundtrip efficiency, there is a need for thermal balance and management in the electrolysis mode. This involves operating the RePCEC stack under conditions that favor methane production to balance out heat needed by water electrolysis, it crucial for the RePCEC system operation. Methanation is enhanced by low temperatures. Leveraging on fabricated BCZYYb-electrolyte RePCEC, the cell model designed revealed that the optimum temperature for methane production is 450℃ at atmospheric pressure. Thus, to achieve optimum system performance, operating in the temperature range 450-525℃ is recommended at the given configuration, combining between the optimum temperature for methane production and temperature for the optimum stack roundtrip efficiency. Configuration with carbon capture system and purge stream is the optimum configuration from the seven conceptualized and evaluated. The modeling outcomes include a thermodynamic examination of integrated RePCEC systems, calibration of cell and stack level models, and steady-state simulation and integration into a 600MW combined cycle power plant retrofitted with two two-stage membrane-based carbon capture system and a wastewater treatment and recovery unit. At 100% powerplant loading, the stack and system roundtrip efficiencies are 72% and 51.37% respectively. Adding a purge stream for produced hydrogen at the system downstream improves the efficiencies to 74 and 55.48% respectively. At atmospheric pressure and 525℃, the system model suggests that a stack roundtrip of 82% is achievable, and overall system efficiency increases by reducing the energy consumption by the balance of plant components for steam generation and storage. Economic analysis of the process gives levelized cost of methane as $2.24/MMBtu lower than the conventional production route that range between $3.46/MMBtu and $9.85/MMBtu. The lifecycle analysis shows that the global warming potential for the production of methane and hydrogen from the RePCEC system is 3.83 kg CO2 eq which is lower than 9.35 kg CO2 eq emission during steam methane reforming for hydrogen production. This answered both the environmental and economic concerns in the raised research question. The proposed RePCEC configuration and analysis carried out in this dissertation to address the surge in renewable energy and challenges with PCEC technology hold significant potential in achieving large-scale energy storage while simultaneously reducing carbon emissions. These advancements, coupled with suitable governmental policies and incentive programs, have the potential to economically disrupt the natural gas industries by using RePCEC systems for methane production, thereby making them more favorable for eventual implementation and commercialization.

25 ENERGY STORAGE↗
NASA NTRS1985

An Innovation for the Energy Industry

REDOX is an economical energy storage system which promises major reductions in the cost of storing electrical energy. The system is based upon the conversion of chemical energy into electrical energy. 75 percent of the energy used to charge the system is returned. It is flexible and the energy may be stored for long periods. It was developed by Lewis Research Center, who transferred the technology to SOHIO for further development and possible commercialization. Redox could eliminate the use of high quality generator levels and would be particularly valuable to utilities which generate power from coal or nuclear energy.

Source record↗
NASA NTRS2019

Life's Requirements

Life on Earth is molecular in nature, with its lifelike attributes- e.g., information processing and catalysis- emerging as a result of both the specific properties of those molecules and the interactions among them. If this is a general model for life, then life must require (i) a source of energy, with which to build and sustain molecular complexity and information processing; (ii) elemental raw materials, from which to construct molecules having specific properties and reactivity; (iii)a solvent that supports the synthesis of the full range of molecules required by life and properly mediates the full range of necessary interactions among those molecules; and (iv) physicochemical conditions in which life's molecules can be synthesized, are appropriately stable, and can interact as needed for lifelike function. For life on Earth, these general requirements, respectively, take the specific form: (i) light energy in visible-to-near-infrared wavelengths or chemical energy as provided by oxidation–reduction disequilibrium, (ii) the "biogenic "elements (carbon, hydrogen, oxygen, nitrogen, phosphorus, and sulfur) (iii)liquid water, and (iv) specific ranges in temperature, pH, salinity, pressure, and other environmental factors. Our knowledge of these factors relates to cellula rlife as we observe it now or can infer from the fossil or molecular records. Life's origin may be constrained by a more stringent set of requirements that are, as yet,not fully understood.

Habitability↗
DOE OSTI2020

Multiscale modeling and cinematic visualization of photosynthetic energy conversion processes from electronic to cell scales

We report conversion of sunlight into chemical energy, namely photosynthesis, is the primary energy source of life on Earth. A visualization depicting this process, based on multiscale computational models from electronic to cell scales, is presented in the form of an excerpt from the fulldome show Birth of Planet Earth. This accessible visual narrative shows a lay audience, including children, how the energy of sunlight is captured, converted, and stored through a chain of proteins to power living cells. The visualization is the result of a multi-year collaboration among biophysicists, visualization scientists, and artists, which, in turn, is based on a decade-long experimental-computational collaboration on structural and functional modeling that produced an atomic detail description of a bacterial bioenergetic organelle, the chromatophore. Software advancements necessitated by this project have led to significant performance and feature advances, including hardware-accelerated cinematic ray tracing and instanced visualizations for efficient cell-scale modeling. The energy conversion steps depicted feature an integration of function from electronic to cell levels, spanning nearly 12 orders of magnitude in time scales. This atomic detail description uniquely enables a modern retelling of one of humanity’s earliest stories—the interplay between light and life.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2023

Experimental demonstration of high-temperature (>1000 °C) heat extraction from a moving-bed oxidation reactor for thermochemical energy storage

Previously developed reduction-oxidation (redox) thermochemical energy storage technologies must store their products at high temperatures, complicating handling and transportation. This work describes a countercurrent, tubular, moving bed oxidation reactor at laboratory scale that produces high grade heat and allows solids to enter and exit the system at ambient temperatures. The particles implemented in the system consist of a novel magnesium manganese-oxide material well-suited for thermochemical energy storage. Output heat is obtained via a separate extraction gas flow, which exits from the middle portion of the main reactor tube. With this design, reactor temperatures in excess of 1000°C and extraction temperatures above 950°C were achieved. Deviation between the two measurements is a result of extraction thermocouple placement and losses in the reactor extraction arm; improvements to these parameters would bring the extraction temperature closer to the bed temperature. The reactor produces enough energy via oxidation to sustain both heat extraction and continued chemical reaction. During one representative steady state experiment at a particle flow rate of 1.5 g/s, an average of 447 W was extracted from the reactor out of an estimated 1083 W of released chemical energy for a duration of 70 minutes. Among the four experiments, the maximum bench-scale oxidation reactor energy efficiency of 36.2% and corresponding round-trip efficiency of 13.7% considering both redox reactors were demonstrated. Characteristics of an ideal system are considered and future improvements are proposed.

25 ENERGY STORAGE↗
DOE OSTI2024

Catalytic Conversion of Biogenic and Synthetic Polymers into Carbon-Negative and -Neutral Chemicals and Fuels

We investigated a technology that enables the distributed decomposition of biogenic (lignin, cellulose) and synthetic (plastic) polymers into renewable or low-carbon-emission chemicals and fuel intermediates that can substitute fossil hydrocarbons for energy, chemical, and fuel production. The specific goal of this project is to (1) selectively convert biogenic polymers such as lignin and synthetic polymers such as polyethylene into hydrocarbons via electrocatalytic and thermocatalytic processes, and (2) optimize (electro)catalyst composition and reaction conditions to mitigate deactivation and control product selectivity.

09 BIOMASS FUELS↗
DOE OSTI2023

Conference Support, 32nd Western Photosynthesis Conference 2023

This DOE-BES award provided conference support for the 32nd Western Photosynthesis Conference (WPC2023), held January 5–8, 2023 at the Bodega Bay Marine Laboratory in Bodega Bay, California. The Western Photosynthesis Conference is one of three regional photosynthesis meetings held annually in the United States and serves as a primary venue for early-career scientists—graduate students, postdoctoral researchers, and undergraduates—to present research and build professional networks alongside established investigators in the field. Photosynthesis research is central to the DOE Office of Science's Basic Energy Sciences mission, underpinning fundamental understanding of solar energy conversion, biofuels, and the biological transformation of light into chemical energy. DOE-BES funds were used, as proposed, to support registration and housing costs for 20 early-career participants (9 postdoctoral researchers, 9 graduate students, and 2 undergraduates) and to help defray travel costs for two junior invited speakers based outside California, for a total DOE-BES expenditure of $10,060. The meeting was executed as planned, with no significant deviations from the approved program, budget, or schedule. WPC2023 drew 76 registrants across six scientific topic areas, featured 8 of 9 invited/keynote speakers, and provided extensive opportunities for early-career scientists to present talks and posters, compete for recognition awards, and network with senior researchers in the field.

conference↗