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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 127 records · Page 7

A phase model approach for thermostatically controlled load demand response

A significant portion of electricity consumed worldwide is used to power thermostatically controlled loads (TCLs) such as air conditioners, refrigerators, and water heaters. Because the short-term timing of operation of such systems is inconsequential as long as their long-run average power consumption is maintained, they are increasingly used in demand response (DR) programs to balance supply and demand on the power grid. Here, we present an ab initio phase model for general TCLs, and use the concept to develop a continuous oscillator model of a TCL and compute its phase response to changes in temperature and applied power. This yields a simple control system model that can be used to evaluate control policies for modulating the power consumption of aggregated loads with parameter heterogeneity and stochastic drift. We demonstrate this concept by comparing simulations of ensembles of heterogeneous loads using the continuous state model and an established hybrid state model. The developed phase model approach is a novel means of evaluating DR provision using TCLs, and is instrumental in estimating the capacity of ancillary services or DR on different time scales. We further propose a novel phase response based open-loop control policy that effectively modulates the aggregate power of a heterogeneous TCL population while maintaining load diversity and minimizing power overshoots. This is demonstrated by low-error tracking of a regulation signal by filtering it into frequency bands and using TCL sub-ensembles with duty cycles in corresponding ranges. As a result, control policies that can maintain a uniform distribution of power consumption by aggregated heterogeneous loads will enable distribution system management (DSM) approaches that maintain stability as well as power quality, and further allow more integration of renewable energy sources.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Laboratory synthesis of C3S on the kilogram scale

An optimized process using amorphous silica for efficient C{sub 3}S synthesis in the laboratory is reported: an estimated production capacity of ~2 kg C{sub 3}S within a week is possible. Amorphous silica (fumed silica) was used as raw material and inter-ground with CaCO{sub 3} and water for C{sub 3}S synthesis, the dried raw mixture has sufficient green strength to be self-supporting, which allows large cylinders to be placed in Platinum crucibles. The mineral composition of the sintered sample was quantified with X-ray powder diffraction using Rietveld analysis. C{sub 3}S with 3 S synthesis was dramatically enhanced because of 1) increased burnability of the raw mix due to amorphous silica and very fine CaCO{sub 3} particles after grinding, 2) simplified sample preparation process avoiding pressing discs and 3) improved capacities of the crucible and furnace.

36 MATERIALS SCIENCE↗

Evaluation of chromatographic resins for high efficacy separation of radium from chemical analogues

The separation of Radium (Ra) from interfering chemical analogues is of major importance for both the accurate measurement of Ra-226 in environmental samples and the preparation of radium targets destined for medical isotope production. The adsorption behavior of Ra, Barium (Ba), and Strontium (Sr) was investigated on multiple crown-ether-based proprietary extraction chromatographic resins developed by TrisKem Int. Among these, the TK101 resin, characterized by a novel room-temperature ionic liquid (RTIL) dual extractant–solvent system, demonstrated enhanced affinity and selectivity, particularly at low acid concentrations, achieving a D w of 3477 ± 73 for Ra in 0.04 M HNO₃, whereas the maximum Ra D w obtained with the traditional Sr resin in 8 M HNO 3 was only 12.33 ± 0.4. In 0.04 M HNO 3 , a Ra distribution ratio (D w ) of 776 was achieved within 1 min, indicating rapid uptake kinetics. The adsorption capacities were estimated at 19.6 ± 0.1 mg/g for Ba and 12.0 ± 0.2 mg/g for Sr. However, competing alkali metals significantly reduced alkaline earth metal uptake, indicating that the TK101 resin is best suited for radium purification following a preconcentration step to minimize matrix effects in high salinity samples. Dynamic column studies confirmed the strong chromatographic performance of the TK101 resin, with no significant Ba or Sr breakthrough in the Ra fraction and a Ra recovery of 87 ± 2.8%. These results demonstrate the potential of the TK101 resin for selective radium separation in analytical and radiochemical applications.

and nuclear chemistry↗

Tradeoffs in forest resilience to satellite-based estimates of water and productivity losses

Climate change is expected to intensify the global hydrological cycle via increased evapotranspiration (ET). Changes in ET have important consequences for water-related ecosystem services as well as for forest productivity. Forests play a critical role in ET: active trees sequester carbon at the expense of losing water, yet if they are not active, water remains in the trees, but productivity stalls. Here, we estimated the capacity of forests to recover (resilience) from extreme water or productivity losses based on modeled ET through remote sensing methods across the conterminous USA. Results show there is a spatial tradeoff in resilience to water or productivity losses. Forests were more resilient to water loss in the drier west, and more resilient to productivity loss in the wetter east. Still, resilience was highly heterogeneous across the continent. Projections under climate change indicate both declines and increases of up to 13% in forest resilience, with broad regional trends but high spatial heterogeneity within regions. This study brings crucial satellite-based insights on how water dynamics, and consequentially productivity and water provision in forests, might be impacted by climate change.

54 ENVIRONMENTAL SCIENCES↗

Improved Sensitivity and Separations for Phosphopeptides using Online Liquid Chromotography Coupled with Structures for Lossless Ion Manipulations Ion Mobility–Mass Spectrometry

Phosphoproteomics greatly augments proteomics and holds tremendous potential for insights into the modulation of biological systems for various disease states, etc. However, numerous challenges hinder conventional methods in terms of measurement sensitivity, throughput, and capabilities for confident phosphopeptide and phosphosite identification. In this work, we report the first example of integrating structures for lossless ion manipulations ion mobility (SLIM) IM-MS with online reversed-phase liquid chromatography (LC) to evaluate its potential for addressing the aforementioned challenges. A mixture of 51 heavy-labeled phosphopeptides was analyzed with a SLIM IM module having integrated ion accumulation and long-path separation regions. The SLIM IM-MS provided improved sensitivity over an established LC-SRM method, with limits of detection as low as 50 pM (50 amol/µl) for several peptides. Conventionally problematic phosphopeptide isomers could be resolved following an 18 m SLIM IM separation. The 2-D peak capacity was estimated as ~9000 for 90 min LC separation coupled to an 18 m SLIM IM separation, considerably higher than LC alone and providing a basis for both improved identification and quantification, with additional gains projected with the future use of longer path SLIM IM separations. Thus, LC-SLIM IM-MS offers great potential for improving the sensitivity, separation, and throughput of phosphoproteomics analyses.

Chouinard, Christopher D.↗

Effectiveness of mineral soil to adsorb the natural occurring radioactive material (norm), uranium and thorium

A study has been performed on U-soil and Th-soil adsorption of three types of soil collected from Selangor State of Malaysia which are Saujana Putra, Bukit Changgang and Jenderam Hilir. In this study, natural radionuclide (U and Th) soil adsorption based on batch experiments with various initial concentrations of the radionuclide elements were carried out. Parameters that were set constant include pH at 5;amount of soil used was 5 g each, contact time was 24 hour and different initial concentration for each solution of U and Th which is 5 mg/L, 10 mg/L, 15 mg/L, 20 mg/L, 25 mg/L and 40 mg/L were used. The K{sub d} values for each type of soil were determined in this batch experiments which was based on US-EPA method, in order to estimate adsorption capacity of the soil.The K{sub d} values of Th found higher than Kd values of U for all of the soil samples, and the highest was found on the soil collected from Bukit Changgang. The soil clay content was one of factors to influence the adsorption of both U and Th from dilute initial solution. The U-soil and Th-soil adsorption process for all the soil samples studied are generally obeying unimolecular layer Langmuir isotherm model. From Langmuir isotherm, the maximum adsorption capacity for U was 0.393mg/g and for Th was 1.53 mg/g for the soil that was taken from Bukit Changgang. From the study, it suggested that the soil from Bukit Changgang applicable as potential enhanced barrier for site disposing waste containing U and Th.

54 ENVIRONMENTAL SCIENCES↗

Graphene oxide and adsorption of chloroform: A density functional study

Chlorinated hydrocarbon compounds are of environmental concerns, since they are toxic to humans and other mammals, and are widespread, and exposure is hard to avoid. Understanding and improving methods to reduce the amount of the substances are important. We present an atomic-scale calculational study of the adsorption of chlorine-based substance chloroform (CHCl{sub 3}) on graphene oxide, as a step in estimating the capacity of graphene oxide for filtering out such substances, e.g., from drinking water. The calculations are based on density functional theory, and the recently developed consistent-exchange functional for the van der Waals density-functional method is employed. We obtain values of the chloroform adsorption energy varying from roughly 0.2 to 0.4 eV per molecule. This is comparable to previously found results for chloroform adsorbed directly on clean graphene, using similar calculations. In a wet environment, like filters for drinking water, the graphene will not stay clean and will likely oxidize, and thus adsorption onto graphene oxide, rather than clean graphene, is a more relevant process to study.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Fast optimization algorithms and the cosmological constant

Denef and Douglas have observed that in certain landscape models the problem of finding small values of the cosmological constant is a large instance of a problem that is hard for the complexity class NP (Nondeterministic Polynomial-time). The number of elementary operations (quantum gates) needed to solve this problem by brute force search exceeds the estimated computational capacity of the observable Universe. Here in this paper, we describe a way out of this puzzling circumstance: despite being NP-hard, the problem of finding a small cosmological constant can be attacked by more sophisticated algorithms whose performance vastly exceeds brute force search. In fact, in some parameter regimes the average-case complexity is polynomial. We demonstrate this by explicitly finding a cosmological constant of order 10 -120 in a randomly generated 10 9 -dimensional Arkani-Hamed–Dimopoulos–Kachru landscape.

79 ASTRONOMY AND ASTROPHYSICS↗

GRAF-Plan for Vietnam

Evaluates the reserve requirements for power system balancing areas based on variability and uncertainty of load as well as wind and solar generation scenarios. The tool uses minute‐by‐minute site‐specific generation and load information, as well as information from generation and load forecasting algorithms used in the balancing areas. The Balancing‐Plan Tool can be used directly by utility planners and operators to aid in the integration of intermittent renewable resources. The tool provides reserve requirements of various kinds, such as day‐ahead, load following and regulation, as well as estimates the capacity of the generation fleet to provide the require reserves.

Campbell, Allison↗

Solar Photovoltaics and Land-Based Wind Technical Potential and Supply Curves for the Contiguous United States (2023 Edition)

Estimates of the potential of renewable energy are essential for understanding how we can decarbonize our electric grid and economy. They provide key data for policymakers, land managers, and energy modelers by defining the quantity, quality, and cost of renewable resources. However, estimating renewable energy potential is challenging and requires frequent updates because of rapid advances in technology, cost reductions, and uncertainty about developable land that are due to social, regulatory, and environmental factors. Additionally, the complex processes involved in renewable energy development require regular reviews of methods and assumptions, which can also impact our understanding of renewable potential. In this, the 2023 edition of this annual report, we present new estimates of the technical potential for land-based wind and solar photovoltaics (PV) for the contiguous United States (CONUS). We also provide cost estimates for the available resources, presenting representative supply curves that can be used in downstream modeling and analysis. Additionally, we introduce the new methodologies used to estimate wind capacity, wind energy losses, transmission cost and representation, updated technology cost and design, and scenarios of siting constraints designed to help bound the uncertainty of renewable potential.

14 SOLAR ENERGY↗

Experimental Warming Changes Phenology and Shortens Growing Season of the Dominant Invasive Plant Bromus tectorum (Cheatgrass)

Bromus tectorum (cheatgrass) has successfully invaded and established throughout the western United States. Bromus tectorum grows early in the season and this early growth allows B. tectorum to outcompete native species, which has led to dramatic shifts in ecosystem function and plant community composition after B. tectorum invades. If the phenology of native species is unable to track changing climate as effectively as B. tectorum’s phenology then climate change may facilitate further invasion. To better understand how B. tectorum phenology will respond to future climate, we tracked the timing of B. tectorum germination, flowering, and senescence over a decade in three in situ climate manipulation experiments with treatments that increased temperatures (2°C and 4°C above ambient), altered precipitation regimes, or applied a combination of each. Linear mixed-effects models were used to analyze treatment effects on the timing of germination, flowering, senescence, and on the length of the vegetative growing season (time from germination to flowering) in each experiment. Altered precipitation treatments were only applied in early years of the study and neither precipitation treatments nor the treatments’ legacies significantly affected B. tectorum phenology. The timing of germination did not significantly vary between any warming treatments and their respective ambient plots. However, plots that were warmed had advances in the timing of B. tectorum flowering and senescence, as well as shorter vegetative growing seasons. The phenological advances caused by warming increased with increasing degrees of experimental warming. The greatest differences between warmed and ambient plots were seen in the length of the vegetative growing season, which was shortened by approximately 12 and 7 days in the +4°C and +2°C warming levels, respectively. The effects of experimental warming were small compared to the effects of interannual climate variation, suggesting that interactive controls and the timing of multiple climatic factors are important in determining B. tectorum phenology. Taken together, these results help elucidate how B. tectorum phenology may respond to future climate, increasing our predictive capacity for estimating when to time B. tectorum control efforts and how to more effectively manage this exotic annual grass.

54 ENVIRONMENTAL SCIENCES↗

Parameterizing the Variability and Uncertainty of Wind and Solar in CEMs

We present current and improved methods for estimating the capacity value and curtailment impacts from variable generation (VG) in capacity expansion models (CEMs). The ideal calculation of these variability metrics is through an explicit co-optimized investment-dispatch model using multiple years of VG and load data. Because of data and computational limitations, existing CEMs typically approximate these metrics using a subset of all hours from a single year and/or using statistical methods, which often do not capture the tail-event impacts or the broader set of interactions between VG, storage, and conventional generators. In our proposed new methods, we use hourly generation and load values across all hours of the year to characterize the (1) contribution of VG to system capacity during high load hours, (2) the curtailment level of VG, and (3) the reduction in VG curtailment due to storage and shutdown of select thermal generators. Using CEM model outputs from a preceding model solve period, we apply these methods to exogenously calculate capacity value and curtailment metrics for the subsequent model solve period. Preliminary results suggest that these hourly methods offer improved capacity value and curtailment representations of VG in the CEM from existing approximation methods without additional computational burdens.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Update on Geothermal Direct-Use Installations in the United States

Direct-use of geothermal energy currently has limited penetration in the United States, with an estimated installed capacity of about 500 MWth, supplying on the order of 0.01% of the total annual U.S. heat demand (about 30 EJ). We see higher penetration levels in other countries such as Iceland (about 90%) and Hungary (2.5%). An updated database of geothermal direct-use systems in the U.S. has been compiled and analyzed, building upon the Oregon Institute of Technology (OIT) Geo-Heat Center direct-use database. Types of directuse applications examined include hot springs resorts and pools, aquaculture farms, greenhouses, and district heating systems, among others; power-generating facilities and ground-source heat pumps were excluded. Where possible, the current operation status, open and close dates, well data, and other technical data were obtained for each entry. The database contains 545 installations, of which 407 are open, 108 are closed, and 30 have an unknown status. Spas are the most common type of installation, accounting for 50% of installations by number. Aquaculture installations (46 out of 407 open installations) account for the largest percentage (26%) of installed capacity in operation (129 MWth out of 501 MWth). Historical deployment curves show the installed capacity significantly increased in the 1970s and 1980s mainly due to development of geothermal district heating, aquaculture, and greenhouse systems. Since the 2000s, geothermal direct-use development appears to have slowed, and the number of sites in operation decreased due to closures. Case studies reveal multiple barriers to geothermal direct-use implementation and operation, including 1) existence of an information gap among stakeholders, developers, and the general public, 2) competition from cheap natural gas, and 3) the family-owned, small-scale nature of businesses might result in discontinuation among generations.

15 GEOTHERMAL ENERGY↗

Performance, Cost, and Financial Parameters of Geothermal District Heating Systems for Market Penetration Modeling under Various Scenarios

Geothermal district heating (GDH) systems have limited penetration in the U.S., with an estimated installed capacity of only 100 MWth for a total of 21 sites. We see higher deployment in other regions, for example, in Europe with an installed capacity of more than 4,700 MWth for 257 GDH sites. The U.S. Department of Energy Geothermal Vision (GeoVision) Study is currently looking at the potential to increase the deployment in the U.S. and to understand the impact of this increased deployment. This paper reviews 31 performance, cost, and financial parameters as input for numerical simulations describing GDH system deployment in support of the GeoVision effort. The focus is on GDH systems using hydrothermal and Enhanced Geothermal System resources in the U.S.; ground-source heat pumps and heat-to-electricity conversion technology were excluded. Parameters investigated include 1) capital and operation and maintenance costs for both subsurface and surface equipment; 2) performance factors such as resource recovery factors, well flow rates, and system efficiencies; and 3) financial parameters such as inflation, interest, and tax rates. Current values as well as potential future improved values under various scenarios are presented. Sources of data considered include academic and popular literature, software tools such as GETEM and GEOPHIRES, industry interviews, and analysis conducted by other task forces for the GeoVision Study, e.g., on the drilling costs and reservoir performance.

15 GEOTHERMAL ENERGY↗

Discovering Geothermal Systems in the Great Basin Region: An Integrated Geologic, Geochemical, and Geophysical Approach for Establishing Geothermal Play Fairways

The Great Basin currently hosts ~24 geothermal power plants with more than 600 MW of capacity, but estimates suggest that the region is capable of producing much greater amounts of geothermal energy. Recent studies indicate that a combination of geological, geochemical, and geophysical features characterize the most robust geothermal systems. Considering that most of the geothermal resources in this region are blind, it is imperative that the favorable characteristics for geothermal activity be synthesized and techniques perfected for the discovery of new viable systems. We therefore utilized a multi-disciplinary approach and synthesized 9 geologic, geochemical, and geophysical parameters to produce a new detailed geothermal play fairway map of a large transect across the Great Basin region (96,000 km2) from west-central to eastern Nevada, with the primary objective of facilitating discovery of commercial-grade, blind geothermal fields (i.e. systems with no surface hot springs or fumaroles). Our analysis included: 1) structural settings (i.e., patterns of faulting), 2) age of recent faulting, 3) slip rates on recent faults, 4) regional-scale strain rates, 5) the tendency of faults to slip or dilate based on their orientation in the regional stress field, 6) earthquake density, 7) gravity data, 8) temperature at 3 km depth, and 9) geochemistry from springs and wells. These parameters were grouped into subsets to delineate rankings for local permeability, regional permeability, and heat, which collectively defined the geothermal play fairways (i.e., most likely locations for significant geothermal fluid flow). A major challenge was developing appropriate weightings of individual data types to best predict permeability and overall geothermal potential. Rigorous statistical methods, utilizing 34 benchmarks of known relatively high-temperature (>130°C) geothermal systems in the region, were employed to determine the hierarchal weights of each parameter. The new geothermal potential maps will help to reduce the risks in prospecting for new geothermal systems throughout the region.

15 GEOTHERMAL ENERGY↗

Equitable Access to Community Solar: Program Design and Subscription Considerations

Over 2.7 GWac community solar has been installed in the U.S. as of 2020, and 44% (1.2 GWac ) were installed after 2018, which indicates a fast-growing segment of the solar market .Community solar refers to a system that allows customers to subscribe part of a solar PV system and receive credit on their electricity bills based on power production. Although the growth of community solar market makes accessing solar energy easier, low and moderate income (LMI) potential subscribers may still face challenges, such as no or low credit scores.To investigate the program designs and subscription considerations for LMI customers, we provide a summary of existing state-level low-income community solar policies, as well as estimated LMI capacity and subscribers in the U.S.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Hierarchical Resilience Planning for Networked Microgrids: A Case Study of Puerto Rico

Microgrids can be designed to enhance the energy resilience of communities and critical infrastructures, such as hospitals, data centers, and communication networks, which are vulnerable to frequent weather-related disruption. Coordinating multiple microgrids in a network can leverage the geographical diversity of load and generation resources while enabling resilient and cost-effective planning of the distribution system. Designing a networked microgrid is complex, involving intricate technical assessment, cost-benefit analysis, site-specific requirements, and the evaluation of existing resources. Therefore, this paper proposes a hierarchical resilience planning framework and performs an extensive techno-economic analysis for the design of a networked microgrid. Hierarchical resilience planning involves technology sizing at an individual community level to meet the critical load and satisfy resilience criteria, and resource optimization at networked microgrid level to provide a higher level of resilience and energy adequacy. A real-world case of Puerto Rico's cooperative microgrid “Microrred de la Montaña” is investigated considering localized electricity tariffs, site-specific demand profiles, solar generation, and existing hydro resources. Multiple optimization scenarios are developed based on the resiliency requirement to estimate the capacity of solar photovoltaic and battery energy storage (BES) to be installed at each substation. The results provide the optimal sizing for individual community and networked microgrid to withstand 1day and 3-day outages along with the criteria for critical load.

13 - HYDRO ENERGY↗

Southern Sector Humate Injection Well Performance Testing

Three short duration injection tests were conducted on wells at the humate test site. For each injection event, potable water was gravity drained into the well casing. Pressure response was monitored in the injection well and these data were used to estimate the injection capacity of each well. Injection capacity was calculated by dividing the average injection flow rate by the head increase observed in the injection well. Nearby injection wells were used as observation wells and data from these wells were used to estimate the local hydraulic conductivity. The results of this analysis show that it is hydraulically feasible to gravity inject water into the test wells. The estimated water injection capacity of each well as determined by injecting potable water is shown. It is important to note that these short duration tests utilized water and not the humate solution that will ultimately be injected into the aquifer. The results of these tests do not account for physical or chemical processes that may occur over longer time scales. Injection well performance typically declines over time due to water-chemistry issues, air entrainment, and aquifer clogging. Therefore, these results should be viewed as optimistic estimates of injection capacity. Data from the injection tests were analyzed to estimate local aquifer properties. Transmissivity values for all tests ranged from 0.62 to 1.07 ft 2 /min with an average value of 0.805 ft 2 /min. Hydraulic conductivity was calculated by dividing transmissivity by the aquifer thickness (53 ft). Hydraulic conductivity ranged from 16.7 to 29.2 ft/day with an average value of 21.9 ft/day. Storativity values ranged from 0.0001 to 0.001 with an average value of 0.0006.

54 ENVIRONMENTAL SCIENCES↗